Echem WKST Key

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CHM 152 Electrochemistry (Ch. 17)

Galvanic Cells
In each of the following equations, indicate the element that has been oxidized and the one that has been
reduced. You should also label the oxidation state of each before and after the process:
1.
2 Na + FeCl2 2 NaCl + Fe
Sodium is oxidized, going from a 0 to +1 oxidation state.
Iron is reduced, going from a +2 to 0 oxidation state.
2 C2H2 + 5 O2 4 CO2 + 2 H2O

Carbon is oxidized, going from a 1 to +4 oxidation state.
Oxygen is reduced, going from a 0 to 2 oxidation state.
2 PbS + 3 O2 2 SO2 + 2 PbO

Sulfur is oxidized, going from a 2 to +4 oxidation state.
2 H2 + O2 2 H2O
Hydrogen is oxidized, going from a 0 to +1 oxidation state.
Cu + HNO3 CuNO3 + H2
Copper is oxidized, going from a 0 to +1 oxidation state.
Hydrogen is reduced, going from a +1 to 0 oxidation state.
2.
3.
4.
5.
6.
AgNO3 + Cu CuNO3 + Ag
Copper is oxidized, going from a 0 to +1 oxidation state.
Silver is reduced, going from a +1 to 0 oxidation state.
7. Assign oxidation numbers to each element in the following equation. Write both half-reactions and indicate
the oxidizing and reducing agents below.
MnO42-
C2O42-
MnO2
Oxidation half-reaction: C2O42Reduction half-reaction: MnO42Oxidizing agent: MnO42Reducing agent: C2O42CHM 152
CO32-
CO32MnO2
Electrochemistry
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8. Assign oxidation numbers to each element in the following equation by filling in the table. Write both halfreactions and indicate the oxidizing and reducing agents below.
NaCl(aq) + H2SO4(aq) + MnO2(s)
ELEMENT
Sodium
Chlorine
Sulfur
Manganese
Oxygen
Hydrogen
REACTANTS
+1
-1
+6
+4
-2
+1
Na2SO4(aq) + Mn2+(aq) + H2O(l) + Cl2(g)
PRODUCTS
+1
0
+6
+2
-2
+1
Oxidation half-reaction: NaCl Cl2

Reduction half-reaction: MnO2 Mn2+
Oxidizing agent: MnO2
Reducing agent: NaCl
9. The oxidizing agent reacts at the (cathode or anode). The reducing agent reacts at the (cathode or anode).
Shorthand Notation
10. Write a balanced equation for the electrode and overall cell reactions in the following galvanic cell. Sketch
the cell, labeling the anode and cathode and showing the direction of electron and ion flow.
Co(s) | Co2+(aq) || Cu2+(aq) | Cu(s)
Co(s) + Cu2+(aq) Co2+(aq) + Cu(s)
Galvanic cell: Co(s) is anode (in left beaker) in a solution

of Co(NO3)2, Cu(s) is cathode (in right beaker)
in solution of Cu(NO)3)2, salt bridge (NaNO3) connects the
two solutions. Electrons flow from anode to cathode.
Eoox (Co) = +0.28 V, Eored (Cu) = +0.34 V

Eocell = 0.62 V
Cell Potentials / Free Energy

11.
A galvanic cell is constructed based on the following reactions:
Zn2+ + 2e- Zn
E red = -0.76 V
Al3+ + 3e- Al
E red = -1.66 V
a) Write the overall balanced equation for the cell and calculate the cell emf under standard conditions.
3(Zn2+ + 2e- Zn)
E red = -0.76 V
2(Al Al3+ + 3e-)
E ox = +1.66 V
3Zn2+ + 2Al 3Zn + 2Al3+
Eocell= -0.76 V + 1.66 V = 0.90 V
b) Calculate G at 298 K.
CHM 152
Electrochemistry
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96500 J
G = -nFE = -(6 mol e-) V mol e 0.90 V = -5.2 x105 J or -520 kJ
c) What is the value of the equilibrium constant, K, for this reaction at 298 K?
Eo = (RT/nF) ln K; n = 6; K = 1.6 x 1091
Standard Reduction Potentials

12. a. Use Table 17.1 to determine which is the best oxidizing agent: Br2, I2, or H+? Br2
reactant with most positive reduction potential
b. Use Table 17.1 to determine which is the best reducing agent: Zn, Ag, or Al? Al
product with most negative reduction potential (most positive oxidation potential)
13. Which substance is the weakest reducing agent?
A. Co2+
B. Mn2+
C. Cd
D. Mn
E. Co
14. Circle the substance in each pair below that will be a stronger reducing agent:
a. Al(s) or Ni(s)
b. Mg(s) or Na(s)
c. H2O2(aq) or Cl2(g)
d. Sn2+(aq) or Cl-(aq)
15. Examine the following half-reactions and select the strongest reducing agent among the substances:
Sr2+ + 2 e- Sr
Eo = 2.89 V
Be2+ + 2 e- Be
Eo = 1.85 V
Sn4+ + 2 e- Sn2+ Eo = +0.13 V
Fe3+ + e- Fe2+
Eo = +0.77 V
a. Be
b. Sr
c. Sn
d. Fe3+
e. Fe2+
16. What is the strongest oxidizing agent in the list above? What is the weakest oxidizing agent?
a. Be2+
b. Sn4+
c. Sr2+ weakest
d. Fe3+ strongest
e. Fe2+
17. A voltaic cell is constructed that uses the following reaction:
Ni(s) + 2Ag+(aq)
Ni2+(aq) +
2Ag(s)
a) Write the half reactions & indicate which is the anode and cathode.
Ni(s) Ni2+(aq) + 2e2Ag+(aq) + 2e- 2Ag(s)
CHM 152
Ox - Anode
Red Cathode
Electrochemistry
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b) Use the reduction potentials provided in Table 17.1 to calculate E cell :

Ni2+(aq) + 2e- Ni(s)
Ag+(aq) + e- Ag(s)
E red = -0.25 V E ox = +0.25 V
E red = +0.80 V
E cell = E red + E ox = 0.80 V + 0.25 V = 1.05 V

c) Is this reaction spontaneous? Yes (positive emf, spontaneous rxn)
Use the following information for question 18
Half-reaction
Co2+(aq) + 2e- Co(s)
Mn2+(aq) + 2e- Mn(s)
Cd2+(aq) + 2e- Cd(s)
E red
-0.28 V
-1.18 V
-0.40 V
18. Which of the following will react spontaneously?

A. Cd with Mn2+
B. Co with Cd2+ C. Mn with Co
D. Mn with Cd2+ E. Co with Mn2+
*A, B, C have Ecell; C has 2 solids and both are being oxidized; D has +Ecell
19. Consider a voltaic cell constructed from a Ag electrode in 1.0 M AgNO3 and a Ni electrode in 1.0 M
Ni(NO3)2, linked by an external circuit and a KCl salt bridge. Based on the reduction potentials shown, which of
the following statements is correct?
Ag+ + e- Ag
Eo = +0.80 V
Ni2+ + 2 e- Ni
Eo = 0.25 V
a.
b.
c.
d.
e.
The Ni electrode is the cathode

The Ag electrode is the anode
Electrons flow from the silver electrode to the nickel electrode
The silver electrode will gain mass
The nickel electrode is will gain mass
20. Which combination below will undergo a spontaneous reaction?

Half Reaction Table
E red
Br2(l) + 2e- 2Br(aq)
+1.06 V
2+
Cu (aq) + 2e- Cu(s)
+0.34 V
2+
Ni (aq) + 2e- Ni(s)
0.28 V
3+
Al (aq) + 3e- Al(s)
1.66 V
a.
b.
c.
d.
e.
CHM 152
Ni 2+(aq) with Br(aq)

Cu(s) with Al3+(aq)
Ni (s) with Br(aq)
Br(aq) with Cu2+(aq)
Br2(l) with Ni(s)
Electrochemistry
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21. Given the two half reactions and the Eored below, write a balanced, overall reaction that would be
spontaneous. Also calculate the emf of the cell.
Pb2+(aq) + 2e- Pb(s)
Mg2+(aq) + 2e- Mg(s)
Eored = -0.13 V
Eored = -2.37 V
Mg(s) + Pb2+(aq) Pb(s) + Mg2+(aq)
Eocell = +2.24 V
Nernst Equation
22. A cell utilizes the following reaction and operates at 298 K:
2H+(aq) + Zn(s) Zn2+(aq) + H2(g)
a) What is the emf of this cell under standard conditions? (Look up E values).
Zn(s) Zn2+(aq) + 2e-
E ox = -(-0.76 V)
2e- + 2H+(aq) H2(g)
E red = 0.00 V
E cell = 0.76 V
b) What is the emf of this cell when [Zn2+] = 0.050 M, PH2 = 0.25 atm, and the pH = 4.00.
0.0592
E = E log Q
n
E = 0.76 V -
n = 2; Q =
[ Zn 2 ] PH 2
[H ]
; [H+] = 1x10-4
[ 0.050 ]( 0.25 )
0.0592
log
[ 1.0 x10 4 ] 2
2
E = 0.76 - 0.0296(log1.25x106)
E = 0.76 - 0.0296(+6.10) = 0.76 - 0.18 = 0.58 V
23. A voltaic cell is constructed that used the following reaction and operates at 298 K:
2Al(s) + 3Mn2+(aq) 2Al3+(aq) + 3Mn(s)
a. What is the EMF of this cell under standard conditions? (Use Appendix D for Eored values.)
+1.66 V + -1.18 V = 0.48 V
b. What is the EMF of this cell when [Mn2+] = 0.10 M and [Al3+] = 1.5 M?
E = 0.48 V (0.0592 V / 6 mol e-) (log (1.5)2/(0.10)3) = 0.45 V
Cell Potentials / Equilibrium Constants

24. Using the standard reduction potentials listed in Table 17.1, calculate the equilibrium constant for each of
the following reactions at 298 K.
a. Zn(s) + Sn2+(aq) Zn2+(aq) + Sn(s)
+0.76 V + -0.14 V = 0.62 V
Eo = (8.314 J/mol e-K * 298 K)/(2 mol e-* 96,500 J/V
mol e-) ln K; K = 9.4 x 1020
b. Co(s) + 2H+(aq) Co2+(aq) + H2(g)
+0.28 V + 0 V = 0.28 V
CHM 152
Eo = (8.314 J/mol e-K * 298 K)/(2 mol e-* 96,500

Electrochemistry
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J/Vmol e-) ln K; K = 3.0 x 109
25. Create a functional Galvanic cell given the following: On the left side of the cell there is 1.00M iron(III) nitrate solution with a
solid iron electrode. On the right side, there is 1.00M cobalt(II) nitrate solution with a solid cobalt electrode. Draw the cell and label
the anode, cathode, metals, solutions and all parts of the cell. Write and balance the half reactions and overall cell reaction. Calculate
the cell potential Eo, Go and K. Indicate where all charged particles flow in the cell and what they are. Calculate the cell potential if
the cell contained 0.25M iron(III) nitrate and 1.75M cobalt(II) nitrate. Finally write the short hand notation for the cell. Reduction
potentials can be found in Appendix D. An example cell is at the bottom of the chapter 13 review.
reduction half rxn: Fe3+(aq) + 3e- g Fe(s)
Eored = -0.04V
oxidation half rxn: Co(s) g Co2+(aq) + 2e- Eoox = +0.28V

total rxn: 2 Fe3+(aq) + 3 Co(s)
shorthand notation:
g 2 Fe(s) + 3 Co2+(aq)
Eocell = + 0.24V
Co(s) | Co2+(aq) || Fe3+(aq) | Fe(s)
Go = (-6 mol e-)(96500 J/Vmole)(0.24V)( kJ / 1000J) = -1.4 x 102 kJ

K: 0.24V = [ (8.314 J/molK)(298K) / (6 mol e)(96500 J/Vmol e-) ] ln K
ln K = 56.08717
K = 2.3 x 1024
E = 0.24V [ (8.314 J/molK)(298K) / (6 mol e)(96500 J/Vmol e-) ] ln [ (1.75)3 / (0.25)2 ] = 0.22V
CHM 152
Electrochemistry
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Electrolysis
26. How many grams of copper can be deposited from CuSO4 solution by the passage of 3.00 A for 2.5 hrs?
Cu+2 + 2e- Cu
1 amp = C/s
3.00
3600 s 1 mol e 1 mol Cu

63.6 g Cu
C
x 2.5 hrs x 1 hr 96500 C 2 mol e 1 mol Cu = 8.9 g Cu
s
27. A Cr3+(aq) solution is electrolyzed using a current of 13.5 A. What mass of Cr(s) is plated out after 3.00
days?
13.5 C/s * 3.0 days * 24 hr/day * 3600 s/hr = 3.499 x 106 C * (1 mol e-/96500 C) * (1 mol Cr/3 mol e-) * (52.00 g Cr/
1 mol Cr) = 629 g Cr
28. A current of 2.000 amps is passed through a solution of Pb(NO3)2 until 6.350 grams of Pb metal has been
deposited. a) Calculate the number of coulombs that pass through this solution. b) How many seconds did the
current flow?
Pb+2 + 2e- Pb
mol Pb
2 mol e
96500 C
a) 6.350 g Pb 207.2 g 1 mol Pb 1 mol e 5915 C

s
b) 5915 C x 2.00 C = 2957 secs

(or use Coul = Amp x sec;
CHM 152
sec = Coul/Amp)
Electrochemistry
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Name: ___KEY____________________

CHM 152 Electrochemistry (Ch. 17)

2 C2H2 + 5 O2 4 CO2 + 2 H2O

2 PbS + 3 O2 2 SO2 + 2 PbO

Silver is reduced, going from a +1 to 0 oxidation state.

Na2SO4(aq) + Mn2+(aq) + H2O(l) + Cl2(g)

Oxidation half-reaction: NaCl Cl2

Galvanic cell: Co(s) is anode (in left beaker) in a solution

Eoox (Co) = +0.28 V, Eored (Cu) = +0.34 V

Cell Potentials / Free Energy

A galvanic cell is constructed based on the following reactions:

2(Al Al3+ + 3e-)

3Zn2+ + 2Al 3Zn + 2Al3+

Eocell= -0.76 V + 1.66 V = 0.90 V

G = -nFE = -(6 mol e-) V mol e 0.90 V = -5.2 x105 J or -520 kJ

Standard Reduction Potentials

b) Use the reduction potentials provided in Table 17.1 to calculate E cell :

E red = -0.25 V E ox = +0.25 V

E cell = E red + E ox = 0.80 V + 0.25 V = 1.05 V

18. Which of the following will react spontaneously?

B. Co with Cd2+ C. Mn with Co

D. Mn with Cd2+ E. Co with Mn2+

The Ni electrode is the cathode

20. Which combination below will undergo a spontaneous reaction?

Ni 2+(aq) with Br(aq)

Mg(s) + Pb2+(aq) Pb(s) + Mg2+(aq)

2e- + 2H+(aq) H2(g)

Cell Potentials / Equilibrium Constants

Eo = (8.314 J/mol e-K * 298 K)/(2 mol e-* 96,500

reduction half rxn: Fe3+(aq) + 3e- g Fe(s)

oxidation half rxn: Co(s) g Co2+(aq) + 2e- Eoox = +0.28V

Co(s) | Co2+(aq) || Fe3+(aq) | Fe(s)

Go = (-6 mol e-)(96500 J/Vmole)(0.24V)( kJ / 1000J) = -1.4 x 102 kJ

3600 s 1 mol e 1 mol Cu

a) 6.350 g Pb 207.2 g 1 mol Pb 1 mol e 5915 C

b) 5915 C x 2.00 C = 2957 secs

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