Formula

c1
c2
c2
c3
c3
ic4
nc4
iC5
nC5
nC6
nC7
nC8
nC9
nC10

Ln

a T1

COMPONENTE

Metano
Etileno
Etano
Propileno
Propano
Isobutano
n-Butano
Isopentano
nPentano
n-Hexano
n-Heptano
n-Octano
n-Nonano
n-Decano

a T2

-292,860
-600,076.875
-687,248.25
-923,484.6875
-970,688.5625
-

1,166,846
-1,280,557
-1,481,583
-1,524,891
-1,778,901
-2,013,803
0
-2,551,040.0000
0.0000

aT 1
aT 2

T
T 2
a T 1
a T

2
T
T

dk
dT

dk
dT

e
d
dT

a T 1

T 2

2 a T 1
T 3

0
0
0
0
0
0
0
0
0
0
0
-7,646.81641
0
-9,760.45703

a T6

a P1

8.24450
7.90595
7.90699
7.71725
7.15059
7.72668
7.94986
7.58071
7.33129
6.96783
6.52914
12.48457
5.69313
13.80354

-0.89510
-0.84677
-0.88600
-0.87871
-0.76984
-0.92213
-0.96455
-0.93159
-0.89143
-0.84634
-0.79543
-0.73152
-0.67818
-0.71470

a T 6 a P 1 LnP

T 6

a T 2
T

P 1

LnP

a P 2
a P

2
P
P

a T 6 a P 1 LnP

a T 2
T 2

a P 2
P 2

a P 2
P 2

a P2

a P3

59.8465
42.94594
49.02654
47.67624
0
0
0
0
0
0
0
0
0
0

a P 2
P 2

P 3

a P 2
P 2

0
0
0
0
6.90224
0
0
0
0
0
0
0
0
0

a P 3
P
ln

a P 3

COMPONENTE
Isobutano
Isopentano
nPentano
n-Octano

FORM.
ic4
iC5
nC5
nC8

dk
dT

aT1
-1,166,846
-1,481,583
-1,524,891
0

aT2
0
0
0
-7,646.81641

a T 1
a T

2
T
T

2 a T 1
T 3

T 6

a T 2
T 2

aT6
7.72668
7.58071
7.33129
12.48457

P 1

LnP

ic4
iC5
nC5
nC8
=

a P 2
a P

2
P
P

j n 1 j n

p (j) =( *Xfi/1-j(1-K)])-1
P (j) = Xfi(1-K)/[1/j(1-K)]2
T=
P=
j =

589.992
38
1

aP3
0
0
0
0

ln

p(j )
P(j )

R
Psia

C = 1-B

D =j*C

Xi
0.18
0.4
0.3
0.12
1

Ki
2.773803
0.937683
0.746698
0.043401

1-K
-1.773803
0.062317
0.253302
0.956599

j(1-K)
-1.773803
0.062317
0.253302
0.956599

j1 =

aP2
0
0
0
0

j = V/F

COMP.

aP1
-0.92213
-0.93159
-0.89143
-0.73152

0.956470

E = 1-D
1/j(1-K)
2.773803
0.937683
0.746698
0.043401
p (j) =

F = A/E
Xfi/[1-j(1-K)]
0.064893
0.426584
0.401769
2.764929
2.658174

G =A*C

H =G/E2

Xfi(1-K)
Xfi(1-K)/[1/j(1-K)]2
-0.319285
-0.041498
0.024927
0.028350
0.075991
0.136292
0.114792
60.942014
P (j) =
61.065158

D =j*C
j(1-K)
-1.696589
0.059605
0.242275
0.914958

E = 1-D
1/j(1-K)
2.696589
0.940395
0.757725
0.085042
p (j) =

Xfi/[1-j(1-K)]
0.066751
0.425353
0.395922
1.411073
1.299100
j1 =

D =j*C
j(1-K)
-1.552470
0.054541
0.221695
0.837236

E = 1-D
1/j(1-K)
2.552470
0.945459
0.778305
0.162764
p (j) =

j(1-K)
-1.306106
0.045886
0.186514
0.704373

H =G/E

F = A/E
Xfi/[1-j(1-K)]
0.070520
0.423075
0.385453
0.737265
0.616313

E = 1-D
1/j(1-K)
2.306106
0.954114
0.813486
0.295627
p (j) =

Xfi(1-K)/[1/j(1-K)]
-0.043908
0.028187
0.132354
15.872598
P (j) =
15.989231
0.875221

j1 =
D =j*C

H =G/E2

F = A/E

Xfi(1-K)/[1/j(1-K)]2
-0.049007
0.027886
0.125447
4.333068
P (j) =
4.437394
0.736331
2

H =G/E

F = A/E
Xfi/[1-j(1-K)]
0.078054
0.419237
0.368783
0.405918
0.271992
j1 =

Xfi(1-K)/[1/j(1-K)]2
-0.060037
0.027382
0.114831
1.313483
P (j) =
1.395659
0.541447

D =j*C
j(1-K)
-0.960420
0.033742
0.137149
0.517948

E = 1-D
1/j(1-K)
1.960420
0.966258
0.862851
0.482052
p (j) =

H =G/E

F = A/E
Xfi/[1-j(1-K)]
0.091817
0.413968
0.347685
0.248936
0.102405
j1 =

Xfi(1-K)/[1/j(1-K)]
-0.083077
0.026698
0.102068
0.493995
P (j) =
0.539684
0.351696
2

D =j*C

E = 1-D

F = A/E

H =G/E

j(1-K)
-0.623840
0.021917
0.089085
0.336433

1/j(1-K)
1.623840
0.978083
0.910915
0.663567
p (j) =

Xfi/[1-j(1-K)]
0.110848
0.408963
0.329339
0.180841
0.029991

Xfi(1-K)/[1/j(1-K)]2
-0.121085
0.026057
0.091581
0.260700
0.257252

j1 =
D =j*C
j(1-K)
-0.417043
0.014652
0.059554
0.224908

0.235112
F = A/E

H =G/E2

Xfi/[1-j(1-K)]
0.127025
0.405948
0.318998
0.154820
0.006791

Xfi(1-K)/[1/j(1-K)]2
-0.159005
0.025674
0.085920
0.191076
0.143663

E = 1-D
1/j(1-K)
1.417043
0.985348
0.940446
0.775092
p (j) =

P (j) =

j1 =

P (j) =
0.187842

D =j*C
j(1-K)
-0.333196
0.011706
0.047581
0.179690

F = A/E

H =G/E2

Xfi/[1-j(1-K)]
0.135014
0.404738
0.314987
0.146286
0.001025

Xfi(1-K)/[1/j(1-K)]
-0.179635
0.025521
0.083773
0.170591
0.100250

E = 1-D
1/j(1-K)
1.333196
0.988294
0.952419
0.820310
p (j) =

j1 =

D =j*C
j(1-K)
-0.315055
0.011069
0.044990
0.169907

0.177615

j(1-K)
-0.314109
0.011035
0.044855
0.169397

E = 1-D
1/j(1-K)
1.314109
0.988965
0.955145
0.830603
p (j) =

H =G/E

Xfi/[1-j(1-K)]
0.136876
0.404477
0.314133
0.144562
0.000048

Xfi(1-K)/[1/j(1-K)]2
-0.184625
0.025488
0.083319
0.166593
0.090775

j1 =

D =j*C

P (j) =

F = A/E

E = 1-D
1/j(1-K)
1.315055
0.988931
0.955010
0.830093
p (j) =

P (j) =
0.177082

F = A/E

H =G/E2

Xfi/[1-j(1-K)]
0.136975
0.404463
0.314089
0.144473
1.32E-07

P (j) =

Xfi(1-K)/[1/j(1-K)]2
-0.184891
0.025486
0.083295
0.166389
0.090280

j1 =

0.177081

D =j*C
j(1-K)
-0.314106
0.011035
0.044855
0.169395

D =j*C
j(1-K)
-0.314106
0.011035
0.044855
0.169395

1/j(1-K)
1.314106
0.988965
0.955145
0.830605
p (j) =

E = 1-D
1/j(1-K)
1.314106
0.988965
0.955145
0.830605
p (j) =

H =G/E

Xfi/[1-j(1-K)]
0.136975
0.404463
0.314088
0.144473
9.95E-13

P (j) =

Xfi(1-K)/[1/j(1-K)]
-0.184891
0.025486
0.083295
0.166388
0.090278

j1 =

0.177081

j(1-K)
-0.314106
0.011035
0.044855
0.169395

E = 1-D
1/j(1-K)
1.314106
0.988965
0.955145
0.830605
p (j) =

F = A/E
Xfi/[1-j(1-K)]

H =G/E
Xfi(1-K)/[1/j(1-K)]2

0.136975
0.404463
0.314088
0.144473
0.00E+00

-0.184891
0.025486
0.083295
0.166388
0.090278

j1 =

D =j*C

F = A/E

E = 1-D

P (j) =
0.177081

F = A/E

H =G/E2

Xfi/[1-j(1-K)]
0.136975
0.404463
0.314088
0.144473
0.000000

Xfi(1-K)/[1/j(1-K)]2
-0.184891
0.025486
0.083295
0.166388
0.090278

P (j) =

j1 =

0.177081

Xi=Xfi/[1-(j)*(1-Ki)]

Yi=ki*Xi

Xi
0.136975
0.404463
0.314088
0.144473
1

Yi
0.379942
0.379258
0.234529
0.006270
1

F=
V=F*j
L= F - V =

1888
334.328456
1553.67154

Lxi
212.814495
628.403171
487.990197
224.463681

Vyi
127.025505
126.796829
78.4098032
2.09631938

ERROR
0.194884

ERROR
0.189750

ERROR
0.116584

ERROR
0.047270

ERROR
0.010227

ERROR
0.000533

ERROR
0.000001

ERROR
1.10E-11

ERROR
0.00E+00

ERROR
0.000000

COMPONENTE
Propileno
Propano
Isopentano
n-Hexano

a T1

FORM.
c3=
c3
iC5
nC6

-923,484.6875
-970,688.5625
-1,481,583.0000
-1,778,901.0000

a T6

a P1

a P2

7.71725
7.15059
7.58071
6.96783

-0.87871
-0.76984
-0.93159
-0.84634

a P3

47.67624
0
0
0

0
6.90224
0
0

j = L/F

yi = Xfi /[1+ j((1/ki)1)]

j n 1 j n

A
Xi
0.22
0.11
0.33
0.34

COMP.
C3
c3
iC5
nC6
=

B
1/K
0.155418584
0.181918941
1.102545263
3.480768406

NOTA LA J=j
2

p (j )
P(j )

C = B-1
[(1/K)-1]
-0.844581416
-0.818081059
0.102545263
2.480768406

T=
P=
j =

D =j*C
j[(1/K)1]
-0.844581416
-0.818081059
0.102545263
2.480768406

1
j1 =

0.862596507

591
40
1

E = 1+D
F = A/E
1/j[(1/K)-1]
Xfi/[1+j[(1/K)-1]]
0.155418584
1.415532133
0.181918941
0.604664911
1.102545263
0.29930744
3.480768406
0.097679581
p (j) =
1.417184065

R
Psia

G =A*C
.-Xfi[(1/K)-1]
0.185807911
0.089988917
-0.033839937
-0.843461258
P (j) =

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
7.692337048
2.71915013
-0.027837914
-0.069616932
10.31403233

D =j*C
j[(1/K)-1]
-0.72853298
-0.705673865
0.088455186
2.139902163

E = 1+D
1/j[(1/K)-1]
0.27146702
0.294326135
1.088455186
3.139902163
p (j) =

F = A/E
Xfi/[1+j[(1/K)-1]]
0.810411517
0.373735074
0.303181982
0.108283629
0.595612202
j1 =

D =j*C
j[(1/K)-1]
-0.582554794
-0.564276024
0.070731173
1.711123997

E = 1+D
1/j[(1/K)-1]
0.417445206
0.435723976
1.070731173
2.711123997
p (j) =

E = 1+D
1/j[(1/K)-1]
0.546359639
0.560593472
1.055078965
2.332466776
p (j) =

P (j) =

F = A/E
Xfi/[1+j[(1/K)-1]]
0.527015275
0.252453402
0.308200609
0.12540924
0.213078526

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
1.066265226
0.473986647
-0.029516758
-0.114753615
P (j) =

1.3959815

0.537118569

F = A/E
Xfi/[1+j[(1/K)-1]]
0.402665176
0.196220622
0.312772798
0.145768421
0.057427018
j1 =

3.446014861

0.689755639

j1 =
D =j*C
j[(1/K)-1]
-0.453640361
-0.439406528
0.055078965
1.332466776

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
2.521332077
1.038798627
-0.028563304
-0.08555254

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
0.622453601
0.286347206
-0.030399022
-0.15503659
P (j) =
0.457729875

0.723365195

D =j*C
j[(1/K)-1]
-0.386590146
-0.374460141
0.04693803
1.135521813

E = 1+D
1/j[(1/K)-1]
0.613409854
0.625539859
1.04693803
2.135521813
p (j) =

F = A/E
Xfi/[1+j[(1/K)-1]]
0.358650906
0.175848107
0.315204903
0.159211673
0.008915589
j1 =

D =j*C
j[(1/K)-1]
-0.371766336
-0.360101457
0.04513819
1.091980198

E = 1+D
1/j[(1/K)-1]
0.628233664
0.639898543
1.04513819
2.091980198
p (j) =

E = 1+D
1/j[(1/K)-1]
0.628891436
0.640535677
1.045058327
2.090048139
p (j) =

P (j) =

0.507962569

0.440178211

F = A/E
Xfi/[1+j[(1/K)-1]]
0.350188175
0.171902251
0.315747719
0.162525439
0.000363584
j1 =

D =j*C
j[(1/K)-1]
-0.371108564
-0.359464323
0.045058327
1.090048139

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
0.493813212
0.229974163
-0.030873623
-0.184951184

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
0.470784107
0.219769176
-0.03098005
-0.192730301
P (j) =

0.466842932

0.439399396

F = A/E
Xfi/[1+j[(1/K)-1]]
0.349821905
0.171731262
0.315771849
0.162675679
6.94341E-07

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
0.469799814
0.21933219
-0.030984785
-0.193086789
P (j) =

0.46506043

j1 =

D =j*C
j[(1/K)-1]
-0.371107303
-0.359463102
0.045058173
1.090044435

E = 1+D
1/j[(1/K)-1]
0.628892697
0.640536898
1.045058173
2.090044435
p (j) =

0.439397903

F = A/E
Xfi/[1+j[(1/K)-1]]
0.349821203
0.171730934
0.315771895
0.162675967
2.54841E-12
j1 =

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2
0.46979793
0.219331353
-0.030984794
-0.193087474
P (j) =
0.439397903

0.465057016

k e

aT 1 aT 2
a
a
aT 3 LnT aT 4T aT 5T 2 aT 6 a P 1LnP P22 P 3 a P 4 Ln 2 P a P 5 Ln 3 P P
2
T
P
T
P

j = V/F
2

P (j) = Xfi(1-K)/[1/j(1-K)]
para xi

B
Ki

C = 1-B
1-K

dk 2 a T1 a T 2 a T 3

k 3 2
a T 4 2a T 5 T
dT T
T
T

ln K

T=
591
R
P=
40
Psia
j =
propuesta
que regularmente es 1

p (j) =( *Xfi/1-j(1-K)])-1

A
COMP. Xfi

D =j*C
j(1-K)

E = 1-D
1/j(1-K)

F = A/E
Xfi/[1-j(1-K)]

p (j) =

j n 1 j n

F -1

G =A*C
Xfi(1-K)

H =G/E

Xfi(1-K)/[1/j(1-K)]

P (j) =

p (j )
P(j )

D =j*C

E = 1-D

F = A/E

H =G/E2

j(1-K)

1/j(1-K)

Xfi/[1-j(1-K)]

Xfi(1-K)/[1/j(1-K)]2

p (j) =

F -1

P (j) =

j = L/F

para yi

yi = Xfi /[1+ j((1/ki)1)]

COMP.
=

A
Xi

B
1/K

C = B-1
[(1/K)-1]

D =j*C
j[(1/K)1]

E = 1+D
1/j[(1/K)-1]

p (j) =

0
D =j*C

E = 1+D

F = A/E
Xfi/[1+j[(1/K)-1]]

F -1
F = A/E

G =A*C
.-Xfi[(1/K)-1]

H =G/E2
Xfi(1-K)/[1/j((1/ki)-1)]2

P (j) =
H =G/E2

j[(1/K)-1]

1/j[(1/K)-1]

Xfi/[1+j[(1/K)-1]]

Xfi(1-K)/[1/j((1/ki)-1)]2