VIRIALMX

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Introduction

VIRIALMX.XLS
This spreadsheet is for calculation of mixture properties for the virial equation.

This worksheet is protected to prevent accidental modification.


You must unprotect before changing formulas. (Tools... Protection... Unprotect...)

You may change values in blue without unprotecting the worksheet.

Copyright 1996-1997, Carl Lira


For use with "An Introduction to Applied Thermodynamics" by J.R. Elliott, C.T. Lira
www.egr.msu.edu/~lira/thermtxt.htm

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55441398.xls

Virial Equation for a Mixture

T (K) 328
P (MPa) 0.1013
kij 0

Compound Tc (K) Pc (MPa) w Vc (cm3/mol) Zc Tr Pr


N2 (1) 126.1 3.394 0.04 90.20 0.292 2.6011 0.0298
C4H10(2) 425.2 3.797 0.193 255.10 0.274 0.7714 0.0267
(1)-(2) 231.56 3.43 0.1165 158.64 0.283 1.4165 0.0295

Compound B0 B1 BPc/RTc Bij(cm3/mol) Bij matrix


N2 (1) -0.008423625 0.135896429 -0.002987768 -0.92 -0.92 -82.51
C4H10(2) -0.556239363 -0.372622903 -0.628155584 -584.83 -82.51 -584.83
(1)-(2) -0.158746934 0.099152065 -0.147195719 -82.51

y1 y2 B   f1 hat(MPa) f2 hat(MPa)


0 1 -584.8303515 1.015716721 0.978509499 0 0.099123012
0.1 0.9 -488.5742642 1.012705057 0.97866244 0.0102587 0.089224655
0.2 0.8 -400.7326977 1.010017981 0.979121406 0.02046296 0.079347999
0.3 0.7 -321.3056518 1.007652952 0.979886829 0.03062257 0.069483775
0.4 0.6 -250.2931268 1.005607741 0.980959425 0.04074723 0.059622714
0.5 0.5 -187.6951224 1.00388042 0.982340204 0.05084654 0.049755531
0.6 0.4 -133.5116388 1.002469365 0.984030462 0.06093009 0.039872914
0.7 0.3 -87.74267593 1.001373248 0.986031789 0.07100738 0.029965506
0.8 0.2 -50.38823381 1.000591042 0.988346071 0.0810879 0.020023891
0.9 0.1 -21.44831242 1.000122012 0.990975491 0.09118112 0.010038582
1 0 -0.922911769 0.999965717 0.993922534 0.10129653 0

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