Process Engineering
Process Engineering
Table of Contents
Table of content ............................................................................................................................................ 1
Introduction .................................................................................................................................................. 2
Calculation .................................................................................................................................................... 2
Simulation ................................................................................................................................................... 11
Conclusion ................................................................................................................................................... 13
References .................................................................................................................................................. 13
Introduction
Calculation
Tm in 10 oC
Stream
Ts
Tt
CP
T*s
T*t
No
Type
(C)
(C)
(kW)
(kW/C)
(C)
(C)
4-6/1
Cold
35.5
150
2,567.8244
22.4
40.5
155
5-7/2
Cold
126.3
150
91.7826
3.9
131.3
155
13-14/3
Cold
80
102
2,934.5150
133.4
85
107
19-20 /4
Hot
62.2
35
-482.4474
17.7
57.2
30
Tm in
2
Tm in
2
H int erval
0
155
131.3
23.7
26.3
623.31
24.3
22.4
544.32
22
155.8
3427.60
27.8
22.4
622.72
107
85
3
2
57.2
4
16.7
4.6
76.82
10.5
-17.8
-186.90
40.5
30
Cascade diagram
First cascade
Second cascade
5294.77
-623.31
4671.46
-1167.63
4127.14
-4595.23
699.54
-5217.95
76.82
-5294.77
5107.87
186.90
155
623.31
131.3
544.32
107
3427.60
85
622.72
57.2
76.82
40.5
-186.90
30
Tpinch*
= 40.5 0C
Tpinch hot
=45.50C
Tpinch cold
=35.50C
QHmin
=5294.77 kW
Qcmin
=186.90 kW
45.5C
35C
150C
35.5C
H
150C
17.7
186.9
22.4
2564.8
126.3C
35.5C
3.9
35.5C
133.4
92.43
102C
80C
H
2639.21
1
295.59
Feasibility Study
Q=CP T
295.59=133.4(T-80)
T=82.22C
T (C)
T (C)
82.22
62.2
80
T= 20.02
45.5
T= 34.5
Feasibility
T1 = 82.22-62.20=20.02C
T2 = 80.00-45.5-=34.50C
The process integration is feasible since the T is greater than the proposed Tmin.
Medium pressure
Low pressure
180
160
140
T shifted
120
100
80
60
40
20
0
0
1000
2000
3000
4000
5000
6000
Cooling water
The most common heat utility is steam and available at several levels (Smith, 2009, p. 372).
The levels address as low pressure, medium pressure, high pressure and very high pressure
steam. Table 1 shows the typical steam available for hot utilities and the shifted temperature for
the Tmin= 20OC
Table 1: Typical steams available for hot utility (Venkatesan, V., 2008).
No. Steam for heating
Pressure (Psig)
Temperature (C)
Temperature
Shifted (C)
Low Pressure
>50
130
120
Medium Pressure
50 - 250
230 280
220
High Pressure
250
350
340
>600
500
490
Usually for the cold utilities, refrigeration, cooling water, air-cooling are used for the cold utilities
and there are more cold utilities that not been mentioned.
Table 2: General information of typical refrigerant available for cold utility (Application guiderefrigerants, 2012).
Table 3: Operation information of typical refrigerant available for cold utility (Application guiderefrigerants, 2012).
So, in this process, we used cooling water as the cold utilities since it has 100oC boiling point
and the temperature below the pinch is below 40 oC.
SAVING
In terms of the amount (kW and %)
For hot utility
QH before = 482.4474 KW
QH after = 5294.77 KW
Saving =
= 997.48%
(5594.122 186.9) KW
100 %
5594.122 KW
= 96.66%
10
Simulation
SIMULATION BY USING ASPEN PLUS
4
6
C1
7
C2
13
14
C3
19
20
H1
11
STREAM TABLE
From
To
C1
C2
Phase
LIQUID
VAPOR
13
C1
C2
14
19
C3
H1
C3
VAPOR
20
VAPOR
H1
MIXED
VAPOR
MIXED
MIXED
kmol/sec
METHANOL
.0560555
WAT ER
8.86111E-4
0.0
.0560555
0.0 8.86111E-4
.0886777
.0886777
.1369305
.1369305
OXYGEN
0.0
.0274250
0.0
.0274250
0.0
0.0
0.0
0.0
NIT ROGEN
0.0
.1036056
0.0
.1036056
0.0
0.0
0.0
0.0
0.0 2.77778E-6
0.0
.0485111
.0485111
.0485083
.0485083
CH2O
2.77778E-6
T otal Flow
kmol/sec
.0569444
.1310306
.0569444
.1310306
.1441750
.1441750
.1855083
.1855083
T otal Flow
kg/sec
1.812188
3.779919
1.812188
3.779919
3.278013
3.278013
3.925592
3.925592
T otal Flow
cum/sec
2.31902E-3
1.972754
.9838637
2.306237
1.653269
3.798914
.5374885
.5027440
T emperature
308.6500
399.4500
423.1500
423.1500
353.1500
375.1500
335.3500
308.1500
Pressure
N/sqm
Vapor Frac
0.0
1.000000
1.000000
1.000000
.5454918
1.000000
.2825654
.2664842
Liquid Frac
1.000000
0.0
0.0
0.0
.4545082
0.0
.7174346
.7335158
0.0
0.0
0.0
0.0
0.0
0.0
0.0
0.0
Solid Frac
Ent halpy
J/kmol
Ent halpy
J/kg
Ent halpy
Wat t
Ent ropy
J/kmol-K -2.4376E+5
6333.582 -1.1666E+5
Ent ropy
J/kg-K
-7659.544
219.5530 -3665.845
Density
kmol/cum
24.55540
.0664201
.0578783
.0568157
.0872059
.0379516
.3451392
.3689916
Density
kg/cum
781.4459
1.916062
1.841910
1.638998
1.982746
.8628816
7.303584
7.808332
31.82379
28.84762
31.82379
28.84762
22.73635
22.73635
21.16127
21.16127
Average MW
Liq Vol 60F
cum/sec
12
Conclusion
References
Smith, R. (2009). Chemical Process Design. West Sussex, England: John Wiley & Sons Ltd.
Venkatesan, V. (2008). How do you define steam? Retrieved May 06, 2013 from
http://www.chemicalprocessing.com/experts/steam-thermal-systems/show/359/
13