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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
34.1.5
1 Identification of the substance/mixture and of the company/
undertaking
Product identifier
Trade name: COOLANT-F
Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the preparation
Anticorrosion additive
Only for proper handling.
Details of the supplier of the safety data sheet
Manufacturer/Supplier:
MOTOREX AG LANGENTHAL
Schmiertechnik
Bern-Zrich-Strasse 31
CH-4901 Langenthal
Tel. +41 (0)62 919 74 74
Only representative in EU:
MOTOREX Deutschland AG, Bismarckstrasse 28, D-69198 Schriesheim
Further information obtainable from: msds@motorex.com
Emergency telephone number:
Toxicological Information Centre, CH-8028 Zurich,
info@toxi.ch,
T. +41 (0) 44 251 51 51
2 Hazards identification
Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Aquatic Chronic 3 H412 Harmful to aquatic life with long lasting effects.
Classification according to Directive 67/548/EEC or Directive 1999/45/EC
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General
Classification guideline for preparations of the EU" in the latest valid version.
Classification system:
The classification is according to the latest editions of the EU-lists, and extended by
company and literature data.
Label elements
Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance
on Hazardous Materials.
Risk phrases:
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Safety phrases:
60 This material and its container must be disposed of as hazardous waste.
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
(Contd. on page 2)
GB
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
Trade name: COOLANT-F
(Contd. of page 1)
34.1.5
Special labelling of certain preparations:
Contains Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo(4,5-d)imidazol-2,5(1H,3H)-
dion. May produce an allergic reaction.
Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
3 Composition/information on ingredients
Chemical characterization: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
Neutr. Prod. Annex V: carboxylic acid / tert. alkanolamine
neutralisation product
R52/53
Aquatic Chronic 3, H412
60-80%
CAS: 5395-50-6
EINECS: 226-408-0
Tetrahydro-1,3,4,6-tetrakis(hydroxymethyl)imidazo(4,5-d)
imidazol-2,5(1H,3H)-dion
Xi R43
Skin Sens. 1, H317
0.1-1.5%
Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
Description of first aid measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Remove residues with soap and water.
After eye contact: Rinse opened eye for several minutes under running water.
After swallowing:
Rinse mouth and drink large amount of water.
Consult a physician immediately.
Information for doctor:
Most important symptoms and effects, both acute and delayed
No further relevant information available.
Indication of any immediate medical attention and special treatment needed
No further relevant information available.
5 Firefighting measures
Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Special hazards arising from the substance or mixture
No further relevant information available.
Advice for firefighters
Protective equipment: No special measures required.
GB
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
Trade name: COOLANT-F
(Contd. of page 2)
34.1.5
6 Accidental release measures
Personal precautions, protective equipment and emergency procedures Not required.
Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Dilute with plenty of water.
Do not allow to enter sewers/ surface or ground water.
Methods and material for containment and cleaning up:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders,
sawdust).
Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
7 Handling and storage
Handling:
Precautions for safe handling No special precautions are necessary if used correctly.
Information about fire - and explosion protection: No special measures required.
Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: No special requirements.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Store containers closed and protect against rain, dust, heat and other atmospheric
influences.
Avoid freezing.
Specific end use(s) No further relevant information available.
8 Exposure controls/personal protection
Additional information about design of technical facilities: No further data; see item 7.
Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that
have to be monitored at the workplace.
Additional information: The lists valid during the making were used as basis.
Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Wash hands before breaks and at the end of work.
Respiratory protection: Not required.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the
preparation.
Due to missing tests no recommendation to the glove material can be given for the product/
the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion
and the degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on
further marks of quality and varies from manufacturer to manufacturer. As the product is a
(Contd. on page 4)
GB
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
Trade name: COOLANT-F
(Contd. of page 3)
34.1.5
preparation of several substances, the resistance of the glove material can not be
calculated in advance and has therefore to be checked prior to the application.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective
gloves and has to be observed.
Eye protection: Goggles recommended during refilling
9 Physical and chemical properties
Information on basic physical and chemical properties
General Information
Appearance:
Form: Fluid
Colour: yellow fluorescent
Odour: Characteristic
Odour threshold: Not determined.
pH-value at 20C: 8.5 (DIN 51369)
Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 100C (DIN EN ISO 3405)
Flash point: Not applicable.
Flammability (solid, gaseous): Not applicable.
Ignition temperature:
Decomposition temperature: Not determined.
Self-igniting: Product is not selfigniting.
Danger of explosion: Product does not present an expl osi on
hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapour pressure at 20C: 23 hPa
Density at 20C: 1.155 g/cm (ASTM D 4052)
Relative density Not determined.
Vapour density Not determined.
Evaporation rate Not determined.
Solubility in / Miscibility with
water: Fully miscible.
Segregation coefficient (n-octanol/water): Not determined.
Viscosity: <3 mm/s @40 C
Dynamic: Not determined.
Kinematic: <3 mm/s @40 C (DIN 51562-1)
Solvent content:
Organic solvents: 0.0 %
Water: 27.9 %
(Contd. on page 5)
GB
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
Trade name: COOLANT-F
(Contd. of page 4)
34.1.5
Other information No further relevant information available.
10Stability and reactivity
Reactivity
Chemical stability
Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
Possibility of hazardous reactions No dangerous reactions known.
Conditions to avoid No further relevant information available.
Incompatible materials: No further relevant information available.
Hazardous decomposition products: No dangerous decomposition products known.
11Toxicological information
Information on toxicological effects
Acute toxicity:
LD/LC50 values relevant for classification:
Oral LD50 >2000 mg/kg (rat)
Primary irritant effect:
on the skin: No irritant effect.
on the eye: No irritating effect.
Sensitization: No sensitizing effects known.
12Ecological information
Toxicity
Aquatic toxicity: No further relevant information available.
Persistence and degradability No further relevant information available.
Behaviour in environmental systems:
Bioaccumulative potential No further relevant information available.
Mobility in soil No further relevant information available.
Ecotoxical effects:
Remark: Harmful to fish
Additional ecological information:
General notes:
Water hazard class 2 (German Regulation) (Self-assessment): hazardous for water
Do not allow product to reach ground water, water course or sewage system.
Danger to drinking water if even small quantities leak into the ground.
Harmful to aquatic organisms
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
Other adverse effects No further relevant information available.
GB
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date 23.04.2012 Revision: 23.04.2012 Version number 1
Trade name: COOLANT-F
(Contd. of page 5)
34.1.5
13Disposal considerations
Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach
sewage system.
European waste catalogue
12 01 09* machining emulsions and solutions free of halogens
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
Recommended cleansing agents: Water, if necessary together with cleansing agents.
14Transport information
UN-Number
ADR, ADN, IMDG, IATA Void
UN proper shipping name
ADR, ADN, IMDG, IATA Void
Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class Void
Packing group
ADR, IMDG, IATA Void
Environmental hazards:
Marine pollutant: No
Special precautions for user Not applicable.
Transport in bulk according to Annex II of
MARPOL73/78 and the IBC Code Not applicable.
UN "Model Regulation": -
15Regulatory information
Chemical safety assessment: A Chemical Safety Assessment has not been carried out.
16Other information
This information is based on our present knowledge. However, this shall not constitute a
guarantee for any specific product features and shall not establish a legally valid contractual
relationship.
Relevant phrases
H317 May cause an allergic skin reaction.
H412 Harmful to aquatic life with long lasting effects.
R43 May cause sensitisation by skin contact.
R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Department issuing MSDS: Abteilung Produktsicherheit
GB