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    Acetoacetanilide (Cas 102-01-2) MSDS

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    Daisyfrankie
    This document provides information on the chemical acetoacetanilide (CAS 102-01-2), including its hazards, safe handling and storage, composition, and regulatory information. It identifies acetoacetanilide as harmful if swallowed or in contact with skin. The document contains the chemical's safety data sheet.

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    Acetoacetanilide (Cas 102-01-2) MSDS

    Uploaded by

    Daisyfrankie
    182 views5 pages
    This document provides information on the chemical acetoacetanilide (CAS 102-01-2), including its hazards, safe handling and storage, composition, and regulatory information. It identifies acetoacetanilide as harmful if swallowed or in contact with skin. The document contains the chemical's safety data sheet.

    Original Description:

    Harmful in contact with skin and if swallowed. Wear suitable protective clothing.

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    © Attribution Non-Commercial (BY-NC)

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    This document provides information on the chemical acetoacetanilide (CAS 102-01-2), including its hazards, safe handling and storage, composition, and regulatory information. It identifies acetoacetanilide as harmful if swallowed or in contact with skin. The document contains the chemical's safety data sheet.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    182 views5 pages

    Acetoacetanilide (Cas 102-01-2) MSDS

    Uploaded by

    Daisyfrankie
    This document provides information on the chemical acetoacetanilide (CAS 102-01-2), including its hazards, safe handling and storage, composition, and regulatory information. It identifies acetoacetanilide as harmful if swallowed or in contact with skin. The document contains the chemical's safety data sheet.

    Copyright:

    Attribution Non-Commercial (BY-NC)
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    of 5

    Click http://www.guidechem.com/cas-102/102-01-2.

    html for suppliers of this product

    Acetoacetanilide (cas 102-01-2) MSDS


    1. 1.1 IDENTIFICATION OF THE SUBSTANCE/MIXTURE AND OF THE COMPANY/UNDERTAKING Product identifiers
    Product name Product Number Brand CAS-No. : : : : :

    acetoacetanilide
    538329 Anonymous 102-01-2 Laboratory chemicals, Manufacture of substances

    1.2 2. 2.1

    Relevant identified uses of the substance or mixture and uses advised against
    Identified uses

    HAZARDS IDENTIFICATION Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 [EU-GHS/CLP]
    Acute toxicity, Oral (Category 4) Acute toxicity, Dermal (Category 4)

    Classification according to EU Directives 67/548/EEC or 1999/45/EC


    Harmful in contact with skin and if swallowed.

    2.2

    Label elements Labelling according Regulation (EC) No 1272/2008 [CLP]


    Pictogram Signal word Hazard statement(s) H302 H312 Precautionary statement(s) P280 Supplemental Hazard Statements Hazard symbol(s) R-phrase(s) R21/22 S-phrase(s) S36 Warning Harmful if swallowed. Harmful in contact with skin. Wear protective gloves/ protective clothing. none

    According to European Directive 67/548/EEC as amended.

    Harmful in contact with skin and if swallowed. Wear suitable protective clothing.

    2.3 3. 3.1

    Other hazards - none COMPOSITION/INFORMATION ON INGREDIENTS Substances


    Formula Molecular Weight Component : : C10H11NO2 177,2 g/mol Concentration 102-01-2 202-996-4 -

    Acetoacetanilide
    CAS-No. EC-No.

    4. 4.1

    FIRST AID MEASURES Description of first aid measures General advice


    Consult a physician. Show this safety data sheet to the doctor in attendance.

    If inhaled

    If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.

    In case of skin contact


    Wash off with soap and plenty of water. Consult a physician.

    In case of eye contact


    Flush eyes with water as a precaution.

    If swallowed
    Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult a physician.

    4.2

    Most important symptoms and effects, both acute and delayed


    Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

    4.3 5. 5.1

    Indication of any immediate medical attention and special treatment needed


    no data available

    FIREFIGHTING MEASURES Extinguishing media Suitable extinguishing media


    Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.

    5.2 5.3 5.4 6. 6.1

    Special hazards arising from the substance or mixture


    Carbon oxides, nitrogen oxides (NOx)

    Advice for firefighters


    Wear self contained breathing apparatus for fire fighting if necessary.

    Further information
    no data available

    ACCIDENTAL RELEASE MEASURES Personal precautions, protective equipment and emergency procedures
    Use personal protective equipment. Avoid dust formation. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Avoid breathing dust.

    6.2 6.3

    Environmental precautions
    Do not let product enter drains.

    Methods and materials for containment and cleaning up


    Pick up and arrange disposal without creating dust. Sweep up and shovel. Keep in suitable, closed containers for disposal.

    6.4 7. 7.1

    Reference to other sections


    For disposal see section 13.

    HANDLING AND STORAGE Precautions for safe handling


    Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Provide appropriate exhaust ventilation at places where dust is formed.Normal measures for preventive fire protection.

    7.2 7.3 8. 8.1 8.2

    Conditions for safe storage, including any incompatibilities


    Store in cool place. Keep container tightly closed in a dry and well-ventilated place.

    Specific end uses


    no data available

    EXPOSURE CONTROLS/PERSONAL PROTECTION Control parameters Components with workplace control parameters Exposure controls Appropriate engineering controls
    Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.

    Personal protective equipment Eye/face protection


    Safety glasses with side-shields conforming to EN166 Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU).

    Skin protection
    Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in accordance with applicable laws and good laboratory practices. Wash and dry hands.

    The selected protective gloves have to satisfy the specifications of EU Directive 89/686/EEC and the standard EN 374 derived from it.

    Body Protection
    Complete suit protecting against chemicals, The type of protective equipment must be selected according to the concentration and amount of the dangerous substance at the specific workplace.

    Respiratory protection
    For nuisance exposures use type P95 (US) or type P1 (EU EN 143) particle respirator.For higher level protection use type OV/AG/P99 (US) or type ABEK-P2 (EU EN 143) respirator cartridges. Use respirators and components tested and approved under appropriate government standards such as NIOSH (US) or CEN (EU).

    9. 9.1

    PHYSICAL AND CHEMICAL PROPERTIES Information on basic physical and chemical properties
    a) Appearance b) Odour c) Odour Threshold Form: powder Colour: light yellow no data available no data available

    d) pH no data available e) Melting point/freezing Melting point/range: 83 - 88 C - lit. point f) Initial boiling point and no data available boiling range g) Flash point 162,8 C - closed cup h) Evaporation rate no data available i) Flammability (solid, gas) no data available j) Upper/lower flammability or explosive limits k) Vapour pressure l) Vapour density m) Relative density n) Water solubility o) Partition coefficient: noctanol/water p) Autoignition temperature q) Decomposition temperature r) Viscosity s) Explosive properties t) Oxidizing properties no data available

    no data available no data available no data available no data available no data available no data available no data available no data available no data available no data available

    9.2

    Other safety information


    no data available

    10. STABILITY AND REACTIVITY 10.1 Reactivity


    no data available

    10.2 Chemical stability


    no data available

    10.3 Possibility of hazardous reactions


    no data available

    10.4 Conditions to avoid


    no data available

    10.5 Incompatible materials


    Strong oxidizing agents

    10.6 Hazardous decomposition products


    Other decomposition products - no data available

    11. TOXICOLOGICAL INFORMATION 11.1 Information on toxicological effects

    Acute toxicity
    LD50 Oral - rat - 1.600 mg/kg LD50 Dermal - guinea pig - > 1.000 mg/kg LD50 Intraperitoneal - rat - 800 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Vascular:Regional or general arteriolar or venous dilation. Cyanosis LD50 Intraperitoneal - mouse - 300 mg/kg

    Skin corrosion/irritation
    no data available

    Serious eye damage/eye irritation


    no data available

    Respiratory or skin sensitization


    no data available

    Germ cell mutagenicity


    no data available

    Carcinogenicity
    IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC.

    Reproductive toxicity
    no data available

    Specific target organ toxicity - single exposure


    no data available

    Specific target organ toxicity - repeated exposure


    no data available

    Aspiration hazard
    no data available

    Potential health effects Inhalation May be harmful if inhaled. May cause respiratory tract irritation. Ingestion Harmful if swallowed. Skin Harmful if absorbed through skin. May cause skin irritation. Eyes May cause eye irritation. Signs and Symptoms of Exposure
    Absorption into the body leads to the formation of methemoglobin which in sufficient concentration causes cyanosis. Onset may be delayed 2 to 4 hours or longer.

    Additional Information
    RTECS: Not available

    12. ECOLOGICAL INFORMATION 12.1 Toxicity


    no data available

    12.2 Persistence and degradability


    no data available

    12.3 Bioaccumulative potential


    no data available

    12.4 Mobility in soil


    no data available

    12.5 Results of PBT and vPvB assessment


    no data available

    12.6 Other adverse effects


    no data available

    13. DISPOSAL CONSIDERATIONS 13.1 Waste treatment methods Product


    Contact a licensed professional waste disposal service to dispose of this material. Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. Offer surplus and non-recyclable solutions to a licensed disposal company.

    Contaminated packaging

    Dispose of as unused product.

    14. TRANSPORT INFORMATION 14.1 UN number


    ADR/RID: IMDG: IATA: -

    14.2 UN proper shipping name


    ADR/RID: Not dangerous goods IMDG: Not dangerous goods IATA: Not dangerous goods

    14.3 Transport hazard class(es)


    ADR/RID: IMDG: IMDG: IMDG Marine pollutant: no IATA: IATA: IATA: no

    14.4 Packaging group


    ADR/RID: -

    14.5 Environmental hazards


    ADR/RID: no

    14.6 Special precautions for user


    no data available

    15.

    REGULATORY INFORMATION
    This safety datasheet complies with the requirements of Regulation (EC) No. 1907/2006.

    15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
    no data available

    15.2 Chemical Safety Assessment


    no data available

    16.

    OTHER INFORMATION Further information


    The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. The informationin this document is based on the resent state of our knowledge and is applicable to the product with regard toappropriate safety precautions. It does not represent any guarantee of the properties of the product. guidechem shall not be held liable for any damage resulting from handling or from contact with the above product. See reverse side of invoice or packing slip for additional terms and conditions of sale.

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