85 1001 ;header lines file format index ATLAS, ELLIOT University of Miami MIXING RATIOS FROM WHOLE AIR SAMPLER CR-AVE 1 1 ;vol total vol 2006 02 09 2007 06 05 ;DATE RDATE 0 ;DX(1) Elapsed UT seconds from 0 hours on T/O DATE ;UTMID 46 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 1 ;scale factors 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 99999 UTSTART (sec) ;MMS data UTSTOP (sec) ;MMS data CCl3F (pptv) CFC 11 CCl2F2 (pptv) CFC 12 C2ClF5 (pptv) CFC 115 C2Cl2F4 (pptv) CFC 114 C2Cl3F3 (pptv) CFC 113 CHClF2 (pptv) HCFC 22 CH3CCl2F (pptv) HCFC 141b CH3CClF2 (pptv) HCFC 142b CHCl2F (pptv) HCFC 21 C2HCl2F3 (pptv) HCFC 123 C2HClF4 (pptv) HCFC 124 C2H2F4 (pptv) HFC 134a C2H4F2 (pptv) HFC 152a CBrF3 (pptv) Halon 1301 CBrClF2 (pptv) Halon 1211 C2Br2F4 (pptv) Halon 2402 OCS (pptv) Carbonyl sulfide CH3Cl (pptv) Methyl chloride C2H5Cl (pptv) Ethyl chloride CH3Br (pptv) Methyl bromide CH3I (pptv) Methyl iodide CHCl3 (pptv) Chloroform CH2Cl2(pptv) Methylene chloride C2H4Cl2 (pptv) 1,2Dichloroethane CH3CCl3 (pptv) Methyl chloroform CCl4 (pptv) Carbon tetrachloride C2Cl4 (pptv) Perchlorethylene CH3ONO2 (pptv) Methyl nitrate C2H5ONO2 (pptv) Ethyl nitrate C3H7ONO2 (pptv) Isopropyl nitrate C3H7ONO2 (pptv) n-propyl nitrate C4H9ONO2 (pptv) 2-butyl nitrate CH2Br2 (pptv) Methylene bromide CHBr2Cl (pptv) Dibromochloromethane CHBr3 (pptv) Bromoform C2H6 (pptv) Ethane C2H2 (pptv) Ethyne C3H8 (pptv) Propane C4H10 (pptv) i-Butane C4H10 (pptv) n-Butane C6H6 (pptv) Benzene CH4 (ppbv) Methane N2O (ppbv) Nitrous Oxide CO (ppbv) Carbon monoxide 0 ;number of special comment lines (specific to this flight) 22 ;number of normal comment lines (occur each flight) UTSTART IS THE TIME THE CANISTER BEGAN FILLING UTMID IS THE AVERAGE OF THE START AND STOP TIMES UTSTOP IS THE TIME THE CANISTER FINISHED FILLING 0.0 - Concentration Below Detection Limit Negative mixing ratios for benzene are reported in cases when a small, constant blank value is subtracted from all the sample values. In previous missions, CO measurements from WAS appeared high in the lower stratosphere (O3>125 ppb) by 10-25 ppb due to canister artifacts. CRAVE data appear less affected by this artifact and are reported with no correction. Some trace gas data were deleted from the archive due to contamination associated with new canisters first used during the mission, and outliers associated with these canisters have been removed from the data set. Mixing ratios of CFCs 114 and 115 are undergoing recalibration, but data reported here is on the same scale as all prior NASA missions. Expected corrections will be approximately 1.25 for CFC115 and 1.15 for CFC114. Additional bromocarbon species were measured for a subset of the samples during CRAVE and are available on request from the PI. For questions, contact Elliot Atlas, RSMAS, University of Miami, Ph: 305-421-4128, e-mail: eatlas@rsmas.miami.edu UTMID UTSTART UTSTOP CFC_11 CFC_12 CFC_115 CFC_114 CFC_113 HCFC_22 HCFC_141b HCFC_142b HCFC_21 HCFC_123 HCFC_124 HFC_134a HFC_152a Halon_1301 Halon_1211 Halon_2402 OCS CH3Cl EtCl CH3Br CH3I CHCl3 CH2Cl2 1_2_dichloroethane CH3CCl3 CCl4 C2Cl4 MeONO2 EthONO2 i_PropONO2 n_PropONO2 2_ButylONO2 CH2Br2 CHClBr2 CHBr3 Ethane Ethyne Propane Isobutane n_Butane Benzene CH4_ppbv N2O_ppbv CO_ppbv 65310 65294 65326 255 537 7.26 14.5 78.5 168 17.6 16.1 0.22 0.16 0.88 99999 3.5 3.02 4.09 0.47 524 545 0.22 7.82 0 7.54 12.1 1.64 15 93 0.98 4.64 0.49 0.11 0 0 0.75 0.07 0.2 287 32 12 2.3 7.6 1.1 1735 319.2 56 65649 65634 65664 253 538 7.03 14.2 79.1 169 17.6 16.3 0.18 0.15 0.82 34.6 3.2 2.38 4.15 0.43 466 547 0.22 7.82 0 6 11.8 1.84 14.4 93 0.56 4.38 0.49 0.11 0 0 0.78 0.07 0.22 292 33 12 1.1 4 0.3 1734 319.3 55 65988 65973 66002 254 536 7.19 14.4 78.9 168 17.5 16 0.17 0.08 0.91 34.4 3.4 2.8 4.04 0.45 510 553 0.25 7.82 0 6.12 11.9 1.77 14.8 94 0.58 3.89 0.55 0.11 0 0 0.81 0.07 0.23 290 33 13 0.8 1.9 1.3 1737 319 58 66326 66310 66341 251 535 6.92 14.2 78.5 167 17.5 16.3 0.2 0.12 0.89 33.9 2.9 2.41 4.05 0.44 477 542 0.24 7.7 0.09 5.7 11.7 1.72 14.4 93 0.56 3.7 0.48 0 0 0 0.72 0.06 0.2 299 36 10 2.6 12.9 0.5 1737 318.9 51 66665 66649 66680 249 533 6.8 14.2 80.4 168 16.7 15.8 0.18 0.13 0.85 33.6 3 2.15 4.04 0.43 99999 549 99999 99999 0.09 99999 11.2 99999 99999 99999 99999 99999 99999 0 0 0 99999 99999 99999 285 29 12 1.9 6.4 0.3 1741 319.4 59 66704 66689 66719 250 534 7.03 14.4 78.7 169 17.3 15.9 0.19 0.14 0.82 34.9 3.4 2.54 3.99 0.45 463 547 0.22 7.75 0 5.65 11.4 1.52 14.5 93 0.53 3.37 0.38 0 0 0 0.67 0.07 0.15 284 33 11 1.1 1.5 -0.1 1739 318.8 53 67042 67027 67057 249 532 7 14.3 78.3 168 17.4 16.1 0.19 0.18 0.87 33.3 3.2 2.52 4.03 0.41 489 547 0.27 7.78 0 6.05 11.7 1.94 14.8 94 0.54 3.37 0.41 0.15 0 0 0.82 0.08 0.25 286 29 12 1.8 6.2 1.4 1737 318.4 48 67381 67365 67396 249 529 6.46 14.1 78.5 166 17.5 16.1 0.19 0.17 0.72 34.4 3.7 1.96 4.01 0.46 495 547 0.71 7.77 0.06 5.75 11.4 1.74 14.4 93 0.5 2.8 0.3 0.11 0 0 0.7 0.04 0.17 291 33 11 1 1.5 0.3 1737 318.2 53 67720 67704 67736 248 529 6.9 14.1 78.3 166 17.4 16 0.17 0.14 0.71 33.6 3.3 2.58 3.94 0.4 472 540 0.23 8.16 0 5.82 11.2 1.71 14.8 94 0.5 2.6 0.39 0.18 0 0 0.75 0.06 0.15 292 31 14 1.5 3 1.7 1737 318.3 51 68014 67998 68030 251 530 6.69 14.2 78.3 165 17.4 16 0.23 0.15 0.76 35.1 3.1 2.47 4 0.41 479 548 0.3 7.69 0 5.66 11.1 1.58 14.4 92 0.49 2.58 0.39 0 0 0 0.64 0.04 0.14 285 33 12 1.1 3.6 0.5 1739 318.1 49 68228 68213 68243 251 536 7.45 14.2 78.8 172 17.8 16.8 0.2 0.14 0.79 35 3.1 2.49 4.12 0.42 482 547 0.28 7.87 0 6.75 13.1 2.55 14.8 94 0.85 5.66 0.85 0.22 0 0 0.89 0.1 0.41 328 38 16 1.2 3.9 2.8 1741 319.3 59 68438 68425 68451 253 537 7.04 14.4 79.5 172 17.9 16.2 0.18 0.13 0.97 37.4 3.5 2.52 4.13 0.46 501 585 99999 99999 0.25 8.39 16.1 3.67 15.6 95 1.11 2.99 0.76 0.51 0 0 0.87 0.09 0.52 447 68 39 3.4 6.8 5.7 1765 319.8 97 68645 68634 68656 252 536 6.83 14.4 78.9 170 17.9 16.8 0.19 0.17 0.9 37.1 4.1 2.56 4.16 0.46 441 575 0.32 8.15 0.14 8.8 15 3.16 15.6 95 1.21 2.3 0.79 0.71 0 0 0.87 0.09 0.53 496 84 42 2.4 5.6 8.1 1778 319.7 110 68850 68839 68861 253 538 6.96 14.6 79.6 173 18.3 17.3 0.22 0.18 0.96 39.1 4.8 2.51 4.13 0.46 448 593 0.39 8.34 0.36 9.85 17.8 3.86 16.3 96 1.68 3.34 1.34 2.47 0.63 1.53 1.02 0.11 0.68 904 219 215 32.1 58 40.5 1799 320 137 69055 69043 69067 252 536 7.01 14.5 80.2 99999 18.5 17 0.21 0.2 0.89 99999 4.4 2.53 4.21 0.46 444 584 0.73 8.26 0.35 9.43 17.2 3.67 16.4 93 1.59 2.99 1.13 1.71 0.58 1.08 0.95 0.1 0.63 751 161 147 20.9 38.3 35.4 1797 321.4 127 69088 69077 69098 253 537 7.31 14.4 80.3 174 18.5 17.1 0.22 0.14 0.89 38 4.8 3.08 4.11 0.46 463 591 0.47 8.36 0.43 10.04 17.7 3.92 16.6 98 1.72 3.34 1.38 2.54 0.8 1.98 1.04 0.12 0.69 886 217 212 30.1 54.7 40.9 1794 319.4 130 69292 69281 69302 253 538 7 14.4 80.4 172 18.3 16.7 0.22 0.17 0.82 37.3 4.2 3 4.21 0.5 451 575 0.45 8.32 0.3 10.43 17.2 3.87 16.9 99 1.63 3.24 1.08 1.55 0.45 1.2 1.03 0.1 0.73 682 139 110 14.3 25.7 23.8 1788 319.6 114 69496 69485 69507 255 537 7.02 14.5 80.7 174 18.4 16.4 0.25 0.18 0.86 36.8 4.6 2.69 4.12 0.45 450 583 0.35 8.38 0.28 9.63 17.2 3.87 16.5 97 1.63 3.06 1.07 1.92 0.45 1.04 0.96 0.13 0.68 739 161 137 18.8 34 26.9 1792 320.1 117 69702 69690 69713 254 541 6.75 14.6 80.1 175 18.3 16.8 0.22 0.17 0.89 38.1 4 2.46 4.07 0.47 406 580 0.37 8.23 0.17 9.14 15.9 3.4 16.3 96 1.42 2.57 0.79 0.84 0.29 0.33 0.94 0.11 0.57 543 95 44 3.8 8.7 12.2 1788 319.5 108 69907 69895 69919 253 532 6.94 14.4 79.6 172 18 16.2 0.21 0.18 0.73 37 4.2 2.4 4.13 0.44 430 570 0.41 8.25 99999 9.19 15.9 3.6 16.1 95 1.42 2.49 0.83 0.83 0.3 0 0.9 0.11 0.62 532 84 41 3.5 6.3 12.1 1789 320.7 108 70114 70102 70125 253 535 6.61 14.6 78.9 172 18.1 16.9 0.21 0.17 0.74 37.4 4.3 2.22 4.14 0.44 426 571 0.3 8.19 0.19 9.25 16.3 3.52 16 95 1.5 2.28 0.89 0.83 0.21 0.37 0.93 0.1 0.6 541 86 44 2.8 5.5 12.3 1791 319.3 110 70320 70308 70331 253 536 6.72 14.5 79.4 173 18.3 16.9 0.21 0.21 0.83 37.5 4.3 2.43 4.11 0.42 425 573 0.32 8.39 99999 9.86 16.7 3.58 16.1 96 1.52 2.16 0.73 0.92 0.34 0.45 0.97 0.1 0.7 552 89 46 3.3 5.5 12.9 1792 319.7 122 70526 70514 70538 254 535 6.78 14.5 78.7 173 18.1 17 0.23 0.13 0.86 37.1 4.2 2.6 4.26 0.4 385 566 0.31 8.14 0.22 9.18 15.7 3.49 15.9 96 1.44 2.07 0.77 0.85 0.29 0.38 0.88 0.1 0.59 531 85 40 2.6 6 11.9 1792 319.9 105 70734 70722 70746 256 545 7.31 14.5 81.1 175 18.4 17.2 0.22 0.13 0.88 39 4.5 2.99 4.28 0.44 440 590 0.33 8.35 99999 9.53 16.9 3.53 16.3 96 1.56 2.09 0.8 0.82 0.25 0.25 0.93 0.13 0.57 548 87 42 2.9 5 12 1794 319.9 120 70941 70929 70953 254 545 6.59 14.5 80.3 177 18.3 17.4 0.22 0.19 0.87 37.9 4.6 2.42 4.31 0.49 99999 581 0.27 7.98 0.24 9.28 16.7 3.53 16.1 96 1.41 2.14 0.73 0.68 0.12 0 0.87 0.1 0.44 556 91 43 2.9 5.7 12.9 1791 320.2 114 70974 70962 70986 258 550 7.19 14.9 80.9 178 18.3 17.5 0.2 0.19 0.92 39.1 4.7 3.07 4.32 0.43 402 591 0.29 8.39 99999 9.71 16.9 3.7 16.4 97 1.51 2.25 0.77 0.9 0.31 0.37 0.93 0.1 0.61 559 99 49 4.5 8.6 12.6 1790 319.8 120 71183 71169 71197 256 548 7.19 14.5 80.5 174 18.2 17 0.2 0.18 0.84 37 3.6 3.07 4.24 0.43 475 577 0.27 8.12 0.09 7.73 14.1 2.8 16 96 0.98 2.57 0.6 0.49 0 0 0.86 0.09 0.42 432 67 35 2.7 5.3 5.6 1763 319.2 80 71397 71380 71413 253 544 6.44 14.8 80.2 174 17.6 16.5 0.19 99999 0.85 36.6 3.5 2.32 4.12 0.46 469 567 0.28 7.98 0.08 6.12 11.3 1.9 15.5 94 0.56 2.08 0.33 0.23 0 0.25 0.73 0.06 0.25 282 35 15 1.5 2.2 0.9 1737 317.8 47 71617 71596 71637 252 545 7.12 14.7 79.9 172 17.7 16.3 0.21 0.16 0.89 36.2 3.5 2.89 4.18 0.46 511 555 0.35 8.02 0 6.67 12.4 2.24 15.8 95 0.64 4.02 0.56 0.15 0 0 0.84 0.09 0.3 294 35 11 1 2.1 1.7 1739 318.4 57 71844 71820 71867 251 533 7.3 14.2 79.8 170 17.6 16.3 0.18 0.12 0.89 36.5 3.6 2.84 4.12 0.42 480 547 0.27 7.65 0.11 6.73 13 2.35 15.4 93 0.65 4.28 0.54 0.16 0 0 0.84 0.06 0.25 319 37 9 0.7 1.2 1.1 1745 319.4 57 72076 72049 72103 252 542 7.09 14.5 79.2 171 17.9 16.3 0.2 0.14 0.85 99999 3.4 2.9 4.15 0.4 503 554 0.28 8 0 6.73 13.2 2.42 15.5 95 0.67 3.32 0.43 0.15 0 0 0.84 0.05 0.25 322 18 12 0.6 1.3 1.7 1748 318.7 55 72316 72286 72346 247 532 6.66 14.2 77.9 169 17.4 16 0.17 0.11 0.83 36.4 3.7 2.58 4.04 0.43 488 546 0.87 7.92 0.14 6.29 12.4 2.13 15.1 92 0.52 2.38 0.62 0.13 0.77 0 0.69 0.06 0.18 299 35 11 0.7 2 0.7 1744 317.6 48 72564 72529 72599 240 527 7.2 14.2 77.2 165 17.1 16.3 0.2 0.14 0.77 36.2 3 2.71 3.91 0.43 477 545 0.47 7.64 0 5.96 11.6 1.84 15 91 0.33 1.34 0.29 0 0 0 0.65 0.05 0.13 258 29 10 1.2 2.6 0.7 1740 316.5 46 72934 72907 72961 251 537 6.42 14.4 78.5 172 17.6 17 0.19 0.13 0.81 37.5 3.7 2.51 3.99 0.39 490 548 0.31 7.83 0 6.27 12.6 2.07 14.9 92 0.55 2.88 0.36 0 0 0 0.69 0.07 0.13 332 32 28 0.8 3.2 0.5 1744 317.7 54 73318 73285 73350 247 531 7.07 14.2 78.1 167 17.3 16.4 0.2 0.13 0.83 99999 3.5 2.87 3.91 0.45 482 543 0.3 7.85 0 5.9 12.1 1.78 14.6 92 0.39 1.95 0.27 0 0 0 0.65 0.06 0.15 279 30 10 0.7 2.9 0.6 1743 317.5 52 73693 73657 73728 246 527 7.15 14.2 78.3 165 17.2 15.9 0.19 0.17 0.88 35.4 3.3 2.75 3.86 0.41 478 535 0.3 7.76 0 5.61 11.6 1.5 14.7 91 0.27 1.09 0.2 0 0 0 0.55 0 0 240 24 7 0.6 1.2 -0.3 1733 315.1 46 74073 74036 74110 245 535 7.25 14.4 78.4 169 17.3 15.9 0.23 99999 0.75 35.7 3.7 2.9 3.86 0.4 482 545 0.33 7.74 0 5.51 11.7 1.55 14.6 92 0.26 0.96 0.15 0 0 0 0.5 0 0 246 24 7 0.7 1.9 0.1 1740 315.9 48 74464 74418 74509 242 520 6.43 14.4 78.1 165 17.1 16.3 0.17 0.11 0.93 34.5 3 2.26 3.77 0.39 401 525 0.36 7.49 0 4.89 10.9 1.24 14.3 89 0.11 0.54 0.13 0 0 0 0.45 0 0 172 20 4 0 2 -0.1 1729 313.2 41 74862 74817 74906 241 523 6.97 14.1 77.3 162 16.9 15.9 0.19 0.11 0.82 37.1 2.5 2.55 3.77 0.39 470 525 0.35 7.32 0 4.9 10.6 1.18 14.1 89 0.08 0.61 0 0 0 0 0.43 0 0 166 17 4 0.5 1.5 -0.6 1729 312.9 41 75258 75214 75301 238 524 6.66 14.2 77.6 165 17 16.1 0.22 0.13 0.98 34 3.2 2.52 3.75 0.4 483 527 0.59 7.3 0.06 4.97 10.6 1.2 13.9 88 0.11 0.69 0 0 0 0 0.4 0 0 177 20 4 0.4 1.5 -0.1 1729 313.4 41 75652 75609 75694 238 516 6.85 14 77 163 16.6 15.6 0.18 0.12 0.77 99999 3.4 2.33 3.61 0.39 441 520 0.38 7.33 0 4.45 10.3 0.92 13.7 87 0.11 0.54 0.13 0 0 0 0.36 0 0 155 20 4 0.7 2.4 0.3 1727 312.4 39 76050 76002 76098 242 518 6.23 14.1 77.3 164 16.9 15.5 0.19 0.12 0.81 99999 3.3 2.19 3.76 0.42 462 515 0.33 7.21 0 4.36 10.1 0.83 13.6 88 0.09 0.57 0 0 0 0.18 0.32 0 0 152 18 4 0.6 1.3 0.1 1725 312.4 34 76455 76406 76503 240 520 6.73 14.2 77.5 166 16.6 15.4 0.19 0.13 0.88 37 3.1 2.51 3.75 0.4 444 518 0.36 7.27 0 4.27 10 0.72 13.1 87 0.05 0.48 0.13 0 0 0 0.28 0 0 149 16 3 0.5 1.3 1.2 1725 312.4 39 76866 76811 76920 232 513 6.67 14 79.6 165 15.8 15.3 0.22 0.08 0.86 30.7 3.3 2.18 3.53 0.42 99999 506 0.34 6.76 0 3.12 9.7 0.44 11.6 77 0.06 0.41 0 0 0 0 0.17 0 0 122 15 15 1 2.8 -0.3 1710 308.6 36 76976 76930 77022 235 516 6.75 14.3 75.3 166 16.3 16 0.2 0.12 0.8 30.8 2.7 2.34 3.56 0.37 457 509 0.27 7.07 0 3.76 9.5 0.65 12.9 83 0 0.35 0 0 0 0 0.22 0 0 115 13 3 0.8 1.5 0.2 1709 308.1 30 77071 77031 77111 239 526 6.88 14.4 77.2 167 16.8 15.9 0.19 0.14 0.76 32.1 3.1 2.11 3.8 0.43 472 531 0.37 7.3 0 4.51 10.3 0.83 13.7 88 0.1 0.54 0 0 0 0 0.34 0 0 184 20 5 0.7 1.7 -0.2 1731 313.3 39 77278 77238 77318 244 523 6.87 14.2 77.2 164 17 15.8 0.19 0.11 0.69 31.8 3.4 2.39 3.84 0.4 451 533 0.31 7.55 0 4.92 10.4 0.99 13.4 90 0.12 0.81 0 0 0 0 0.37 0 0 210 9 6 0.7 1.7 3.4 1731 314.8 42 77487 77445 77529 247 535 7.14 14.6 78.7 169 17.2 16.3 0.19 0.16 0.92 39.3 3.1 2.55 3.99 0.46 451 547 0.31 7.75 0 4.73 10.7 1.02 13.5 90 0.14 0.81 0 0 0 0 0.36 0 0 207 21 6 1.6 4 1.8 1736 314.5 40 77697 77656 77738 248 533 6.87 14.6 77.9 168 17.3 16.3 0.19 0.15 0.83 99999 3.2 2.57 4.06 0.44 382 541 0.31 7.6 0 4.93 11 1.13 13.7 91 0.18 1.02 0.12 0 0 0 0.41 0 0 219 37 11 1 1.6 0.9 1734 314.8 46 pFad - Phonifier reborn

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