Ethanol Plants Manual
Ethanol Plants Manual
Ethanol Plants Manual
ENVIRONMENTAL LAWS
Applicable to
Construction and Operation
of
Ethanol Plants
www.epa.gov/region07/priorities/agriculture
This compliance assistance manual serves as a road map of information on federal environmental
programs and federal and state agency roles. Air, water, hazardous waste, accident prevention and
release reporting are examples of requirements that might apply. This manual, like a road map,
does not contain all the details of the federal and state statutes and regulations. Ethanol facility
operators need to review the applicable statutes and regulations.
There are many federal environmental requirements that apply to ethanol production
facilities. State environmental agencies
may take the lead in implementing federal
environmental programs and may have
state requirements in addition to federal
environmental requirements. The U.S.
Environmental Protection Agency and
state environmental agencies work in
partnership and are available to answer
questions about applicability of
environmental requirements to individual
ethanol production facilities. Our goal is
to work with ethanol facility operators to
ensure that human health and the
environment are protected as ethanol
production continues to increase in EPAs
Region 7 (Iowa, Kansas, Missouri, and Nebraska).
DISCLAIMERS:
This manual provides guidance to help the regulated community and the public understand
ethanol facility obligations under environmental laws.
This manual is not a substitute for regulations, nor is it a regulation. It cannot impose legally
binding requirements on EPA, states, or the regulated community. The reader must refer to
federal and state laws and regulations for a complete understanding of all legal requirements.
This manual does not represent final agency action and can be updated in the future.
This manual does not limit the otherwise lawful prerogatives of regulating agencies. Agencies
may act at variance with this guidance based on facility-specific circumstances.
The mention of trade names, commercial products, industry references, and technical resources
does not constitute an endorsement or recommendation for use.
The information in this document is current as of its publication date.
This manual has been prepared by the U.S. Environmental Protection Agency Region 7 Biofuels work group.
TABLE OF CONTENTS
INTRODUCTION
I.1 Requirement for Renewable Fuels.............................I-1
To Know Act.............................................................2-5
Hazardous Waste..................................................2-20
TABLE OF CONTENTS
APPENDICES
APPENDIX A - SUMMARY OF LAWS PERTAINING TO ETHANOL
PRODUCTION AND WHO TO CONTACT
TABLE OF CONTENTS
ii
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
INTRODUCTION
I.1 Requirement for Renewable Fuels
fuels would include ethanol, biodiesel and other motor vehicle fuels made from
renewable sources.
About 4.5 billion gallons of renewable fuels were used in the United States in 2006
as motor vehicle fuel. The RFS program requires that this volume increase to at
least 7.5 billion gallons by 2012.
INTRODUCTION
I-1
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
Program.
Register
Generate Renewable Identification
Numbers (RINs),
Transfer RINs with fuel,
Product Transfer Documents,
Blending,
Exporting,
Non-Road Use of Fuel,
Attest Engagements,
Keep records for 5 years, and
Report quarterly; see http://epa.gov/otaq/regs/fuels/rfsforms.htm for forms.
Some producers may have additional requirements, if they sell or export renewable
fuel, or create derived waste or cellulosic ethanol.
Facilities producing less than 10,000 gallons of renewable fuel per year are not
subject to RFS requirements but may opt in voluntarily.
INTRODUCTION
I-2
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
Registration
Ethanol producers are required to fill out one 3520-20A for the company and one
3520-20B for each facility. On form 3520-20A, ethanol producers are required to
select RFS for question 7 and RIN Generator for question 8. On form
3520-20B, ethanol producers need to select RIN generator. After the forms are
received, EPA will provide the ethanol producer with its Company and Facility IDs
for the RFS program. (Remember that registration numbers discussed above for
FFARS are not the appropriate registration numbers to be utilized in the RFS
program and the generation of RINs, as discussed below.)
RIN Generation
INTRODUCTION
I-3
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
All renewable producers/importers that sell only the fuel that they create or import
must transfer RINs with fuel to the next party at the equivalence value. For
ethanol, that is 1 RIN per gallon sold to the next party. RINs can only be
transferred to parties registered for the RFS program; therefore renewable
producers/importers that sell only the fuel they create or import can only sell to
registered parties. [40 CFR 80.1128(a)(6)].
All parties that transfer renewable fuel must follow the Product Transfer Document
(PTD) regulations per 40 CFR 80.1153. Every product transfer document must
have the following information:
If no assigned RINs are being transferred with renewable fuel, the PTD which is
used to transfer ownership of the fuel shall state No RINs Transferred.
Blending
Blenders of renewable fuel that create motor vehicle fuel (for example by blending
ethanol with gasoline to produce E-85 or E-10), must separate RINs associated
with the volume of renewable fuel [40 CFR 80.1129(b)(2)]. In addition, renewable
fuel producers may, upon agreement with their customers, separate RINs from fuel
in situations where customers are splash blending. Blenders of renewable fuel
INTRODUCTION
I-4
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
with assigned RINs, must separate the RINs and change the first digit (K code) of
the RINs from 1 to 2 during the compliance quarter when the blending took place
and before transferring those RINs to another party.
Exporting
Any company that exports renewable fuel in its neat form or blended with gasoline
or diesel outside of the lower 48 states [40 CFR 80.1126(a)] (and after January 1,
2007, Hawaii) has a Renewable Volume Obligation (RVO). The RVO for
exporters is determined by retiring RINs equal to the volume of fuel exported times
the equivalence value, plus any prior year deficit. A producer that exports
renewable fuel, must generate RINs for that volume, and upon export, separate
those RINs [40 CFR 80.1129(b)(3)]. At the end of the compliance year, the
exporter must determine its RVO [40 CFR 80.1130(b)]. In the event that an
exporter does not have enough separated RINs to cover their RVO, they must
acquire separated RINs to meet the RVO [40 CFR 80.1130(a)].
EPA believes that most fuel that can be used as motor vehicle fuel and which
otherwise meets the definition of renewable fuel (such as biodiesel and ethanol)
will ultimately be used as motor vehicle fuel. Therefore, producers and importers
of such products can assume that they meet the definition of renewable fuel and
can assign RINs to them without tracking their ultimate use.
However, if fuel with assigned RINs is actually blended into gasoline or diesel that
is known to be destined for use in a nonroad application, such as agricultural
equipment, the presumption that led the fuel producer/importer to assign RINs to
the product is no longer valid. Such fuel cannot be considered a motor vehicle fuel
and thus is not in fact a renewable fuel that is valid for RFS compliance
purposes. In such cases, the blender should treat the RINs associated with the
blended fuel in the same way as for fuel with assigned RINs that is used in a heater
or boiler.
Recordkeeping Requirements
Renewable producers and importers, obligated parties and owners of RINs who are
neither renewable producers/importer nor obligated parties have several record
keeping requirements. 40 CFR 80.1151(e) states records must be kept for 5 years.
INTRODUCTION
I-5
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
Report
Exporters of renewable fuel and obligated parties must also use the annual RFS
Obligated Party Annual Compliance Report (RFS0300).
All reports must be submitted via EPAs Central Data Exchange (CDX). CDX is
an online portal that encrypts and sends reports to the EPA. In order for companies
to use CDX they must register users well in advance of the reporting deadline.
Attest Engagements
INTRODUCTION
I-6
Environmental Laws Applicable to Construction and Operation of Ethanol Plants
U.S. Environmental Protection Agency Region 7
The most common process for Photo courtesy of the Marshall Democrat News
ethanol production is dry milling,
where the whole corn kernel or
other grain is ground into a flour
or meal. The meal is mixed with
water after milling to form a mash. The mash is heated and enzymes are added to
break down the starch to fermentable sugars. The next stage is the fermentation
process, which involves adding yeast to convert the sugars to ethanol and carbon
dioxide.
INTRODUCTION
I-7
This Page is
Intentionally
Left Blank
The NEPA assessment for ethanol plants should include all potential environmental
and human health impacts. Resources such as wetlands, water quality, hazardous
waste, and air quality are commonly analyzed. Ethanol plants should also consider
potential impacts to road and railway capacity; water supply and local municipal
water systems; and handling and deposition of byproducts (wet or dry cake) from
the plant operation. Significant effects that are identified and determined to be
unavoidable, may require mitigation to reduce or minimize the environmental or
human health impacts.
Ethanol plants can have significant air emissions including volatile organic
compounds, sulfur dioxide, nitrogen oxides, hazardous air pollutants and
particulate matter. Selection of the plant location should focus on minimizing air
quality impacts to downwind residents and consider other air emission sources in
the area.
The Clean Air Act, which was last amended in 1990, requires EPA to set national
ambient air quality standards for widespread pollutants from numerous and diverse
sources considered harmful to public health and the environment. The Clean Air
Act establishes two types of national air quality standards:
1. Primary Standards, which set limits to protect public health, including the
health of sensitive populations such as asthmatics, children and the elderly.
The types of pollutants emitted from these sources are listed in the table below.
(Note: Some of the VOCs emitted are hazardous air pollutants (HAPs) ).
PM, particulate matter; NO2, nitrogen dioxide; CO, carbon monoxide; VOCs, volatile
organic compounds; H2S, hydrogen sulfide; HAPs, hazardous air pollutants
The Clean Air Act requires certain permits to be obtained to minimize air
emissions and protect human health and the environment before construction
begins on an ethanol plant. These are described below.
New source review permits are issued by state or local air pollution control
agencies. In very rare circumstances, EPA might issue the permit. We recommend
having pre-application meetings with the permitting agency for construction
permits; this makes sure your application is complete which helps speed up the
permitting process.
The type of permit required depends on the facilitys potential to emit pollutants
and the location of the facility.
There are two types of major construction permits under the new source review
program:
Prevention of significant deterioration permits are required for new major sources
or a major source making a major modification in an attainment area.
Note: EPA published a final rule in the May 1, 2007 Federal Register that changed the
federal prevention of significant deterioration regulations. The final rule changed the
major source threshold for ethanol plants from 100 tons per year to 250 tons per year.
Some state regulations may have retained the 100 ton per year major source threshold and
will therefore be more stringent than the federal regulations. In those instances, facilities
will need to comply with the more stringent state regulations. Boilers, or a combination of
boilers, totaling more than 250 MMBtu/yr heat input, will be subject to the 100 ton per
year major source threshold. Check with your state permitting agency to determine which
threshold applies to your ethanol plant.
Particulate Matter
25 tons per year of particulate matter emissions
15 tons per year of PM10,
An additional impact
analysis, and
Public involvement.
The main purpose of the air quality analysis is to demonstrate that new emissions
emitted from a proposed major stationary source or major modification, in
conjunction with other applicable emissions from existing sources, will not cause
or contribute to a violation of any applicable national ambient air quality standards
or prevention of significant deterioration increment. Generally, the analysis will
involve;
The additional impacts analysis assesses the impacts of air, ground, and water
pollution on soils, vegetation, and visibility from any increase in emissions of any
regulated pollutant from the source or modification under review and from
associated growth. Associated growth is industrial, commercial, and residential
growth that will occur in the area because of the source.
The most stringent emission limit contained in the implementation plan of any
state for such class or category of source, or
The most stringent emission limit achieved in practice by such class or category
of source.
The emissions rate may result from a combination of emissions limiting measures
such as:
Offsets are emission reductions, generally obtained from existing sources in the
vicinity of a proposed source that must offset the emissions increase from the new
source or modification and provide a net air quality benefit. The obvious purpose
for requiring offsetting emissions decreases is to allow an area to move toward
attainment of the national ambient air quality standards while allowing some
industrial growth.
Minor new source review is for pollutants from stationary sources that do not
require prevention of significant deterioration or nonattainment new source
review permits. The purpose of minor new source review permits is to prevent
building sources that would interfere with attainment or maintenance of national
ambient air quality standards or violate the control strategy in nonattainment areas.
Minor new source review permits often contain permit conditions that will limit the
sources emissions to avoid becoming subject to the prevention of significant
deterioration or nonattainment new source review regulations. The permit
conditions generally involve enforceable emission and/or operating limits that will
ensure air quality protection. As a result, the permits usually contain
recordkeeping, reporting, monitoring, and testing requirements to ensure
compliance with the permit conditions.
The public is given notice when a construction permit might be issued for all three
types of construction permits (prevention of significant deterioration,
nonattainment new source review, and minor new source review). Each state has
different procedures for notification on minor new source review permits. Please
check with the applicable state to verify the procedures.
The following new source performance standards typically apply to ethanol plants.
Regulated pollutants
o Nitrogen oxides, particulate matter, sulfur dioxide
o Opacity
Regulated pollutants
o Particulate matter, sulfur dioxide
o Opacity
Regulated pollutant
o Volatile organic compounds
Regulated pollutant
o Particulate matter
Regulated pollutants
o Particulate matter
o Opacity
Regulated pollutant
o Volatile organic compounds
Regulated pollutants
o Nitrogen oxides, particulate matter, carbon
monoxide
o Non-methane hydrocarbons (NMHC)
o Sulfur oxides (through the use of lower sulfur fuels)
The asbestos NESHAP prohibits any visible emissions from demolition and
renovation projects. The asbestos-containing materials must be wetted, and kept
adequately wet, during the removal and disposal process. The asbestos waste must
be stored in leak-tight containers prior to disposal, and must ultimately be disposed
in approved landfills.
The asbestos NESHAP program has been delegated to each of the Region 7 states.
For questions regarding specific demolition or renovation projects, contact the
appropriate state agency. In some instances, states have requirements that are more
stringent than the federal asbestos NESHAP.
http://www.epa.gov/ttn/atw/orig189.html
Compliance date
o Existing sources May 10, 2008
o New sources
Startup before Nov. 10, 2003 comply by
Nov. 10, 2003
Startup after Nov. 10, 2003 comply upon
startup
Compliance date
o Existing sources April 12, 2004
o New sources
Startup before April 12, 2001 comply by
April 12, 2001
Startup after April 12, 2001 comply upon
startup
This section discusses regulations pursuant to the Clean Water Act that may apply
during the construction or modification of an ethanol plant. Plant operators should
be aware that many requirements that apply during plant operation require permit
applications be submitted well in advance of plant startup (i.e., before or during
construction activities). While this chapter focuses on regulations that apply during
plant construction and modification activities, operators should read and
understand this entire document prior to commencing construction or modification
of an ethanol plant.
If there is a potential for placing dredge or fill materials into a water of the United
States during the construction or expansion of an ethanol plant, then a 404 permit is
required. The following types of activities are regulated through the permitting
process:
If you will need to construct any type of wastewater treatment or holding system
(including collection systems, pumping stations, storage units, etc.) to meet limits
established in a wastewater disposal permit (See Section 2.3), you may be required
to obtain a non-CWA construction permit from your state. The state will require
you to submit plans and specifications for review and approval before any
construction can begin on the treatment system. The treatment system and its
appurtenances must be designed in accordance with the states design standards
which have been established to ensure adequate treatment prior to disposal. Please
contact the person listed for your state in Appendix A, CWA National Pollutant
Discharge Elimination (NPDES) Permits.
The majority of Americans receive drinking water from public water systems. A
public water system is defined as any system that provides water to 25 or more
users or that has 15 or more connections. This includes many types of systems that
might not normally be thought of as public water systems, such as industries,
mobile home parks, rest stops, schools, and park facilities that have their own
source of water. If there are 25 or more workers or daily visitors to a facility that
provides drinking water, the facility might be a public water system, regardless of
ownership.
The Safe Drinking Water Act authorizes EPA to set national health-based
standards for drinking water to protect against naturally occurring and man-made
contaminants that might be found in drinking water.
Nationally, there are more than 170,000 public water systems providing water to
the public, with more than 11,000 of those systems in Region 7. The public water
system owners and operators are responsible for making sure they provide water
that meets EPA standards. Oversight of these public water systems is the
responsibility of EPA, states, and tribes.
Industrial facilities that have their own source of water (such as a well or stream)
and provide drinking water to workers, visitors, or the public, are considered public
water systems. A facility that uses water from another source, such as a municipal
water supply, for drinking water is not regulated as a public water system.
If you also plan to use this existing water supply as the source of cooling or
industrial processing water, you should check with the system operator to make
sure the system can provide a sufficient quantity and quality of water for your
needs. This is important for industries such as ethanol plants that need large
quantities of water for manufacturing or processing.
If your facility will use its own water supply source to provide drinking water to 25
or more people per day for at least 60 days of the year, then you are regulated by
the Public Water System Supervision Program, and you must obtain permits from
the state to build and operate the water supply system. You will be required to
perform routine testing of the water for a variety of contaminants, including
microbiological, radiological, synthetic organics, and inorganics such as nitrate and
lead.
Every public water system must be operated by a trained and qualified operator
who is responsible for the quality of the water and meeting regulatory
requirements. States have programs for training and certifying operators at a level
appropriate to the level of water treatment at the facility. It is the responsibility of
the water system owner to have a certified operator in charge.
Even if you plan to use your own water source for just supplying cooling or
industrial processing water, there are several state water-supply related permits that
might be required. These include:
It is important for facilities that plan to use their own water supply source(s) to
make sure that all of the necessary permits are in place before proceeding. Check
with the state environmental, health or natural resources office listed in the Public
Water System Supervision section of Appendix A before building or modifying a
water supply.
It is disposing of storm water, cooling water, industrial or other fluids into the
subsurface via an injection well;
It has an on-site sanitary waste disposal system (e.g., septic system) that serves
or has the capacity to serve 20 or more persons; or
It has an on-site sanitary waste disposal system that is receiving other than a
solely sanitary waste stream regardless of its capacity; or
Facilities that discharge fluids to streams, ponds, lagoons, or treatment facilities are
not subject to the provisions of the UIC program but could be regulated by the
Clean Water Act.
It is important that facilities planning on using an injection well check with the
state environmental, health or natural resources office listed in the UIC section of
Appendix A before constructing a new injection well or modifying their existing
injection well to make sure that all of the necessary permits or approvals are in
place before proceeding.
1.
Almost every EPA program (e.g., Superfund, pesticides, etc.) has some
measure of ground-water protection written into its legislation. Therefore, by
carrying out these programmatic responsibilities, each program office
contributes to EPA's overall ground-water protection effort.
2.
Since formation of EPA's Office of Ground Water Protection in 1984, the
Agency has placed the primary responsibility for developing, implementing,
and coordinating ground-water protection programs with the states.
The following is a summary of the most significant programs that might affect
ethanol plant operations:
Ground Water Protection Strategy - In 1984, EPA released its "Ground Water
Protection Strategy" in which the Agency proposed a national program to protect
ground water as a resource. Among its provisions was the principle that states are
responsible for managing the ground-water resources within their own borders. In
response to the national strategy, each state developed its own ground-water
protection strategy.
Source Water Protection Program - The Safe Drinking Water Act Amendments
of 1996 added another initiative, the Source Water Protection Program. The
program goes beyond just protecting ground water, which previous legislation has
created, to encompass protecting the source of every communitys water supply,
regardless of whether it is from ground water or surface water. All of the states in
Region 7 have an approved state source water protection programs.
It is important that facilities check with the state environmental, health or natural
resources office listed in the Source Water Protection Program section of Appendix
A prior to construction or modification to ensure that they will comply with any
source water protection requirements before proceeding.
Pollution prevention opportunities might differ from facility to facility, even if the
processes are similar. A company should conduct a pollution prevention
assessment to determine the benefits and opportunities available.
1.
Planning and Organization,
2.
Assessment,
3.
Feasibility Analysis, and
4.
Implementation.
http://www.p2pays.org/ref/01/00370.pdf
http://www.epa.gov/chp/project_resources/ethanol.htm.
An ethanol plant might need to obtain an air permit for day-to-day facility
operations. There are two types of operating permits:
The potential emissions from the plant will determine whether a facility will obtain
a major or minor operating permit.
The federal operating permit program, known as the Title V program, was created
by the Clean Air Act Amendments of 1990 and was designed to create a one stop
permit. The Title V operating permit compiles all of the applicable state and
federal regulatory
requirements, existing
construction permit
provisions, and
recordkeeping,
reporting, testing, and
monitoring
requirements into one
permit. The intention
behind listing everything
in one permit is to help
facilities maintain
compliance. It is common
for a facility to have
several construction permits for several pieces of equipment and it is difficult to
keep track of all of the requirements in each permit. One permit with all of the
facilitys requirements is intended to make it easier to track the requirements.
An ethanol plant would need to obtain a Title V operating permit if the plant
has the potential-to-emit quantities greater than 100 tons per year of any
criteria pollutant or is a major source of hazardous air pollutants
(See Page 1-13).
An ethanol plant can limit the facilitys potential to emit criteria pollutants to less
than 100 tons per year by accepting operational limits in a minor source operating
permit. However, minor sources have less operational flexibility because they
must keep their emissions below the major source threshold. Minor operating
permits are not subject to review by EPA.
2 - 2
at:
(800) 424-9346
or
(800) 553-7672
(TDD).
If one or more processes in an ethanol facility are subject to this rule, they will
probably need to develop an accident prevention program and address emergency
response issues. In order to develop the correct level of prevention program,
facility personnel will need to determine whether it is subject to Program 1,
Program 2, or Program 3. Appendix C will help you determine your program level
and corresponding responsibilities.
2 - 3
Chlorine 2,500
2 - 4
Planning Requirements
Section 302 of the Emergency Planning Community Right to Know Act requires
facilities with regulated chemicals above threshold planning quantities to notify the
state emergency response commission and the local emergency planning
committee within 60 days after they first receive a shipment or produce the
substance on-site.
Section 303 of the Emergency Planning Community Right to Know Act requires
local emergency planning committees to prepare comprehensive emergency
response plans. These plans should identify all facilities subject to comply with
this section, including ethanol facilities. These plans should also describe
emergency response procedures, training schedules, and practice schedules,
amongst other requirements.
Reporting Releases
Section 304 of the Emergency Planning Community Right to Know Act requires
regulated facilities to report a release of an extremely hazardous substance.
Ethanol production facilities are subject to spill reporting provisions if they release
more than a reportable quantity of a chemical. A list of chemicals and their
reportable quantities can be found at 40 CFR 302.4 and 355. A few examples of
chemicals that might be spilled or released from an ethanol production facility are
listed in the table, below.
Chlorine 10
2 - 5
2 - 6
Section 311 of the Emergency Planning Community Right to Know Act requires
the facility to have material safety data sheets on site for regulated chemicals that
exceed certain quantities and to submit copies to their state emergency response
commission, local emergency planning committee, and local fire department within
three months of chemical receipt or production. This is a one-time submission that
is updated only if new chemicals are stored and/or produced.
The purpose of the Tier II report is to provide emergency responders and the public
with important information on the hazardous chemicals in their communities for
the purpose of enhancing community awareness of chemical hazards and
facilitating development of state and local emergency response plans.
Practically all ethanol production facilities need to file a Tier II report. A list of
extremely hazardous chemicals and their threshold planning quantities can be
found at 40 CFR Part 355. There is no formal list of hazardous chemicals, but a
good rule of thumb is any chemical that has an OSHA Material Safety Data Sheet
(MSDS) could be reportable if storage exceeds 10,000 pounds. A few examples of
chemicals that an ethanol production facility may be required to file a Tier II form
are listed in the table, below.
Chlorine 100
Propane 10,000
Ethanol 10,000
NOx 100
Section 313 of the Emergency Planning Community Right to Know Act requires
facilities to report air emission quantities for chemicals exceeding listed amounts.
Each year these facilities are required to complete a Toxic Release Inventory (TRI)
Form A or Form R report and submit it to EPA. The purpose of the inventory is to
gather information on toxic chemicals so that the public and government can assess
the hazards of toxic releases in a community.
A list of more than 600 regulated chemicals can be found at 40 CFR 372. A few
examples of toxic chemicals released into the environment as reported by ethanol
manufacturers in Region 7 include ammonia, chlorine, nitrates, benzene,
cyclohexane, n-hexane, acetaldehyde, barium compounds, zinc compounds and
copper compounds. While the range of quantities released varies from facility to
facility, most toxic chemicals released during ethanol manufacturing are below 500
pounds per year.
If a facility meets all of the following criteria, then it must submit a TRI Form A or
Form R report to EPA by July 1 for toxic chemical releases which occurred during
the preceding calendar year:
2 - 10
Water is required at ethanol facilities for processing and for the production of
steam that is typically used in biomass pretreatment and ethanol distillation
processes. An ethanol plants wastewater is typically comprised of cooling tower
blowdown, boiler blowdown, and water softener discharge.
Wastewater from an ethanol plant can be disposed of in various ways. The method
of disposal determines what kind of permit is needed and what permitting authority
will issue it. In general, there are three alternatives for the disposal of wastewater:
Land application.
An NPDES permit regulates the amount of pollutants that can be discharged. The
permit writer will establish limits in that permit that protect the water quality of the
receiving water body. In addition to numeric effluent limitations, NPDES permits
will include monitoring, reporting, and recordkeeping requirements. Permits are
required whether or not on-site treatment occurs.
General Information,
For further information, refer to the state contact information in Appendix A under
CWA National Pollutant Discharge Elimination System (NPDES) Permits.
To determine if your city has a pretreatment program, either contact the citys
Public Works Department or contact the state pretreatment coordinator listed in
Appendix A under CWA Pretreatment Program.
2 - 12
For discharges to cities that are too small to implement a pretreatment program, the
state is the permitting authority. Depending on the state in which the plant is
located, you may be required to obtain a discharge permit or enter into a treatment
agreement with the municipality receiving the wastewater. To determine if you
will be required to apply for a permit, contact the state pretreatment coordinator
listed in Appendix A under CWA Pretreatment Program.
There are no federal regulations that apply to wastewater that is properly disposed
of by land application. However, land application of wastewater may be covered
by an NPDES permit
(stormwater or non-
stormwater) where it is
determined that pollutants run
off the application site to a
water of the United States. In
Region 7, states administer
programs that establish
proper land application
procedures to ensure that
wastewaters are applied at
agronomic rates, which are
rates that plants assimilate the
nutrients in the wastewater
without pollutant loss through
runoff. For more information about land application, contact the same state
officials that are listed in Appendix A under CWA National Pollutant Discharge
Elimination System (NPDES) Permits.
2 - 13
Industrial activity by its very nature can create pollution problems if not controlled.
Therefore, industrial facilities must obtain stormwater permits during plant
operation in addition to construction permits described in Section 1.3.
2 - 14
1) It is non-transportation
related;
3) There is a reasonable
expectation of an oil discharge
into or upon navigable waters
of the United States or
adjoining shorelines.
Storage capacity for oil of any kind in any form as defined in 40 CFR 112.2.
This includes oils such as gasoline and natural gasoline, which are often stored
on-site and used to denature ethanol, and ethanol that has been denatured with
oil.
2 - 15
When calculating oil storage capacity, the facility should not include:
Completely buried tanks that are subject to all the technical requirements of the
Underground Storage Tank Regulation (40 CFR 280), or technical
requirements of a state underground storage tank program approved under
40 CFR 281;
Parts of the facility used exclusively for wastewater treatment and not used to
satisfy any requirements of 40 CFR 112.
A reasonable expectation that the facility could discharge oil into or upon
navigable waters is based upon the location of the ethanol plant. The plants
location relative to streams, ponds,
ditches, storm or sanitary sewers,
wetlands, mud flats, sand flats, or
navigable waters should be considered.
The distance to navigable waters, volume
of materials stored, worst-case weather
conditions, drainage patterns, land
contours, soil conditions, etc., must be
taken into account. Man-made features
such as dikes, equipment or other
structures which may serve to restrain,
hinder, contain, or prevent an oil Photo Courtesy of Coast Guard
Facilities that are subject to the oil spill prevention regulation must prepare and
implement a spill prevention plan. The owner or operator of a facility existing on
or before Aug. 16, 2002, must maintain and implement the current plan and amend
and implement a plan revised to meet the 2002 rule amendments on or before
July 1, 2009. The owner or operator of a facility that became operational after
Aug. 16, 2002 must prepare and implement a plan on or before July 1, 2009 or
before beginning operations, whichever is later.
A facility that transfers oil over water to or from vessels and has a total oil storage
capacity of 42,000 gallons or more, and a facility that has a total storage capacity
of 1 million gallons or more, might be subject to the Facility Response Plan
requirements in 40 CFR 112, Subpart D. For additional information about Facility
Response Plans, see Appendix F, Do I need a facility Response Plan?
2 - 17
Routine testing Your drinking water must be tested for compliance with all
the federal and state drinking water standards. The cost of sampling and
analysis are the responsibility of the water system owner. Standards are set for
microbiological contaminants, man-made chemicals and pesticides, naturally-
occurring inorganics, and contamination caused by human activity, such as lead
and nitrates. There are also requirements for operational testing, record-
keeping and reporting, correction of sanitary deficiencies, and notification of
the public when problems occur.
It is important that facilities planning to develop their own water supply or modify
their existing source(s) first check with the state environmental, health or natural
resources office listed in the public water system supervision section of Appendix
A to ensure that all of the necessary permits are in place before proceeding.
If your facility is using water from an existing water supply system such as a
municipal water supply for your drinking water source, then the Public Water
System Supervision Program does not apply. However, if you also plan to use this
existing water supply as the source of cooling or industrial processing water, you
should check with the system operator to make sure the system can provide a
sufficient quantity of water for your needs. This is important for industries such as
ethanol plants, which need large quantities of water for manufacturing or
processing.
The Underground Injection Control program regulates wells that are used by cities,
agriculture, business and industry to inject fluids underground for disposal,
hydrocarbon production and storage, or mineral recovery. The program defines an
injection well as any bored, drilled or driven shaft or dug hole, where the depth is
greater than the largest surface dimension and is used to discharge fluids
underground or a subsurface fluid distribution system. This definition covers a
wide variety of injection practices that range from technically sophisticated and
highly monitored wells that pump fluids into isolated formations up to two miles
below the Earth's surface to the far more numerous on-site drainage systems, such
as septic systems, cesspools, and storm water wells which discharge fluids a few
feet underground. The program requirements are designed to ensure that injected
fluids stay within the wells and the intended injection zones and do not endanger
underground drinking water sources. No injection is authorized without approval
from the appropriate regulatory authority.
it has an on-site sanitary waste disposal system (eg. septic system) that
serves or has the capacity to serve 20 or more people; or
it has an on-site sanitary waste disposal system that is receiving other than a
solely sanitary waste stream regardless of its capacity; or
Facilities that discharge fluids to streams, ponds, lagoons, or treatment facilities are
not subject to the provisions of the underground injection program but could be
regulated by the Clean Water Act.
All ethanol plants will probably generate some quantities of hazardous waste.
However, the hazardous waste being generated might not be directly related to the
production of ethanol. Hazardous waste generation at ethanol plants is mostly
associated with other plant operations that might result in waste streams such as
gasoline, spent solvents, lab packs, various paint wastes, used oil, waste ethanol
(D001), waste lamps, and batteries. There are usually no hazardous waste
permitting requirements for ethanol plants that generate hazardous waste.
The full definition of underground storage tanks, including the exemptions, can be
found in 40 CFR 280.12. The term regulated substance is defined in
40 CFR 280.12. It includes any substance defined in Section 101(14) of the
Comprehensive Environmental Response, Compensation and Liability Act of 1980
and petroleum, including crude oil or any fraction thereof that is liquid at standard
conditions of temperature and pressure. Regulated substance includes substances
such as gasoline, diesel, fuel oils, petroleum solvents, and used oils. It does not
include any substance regulated as a hazardous waste under subtitle C.
This appendix includes a list of contact and resource information for Region 7. Contact
information for locations outside of Region 7 may be found at www.envcap.org/statetools/
or by contacting the EPA Region where the facility is located.
For additional information about the Clean Air Act (CAA), please contact:
Law
Regulation Description Contacts
Citing
Iowa Department of Natural Resources:
- Dave Phelps (515) 281-8189
CAA 40 CFR 52.21 Air Permits
- Web site: www.iowacleanair.com
Joe Cothern
(913) 551-7148
cothern.joe@epa.gov
Don Carlson
Kansas Department of (785) 296-5547 www.kdheks.gov/indust/
Health and Environment dcarlson@kdhe.state.ks.us
Rob Morrison
Missouri Department (573) 526-0991 www.dnr.mo.gov/env/wpp/permits/index.html
of Natural Resources
rob.morrison@dnr.mo.gov
Donna Garden
Nebraska Department (402) 471-1367 www.deq.state.ne.us
of Environmental Quality donna.garden@ndeq.state.ne.us
Pradip Dalal
(913) 551-7454 http://cfpub.epa.gov/npdes/home.cfm?
EPA dalal.pradip@epa.gov program_id=45
CWA Stormwater
District\State
Contact Internet Site
Coverage
Iowa and Missouri U.S. Army
Rock Island District
Rock Island Dist. Corps of Engineers www2.mvr.usace.army.mil/
Covers Iowa except area Rock Island, Ill. Regulatory/default.cfm
covered by the Omaha (309) 794-5376
District and northeastern
part of Missouri
Nebraska U.S. Army
www.nwo.usace.army.mil/html/od-
Omaha District Omaha District Corps of Engineers
r/regwebpg.htm
Omaha Office (402) 896-0896
Nebraska U.S. Army
www.nwo.usace.army.mil/html/od-
Omaha District Omaha District Corps of Engineers
r/regwebpg.htm
Kearney Office (308) 234-1403
U.S. Army
Missouri St. Louis District Corps of Engineers
www.mvs.usace.army.mil/
St. Louis District permits/permits.html
(314) 331-8574
U.S. Army Corps of Engineers
Northwestern Division
Missouri Kansas City District
www.nwk.usace.army.mil/
Kansas City District regulatory/regulatory.htm
Kansas City, Mo.
(816) 389-3990
U.S. Army Corps of Engineers
Kansas Northwestern Division
Kansas City District www.nwk.usace.army.mil/
Kansas City District
regulatory/regulatory.htm
Marquette, Kan.
Northern Kansas Area (785) 546-2130
U.S. Army Corps of Engineers
Kansas Northwestern Division
Kansas City District www.nwk.usace.army.mil/
Kansas City District
regulatory/regulatory.htm
El Dorado, Kan.
Southern Kansas Area (316) 322-8247
U.S. Army Corps of Engineers
Memphis District www.mvm.usace.army.mil/
Memphis District
Memphis, Tenn. regulatory/memphis.htm
(901) 544-0736
U.S. Army Corps of Engineers
Little Rock District www.swl.usace.army.mil/
Little Rock District regulatory
Little Rock, Ark.
(501) 324-5295
Additional information on CWA wetlands is available from the following at the EPA
Region 7 office:
Law and
Subject Who to Notify When
Regulation
CWA
National Response Center
CWA Release
40 CFR 117
Notification of Slug
CWA
Notification of
injection program
System
State Statutes
State Laws
State Environmental Agency Varies
Law and
Subject Who to Notify When
Regulation
-State Emergency Response Commissions (SERC)s:
Iowa Department of Natural Resources
(515) 281-8694
(402) 471-4545
State
State Laws State Environmental Agency Varies
Statutes
Tier II
Admini- Tier II Reporting Contact
stration
Submit to:
Iowa Adam Broughton Adam Broughton
Department of Emergency Response Unit Phone: (515) 281-8694
Natural Iowa Department of Natural Resources Fax: (515) 725-0218
Resources 401 SW 7th Street, Suite I emergencyresponse@dnr.state.ia.us
Des Moines, IA 50309
Web site:
www.kdhe.state.ks.us/bar/index.html
Submit to:
Kansas State Emergency Response Commission
Kimberly Steves
Kansas Topeka, KS 66612-1366
ksteves@kdhe.state.ks.us
Division of
Phone: (785) 296-4359
Information regarding the reporting process,
Health and
Fax: (785) 296-1545
instructions, or blank forms may be requested by
Environment
writing to:
Topeka, KS 66612-1366
(785) 296-1691
Submit to:
Missouri Emergency Response Commission
For more information, including
Missouri 2302 Militia Drive
sample forms and instructions, visit
Emergency
PO Box 3133
http://hazmat.dps.mo.gov/
Response
Jefferson City, MO 65102
(800) 780-1014
Commission
Or (573) 526-9239
Special Instructions:
Fax - (573) 526-9261
http://hazmat.dps.state.mo.us
Submit to:
Nebraska Nebraska Deptartment of Environmental Quality Mark Lohnes
Department of 1200 N Street, Suite 400 (402) 471-4251
Environmental P.O. Box 98922 mark.lohnes@ndeq.state.ne.us
Quality Lincoln, NE 68509
www.deq.state.ne.us/EAD.nsf/Pages/NEPCRA
Submit to:
For TRI reporting questions, you may
Iowa Adam Broughton
contact Adam Broughton at:
Department Emergency Response Unit
Phone: (515) 281-8694
of Natural Iowa Department of Natural Resources
Fax: (515) 725-0218
Resources 401 SW 7th Street, Suite I
emergencyresponse@dnr.state.ia.us
Des Moines, IA 50309
Submit to:
Kimberly Steves, Environmental Health Scientist
Department of
Health and
Topeka, KS 66612-1366
Fax: (785) 296-1545
Environment
Web Site:
www.kdhe.state.ks.us
Mark Lohnes
Department of
1200 N. Street, Suite 400
mark.lohnes@ndeq.state.ne.us
Environmental
Lincoln, NE 68509
Phone: (402) 471-4251
Quality
Fax: (402) 471-2909
Web Site:
www.deq.state.ne.us
Edwin G. Buckner, PE
RCRA Enforcement and
EPA State Programs Branch www.epa.gov
(913) 551-7621
buckner.edwin@epa.gov
Steve Sturgess
Missouri Department of (573) 751-1187 www.dnr.mo.gov/env/wpp/dw-index.htm
Natural Resources steve.sturgess@dnr.mo.gov
Jack Daniel
Nebraska Department of (402) 471-0510 www.hhs.state.ne.us/enh/pwsindex.htm
Health and Human Services jack.daniel@hhs.state.ne.us
Mary Mindrup
(913) 551-7431
EPA mindrup.maryp@epa.gov www.epa.gov/safewater/pws/index.html
David Miesbach
Nebraska (402) 471-4982
Department of www.deq.state.ne.us/GroundW.nsf/Pages/UIC
david.miesbach@ndeq.state.ne.us
Environmental Quality
Kurt Hildebrandt
(913) 551- 7413 www.epa.gov/safewater/uic
EPA hildebrandt.kurt@epa.gov
http://www.epa.gov/oilspill/guidance.htm.
P2 Internet Sites:
- EPA Region 7 Pollution Prevention www.epa.gov/region07/p2
- EPA Pollution Prevention www.epa.gov/p2
- Pollution Prevention Resource Information Center www.p2ric.org/
- EnviroSense http://es.epa.gov/
1. Systematic Planning;
3. Consideration of
Counterterrorism Measures.
Ethanol fire drill using 500 gallons
Response actions during the first few minutes of release are the most critical.
They should not only be planned, but also well rehearsed to minimize the effects
of a release. Facilities that take a comprehensive approach in developing a
facility-specific emergency response program are better prepared to respond in a
release event.
Systematic Planning
A facility should select a team of employees who bring expertise from each
of its functional areas. Ideally, the team members should also have varying
degrees of emergency response responsibilities and experience within and
outside the facility. A three-member team for a small facility might involve
a couple of process operators who are cross-trained as emergency
responders. A large facility with its own response team might need
representatives from the following areas:
Maintenance;
Security;
Members of the development team should collect, review, and maintain copies
of the following types of facility-specific materials:
Site plans;
The team might also identify related program materials from the following
sources:
Federal, state, and local government safety, training, and planning efforts.
Facilities are responsible under this General Duty Clause for ensuring that any
process release can be effectively handled. Facilities that rely on local responders
must determine if the local responders have suitable equipment and training. If
they do not, the facility must take steps to meet any needs (e.g., develop facility
response capabilities, develop mutual aid agreements, hire response contractors,
partially fund local responders).
The team or a leadership subset should use the information collected to assess
compliance with each emergency response program element of EPAs Risk
Management Program (40 CFR Part 68). This assessment will expose gaps
that exist.
hurricanes;
Introduction
Background Information
Facility Overview
Supporting Annexes
Some facilities have developed posters and signs with information for
employees and emergency responders. These materials should be effective
for the intended people (e.g., other languages, appropriate reading level,
locations of signs relative to hazards and emergency exits).
For example: the significance of the position of the windsock and its
implications relative to evacuation routes should be discussed with all staff
members so that an orderly emergency response will result.
EMS personnel should also participate in annual disaster drills and emergency
plan reviews, keeping in mind lessons learned during other emergency events.
Your state emergency response commission and your local emergency planning
committee play extremely important roles in emergency response planning. Their
roles are:
State Commission:
Establish local emergency planning districts,
Local Committee:
Prepare and maintain a comprehensive emergency response plan for the
district,
Before specifically considering CT, a facility should ensure their emergency plan
is up to date. Simply adding CT materials to an outdated plan will not produce an
effective emergency plan. For example, review of an emergency plan sometimes
identifies outdated emergency contact information or process modification and
facility construction that had not yet been addressed. After updating an
emergency plan, a facility should consider adding information and procedures
related to potential terrorist threats.
The National Response Center is the sole federal point of contact for
reporting chemical spills/releases. NRC duty officers take reports of actual
or potential terrorism, then link emergency calls to the following:
2. Response Functions
3. Hazards Analysis
4. Mitigation Procedures
Inspect Emergency
emergency equipment.
The process has not had an accidental release of a regulated substance that
resulted in death or injury, or required restoration of an environmental
receptor, within five years of the date you submit your facilitys risk
management plan;
It has any process that does not meet criteria for Program 1 or Program 3.
It has any covered process that does not meet the eligibility requirements
for Program 1 and the process is subject to the Occupational Safety and
Health process safety management standard (29 CFR 1910.119). Most
ethanol plants that handle risk management plan toxic chemicals are
Program 3 facilities.
If you arent sure whether this rule applies to your facility or which
REQUIREMENTS
C1 of 10
HAZARD ASSESSMENT
One worst-case representative of all
Worst-Case regulated toxics and one
One for each covered process.
Scenario representative of all regulated
flammables.
One for each regulated toxic and one
Alternative Release None required
representative of all flammables.
Provide information for accidental
releases from covered processes that
resulted in:
Five-Year Program 1 facilities have 1. On-site deaths, injuries, or
Accident History certified no accidents. significant property damage; or
2. Off-site deaths, injuries,
evacuations, sheltering in place,
property damage, or
environmental damage.
Prevention
None required Required
Program
Submit a Risk
Required Required
Management Plan
REQUIREMENTS
C2 of 10
Management System
Hazard Assessment
The hazard assessment referred to in the table on the previous page must include a
worst-case scenario for Program 1 facilities and an off-site consequence analysis
for each covered Program 2 or 3 process as follows:
REQUIREMENTS
C3 of 10
Prevention Program
Assessing all hazards that could affect the public or the environment off
site;
REQUIREMENTS
C4 of 10
REQUIREMENTS
C5 of 10
Date and Time. Date and approximate time when accidental release
began.
Chemical(s).
Release Event. Identify cause of release event (e.g., gas release, liquid
spill, evaporation, fire, explosion).
REQUIREMENTS
C6 of 10
A facility has the option to coordinate its response with its LEPC, with the intent
that the facility employees will not be responding to an accidental release (40
CFR 68.90(b)). If this is the case, then the emergency response program must
have mechanisms in place to notify emergency responders and the facility is not
required to comply with the requirements of 40 CFR 68.95, as described
below.
Procedures for informing the public and local emergency response agencies
about accidental releases;
REQUIREMENTS
C7 of 10
Registration
A facility must update and resubmit its risk management plan within six months
of:
4. The date of an accident that meets the criteria for the five-year accident
history after April 9, 2004.
REQUIREMENTS
C8 of 10
A facility must update and resubmit its risk management plan within one month
of a change of the emergency contact information.
Facilities no longer covered under the risk management plan rule are required by
40 CFR 68.190(c to de-register with EPA within six months of the time it is no
longer covered. (See Chapter 8 of RMP*Submit User 2004 Manual. The RMP
Submit 2004 software can be downloaded at: http://www.epa.gov/ceppo/. Click on
Chemical Preparedness and Prevention, Tools & Resources, Databases and
Software, EPA Databases and Software, then RMP Submit 2004.)
REQUIREMENTS
C9 of 10
Best practices in the ethanol industry are still being established. According to the
American Petroleum Institute, the oil and natural gas industry is becoming an
increasingly safer place to work, despite a job environment that often involves
heavy equipment, hazardous materials, high temperatures and high pressure
equipment. This is reflected by a declining rate of illnesses and injuries For
more safety tips, please visit: http://www.api.org.
Risk management plan guidance documents and training modules are available
through the following sources:
REQUIREMENTS
C10 of 10
Below is a list of common acronyms and their meaning you might encounter. You can
also find a more comprehensive list of environmental terms and acronyms at
http://www.epa.gov/OCEPAterms/.
D1 of 2
D2 of 2
A federal agency will prepare a public record of its decision after a final environmental
impact statement is prepared. The public record will address how the findings, including
consideration of alternatives, were incorporated into the agency's decision-making
process.
E1 of 1
Your facility meets the substantial harm criteria outlined in 40 CFR 112.20(f)
(1); or
F1 of 7
F2 of 7
You can determine whether your facility meets the over water transfer criterion by
answering the following question:
Does your facility transfer oil over water to or from vessels, and does
In order to answer the above question you must first know the following:
Your facilitys oil storage capacity can be determined by adding the capacities of
all oil storage containers (e.g., drums, tanks, electrical equipment), including
aboveground containers with a capacity of 55 gallons or more.
transportation on water.
If you answered yes to the above question, your facility might pose a risk of substantial
harm and you must prepare and submit a facility response plan to the regional
administrator.
If you answered no to the above question, you must consider whether your facility
meets any of the criteria for facilities with 1 million gallons or more of oil storage
capacity. (Please see the next section.)
You can determine whether your facility meets the oil storage capacity criterion by
answering the following question:
Does your facility have a total oil storage capacity of 1 million gallons or
more?
Secondary containment
environments
Reportable discharge of 10,000 gallons or more within the last five years
F3 of 7
If you answered no to the above question, you do not have to prepare and submit a
facility response plan except at the discretion of the EPA regional administrator. Instead,
you are required to prepare a certification that your facility is not a substantial harm
facility (40 CFR 112, Appendix C, Attachment C-II) and maintain this at your facility
along with your spill prevention, control and countermeasures plan.
Secondary Containment
You can determine whether your facility meets the secondary containment criterion by
answering the following question:
Does your facility lack secondary containment large enough to hold the
capacity of the largest aboveground storage tank within each storage area
If you answered yes to the above question, your facility is a substantial harm
facility, and you have to prepare and submit a facility response plan.
If you answered no to the above question, you do not have to prepare and submit a
facility response plan because of the secondary containment criterion. You must consider
whether your facility meets other specified factors. (Please see the next section.)
You can determine whether your facility meets the fish and wildlife and sensitive
environments criterion by answering the following question:
Could a discharge from your facility cause injury to fish and wildlife and
sensitive environments?
Calculate the distance that discharged oil could travel from your facility before it
is contained. You should use the planning distance calculations for fish and
wildlife and sensitive environments to identify all fish and wildlife and sensitive
environments within the planning distance. (See 40 CFR 112, Appendix C,
Attachment C-III.)
F4 of 7
If you answered yes to the above question, your facility is a substantial harm
facility, and you have to prepare and submit a facility response plan.
If you answered no to the above question, you do not have to prepare and submit a
facility response plan because of the fish and wildlife and sensitive environments
criterion. You must consider whether your facility meets other specified factors. (Please
see the next section.)
F5 of 7
You can determine whether your facility meets the public drinking water intake criterion
by answering the following question:
To answer the above question, you must first determine the following:
You must calculate the distance that discharged oil could travel from your facility
before it is contained. To do so, you may use the formulas provided in the
regulation. (See 40 CFR 112, Appendix C, Attachment C-III.)
distribution facilities.
To locate a downstream public drinking water intake, consult the appropriate area
contingency plan, and contact the municipal or county water authority for each
area that might be affected by an oil discharge from your facility.
If you answered yes to the above question, your facility is a substantial harm
facility, and you have to prepare and submit a facility response plan.
If you answered no to the above question, you do not have to prepare and submit a
facility response plan because of the public drinking water intake criterion. You must
consider whether your facility meets other specified factors. (Please see the next
section.)
F6 of 7
You can determine whether your facility meets the reportable discharges criterion by
answering the following question:
If you answered yes to the above question, your facility is a substantial harm
facility, and you have to prepare and submit a facility response plan.
If none of the substantial harm criteria applies to your facility, as described in 40 CFR
112.20(e) and in Appendix C, paragraph 3.0 of Part 112, you must complete and
maintain at your facility, within your spill prevention, control and countermeasure plan, a
certification form indicating that you have determined that your facility is not a
substantial harm facility. If you decide to use an alternative formula (i.e., one that is
not described above or in 40 CFR 112.20(f)(1)(ii)(B) or (C)) to determine that your
facility does not meet the substantial harm criteria, you must attach documentation to the
certification form that demonstrates the reliability and analytical soundness of the
comparable formula and you must notify the EPA regional administrator in writing that
you used an alternative formula.
F7 of 7