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Introduction
Introduction
Introduction
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*7190250824*
0620/31
CHEMISTRY
May/June 2008
Paper 3 (Extended)
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES
Answer all questions.
A copy of the Periodic Table is printed on page 12.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.
[Turn over
2
1
For each of the following select an element from Period 4, potassium to krypton, that
matches the description.
UCLES 2008
0620/31/M/J/08
For
Examiner's
Use
3
2
(a) Complete the table which gives the names, symbols, relative masses and relative
charges of the three subatomic particles.
name
symbol
electron
e-
proton
relative mass
For
Examiner's
Use
relative charge
1
n
0
[3]
[2]
(ii) Atoms can form positive ions.
[2]
(iii) Atoms of the same element can have different masses.
[2]
(iv) Scientists are certain that there are no undiscovered elements missing from the
Periodic Table from hydrogen to lawrencium.
[1]
[Total: 10]
UCLES 2008
0620/31/M/J/08
[Turn over
4
3
For
Examiner's
Use
[3]
(b) Write an ionic equation for the reaction at the positive electrode (anode).
[2]
in cooking utensils.
[2]
UCLES 2008
0620/31/M/J/08
5
4
For
Examiner's
Use
[2]
Cu2+ + H2O
(iii) CuO + 2H+
Change the ionic equation into a symbol equation.
[2]
(iv) Na2CO3 + H2SO4
Na2SO4 + CO2 + H2O
Change into a word equation.
[1]
(b) When sulphuric acid dissolves in water, the following reaction occurs.
HSO4- + H3O+
H2SO4 + H2O
Explain why water is behaving as a base in this reaction.
[2]
[2]
[Total: 10]
UCLES 2008
0620/31/M/J/08
[Turn over
6
5
For
Examiner's
Use
cool
CO(g) + Cl2(g)
COCl2(g)
heat
(a) When the pressure on the equilibrium mixture is decreased, the position of equilibrium
moves to left.
(i) How does the concentration of each of the three chemicals change?
[2]
(ii) Explain why the position of equilibrium moves to left.
[2]
(b) Using the information given with the equation, is the forward reaction exothermic or
endothermic? Give a reason for your choice.
[2]
(c) Carbonyl chloride reacts with water to form two acidic compounds.
Suggest which acidic compounds are formed.
1.
2.
[2]
C
Cl
Draw a diagram that shows the arrangement of the valency electrons in one molecule
of this covalent compound.
Use x for an electron from a chlorine atom.
Use o for an electron from a carbon atom.
Use for an electron from an oxygen atom.
[4]
[Total: 12]
UCLES 2008
0620/31/M/J/08
7
6
Three of the factors that can influence the rate of a chemical reaction are:
For
Examiner's
Use
(a) The first recorded dust explosion was in a flour mill in Italy in 1785. Flour contains
carbohydrates. Explosions are very fast exothermic reactions.
(i) Use the collision theory to explain why the reaction between the particles of flour
and the oxygen in the air is very fast.
[2]
(ii) Write a word equation for this exothermic reaction.
[1]
The decomposition of silver(I) bromide is the basis of film photography. The equation for
this decomposition is:
2AgBr
white
2Ag + Br2
black
not covered
covered with
thin paper
exposure
to light
covered with
thick card
grey
white
[3]
UCLES 2008
0620/31/M/J/08
[Turn over
8
(c) The fermentation of glucose is catalysed by enzymes from yeast. Yeast is added to
aqueous glucose, the solution starts to bubble and becomes cloudy as more yeast
cells are formed.
C6H12O6(aq)
2C2H5OH(aq) + 2CO2(g)
[2]
(iii) On a large scale, the reaction mixture is cooled. Suggest a reason why this is
necessary.
[1]
(iv) Why does the fermentation stop? Suggest two reasons.
[2]
(v) When the fermentation stops, there is a mixture of dilute aqueous ethanol and
yeast. Suggest a technique which could be used to remove the cloudiness due to
the yeast.
[1]
Name a technique which will separate the ethanol from the ethanol / water mixture.
[1]
[Total: 14]
UCLES 2008
0620/31/M/J/08
For
Examiner's
Use
9
7
For
Examiner's
Use
conical flask
[4]
(b) Using 25.0 cm3 of aqueous sodium hydroxide, 2.24 mol / dm3, 3.86 g of crystals were
obtained. Calculate the percentage yield.
2NaOH + H2SO4
Na2SO4 + 2H2O
Na2SO4 + 10H2O
Na2SO4.10H2O
g
%
[4]
[Total: 8]
UCLES 2008
0620/31/M/J/08
[Turn over
10
8
Large areas of the Amazon rain forest are cleared each year to grow soya beans. The trees
are cut down and burnt.
(a) Why do these activities increase the percentage of carbon dioxide in the atmosphere?
[2]
(b) Soya beans contain all three main food groups. Two of which are protein and
carbohydrate.
(i) What is the third group?
[1]
(ii) Draw the structural formula of a complex carbohydrate such as starch.
[3]
(iii) Compare the structure of a protein with that of a synthetic polyamide. The structure
of a typical protein is given below.
[3]
[Total: 9]
UCLES 2008
0620/31/M/J/08
For
Examiner's
Use
11
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
UCLES 2008
0620/31/M/J/08
UCLES 2008
Magnesium
Sodium
Calcium
0620/31/M/J/08
Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
51
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Pu
94
Plutonium
62
Eu
152
Platinum
Am
95
Americium
63
Europium
78
195
Pt
Ir
46
Palladium
Pd
106
Nickel
Ni
192
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Tl
204
Indium
Cf
98
Californium
66
Es
Holmium
Ho
165
Lead
Pb
207
Tin
99
Einsteinium
67
82
50
119
Sn
115
32
Germanium
Ge
73
Silicon
In
Gallium
Dysprosium
81
49
31
70
Ga
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulphur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
Group
DATA SHEET
The Periodic Table of the Elements
12
*8672182532*
0620/32
CHEMISTRY
May/June 2008
Paper 3 (Extended)
1 hour 15 minutes
Candidates answer on the Question Paper.
No Additional Materials are required.
READ THESE INSTRUCTIONS FIRST
Write your Centre number, candidate number and name on all the work you hand in.
Write in dark blue or black pen.
You may use a pencil for any diagrams, graphs or rough working.
Do not use staples, paper clips, highlighters, glue or correction fluid.
DO NOT WRITE IN ANY BARCODES
Answer all questions.
A copy of the Periodic Table is printed on page 12.
At the end of the examination, fasten all your work securely together.
The number of marks is given in brackets [ ] at the end of each question or part
questions.
[Turn over
2
1
For each of the following select an element from Period 4, potassium to krypton, that
matches the description.
UCLES 2008
0620/32/M/J/08
For
Examiner's
Use
3
2
(a) Complete the table which gives the names, symbols, relative masses and relative
charges of the three subatomic particles.
name
symbol
electron
e-
proton
neutron
relative mass
For
Examiner's
Use
relative charge
1
n
[3]
[2]
(ii) Atoms can form negative ions.
[2]
(iii) Different atoms of the element chlorine are
35
17
Cl and
37
17
Cl.
[2]
(iv) Scientists are certain that there are no undiscovered elements missing from the
Periodic Table from hydrogen to lawrencium.
[1]
[Total: 10]
UCLES 2008
0620/32/M/J/08
[Turn over
4
3
For
Examiner's
Use
[3]
(b) Write an ionic equation for the reaction at the positive electrode (anode).
[2]
in cooking utensils.
[2]
UCLES 2008
0620/32/M/J/08
5
4
For
Examiner's
Use
[2]
(iii) CuCO3 + 2H+
Cu2+ + H2O + CO2
Change the ionic equation into a symbol equation.
[2]
Na2SO4 + CO2 + H2O
(iv) Na2CO3 + H2SO4
Change into a word equation.
[1]
(b) When sulphuric acid dissolves in water, the following reaction occurs.
HSO4- + H3O+
H2SO4 + H2O
Explain why water is behaving as a base.
[2]
(c) Sulphuric acid is a strong acid, ethanoic acid is a weak acid. One way of distinguishing
between them is to measure their pH. The weaker acid will have the higher pH.
Describe another way by which they could be distinguished.
[2]
[Total: 10]
UCLES 2008
0620/32/M/J/08
[Turn over
6
5
For
Examiner's
Use
cool
CO(g) + Cl2(g)
COCl2(g)
heat
(a) When the pressure on the equilibrium mixture is increased, the position of equilibrium
moves to right.
(i) How does the concentration of each of the three chemicals change?
[2]
(ii) Explain why the position of equilibrium moves to right.
[2]
(b) Using the information given with the equation, is the forward reaction exothermic or
endothermic? Give a reason for your choice.
[2]
(c) Carbonyl chloride reacts with water to form two acidic compounds.
Name them.
[2]
(d) The structural formula of carbonyl chloride is given below.
Cl
O
C
Cl
Draw a diagram that shows the arrangement of the valency electrons in one molecule
of this covalent compound.
Use x for an electron from a chlorine atom.
Use o for an electron from a carbon atom.
Use for an electron from an oxygen atom.
[4]
[Total: 12]
UCLES 2008
0620/32/M/J/08
7
6
Three of the factors that can influence the rate of a chemical reaction are:
For
Examiner's
Use
(a) The first recorded dust explosion was in a flour mill in Italy in 1785. Flour contains
carbohydrates. Explosions are very fast exothermic reactions.
(i) Use the collision theory to explain why the reaction between the particles of flour
and the oxygen in the air is very fast.
[2]
(ii) Write a word equation for this exothermic reaction.
[1]
The decomposition of silver(I) bromide is the basis of film photography. The equation for
this decomposition is:
2AgBr
white
2Ag + Br2
black
not covered
covered with
thin paper
exposure
to light
covered with
thick card
grey
white
[3]
UCLES 2008
0620/32/M/J/08
[Turn over
8
(c) The fermentation of glucose is catalysed by enzymes from yeast. Yeast is added to
aqueous glucose, the solution starts to bubble and becomes cloudy as more yeast
cells are formed.
C6H12O6(aq)
2C2H5OH(aq) + 2CO2(g)
[2]
(iii) On a large scale, the reaction mixture is cooled. Suggest a reason why this is
necessary.
[1]
(iv) Why does the fermentation stop? Suggest two reasons.
[2]
(v) When the fermentation stops, there is a mixture of dilute aqueous ethanol and
yeast. Suggest a technique which could be used to remove the cloudiness due to
the yeast.
[1]
Name another technique which will separate the ethanol from the ethanol / water
mixture.
[1]
[Total: 14]
UCLES 2008
0620/32/M/J/08
For
Examiner's
Use
9
7
For
Examiner's
Use
conical flask
[4]
(b) Using 25.0 cm3 of aqueous sodium hydroxide, 2.64 mol / dm3, 3.95 g of crystals were
obtained. Calculate the percentage yield.
2NaOH + H2SO4
Na2SO4 + 2H2O
Na2SO4 + 10H2O
Na2SO4.10H2O
g
%
[4]
[Total: 8]
UCLES 2008
0620/32/M/J/08
[Turn over
10
8
Large areas of the Amazon rain forest are cleared each year to grow soya beans. The trees
are cut down and burnt.
(a) Why do these activities increase the percentage of carbon dioxide in the atmosphere?
[2]
(b) Soya beans contain all three main food groups.
carbohydrate.
[3]
(iii) Compare the structure of a protein with that of a synthetic polyamide. The structure
of a typical protein is given below.
[3]
[Total: 9]
UCLES 2008
0620/32/M/J/08
For
Examiner's
Use
11
BLANK PAGE
Permission to reproduce items where third-party owned material protected by copyright is included has been sought and cleared where possible. Every
reasonable effort has been made by the publisher (UCLES) to trace copyright holders, but if any items requiring clearance have unwittingly been included, the
publisher will be pleased to make amends at the earliest possible opportunity.
University of Cambridge International Examinations is part of the Cambridge Assessment Group. Cambridge Assessment is the brand name of University of
Cambridge Local Examinations Syndicate (UCLES), which is itself a department of the University of Cambridge.
UCLES 2008
0620/32/M/J/08
UCLES 2008
Magnesium
Sodium
Calcium
0620/32/M/J/08
Strontium
Key
X = atomic symbol
Actinium
Ac
89
Ra
Radium
88
Fr
Francium
87
Hafnium
72
Lanthanum
57
178
Hf
40
Zirconium
Zr
91
Titanium
139
Yttrium
22
48
Ti
La
39
89
Scandium
21
227
Barium
56
Caesium
45
Sc
226
55
137
Ba
133
Cs
38
Rubidium
37
88
Sr
85
Rb
20
Potassium
19
40
Ca
39
12
24
Mg
23
Na
Beryllium
Lithium
11
Be
II
Li
93
Ta
181
Niobium
Nb
90
58
73
52
96
Mo
184
Protactinium
Thorium
55
Tc
186
Re
144
Nd
92
60
Uranium
238
Neodymium
75
Rhenium
43
Technetium
25
Manganese
Mn
27
59
28
59
29
64
30
65
Ru
101
Iron
190
Pm
Osmium
Os
Np
93
Neptunium
61
Promethium
76
44
Ruthenium
26
56
Fe
Sm
150
Iridium
Ir
192
Pu
94
Plutonium
62
Samarium
77
45
Rhodium
Rh
103
Cobalt
Co
195
Eu
152
Platinum
Pt
Am
95
Americium
63
Europium
78
46
Palladium
Pd
106
Nickel
Ni
Gd
157
Gold
Au
197
Silver
96
64
Curium
Cm
Gadolinium
79
47
Ag
108
Copper
Cu
201
Bk
Terbium
Tb
159
Mercury
Hg
97
Berkelium
65
80
48
Cadmium
Cd
112
Zinc
Zn
Dy
162
Thallium
Tl
204
Indium
In
115
Gallium
Cf
98
Californium
66
Dysprosium
81
49
31
70
Ga
Ge
73
Silicon
119
Es
Holmium
Ho
165
Lead
Pb
207
Tin
Sn
99
Einsteinium
67
82
50
32
Germanium
14
28
Si
Carbon
27
Aluminium
13
12
Al
Boron
11
75
Sb
122
Arsenic
As
Bi
209
Fermium
Fm
Erbium
Er
167
Bismuth
100
68
83
51
Antimony
33
15
Phosphorus
31
Nitrogen
14
Se
79
Sulphur
Po
169
Md
Thulium
Tm
101
Mendelevium
69
84
Polonium
52
Tellurium
Te
128
Selenium
34
16
32
Oxygen
16
Yb
173
Astatine
At
Iodine
127
Bromine
Br
80
Chlorine
No
102
Nobelium
70
Ytterbium
85
53
35
17
Cl
35.5
Fluorine
19
Lr
Lutetium
Lu
175
Radon
Rn
Xenon
Xe
131
Krypton
Kr
84
Argon
Ar
40
Neon
103
Lawrencium
71
86
54
36
18
10
Ne
20
Helium
VII
Hydrogen
VI
He
IV
III
1
The volume of one mole of any gas is 24 dm3 at room temperature and pressure (r.t.p.).
91
Pa
Th
232
Praseodymium
Cerium
59
141
Pr
140
74
Tungsten
42
Molybdenum
24
Chromium
Cr
Ce
Tantalum
41
23
Vanadium
51
Group
DATA SHEET
The Periodic Table of the Elements
12