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    Chem 626: Spring 2013

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    tophat36
    This document provides information about the CHEM 626 Organic Chemistry 2 course for Spring 2013 at the University of Kansas, including: - Contact information for the instructor, Prof. David Benson, and head TA Jessica Lohrman. - Required and recommended course materials, including the textbook by Janice Gorzynski Smith and access to the Connect Plus homework system. - Details on getting help outside of class hours through office hours, email, study groups, and PLUS sessions. - The exam schedule for the semester and policies on conflicts. - Information on electronic quizzes and how the final course grade will be calculated based on exams and quizzes.

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    Chem 626: Spring 2013

    Uploaded by

    tophat36
    68 views5 pages
    This document provides information about the CHEM 626 Organic Chemistry 2 course for Spring 2013 at the University of Kansas, including: - Contact information for the instructor, Prof. David Benson, and head TA Jessica Lohrman. - Required and recommended course materials, including the textbook by Janice Gorzynski Smith and access to the Connect Plus homework system. - Details on getting help outside of class hours through office hours, email, study groups, and PLUS sessions. - The exam schedule for the semester and policies on conflicts. - Information on electronic quizzes and how the final course grade will be calculated based on exams and quizzes.

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    This document provides information about the CHEM 626 Organic Chemistry 2 course for Spring 2013 at the University of Kansas, including: - Contact information for the instructor, Prof. David Benson, and head TA Jessica Lohrman. - Required and recommended course materials, including the textbook by Janice Gorzynski Smith and access to the Connect Plus homework system. - Details on getting help outside of class hours through office hours, email, study groups, and PLUS sessions. - The exam schedule for the semester and policies on conflicts. - Information on electronic quizzes and how the final course grade will be calculated based on exams and quizzes.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    68 views5 pages

    Chem 626: Spring 2013

    Uploaded by

    tophat36
    This document provides information about the CHEM 626 Organic Chemistry 2 course for Spring 2013 at the University of Kansas, including: - Contact information for the instructor, Prof. David Benson, and head TA Jessica Lohrman. - Required and recommended course materials, including the textbook by Janice Gorzynski Smith and access to the Connect Plus homework system. - Details on getting help outside of class hours through office hours, email, study groups, and PLUS sessions. - The exam schedule for the semester and policies on conflicts. - Information on electronic quizzes and how the final course grade will be calculated based on exams and quizzes.

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    You are on page 1of 5

    Reading for Friday

    Sections 15.6-15.10

    Chem 626 Organic Chemistry 2


    Spring 2013
    Prerequisite: Chem 624 or equivalent

    Instructor: Prof. David R. Benson


    5070 Malott Hall Office Hours Mon. and Wed. 11 AM-Noon Thurs. 10-11 AM or by appointment

    Head TA: Jessica Lohrman


    5017 Malott Hall Office Hours Tues. 11 AM Noon Thurs. 2-3 PM or by appointment

    Course Email Address:


    chem626@ku.edu
    Please use this account for all course-related questions

    Required Course Materials:


    1) Janice Gorzynski Smith: Organic Chemistry (3rd Ed.) McGraw-Hill, 2011
    Special KU Edition

    Required Course Materials:


    Four (4) Copies of the textbook are on reserve in Anschutz Science Library 2) Connect Plus Electronic Homework System: Packaged with the special KU version of the textbook (sold only in the KU bookstore and other local textbook outlets). May be purchased separately online (see Blackboard for info)

    If you set up a Connect account for CHEM 624 last semester, it will still be active for this semester. Registration instructions for new users are available on Blackboard

    Recommended materials
    1) Student Study Guide and Solutions Manual for the textbook (ISBN: 978-0-07-304987-8) 20 copies of this manual are on reserve in Anschutz Science Library

    Recommended materials
    2) Molecular Models Available in the bookstores; Other types available online (Molecular Models tab on Bb has my recommendation) A set is also on reserve in Anschutz Science Library

    How you can get help outside of class


    1) Visit us during office hours 2) Contact us via the course e-mail account 3) Form/join a study group 4) Attend PLUS sessions

    CHEM 626 PLUS Sessions SP13


    Monday Tuesday Wednesday Thursday Friday Saturday 3:00-4:30 PM 4:00-5:30 PM 3:00-4:30 PM 5:30-7:00 PM 2:30-4:00 PM 10:30-Noon MS 107 MAL 2007 MS 107 MAL 2007 MAL 2007 MAL 2007

    Dr. Benson will hold a discussion/review session the Tuesday evening before each exam Time: 6:30 pm Location: 1001 Malott

    Sessions begin Monday 1/28

    Exam Schedule (6:00-7:30 PM) Exam 1: Thursday, February 21 Exam 2: Thursday, March 14 Exam 3: Thursday, April 11 Exam 4: Thursday, May 2 Final : Wed., May 15, 7:30 AM *All exams in 120 Budig *No Make-up exams!

    Inform us of valid EXAM CONFLICTS at least two weeks in advance, so we can arrange an alternate time for you to take the exam Valid time conflicts are activities that you know about in advance and that are integral to your KU academic program (other classes, exams, conference attendance, etc.) or athletic program. *You will be required to provide documentation of the conflict*

    Conflicts do NOT include planned or unplanned absences resulting from, for example, illness, family emergencies, or trips out of town for personal reasons The fact that such events are sometimes unavoidable is part of our rationale for using only your top three hour exam scores in determining your grade

    Electronic Quizzes: Approximately bi-weekly quizzes (each worth 10 points) will be administered via Connect. The quiz schedule has been posted to Blackboard

    Course Grading Top 3 hour exams Top 7 quizzes Final Exam Total:

    300 pts 70 pts 200 pts 570 pts

    Lecture Materials on Bb
    1) Powerpoint slides (pdf format) Course Documents tab 2) Audio recording EchoCenter tab

    Classroom Conduct
    *Newspapers *Talking *Laptop Computers *Cell phones, texting, etc. *Packing up to go.

    Chapter 15 Radical Reactions

    Radicals (15.1)
    A radical is a reactive intermediate

    C-H BDEs (from Table 6.2)


    Methyl 1 1

    with a single unpaired electron


    Relative stabilities of radicals can be

    Bond H (kJ/mol) CH3H 435 CH3CH2H 410 410 CH3CH2CH2H (CH3)2CHH 397 2 (CH3)3CH 381 3

    predicted from bond dissociation energies (BDEs)

    Comparing the 1 and 2 C-H bonds in propane

    Radical Reactions (15.2, 15.2A)


    Initiators of radical reactions contain

    weak bonds that can be broken by heat or light


    Examples include halogens (X2) and

    peroxides (ROOR)

    Bond strength: Radical stability:

    1 > 2 2 > 1

    Bond Dissociation Energies of some common radical initiators


    Bond ClCl BrBr HOOH H (kJ/mol) 242 192 213

    Halogenation of Alkanes (15.3)


    Radical substitution reaction R-H + X2

    h or

    R-X + H-X

    X2 = Cl2 or Br2

    Evidence for Radical Chain Mechanism rather than Ionic Mechanism (15.4)
    , h or added peroxide (ROOR) is

    Chlorination of Ethane (Fig. 15.4)

    necessary for the reaction

    O2 inhibits the reaction No rearrangements are observed Unlike carbocations, radicals do not rearrange

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