Energies: Current State of Technology of Fuel Cell Power Systems For Autonomous Underwater Vehicles

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Energies 2014, 7, 4676-4693; doi:10.

3390/en7074676

energies
ISSN 1996-1073
www.mdpi.com/journal/energies
Article
Current State of Technology of Fuel Cell Power Systems for
Autonomous Underwater Vehicles
Alejandro Mendez
1
, Teresa J. Leo
1,
* and Miguel A. Herreros
2

1
Department of Sistemas Ocenicos y Navales, ETSI Navales, Universidad Politcnica de Madrid,
28040 Madrid, Spain; E-Mail: alejandro.mendezg@alumnos.upm.es
2
Department of Arquitectura y Construccin Navales, ETSI Navales, Universidad Politcnica de Madrid,
28040 Madrid, Spain; E-Mail: miguelangel.herreros@upm.es

This paper is based on another one that was previously presented at the 1st International
e-Conference on Energies, 1431 March 2014.
* Author to whom correspondence should be addressed; E-Mail: teresa.leo.mena@upm.es;
Tel.: +34-913-367-147; Fax: +34-915-442-149.
Received: 3 June 2014; in revised form: 8 July 2014 / Accepted: 16 July 2014 /
Published: 22 July 2014

Abstract: Autonomous Underwater Vehicles (AUVs) are vehicles that are primarily used
to accomplish oceanographic research data collection and auxiliary offshore tasks. At the
present time, they are usually powered by lithium-ion secondary batteries, which have
insufficient specific energies. In order for this technology to achieve a mature state,
increased endurance is required. Fuel cell power systems have been identified as an
effective means to achieve this endurance but no implementation in a commercial device
has yet been realized. This paper summarizes the current state of development of the
technology in this field of research. First, the most adequate type of fuel cell for this
application is discussed. The prototypes and design concepts of AUVs powered by fuel
cells which have been developed in the last few years are described. Possible commercial
and experimental fuel cell stack options are analyzed, examining solutions adopted in the
analogous aerial vehicle applications, as well as the underwater ones, to see if integration
in an AUV is feasible. Current solutions in oxygen and hydrogen storage systems are
overviewed and energy density is objectively compared between battery power systems
and fuel cell power systems for AUVs. A couple of system configuration solutions are
described including the necessary lithium-ion battery hybrid system. Finally, some closing
remarks on the future of this technology are given.
OPEN ACCESS
Energies 2014, 7 4677


Keywords: AUV; UUV; fuel cell; underwater vehicle; hydrogen

1. Introduction
Autonomous Underwater Vehicles (AUVs) are unmanned underwater vehicles that are used to
accomplish various missions autonomously, most commonly imaging of the ocean environment and
ocean floor, oceanographic data collection, offshore applications and submarine cable applications [1,2].
There are two general types of AUVs. The torpedo-like survey AUVs and the highly maneuverable
hovering AUVs. The former are the ones that are dealt with in this article, due to the fact that there has
not been any documented development of fuel cell technology on hovering AUVs.
When a mission for an AUV is proposed the first thing that must be done is to define the
requirements that will enable the vehicle to accomplish the tasks that are required for said mission.
These requirements generally include the nominal speed, the maximum depth, the payload necessary
for the mission and the endurance. All of these requirements affect each other, but the endurance
is directly related to the energy storage, that is part of the power system, and is limited by the
existing technology
The standard power system currently used in AUVs is secondary batteries (lithium-ion), and in
some cases aluminum semi fuel cells are also used [3]. Secondary batteries are a simple and relatively
inexpensive solution, and provide enough power for current applications. However, they suffer from
limited energy capacity, which greatly limits their autonomy and the missions they can be used for.
Fuel cells, unlike batteries, store their reactants outside of their structure and have as much energy as
reactant can be stored. For this reason they have greater specific energies than batteries, as will be
shown, even when taking into account the weight from the additional components such as storage
tanks, pumps and blowers.
Despite the benefits they would provide, there are currently no commercial AUVs powered by a
fuel cell system, or a hybrid fuel cell system. This is because the technology still requires further
development, and this has a significant associated cost. Because of this reason, and also because of the
strategic importance of this technology, there recently has been a concentrated effort from the Office
of Naval Research, of the United States Department of the Navy to fund through contracts and research
grants several companies to achieve progress in this area. In addition, fuel cells have been successfully
implemented in UAV (unmanned aerial vehicle) and in automobiles, both of which have similarities to
AUVs in that they also require a compact integrated power system.
There have been several prototypes and concept designs which are discussed in this article. Greater
emphasis will be given to the proton exchange membrane fuel cells (PEMFC) because they have been
successfully demonstrated for use in AUVs. Direct methanol fuel cells (DMFC) have low energies,
solid oxide fuel cells (SOFC) require temperatures that are too high, alkaline fuel cells require
ultra-pure hydrogen and oxygen so they are not developed for commercial use, and the phosphoric acid
fuel cells (PAFC) and molten carbonate fuel cells (MCFC) are not compact enough [4].
This manuscript describes the state of the art of fuel cell technology in AUVs. The most important
fuel cell powered AUV prototypes and bench fuel cell power systems will be described. Current fuel
Energies 2014, 7 4678


cell stack technology and reactant storage systems will be explored. Afterwards, hybrid secondary
battery-fuel cell power system options will be evaluated and an overview of the complete power
system configuration will be given. Finally, specific and volumetric energy parameters of the entire
power system, for different storage system configurations will be estimated for a typical AUV,
using data collected by different stack manufacturers and research publications.
2. AUV Fuel Cell Power Systems: Current Situation
2.1. Prototypes
2.1.1. Urashima (JAMSTEC and Mitsubishi Heavy Industries)
Urashima was an experimental AUV powered by PEFC and lithium ion cells as an auxiliary power
source. It started development in 1998 by the Japan Agency for Maritime Earth Science and
Technology (JAMSTEC) [5]. The AUV weighs 10 tons, is 10 m in length and 1.4 m in diameter. It has
a 300 km cruise capacity and can dive up to 3500 m depth [6]. Its fuel cell power system has two
2 kW fuel cell stacks at 120 V [7], and was developed by Mitsubishi Heavy Industries Ltd. (Tokyo,
Japan) [5]. It is part of a hybrid system, which also has a 30 Ah lithium-ion battery, used for dealing
with peak power demands that the fuel cell cannot supply [8].
The system configuration includes the fuel cell stacks, humidifier, heat exchanger, reaction water
tank, oxygen tank and fuel tank. There are two pressure vessels, one for the fuel cell stack and its
auxiliaries which is made of titanium alloy [9] and the other one for the hydrogen fuel as AB5 alloy
metal hydride (for each 1 kg of hydrogen, 66 kg of hydride is required) [10]. There is also an
independent pressurized oxygen tank. The metal hydride releases the hydrogen using heat transferred
from the stack through water [6].
In September 2003, a 21 km six hour sea trial was done using fuel cell only [6]. In June 2004,
a 220 km, 44 h cruise was done in four trips among transponders [11]. In February 2005, a 56 h 317 km
autonomous cruise was performed continuously at a depth of 800 m, with an average speed of 1.55 m/s
(3 knots) [9].
The developers had identified certain issues with the Urashima power system, which they are
currently working to improve. These included slow start up, the blowers for reactant circulation did not
work well, there was considerable hydrogen leakage and the system was too large [12].
2.1.2. Second Generation Long Cruising AUV (JAMSTEC and Mitsubishi Heavy Industries)
It is a second generation long cruising range AUV currently being developed by JAMSTEC. It was
required by its developers to possess 600 h endurance, 3000 km range, 10 kW power and 5000 kWh
capacity. A desktop PEMFC prototype for the AUVs fuel cell power system has been developed. This
fuel cell system is called HEML (High-Efficiency Multi-Less) FC, and is a novel concept that changes
and is supposed to improve from standard fuel cell stack design and operation. This is done by
eliminating recirculation blowers and replacing them by valves. Eliminating also humidifiers by
improving materials and MEA composition, and reducing hydrogen leakage [13].
Energies 2014, 7 4679


The desktop model was completed in 2009 to test the new concept. An operation time of over
1000 h was accomplished as well as operating efficiencies of 60%. In October 2010 a fuel cell system
prototype consisting of two 150 W fuel cell stacks, an electronic controller and a pressure vessel was
completed, and in January 2011 it achieved 600 h continuous electric power generation. In March
2011, a successful sea-trial of the prototype installed on a deep tow was done, with success in
generating electricity during the sea trial [13]. In November 2013, the fuel cell system was successfully
installed on JAMSTECs Deep Tow research towing unit. The system was submerged to a depth of
180 m and supplied power to two units of observation equipment. The developers reported that power
was supplied stably and that the equipment being supplied functioned without interruption [14].
2.1.3. DeepC
DeepC is an experimental German AUV development project conducted by a consortium
coordinated by STN ATLAS Elektronik. It was funded by the German Federal Ministry for Education
and Research [5]. It had requirements of two to four tons weight, 2 m/s (4 knots) cruising speed, 60 h
endurance and 4000 m mission depth. The vehicle has three connected hulls, two identical propulsion
hulls and one for the payload [15].
This AUV possessed a hybrid battery-PEM fuel cell system, with the batteries taking peak loads.
The fuel cell system consisted of two 30 cell stacks with a total output of 3.6 kW and each located
inside each of the two propulsion hulls. Due to safety reasons they are located in a gas proof chamber
with a pressure relief valve. The hydrogen and oxygen are stored in pressure gas bottles of 250 bar and
350 bar allowing for a total electrical energy of 140 kWh to be obtained [15].
2.1.4. IDEF Ifremer
It is an experimental AUV powered by PEM fuel cell adapted to an existing AUV. It weighs
1.6 tons and has 6 m length. The fuel cell system was designed by the HELION firm, a subsidiary of
the Areva group. The PEM fuel cell stack is composed of 63 cells, and produces 1.5 kW. Its system
efficiency including auxiliaries consumption is 55%. Hydrogen and oxygen gases are recirculated and
full reactant conversion is achieved. The system is located in an aluminum pressure vessel which is
pressurized with nitrogen so as to prevent gas leaks and explosive hydrogen-oxygen mixtures. The
hydrogen and oxygen are stored in 50 L pressure gas bottles, two 300 bar hydrogen ones, and a
250 bar oxygen, allowing for a total electrical energy of 36 kWh. The IDEF AUV has a 300 km range,
it dived seven times in October 2009, with gas refills before each one, reaching depths of 400 m [16].
2.2. Conceptual Designs
2.2.1. Underwater Glider Dragon
Underwater glider designed by the School of Mechanical Engineering Tianjin University to surpass
the performance of established commercial gliders, including nominal power ratings and endurances.
It would weigh 70 kg, have 2.3 m length, 22 cm diameter, and PEMFC volume of 6500 cm
3
.
A test was done to determine the efficiency and feasibility of a PEMFC system, using a stack
that has a 12 V voltage rating and a power rating of 100 W. It has a 32 cm
2
Nafion membrane.
Energies 2014, 7 4680


Two hydrogen and two oxygen tanks were adopted. The excess gas of the fuel cell would recirculate in
the system by jet pump and the reacted water would be collected [17]. There has not been a prototype
of this system yet.
2.2.2. Seahorse
Pennsylvania State University ARL (Applied Research Laboratory) has investigated the use of fuel
cells for undersea propulsion applications, particularly for AUVs and for hybrid torpedoes. They have
worked on a 400 W PEM Cell at ARLs Energy Science and Power Systems Division. ARL has a large
battery powered AUV called Seahorse that may be converted to fuel cell operation. The fuel cell
system was never operated in the Seahorse [18,19]. Oxygen would be supplied by converting lithium
perchlorate (LiClO
4
) to oxygen using technology developed by ARL/Penn State.
2.3. Office of Naval Research (ONR) Large AUV Development
The ONR is an office of the United States Department of the Navy that is in charge of the U.S Navy
and Marine Corps science and technology programs. They have been involved in AUV development
since the technologys early stages. They have been especially interested in developing a large AUV,
capable of possessing greater endurances [20]. For this very reason, they have also invested resources
in developing fuel cell power systems for AUVs. One of the ways they have done this is by
announcing a formal request for proposals on technology for Long Endurance Undersea Vehicles, in
March 2011. The winners of the awards would be provided with grants or contracts for project
funding. The total funding amount was 18 million dollars over a five-year period. The projects would
be developed following a three phase scheme in which a series of project objectives would have to be
achieved. In this document they also set forth objective metrics for the power system which would also
have to be achieved. Among these metrics were a 20 W/L nominal power density requirement, 76.2 cm
energy section max length, an energy content of 68 kWh, and an endurance of over 30 h [21]. Table 1
includes projects the ONR has been involved in.
Table 1. Projects the Office of Naval Research (ONR) has been involved in
(based on [4,2232]).
Project Description
UTC Aerospace Systems
for 44-in AUV
In the early nineties, UTC, then called International Fuel Cells (IFC) sponsored by the
Defense Advanced Research Projects Agency (DARPA) developed a 4 stack,
15 kW PEM fuel cell system for a 1.12 m (44 inch) diameter AUV. The system was tested
in the laboratory for over 500 h. It was never used at sea [4,22,23].
UTC Aerospace Systems
AUV Power and energy
storage system
UTC is developing an energy dense, air independent rechargeable energy system for a Large
AUV (LAUV), based on a PEM fuel cell developed for an air independent submarine
propulsion system. It uses cryogenic energy storage system and a simplified balance of
plant, with minimal moving parts [24].

Energies 2014, 7 4681


Table 1. Cont.
Project Description
UTC S-80 Fuel Cell
Power Module (FCPM)
UTC has developed a power system that provides 300 kW of electrical power from a PEM
Fuel Cell on Navantias S-80 Air Independent Propulsion (AIP) submarine for the Spanish
Navy. It uses reformed bio-ethanol for H
2
, and oxygen from liquid oxygen [25].
API Engineering LLC
and Nextech Materials
Oxygen source for air
independent AUV SOFC
power sources
A 2.5 kW SOFC power system for a 54 cm (21 inch) AUV is currently being developed by
API Engineering LLC and Nextech Materials, through the grants obtained from ONR in
2011, worth more than $500,000. The system is based on an innovative oxygen source that
uses an aqueous chlorate solution for its oxygen storage composition. The integrated system
requires less than 19 inches of length to provide 50 kg of deliverable oxygen in a 54 cm
AUV [26,27].
General Atomics and
Infinity LAUV
General Atomics funded by the ONR is in the Phase 1 of the development of a
5 kW PEM power system which comprises a timespan from July 2012 until January 2014.
The air independent PEM stack is being developed by Infinity, and features passive water
removal which allows for a compact and simple balance of plant directly to the fuel cell
stack and plates [28]. They have successfully tested a 1 kW stack during a 40 h continuous
test [29].
Lynntech, Inc LAUV
Lynntech is developing a long endurance air-independent fuel cell power system for a 54 cm
(21 inch) diameter AUV using a proprietary chemical hydride fuel source and hydrogen
peroxide for oxidant acquisition [30].
Sierra Lobo Cryogenic
Reactants Energy
System
Sierra Lobo was awarded a $3.9 million contract from the ONR to develop, fabricate, and
test a fuel cell and cryogenic reactants energy system. The system uses liquid hydrogen as
the fuel, liquid oxygen as the oxidizer, and a Teledyne Energy Systems PEM fuel cell for
power generation [31].
FuelCell Energy, Inc
SOFC power system
for LAUV
FuelCell Energy, Inc. received in 2012 a $3.8 million contract award from the ONR, for a
SOFC-Battery power system for large displacement undersea vehicle propulsion. The
Hybrid SOFC-Battery system would be capable of generating 1800 kWh of electricity
during a 70 day mission according to reference [32]. It will use liquid fuel and be
self-contained with no reliance on external air. This 18 month phase I award will fund
development and laboratory testing of the SOFC propulsion system.
2.4. Fuel Cell Stacks
The fuel cell stack is the power generating component of the power system. Given the mass and
volume constraints imposed on an AUV, specific energy and energy density arise as two of the main
design variables.
Due to the fact that there hasnt yet been a commercial fuel cell powered AUV, there also hasnt
been a commercial fuel cell stack developed specifically for this application. Instead, standard stacks
have been adapted for use in AUVs in some cases, such as the IDEF AUV and the Seahorse concept.
Another example of a stack adapted for an underwater application is the 3 kW one that Ballard
supplied the Perry PC-14 submersible and the Ballard-Mark-V 35-cell 5 kW PEM stack which has
been studied for AUVs [33]. In other cases, novel designs have been used. This is the case of the stack
that JAMSTEC is currently developing, and also of a few firms which have received financing from
the defense industry and are also developing their own systems, as has been mentioned in the
previous section.
Energies 2014, 7 4682


This lack of maturity for this concrete application entails a lack of application specific data with
which to assess system performance. This can nevertheless be bridged by comparing data from similar
applications such as fuel celled powered UAVs (unmanned aerial vehicle) and fuel cell hydrogen
vehicles to a lesser extent.
UAVs impose very similar conditions on their power systems in terms of mass and volume
constraints, with a big difference being that UAVs do not require oxygen storage due to the availability
of oxygen in the atmosphere. Several small size UAVs, powered by fuel cells, exist. They are usually
lighter than a similar AUV would be, due to the higher speeds required, and thus have higher thrust
power/total vehicle mass ratio. Despite this fact, since AUVs are currently operated at slow speeds
12.5 m/s (25 knots) the power range of both types of vehicles is similar (approximately from 200 W
to 3 kW).
Fuel cell powered UAV systems that stand out due to their performance include Protonex
Technologys Protonex ProCore fuel cell system, used to power the UAV Puma, which flew
continuously for more than 7 h [34]. More impressive is the UAV-H500 PEM fuel cell power system
they have developed. This system is a commercial variant of the one used to set a flight record of over
26 h in an Ion Tiger UAV [35]. In addition, Horizon Fuel Cell Technologies high-performance
hydrogen fuel cell power system which is used in the UAV Boomerang, a 9 kg electric UAV, is able to
fly for more than 9 h [34]. A summary of the fuel cell powered UAV application can be found in [36].
In Table 2 several stack specifications of commercial fuel cells and fuel cells used in AUVs are
presented. Most of these commercial stacks, include integrated balance of plant components such as
blowers, cooling system, valves. Additionally, some are self-humidified and some of them are scalable
to different power needs.
Table 2. Fuel cell stack specifications (based on [19,3646]).
Manufacturer/Model
Fuel Cell
Weight (kg)
Fuel Cell Dimensions
(mm) or volume (L)
Specific
Power
(W/kg)
Power
Density
(W/L)
Remarks
Stacks used in AUV prototypes
UBZM Gmbh-BZ100
(1200W standard)
0.32 kg/cell
(with 48 cells)
(180520) 145 125 78 127

UBZM Gmbh related to
ZSW, manufacturer of
DeepC PEMFC
MHI Urashima FC Stack 150
Stacks used in UAV applications
ProtonexProCore 2.7 2.8

74 71.5 Spider Lion UAV
Protonex UAV C-250 1.2 1.35 208 185
Protonex Ion Tiger
UAV (NRL)
1 550
EnergyOr 310-XLE 3.95 78.5
Mass includes H2 fuel and
storage. Radiant Coral
Technologies UAV
EnergyOr 210-XLE 3.65 57.5
Horizon AEROSTACK
A-1000 PEM FUEL CELL
1.75 275 135 120 571 224
With fan and casing,
self-humidified

Energies 2014, 7 4683


Table 2. Cont.
Manufacturer/Model
Fuel Cell
Weight (kg)
Fuel Cell Dimensions
(mm) or volume (L)
Specific
Power
(W/kg)
Power
Density
(W/L)
Remarks
Horizon AEROSTACK A-500
PEM FUEL CELL 500W
1.15 192 107 150 434 162
With fan and casing,
self-humidified
Horizon AEROSTACK A-200
PEM FUEL CELL 200W
0.5 120 80 75 400 278
With fan and casing,
self-humidified
Horizon Stack for HyFish UAV 3 334
United Technologies Research
Center (UTRC) Stack for FC
rotorcraft
1.78 675
Lynntech Gen IV 5 kW stack
for Helios UAV
20 19 250 263
Commercial stacks
Ballard FCgen-1020ACS
0.196 kg/cell
56 cell
standard
(110495) 103 351 230 192
Air cooled. Scalable.
Self-humidifying membrane.
Horizon H-500XP 5.8 150 203 52 86 316
With blower, H2 supply and
purge valve
Horizon H-1000XP 5.9 203 104 264 169 179
With blower, H2 supply and
purge valve
Horizon H-300 2.79 118 262 94 108 103
With fan and casing,
self-humidified, and blower
Horizon H-500 2.52 268 130 122.5 196 117
Blower, electronic valves,
self-humidified, fan,
Horizon H-1000 4 268 219 122.5 250 139
Blower, electronic valves,
self-humidified, fan,
Horizon H-2000 10 350 183 303 200 103
Blower, electronic valves,
self-humidified, fan,
AREVA Helion 20 kW 160 690 470 335 125 182
Nedstack HP 2.0 15 217 194 288 133 18.4
Nedstack HP 5.0 22 353 194 288 227 254
Siemens BZM 34 kW 650 480 480 1450 52 102
Stack + balance of
plant components
Siemens BZM 120 kW 900 500 530 1760 133 257
Stack + balance of
plant components
2.5. Storage
Reactant storage is an important issue in an AUV power system, due to the fact that it has a direct
impact on the endurance, and on the efficiency of the power plant itself. More efficient storage designs
are those which have higher specific energy and energy density. Hydrogen and oxygen storage for fuel
cell powered AUVs is an active field research, as evidenced by the ONRs funded research projects
previously mentioned in this article. In this section the main reactant storage options used in AUVs
will be overviewed, and representative energy content values will be presented.
Energies 2014, 7 4684


High pressure gas storage of reactants is a straightforward simple solution to the storage problem
but it imposes big, heavy containers. Liquid storage of the reactants on the other hand is more efficient
and has the lowest weight and volume but presents difficulties like required low temperatures, high
cost and greater system complexity. Metal hydride storage can be a simple solution for hydrogen
storage, but these are the heaviest due to the fact that there are atoms other than hydrogen that are part
of the system [47].
2.5.1. Hydrogen Storage
In Table 3, ranges of specific energies and energy densities of different hydrogen storage systems
obtained in [19] are shown. An important issue that arises when dealing with hydrogen is the fact that
hydrogen leakage is very high. This fact has to be taken into account for safety reasons when designing
the system in order to reduce it to acceptable levels [47].
2.5.1.1. Gaseous Hydrogen
Compressed Hydrogen offers the simplest and least expensive solution to fuel storage and it also
has the advantage of not needing preprocessing [48]. Since gaseous hydrogen has a very low energy
density, high pressures are usually applied (up to 700 bar), in order to maximize hydrogen content [19],
which requires the use of very heavy storage vessels in order to avoid mechanical failure due to the
high pressures. The hydrogen bottles can be made out of high strength steel, aluminum or composite
fiber [48]. For compressed hydrogen specific energies vary between 1.1 kWh/kg and 1.7 kWh/kg and
energy densities between 0.5 kWh/L and 0.7 kWh/L [19]. Operational difficulties that must be taken
into account are that tanks suffer from hydrogen embritlement after several recharges [4], and are an
explosive hazard if not handled properly [49].
2.5.1.2. Liquid Hydrogen
Liquid Hydrogen has a higher energy density than gaseous, but still low. They require very low
temperatures, less than 20.15 K, so they must be stored in cryogenic Dewars, which are multi shell
flasks using an evacuated interstitial space and multi-layer Mylar insulation to reduce heat transfer
through the flask and avoid boil off of the gas. Fuel processing in this case is through gas
vaporization [48], this occurs naturally to a certain extent due to heat transfer from the fuel cell and the
surrounding ocean water. As long as the natural vaporization rate is less than that of consumption the
system is stable and no fuel would need to be wasted [19]. In addition, boil-off losses happen during
refueling and storage [47]. This storage method has several issues, like high cost and complexity and
safety concerns [48]. There are also logistics issues, such as limited availability and refueling, which
requires special equipment and skills [47]. With this solution values of 1.6 kWh/kg and 1.2 kWh/L
with liquid hydrogen storage have been obtained [19].
2.5.1.3. Hydrocarbons and Chemical Sources
Hydrocarbon sources are cheap, common hydrogen carrying liquids, but add complexity, weight
and volume. The most common options are methanol, kerosene and diesel. They require being
Energies 2014, 7 4685


reformed with steam at high temperatures. The steam carries hydrogen (70%75%), CO
2
, CO, and water.
Sulfur must be completely removed from the fuel so as to not affect the reformer catalyst. CO must
also be removed to avoid the fuel cells platinum catalysts degradation. Hydrodesulphurization for
eliminating the sulfur content requires the use of expensive a complex reforming equipment. An issue
that arises in undersea reforming systems is that carbon dioxide produced by the reforming process
must be disposed of or stored [48].
2.5.1.4. Rechargeable Metal Hydrides
They are metal alloys that react reversibly with hydrogen, storing it at low pressures [50]. By
heating the hydride hydrogen is liberated from the alloys structure. Metal hydrides have a good energy
density but a very low specific energy. Usually is less than 3.6% hydrogen by weight. Their heavy
weight limits their applications, making them feasible only for large vehicles. They suffer from high
cost and sensitivity to water, carbon monoxide, and oxygen [48] and also lose storage efficiency over
multiple cycles [4]. Hydrogen production rates can be controlled making it the safest medium.
2.5.1.5. Chemical Hydrides
Chemical hydrides are used to generate H
2
either by hydrolysis or by pyrolysis, which involves
applying heat. They have the advantages of having high hydrogen content and of not requiring a
complex and voluminous feed regulation system. Examples of compounds that use hydrolysis are
NaBH
4
, NaAlH
4
, LiBH
4
and LiH, while NH
3
BH
3
and NH
4
BH
4
are examples of compounds that suffer
decomposition by pyrolysis. Reference [51] compares several hydrogen storage options and based on
the available manufacturer data determined that a NH3BH3 solution (which is still under development)
gave the greatest endurances of all, presenting values of 0.11 kg H
2
/kg.
Table 3. Hydrogen storage system energy content (based on [19]).
Storage Type Energy Density (Wh/L) Specific Energy (Wh/kg)
Compressed gas 560700 11001710
Liquid H
2
1220 1620
Metal Hydrides 7701670 280520
2.5.2. Oxygen Storage
Unlike in conventional fuel cells, underwater fuel cells require oxygen storage because atmospheric
air is not available. This oxygen usage increases stack performance two to three times. In addition,
excess oxygen is required to carry away the product water from the stack, which has to be considered
when sizing this system [51]. Oxygen storage will be evaluated in terms of energy density and specific
energy [19] and ranges of values for different storage systems from the same reference are shown in
Table 4. The oxygen storage can be evaluated in terms of these parameters, taking into account the
stoichiometric ratio of the fuel cell reaction.

Energies 2014, 7 4686


2.5.2.1. Chemical Storage
Oxygen is released due to an exothermic chemical reaction, through thermal or catalytic processes.
Its less efficient because there are non-oxygen atoms and also unreleased oxygen, so it possesses a
higher system weight [4,49]. Common chemicals that can be used include Sodium chlorate, lithium
perchlorate, other oxyhalides, or peroxides/superoxides. This solution presents the problem that highly
oxidizing chemicals must be stored and dealt with when refueling [4].
2.5.2.2. Pure Oxygen
High pressure oxygen has the simplest delivery mechanism. Required tank wall thickness increases
with pressure, which in turn decreases the energy density advantages [4]. Tanks up to 690 bar can be
commercially obtained. Lightweight compressed oxygen tanks for transport applications are not as
developed as hydrogen due to the fact that air is usually used in terrestrial hydrogen vehicles.
Compressed oxygen storage energy density values ranges between 0.5 kWh/L and 1 kWh/L, and
specific energy content reaches values up to 2 kWh/kg [19]. This technology has been successfully
implemented in the AUV Urashima prototype [52].
2.5.2.3. Cryogenic Liquid Oxygen (LOX)
LOX is the optimal solution for limited space applications. There is higher complexity due to the
need for safety conditions in handling and storage. Refueling requires special equipment and skills [4].
The boiling point of oxygen is 90.18 K and boiling losses when refueling and during storage must
be considered [47].
Sierra Lobo, Inc., designed a LOX storage system prototype for a 54 cm (21 inch) diameter AUV [19].
It works with a 1 kW output PEM fuel cell and stores 50 kg of LOX at 94 K. The system dimensions
are 0.94 m long, 0.32 m in diameter and 13.6 kg weight when empty (and 63.6 kg when full) [10].
Table 4. Oxygen storage system energy content (based on [19]).
Storage Type Energy Density (Wh/L) Specific Energy (Wh/kg)
LOX 27802980 29003300
Chemical 13402090 11701300
Compressed 6001090 7701680
2.6. System Configuration
The fuel cell power system is composed of a fuel cell stack, oxygen and hydrogen supply systems,
the cooling system, the humidification system and the electrical subsystems. The oxygen and hydrogen
supply systems are composed of the storage mechanism, pressure regulator, humidifier, water
separator and recirculation pump. If the reactants are fed passively they do not require feeding
regulation because they are fed as they are consumed in the stack. Otherwise a blower and regulation
are used. Recirculation improves the reactant usage and removes impurities and condensing water
from the stack. Humidification of reactants is necessary to maintain the MEA hydrated. Water and heat
required for humidification is supplied by the cooling system [47].
Energies 2014, 7 4687


The cooling system can use a fan for lower power fuel cells or drive water through the stack using
pumps to transfer heat from the fuel cell to the hull [51]. It uses the liquid water that is separated from
the reactants and is collected in the tank for the cooling of the stack and for humidification of both
reactant gases. The heat from the stack is rejected through a water cooled heat exchanger [47].
The electrical subsystem includes a constant voltage regulation system, a smart battery charger, an
electricity supply regulation system and a startup battery [51]. The voltage generated from the fuel cell
ranges from the open circuit voltage to the nominal cell voltage and requires a DC/DC power
conditioner for constant voltage electrical components such as pumps, solenoids and the controller
typically operate on 24 V DC The startup battery energizes the solenoid valves on the fuel and oxidant
supply lines. When the fuel cell receives fuel and oxygen it takes over and recharges the battery [47,53].
2.7. Hybrid Systems
In an AUV, a hybrid fuel cell-battery system would improve upon the performance of either of
these separate systems. Both components would be of smaller dimensions and would operate with
higher efficiency because neither would have to provide full power [51]. On the other hand, in a
non-hybrid fuel cell system the stack must be sized to the maximum required power.
In a hybrid fuel cell system two different system configurations are identified. In a first scenario the
fuel cell constantly supplies power at maximum efficiency. When power demand is low the fuel cell
recharges the batteries and supplies power to the load. The batteries provide the remaining power at
times of high demand [10,47]. This approach presents the issue that when the battery provides all the
power to the load, the fuel cell is switched out of the circuit with it still consuming oxidant and
fuel [10]. In a second scenario, all the power would be supplied from the batteries, while the fuel cell is
used for recharging [47,54].
3. Estimation of Energy Parameters on an Example AUV
Knowing the energy parameters of different storage systems, the mass and volume of the complete
power plant can be taken into account to calculate the energy parameters of the whole power system,
for different storage solutions [55]. These estimates can be then compared to standard energy storage
solutions, as are lithium-ion batteries.
In this section a couple different storage solutions, which are considered to be representative, will
be analyzed as an example. In order to do this a 1 kW AUV with 72-h endurance will be examined,
which is accurate for medium to large size vehicles. In this example, two different Horizon fuel cell
stacks and three different storage combinations are used, thus providing six power system
combinations. The Horizon fuel cell stacks are the Aerostack A1000 PEM and the Horizon H-1000,
which were included in Table 2. They were chosen because of the high quality of Horizon fuel cells,
and their proven experience in multiple fuel cell powered UAVs. They also cover a wide power
density range, from 250 to 570 W/kg, and so are considered to be a representative enough sample for
this estimate. Both of these fuel cells have some integrated balance of plant components, but in order
to account for the closed cycle design necessary for the air independent propulsion requirement
imposed on AUVs, total balance of plant component weight and size have been estimated from data
taken from [56]. In this study, an integrated fuel cell power system was designed to be adapted into an
Energies 2014, 7 4688


existing military vehicle with great volume and weight constraints. This data is considered to be a good
estimation because a hypothetical commercial fuel cell system would be designed optimizing these
same parameters. The weight and volume of the total fuel cell system can be seen in Table 5.
Table 5. Example stacks weight and volume.
Fuel Cell Stack Fuel Cell System Weight (kg) Fuel Cell System Volume (L)
Aerostack A1000 PEM 31.75 37.20
Horizon H-1000 34.00 40.00
The reactant storage combinations considered were liquid hydrogen/liquid oxygen, compressed
hydrogen/compressed oxygen and metal hydride/compressed oxygen.
The energy density (ED) and specific energy (SE) of the complete storage system are calculated,
assuming the storage system components are sized to the same energy, as [19]:
2 2
2 2
H O
SS
H O
ED ED
ED
ED ED


(1)
2 2
2 2
H O
SS
H O
SE SE
SE
SE SE

(2)
For the systems energy density and specific energy calculation, the supposition is made that the
whole systems mass and weight is the sum of that of the storage and the fuel cell system. The results
are presented in Table 6.
Table 6. Energy density and specific energy for storage and total system.
Storage Combination
Storage System Total System (Aeropack) Total System (H-1000)
ED (Wh/L) SE (Wh/kg) ED (Wh/L) SE (Wh/kg) ED (Wh/L) SE (Wh/kg)
LOX/LH2 850 1052 590 719 577 703
GasO
2
/Gas H
2
323 624 277 489 274 482
Met Hydri/Gas O
2
428 271 350 242 346 240
Lithium-Ion batteries have energy densities between 329 Wh/L and 490 Wh/L and specific energys
between 165 Wh/kg and 207 Wh/kg [57,58]. From the approximate results shown in Table 6, it can be
seen that for these combinations, there is significant improvement on the specific energy of the fuel
cell power systems, when compared to lithium ion ones, and the energy density is also higher in the
optimal cryogenic storage solution, and has similar values to lithium-ion in the remaining ones.
4. Conclusions
The current development of fuel cell powered AUVs has been overviewed. Interested researchers in
this field can find the information given very useful to gain insight into the fuel cell AUVs technology
development. It has been shown how limited progress has been in this field due to the complexity and
high costs involved. Only two fuel cell AUV prototypes have been constructed, and several bench
AUV fuel cell power systems have been tested out of the water.
Energies 2014, 7 4689


At this time interest in autonomous unmanned systems is high and in the case of AUVs, in order for
serious development to be achieved, system endurance must necessarily be increased. Fuel cell
powered systems have been shown to have higher specific energies than the more commonly used
lithium-ion batteries, and also comparable to higher energy densities depending on the specific storage
system used. This fact has been evidenced by its successful implementation in UAVs, breaking several
flight endurance records. And it has also been evidenced in the multi-million dollar investment of the
US Navy in the development of these systems. A lot of work needs to be done in compact, lightweight,
efficient integrated fuel cell power systems, with a special focus on reactant storage optimization.
One of the avenues to achieving greater endurances is through the use of hybrid fuel cell-secondary
battery power systems that allow the possibility to increase the overall efficiency while reducing
component sizes.
Acknowledgments
The authors gratefully acknowledge the Spanish Ministry of Economy and Competitiveness
(Project ENE2011-28735-C02-02) and the E.T.S.I. Navales from the Universidad Politcnica de
Madrid (Spain) for its support and help. The authors gratefully acknowledge ETSI Navales (UPM)
Library Staff for the help received.
Author Contributions
All co-authors have made important contributions to the conception and design of this paper,
as well as to the acquisition, analysis or interpretation of data. The review task for data collection has
been thoroughly and especially carried out by Mr. Alejandro Mendez. All of the co-authors have been
also involved in drafting and revising the manuscript, so that everyone has given final approval of the
current version to be published in Energies.
Conflicts of Interest
The authors declare no conflict of interest.
References
1. Yuh, J.; Marani, G.; Blidberg, D.R. Applications of marine robotic vehicles. Intel. Serv. Robot.
2011, 4, 221231.
2. Lee, Y.-D.E.; George, R.A. High-resolution geological AUV survey results across a portion of the
eastern Sigsbee Escarpment. Am. Assoc. Pet. Geol. Bull. 2004, 88, 747764.
3. Bradley, A.M.; Feezor, M.D.; Singh, H.; Sorrell, F.Y. Power systems for autonomous underwater
vehicles. IEEE J. Ocean. Eng. 2001, 26, 526538.
4. Swider-Lyons, K.E.; Carlin, R.T.; Rosenfeld, R.L.; Nowak, R.J. Technical issues and
opportunities for fuel cell development for autonomous underwater vehicles. In Proceedings of the
2002 Workshop on Autonomous Underwater Vehicles, Taibei, Taiwan, 21 June 2002; pp. 6164.
Energies 2014, 7 4690


5. Wang, X.; Shang, J.; Luo, Z.; Tang, L.; Zhang, X.; Li, J. Reviews of power systems and
environmental energy conversion for unmanned underwater vehicles. Renew. Sustain. Energy Rev.
2012, 16, 19581970.
6. Sawa, T.; Aoki, T.; Yamamoto, I.; Tsukioka, S.; Yoshida, H.; Hyakudome, T.; Ishibashi, S.;
Inada, T.; Kabeno, T.; Sasamoto, R.; et al. Performance of the fuel cell underwater vehicle
urashima. Acoust. Sci. Technol. 2005, 26, 249257.
7. Ishibashi, S.; Aoki, T.; Tsukioka, S.; Yoshida, H.; Inada, T.; Kabeno, T.; Maeda, T.;
Hirokawa, K.; Yokoyama, K.; Tani, T.; et al. In An ocean going autonomous underwater vehicle
urashima equipped with a fuel cell. In Proceedings of 2004 International Symposium on
Underwater Technology, Taibei, Taiwan, 2023 April 2004; pp. 209214.
8. Yamamoto, I.; Aoki, T.; Tsukioka, S.; Yoshida, H.; Hyakudome, T.; Sawa, T.; Ishibashi, S.;
Inada, T.; Yokoyama, K.; Maeda, T.; et al. Fuel cell system of AUV Urashima. In Proceedings
of OCEANS '04. MTTS/IEEE TECHNO-OCEAN '04, Kobe, Japan, 912 November 2004;
pp. 17321737.
9. Maeda, T.; Ishiguro, S.; Yokoyama, K.; Hirokawa, K.; Hisatome, N.; Tani, T. Fuel Cell AUV
URASHIMA. Mitsubishi Heavy Ind. Tech. Rev. 2006, 43, 2425.
10. Griffiths, G.; Reece, D.; Blackmore, P.; Lain, M.; Mitchell, S.; Jamieson, J. Modeling hybrid
energy systems for use in AUVs. In Proceedings of the 14th Unmanned Untethered Submersible
Technology, Durham, NC, USA, 2124 August 2005; pp. 110.
11. Tsukioka, S.; Aoki, T.; Yamamoto, I.; Yoshida, H.; Hyakudome, T.; Ishibashi, S.; Sawa, T.;
Ishikawa, A.; Hirokawa, K. Results of a long distance experiment with the AUV Urashima.
In Proceedings of OCEANS '04. MTTS/IEEE TECHNO-OCEAN '04, Kobe, Japan, 912
November 2004; pp. 17141719.
12. Hyakudome, T.; Yoshida, H.; Nakatani, T.; Ohta, Y.; Tani, T.; Sugihara, K.; Moriga, T.;
Iwamoto, T.; Kawaharazaki, Y.; Oda, T.; et al. Development of fuel cell system for underwater
power source. In Proceedings of 2013 MTS/IEEE OCEANS-Bergen, Bergen, Norway, 1014
June 2013; pp. 16.
13. Yoshida, H.; Sawa, T.; Hyakudome, T.; Ishibashi, S.; Tani, T.; Iwata, M.; Moriga, T. The high
efficiency multi-less (HEML) fuel cellA high energy source for underwater vehicles, buoys,
and stations. In Proceedings of IEEE OCEANS, Santander, Spain, 69 June 2011; pp. 16.
14. Mitsubishi Heavy Industries, Ltd. Available online: https://www.mhi-global.com/ (accessed on 7
July 2014).
15. Hornfeld, W. DeepC: The new deep water AUV generation. In Proceedings of the 22nd
International Conference of Offshore Mechanics and Artic Engineering, Cancun, Mexico, 813
June 2003; pp. 713721.
16. Raugel, E.; Rigaud, V.; Lakeman, C. Sea experiment of a survey auv powered by a fuel cell
system. In Proceedings of 2010 IEEE/OES Autonomous Underwater Vehicles (AUV), Monterey,
CA, USA, 13 September 2010; pp. 13.
17. Wu, J.-G.; Chen, C.-Y.; Zhang, H.-W.; Xie, C.-G.; Wang, X.-M. In Study on well-to-drag
efficiency of pemfc powered glider. In Proceedings of 4th IEEE Conference on Industrial
Electronics and Applications, Xian, China, 2527 May 2009; pp. 19701975.
Energies 2014, 7 4691


18. The Pennsylvania State University, H2E Center. Available online: http://www.engr.psu.edu/h2e/
Professors/Dr._Klanchar,_Martin/Fuel%20Cell%20Systems%20for%20Undersea%20Propulsion%
20%20Dr.%20Klanchar.pdf (accessed on 31 May 2013).
19. Davies, K.L.; Moore, R.M. UUV FCEPS Technology Assessment and Design Process. Available
online: http://web41.its.hawaii.edu/www.hnei.hawaii.edu/sites/web41.its.hawaii.edu.www.hnei.
hawaii.edu/files/page/2010/06/UUV_FCEPS_ReportRev5.pdf (accessed on 18 July 2014).
20. U.S. Navy. The Navy Unmanned Undersea Vehicle (UUV) Master Plan. Available online:
http://www.navy.mil/navydata/technology/uuvmp.pdf (accessed on 18 July 2014).
21. Office of Naval Research. Long Endurance Undersea Vehicle Propulsion. Office of
Naval Research. Available online: https://www.fbo.gov/index?s=opportunity&mode=form&id=
012446f173f12e1d6ed4aba14e13f0f1&tab=core&_cview=1 (accessed on 18 July 2014).
22. Davies, K.L.; Moore, R.M. Unmanned underwater vehicle fuel cell energy/power system
technology assessment. IEEE J. Ocean. Eng. 2007, 32, 365372.
23. Rosenfeld, R.L.; Prokopius, P.R.; Meyer, A.P. In Fuel cell power system development for
submersibles. In Proceedings of the 1992 Symposium on Autonomous Underwater Vehicle
Technology, Washington, WA, USA, 23 June 1992; pp. 184188.
24. Roy, R. Development of a Power and Energy Storage System for Unmanned, Undersea Vehicles
(UUVs). Available online: http://www.fuelcellseminar.com/media/51137/b2b24-1.pdf (accessed
on 18 July 2014).
25. Utc aerospace systems. S-80 fuel cell power module. Available online: http://utcaerospacesystems.
com/cap/products/Pages/fuel-cell-power-module.aspx (accessed on 31 May 2014).
26. Swartz, S.L.; Arkenberg, G.B.; Thrun, L.B.; Sellers, C.T.; Emerick, J.S. SOFC-Based UUV
Energy System. Available online: http://www.fuelcellseminar.com/media/51140/b2b24-2.pdf
(accessed on 18 July 2014).
27. Presley, K.; Swartz, S. A New Oxygen Source for SOFC Based Power Systems for Long Duration
UUVs. Available online: http://www.fuelcellseminar.com/media/51275/b2b42-3.pdf (accessed on
18 July 2014).
28. Infinity-air independent fuel cells. Available online: http://www.infinityfuel.com/products/
air-independent-fuel-cells/ (accessed on 31 May 2014).
29. Bever, D. Energy and Power System for ONRs LDUUV Program. Available online:
http://www.fuelcellseminar.com/media/51188/b2b32-2-1.pdf (accessed on 18 July 2014).
30. Rhodes, J.; Fenimore, F.; Hennings, B. Long Endurance Fuel Cell Energy System For Unmanned
Undersea Vehicles. Available online: http://www.fuelcellseminar.com/media/51272/b2b42-2.pdf
(accessed on 18 July 2014).
31. Navy sbir/sttr. Available online: http://www.navysbir.com/docs/Sierra_FINAL_ONR.pdf
(accessed on 31 May 2014).
32. Fuelcell energy wins $3.8m contract for unmanned underwater vehicle power system.
Available online: http://www.unmannedsystemstechnology.com/2012/07/fuelcell-energy-wins-3-
8m-ontract-for-unmanned-underwater-vehicle-power-system/ (accessed on 31 May 2014).
33. Lee, C.-H.; Yang, J.-T. Modeling of the ballard-mark-v proton exchange membrane fuel cell with
power converters for applications in autonomous underwater vehicles. J. Power Sources 2011,
196, 38103823.
Energies 2014, 7 4692


34. Dudek, M.; Tomczyk, P.; Wygonik, P.; Korkosz, M.; Bogusz, P.; Lis, B. Hybrid fuel cellbattery
system as a main power unit for small Unmanned Aerial Vehicles (UAV). Int. J. Electrochem. Sci.
2013, 8, 84428463.
35. Protonex fuel cell power system for uav now commercially available. Available online:
http://www.fuelcelltoday.com/news-events/news-archive/2012/august/protonex-fuel-cell-power-
system-for-uav-now-commercially-available (accessed on 31 May 2014).
36. Gonzlez-Espasandn, .; Leo, T.J.; Navarro-Arvalo, E. Fuel Cells: A Real Option for
Unmanned Aerial Vehicles Propulsion. Sci. World J. 2014, 497642:1497642:12.
37. Ballard product. Available online: http://www.ballard.com/files/PDF/ProductPortfolio.pdf
(accessed on 31 May 2014).
38. Quintech catalog download. Available online: http://www.quintech.de/englisch/special-offer.php
(accessed on 31 May 2014).
39. Aps physicsIon tiger. Available online: http://www.aps.org/units/gera/meetings/march10/
upload/Swider-LyonsAPS3-14-10.pdf (accessed on 31 May 2014).
40. Energyor product brochure. Available online: http://www.energyor.com/energyor/pdf/
EnergyOr%20EPOD%20EO-310-XLE%20Product%20Brochure%20-%20Version%201.2.pdf
(accessed on 31 May 2014).
41. Horizon fuel cells aerostack borchure. Available online: http://media.wix.com/ugd/
047f54_5efe66b2736846bb8d25a7a326559c84.pdf (accessed on 31 May 2014).
42. Horizon fuel cells pem borchure. Available online: http://media.wix.com/ugd/047f54_
8728bcd6c312a384c513237545f289ae.pdf (accessed on 31 May 2014).
43. H-1000 fuel cell stackuser manual. Available online: http://media.wix.com/ugd/047f54_
86b712599dda8542adcca251d9904ca4.pdf (accessed on 31 May 2014).
44. 2000 w fuel cell stack user. Available online: http://media.wix.com/ugd/047f54_
86b712599dda8542adcca251d9904ca4.pdf (accessed on 31 May 2014).
45. Nedstack pem fuel cell product specifications. Available online: http://www.nedstack.com/
images/stories/products/nedstack_product-specifications-of-hp-stacks.pdf (accessed on 31 May 2014).
46. Zentrum fr Sonnenenergie- und Wasserstoff-Forschung (ZSW). Available online: http://www.
zsw-bw.de/en/topics/fuel-cells/components-and-stacks.html (accessed on 31 May 2014).
47. Barbir, F. In Proton exchange membrane fuel cell technology status and applicability for
propulsion of autonomous underwater vehicles. In Proceedings of the 2002 Workshop on
Autonomous Underwater Vehicles, Taibei, Taiwan, 21 June 2002; pp. 6569.
48. Baumert, R.; Epp, D. Hydrogen storage for fuel cell powered underwater vehicles, In Proceedings
of Engineering in Harmony with Ocean, Victoria, BC, Canada, 1821 October 1993; pp. 166171.
49. Gish, L. A. Design of an AUV Recharge System. Master Thesis, Massachusetts Institute of
Technology: Cambridge, MA, USA, June 2004.
50. Hyakudome, T. Design of autonomous underwater vehicle. Int. J. Adv. Robot. Syst. 2011, 8,
131139
51. Cai, Q.; Browning, D.J.; Brett, D.J.; Brandon, N.P. Hybrid fuel cell/battery power systems for
underwater vehicles. In Proceedings of 3rd SEAS DTC Technical Conference, Edinburgh,
UK, 2425 June 2008.
Energies 2014, 7 4693


52. Hyakudome, T.; Yoshida, H.; Tsukioka, S.; Sawa, T.; Ishibashia, S.; Aoki, T.; Iwamoto, T.;
Kawaharazaki, Y.; Muto, A.; Oda, T.; et al. High Efficiency Hydrogen and Oxygen Storage
System Development for Underwater Platforms Powered by Fuel Cell. ECS Trans. 2010, 26,
465474.
53. Hasvold, O.; Johansen, K.H. The alkaline aluminium hydrogen peroxide semi-fuel cell for the
hugin 3000 autonomous underwater vehicle. In Proceedings of the 2002 Workshop on
Autonomous Underwater Vehicles, Taibei, Taiwan, 18 June 2002; pp. 8994.
54. Cai, Q.; Brett, D.J.L.; Browning, D.; Brandon, N.P. A sizing-design methodology for hybrid fuel
cell power systems and its application to an unmanned underwater vehicle. J. Power Sour. 2010,
195, 65596569.
55. Takagawa, S. In Feasibility study on dmfc power source for underwater vehicles. In Proceedings
of Symposium on Underwater Technology and Workshop on Scientific Use of Submarine Cables
and Related Technologies, Tokyo, Japan, 1720 April 2007; pp. 326330.
56. Andrukaitis, E.E. Fuel Cells as Tactical Auxiliary Power in Military Vehicles. ECS Trans. 2010,
26, 445454.
57. Boston powerData sheets. Available online: http://www.boston-power.com/resources/
data-sheets (accessed on 31 May 2014).
58. Henderson, E.; Pantelakis, T.; An, E. Energy systems for FAU AUVs [autonomous underwater
vehicles]. In Proceedings of the 2002 Workshop on Autonomous Underwater Vehicles, Taibei,
Taiwan, 18 June 2002; pp. 510.
2014 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article
distributed under the terms and conditions of the Creative Commons Attribution license
(http://creativecommons.org/licenses/by/3.0/).

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