Emergency Action Code 2013

Dangerous Goods Emergency Action Code List 2013
www.tso.co.uk
8175 Dangerous Goods Cover v1_1.indd 1
25/02/2013 16:10
Dangerous Goods
Emergency
Action Code List
2013
London:TSO
Book 1.indb 1
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Published by TSO (The Stationery Office) and available from:

Online
www.tsoshop.co.uk
Mail, Telephone, Fax & E-mail
TSO
PO Box 29, Norwich, NR3 1GN
Telephone orders/General enquiries: 0870 600 5522
Fax orders: 0870 600 5533
E-mail: customer.services@tso.co.uk
Textphone 0870 240 3701
TSO@Blackwell and other Accredited Agents
Part of Ricardo-AEA
The publication is produced by NCEC (National Chemical Emergency Centre). NCEC is part of
Ricardo-AEA Ltd. Registered Office Shoreham Technical Centre, old Shoreham Road, Shorehamby-Sea, West Sussex, BN43 5FG. Registered in England and Wales No.8229264.
This publication is produced with the co-operation of the Department for Communities and Local
Government and builds on the previous publication, in the same name, produced by them and
published by the Stationery Office Limited.
Ricardo-AEA Technology Ltd 2013
All rights reserved.
ISBN 978 0 11 754118 4
Printed in Great Britain on material containing 75% post-consumer waste and 25% ECF pulp.
Printed in the United Kingdom by TSO
J002714677C1904/13
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Foreword
(i)
This document supersedes the Dangerous Goods Emergency

Action Code List 2011.
(ii)
Duty holders are required to use this document for the

application of the appropriate Emergency Action Codes (EACs)
under Schedule 1 of the Carriage of Dangerous Goods and
Use of Transportable Pressure Equipment Regulations 2009
(CDG 2009), as amended. These regulations implement the
Regulations Concerning the International Carriage of Dangerous
Goods by Rail (RID1), and the European Agreement Concerning
the International Carriage of Dangerous Goods by Road (ADR2).
(iii)
The assignment of emergency action codes and additional

personal protection codes at Section 4 of this document is based
upon the physical and chemical properties of the particular
dangerous goods.
(iv)
This document is effective immediately in connection with the

use of ADR/RID 2013 Edition and is mandatory from 1 July 2013
and the Emergency Action Code List 2011 should no longer be
used from that date.
(v)
Sections 4 and 5 of this Document will continue to be revised in

line with any changes made to the RID and ADR Agreements
(normally every two years), as provided for in domestic regulations.
1 Rglements Internationales Relatif au Transport des Marchandises Dangereuses par Chemin de Fer
2 Accord Europen Relatif au Transport International des Marchandises Dangereuses par Route
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Contents
Section 1: Introduction to the Emergency Action Codes
Introduction
Danger Labels
Section 2: Displaying Emergency Action Codes
13
Assigning Emergency Action Codes
13
Assigning Emergency Action Codes to multi-loads
14
Section 3: A
pplication of Emergency Action Codes for the
17
Emergency Services

Interpretation of Codes
Extinguishing Media
18
Personal Protection
18
Violent Reaction
19
Contain/Dilute

E Public Safety Hazard
19
21
Section 4: Numerical List of Dangerous Goods
23
23
Explanation of headings in Numerical List
Column 1: United Nations (UN) Number
23
Column 2: Substance
24
Column 3: Emergency Action Code (EAC)
24
Column 4: Advice on Additional Personal Protection (APP)
24
Column 5: Hazards
25
Column 6: Hazard Identification Number (HIN)
26
Book 1.indb 5
17
List of Dangerous Goods
31
Section 5: Alphabetical List of Dangerous Goods
137
Acknowledgements
193
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Section 1
Introduction to the
Emergency Action Codes
1.1 Introduction
1.1.1
Emergency Action codes (EACs), also known as Hazchem codes,

are for the use of the emergency services in conjunction with
Emergency Action Code Cards. EACs indicate to the emergency
services actions that may be necessary, during the first few
minutes of an incident involving dangerous goods, should the
officer in charge of the incident deem it necessary to take
immediate actions.
1.1.2
This document shall not be used for the purposes of markings on

the orange coloured plate without reference to the Carriage of
Dangerous Goods and Use of Transportable Pressure Equipment
Regulations 2009 (CDG 2009), as amended, and ADR/RID. The
fact that a United Nations (UN) number and emergency action
code (EAC) for a given substance are shown in this document
does not necessarily mean they should be used for the marking
of road tankers, rail tank wagons or tank containers used for the
carriage of that substance. An annotation (1) in the EAC column
of Section 4 indicates that it is not applicable to the carriage of
dangerous goods under RID or ADR.
1.1.3
This document contains all items listed by the United Nations

in their publication Recommendations on the Transport of
Dangerous Goods Model Regulations (seventeenth revised
edition) with the exception of substances in UN Class1, i.e.
explosives. EACs are not allocated to UN Class 7 substances, i.e.
radioactive material and these are annotated (2) in the EAC
column of Section 4 of this document.
Introduction to the emergency action codes 7
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1.1.4
For internal transport operations in Great Britain there are two

forms of placarding/plate marking permitted for tank transport
and carriage in bulk under CDG 2009 (as amended). Both of
these include the hazard warning diamond and the UN number.
Road and Rail vehicles must also display one of two additional
identification numbers.
GB registered road and rail vehicles on domestic journeys
must display the Emergency Action (Hazchem) Code

All other vehicles must display the Hazard Identification
Number (HIN) (see paragraphs 4.1.134.1.18).

1.1.5
Examples of these two systems are shown below. The requirements

are contained in CDG 2009 (as amended).
Hazard Warning Panel
RID/ADR (Hazard Identification Number) orange coloured plate and placard
8 dangerous goods emergency action code list 2013
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1.2
Danger Labels
1.2.1
The following are danger labels that will be shown during the
transport of dangerous goods:
CLASS 1 Explosive substances or articles
Division 1.1, 1.2

and 1.3
Division 1.4
Division 1.5
Division 1.6
CLASS 2 Gases
Flammable gases
Non-flammable,
non-toxic gases
Toxic gases
CLASS 3 Flammable liquids
Introduction to the emergency action codes 9
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CLASS 4.1 Flammable solids, self-reactive substances and

desensitized explosives
CLASS 4.2 Substances liable to spontaneous combustion
CLASS 4.3 Substances which, in contact with water, emit flammable gases
CLASS 5.1 Oxidising substances
CLASS 5.2 Organic peroxides
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CLASS 6.1 Toxic substances
CLASS 6.2 Infectious substances
CLASS 7 Radioactive material
CLASS 8 Corrosive substance
CLASS 9 Miscellaneous dangerous substances and articles
dangerous goods emergency action code list 2009 11
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1.2.2
Under the requirements of the 2011 and 2013 editions of ADR

and RID goods classified as dangerous in carriage may need to
have the EHS mark displayed on their packaging if they meet the
EHS criteria contained in 2.2.9.1.10 of ADR and RID.
Environmentally hazardous substance mark
1.2.3
The following are marks that may appear on vehicles during the
transport of dangerous goods and would appear in addition to
the danger labels at 1.2.1.
Mark for elevated temperature substances
Dangerous goods packed in limited quantities
DANGER
THIS UNIT IS UNDER FUMIGATION

WITH ( fumigant name* ) APPLIED ON
( date* )
( time* )
VENTILATED ON ( date* )
DO NOT ENTER
Fumigation warning sign

Risk of Asphyxiation warning sign
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Section 2
Displaying Emergency
Action Codes
2.1
2.1.1
The codes allocated and shown in the list apply to tank transport
and carriage in bulk of the single substance by road or rail except
where it is also annotated (1). These codes will not necessarily
apply for non-transport incidents although they may be used to
provide some indication of the action that may be necessary.
2.1.2
Substances in Class 7, i.e. radioactive material, have not been

allocated emergency action codes and are annotated (2).
ADR 5.3.2.1.4 and RID 5.3.2.1.1 and 5.3.2.1.2 stipulate that

transport units, containers or wagons carrying packaged
radioactive material with a single UN number, required to be
carried under exclusive use and with no other dangerous goods,
display orange-coloured plates bearing the appropriate hazard
identification number (HIN) and UN number.
2.1.3
The prefix l will sometimes appear before the EAC in the

third column, e.g. UN 1193 Ethyl Methyl Ketone appears as l2YE.
The l here indicates to the emergency services that alcohol
resistant foam is the preferred firefighting medium but this prefix
shall not be displayed on plates, i.e. EACs displayed on road or
rail vehicles will either be two characters without an E or three
characters including an E. In a similar way an APP code will
sometimes appear in the 4th column of the List at Section 4
indicating additional information for the emergency services but
again this shall not be displayed on plates.
Displaying emergency action codes 13
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2.1.4
In some cases, where there is more than one EAC for a single
UNnumber, it will be necessary to determine the EAC by
reference to the packing group, e.g. for UN 1224 the EAC will
be 3YE for ketones of packing group II whereas the EAC will be
3Y for ketones of packing group III. In these cases the relevant
packing groups will be identified in the Substance column.
2.2

to multi-loads
2.2.1
The following procedure shall be used to assign EACs when each

of the dangerous goods comprising the multi-load is listed for
carriage in a tank under RID or ADR.
1st character of the code

2.2.2
The number forming the first character of the code for a multiload is the highest of the numbers occurring in the EACs for the
individual dangerous goods.
2nd Character of the code

2.2.3
The letter forming the second character of the code shall be

determined from the first letter of the EAC for each of the
dangerous goods from the chart below.
Code chart for the determination of emergency action codes
for multi-loads
P
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2.2.4
If the letter forming the second character of the code for each of
the dangerous goods is the same, then that letter will automatically
form the second character of the EAC for the multi-load.
2.2.5
If, however, the letter forming the second character of the code
for each of the dangerous goods is different, then one of those
letters shall be selected along the top of the horizontal line) and
then a second letter shall be selected down the far left-hand
column, i.e. the two bold sections. The letter in the square where
the appropriate column and row meet is the resultant letter for
those two substances. If there are only two dangerous goods to
be carried in the multi-load, then that resultant letter is the letter
forming the second character of the EAC for that multi-load.
2.2.6
If there are more than two dangerous goods to be carried in the

multi-load, then use the resultant letter obtained in paragraph
2.2.5 along the top horizontal line as above and select another
letter down the far left-hand column as above. The letter in
the square where the appropriate column and row meet is the
new resultant letter. If there are no more dangerous goods to
be carried in the multi-load, then that resultant letter is the
letter forming the second character of the code. If there are
any further dangerous goods to be carried then this procedure
must be repeated until all the other letters have been used.
Letter E
2.2.7
2.2.8

The letter E shall be included as the third character in the

multi-load emergency action code if it occurs in the EAC of any
of the dangerous goods to be carried. If the letter E does not
occur in any of the EACs of the dangerous goods to be carried,
the EAC shall be just a two character code determined from
paragraphs 2.2.2 to 2.2.6 above.
Example:
The following is an example of how to calculate the emergency
action code for a multi-load.
There are three substances to be carried as a multi-load,
having emergency action codes of 3Y, 2S and 4WE.
Displaying emergency action codes 15
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1st Character (number)
The first character of the EAC for each of the three substances is
3, 2 and 4. The highest number must be taken as the first character
of the code for the multi-load and therefore the first character
shall be 4.
2nd Character (letter)
The second character for the EAC for each of the three substances
is Y, S and W. Taking the Y along the top row of the chart and the
S along the left hand column, the intersection is at Y and therefore
the character for the first two substances would be Y. This resultant
character (Y) is then taken along the top row and the character
for the third substance (W) is taken along the left hand column.
The intersection point is now W. The second character of the
code for the three substances shall therefore be W.
Letter E
The third substance has an E as a third character and therefore
the multi-load shall also have an E.
The resultant emergency action code for the three substances

carried as a multi-load shall therefore be 4WE.
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Section 3
Application of Emergency
Action Codes for the
Emergency Services
3.1
Interpretation of Codes
3.1.1
The interpretation of an emergency action code is determined

using Emergency Action Code pocket cards, the latest version of
which is shown below.
Note: Laminated Emergency Action Code Cards Hazchem Scale Cards

are available from NCEC. Similar cards are also available from TSO
(ISBN 978 0 11 341295 2)
application of emergency action codes for the emergency services 17
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Extinguishing Media
3.1.2
The firefighting extinguishing medium is determined by

reference to the first character of the EAC as follows:
1
denotes coarse water spray
denotes fine water spray
denotes normal foam i.e. protein based foam that is not

alcohol resistant
denotes dry agent water MUST NOT be allowed to

come into contact with substance
3.1.3
l2 and l3, which sometimes appear in the List, are not displayed
on the vehicle plates or on the Emergency Action Code Cards
and will only be shown as 2 and 3 respectively. This information
can therefore only be obtained by reference to this document or
another appropriate source, e.g. fire control. l2 denotes alcohol
resistant foam but, if not available, fine water spray can be
used. l3 denotes alcohol resistant foam but, if not available,
normal foam can be used.
Note: Any higher number than the one shown can be used but
a lower number must not be used.
Personal Protection
3.1.4
Where the second character of the EAC is S, T, Y or Z normal

firefighting clothing is appropriate, i.e. self-contained open
circuit positive pressure compressed air breathing apparatus
conforming to BS EN 137 worn in combination with fire kit
conforming to BS EN 469, firefighters gloves conforming to
BS EN 659 and firefighters boots conforming to Home Office
Specification A29 (rubber boots) or A30 (leather boots).
Note: Boots conforming to Home Office Specification
A30 (leather boots) may not provide adequate chemical
resistance and therefore caution should be exercised in the
use of these boots.
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3.1.5
Where the second character of the EAC is P, R, W or X chemical

protective clothing with liquid tight connections for whole body
(Type 3) conforming to the relevant standards such as BS 8428 or
EN 14605, in combination with breathing apparatus specified in
paragraph 3.1.4, shall be used.
Violent Reaction
3.1.6
Where the second character of the EAC is a P, S, W or Y there

is a danger that the substance can be violently or explosively
reactive. This danger may be present due to one of the following:
Violent or explosive decomposition of the material involved,
including ignition or friction.

The ignition of a flammable gas or vapour cloud (this danger
exists for all flammable gases and flammable liquids with a

flash point below 60C).
The rapid acceleration of combustion due to the involvement
of an oxidiser.
A reaction with water which is itself violent, and may also
evolve flammable gases.

3.1.7
The actual danger present can be determined from the vehicle

placards or by reference to the United Nations Class in this
document or another appropriate source, e.g. fire control.
Contain/Dilute
3.1.8
Where the second character of an EAC is W, X, Y or Z

spillages, contaminated fire and decontamination run-off
should be prevented from entering drains and surface and
groundwaters. Where the second character of the code is P, R,
S or T and there is an immediate threat to people, spillages and
decontamination run-off may be washed to drains with large
quantities of water. In such cases due care must be exercised
to avoid unnecessary pollution of surface and groundwaters
and wherever possible control measures such as the sealing of
drains should be employed. More detailed advice on pollution
control techniques and equipment is contained in the Fire
& Rescue Service Manual Environmental Protection.
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Note 1: It should be noted that pollution offences within

environmental legislation do apply to the Fire & Rescue Service.
There maybe a defence available to FRS if pollution results from
a discharge they made in an emergency, but this defence will
only apply if all the criteria set out in the relevant legislation have
been met.
Note 2: In recognition of the practical difficulties at incidents,
the liaison between the environment agencies and the Fire and
Rescue Service has been formalised. These are in the form of a
Protocol in England and Wales and in Scotland and Northern
Ireland that set out the roles and responsibilities of both parties
together with the arrangements that should be followed when
dealing with incidents where pollution may occur. These
arrangements are detailed in the Fire & Rescue Service Manual
Environmental Protection (see Note 5).
Note 3: Ideally most spillages/run off and decontamination
run-off should be contained. However, environment agencies
accept that life saving will take precedence over environmental
protection activities. Nevertheless, all steps that are reasonably
practicable should be taken to contain contaminants and the Fire
& Rescue Service should always inform the environment Agencies
as soon as possible so that appropriate advice can be given.
Specific information on the legal position of fire & rescue services
at incidents in these circumstances can be found in the Fire &
Rescue Service Manual Environmental Protection.
Note 4: Potentially polluting substances include even apparently
harmless substances such as food and beverages, which can cause
serious problems if discharged into a water body: e.g. a spillage of
a soft drink or beer above domestic quantities can constitute a
pollutant as it can lead to deoxygenation of the water. Firefighting
foams are also a potential source of pollution and their entry into
a drainage system and or ground and surface waters should be
prevented whenever possible.
Note 5: Other helpful guidance on environmental issues is
as follows:
Working better together Protocol Series No 8 between English
and Welsh Local Government Association and the Environment

Agency on fire and rescue service issues, August 2006
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http://www.environment-agency.gov.uk/static/documents/
Research/protocol8_1567970.pdf
(Many fire & rescue services have entered into formal Local
Working Arrangements with the Environment Agency, as
encouraged in the above protocol)
Health and Safety Executives Guidance Note EH70 Control
of fire-water run-off from COMAH sites to prevent

environmental damage.
The Environment Agency Pollution Prevention Guidelines
PG 18 Managing Firewater and Major Spillages

The Environment Agency Pollution Prevention Guidelines
PG 22 Incident response - dealing with spills

The above Environment Agency Pollution Prevention Guidelines,
together with other PPGs can be found at: http://www.
environment-agency.gov.uk/business/topics/pollution/39083.aspx
Fire and Rescue Service Manual Volume 2 Fire Service
Organisations - Environmental Protection, The Stationery

Office - ISBN 9780113413164 http://www.communities.gov.
uk/publications/fire/environmentprotectvol2
E Public Safety Hazard

3.1.9
An E following the first two characters of an EAC

indicates that there may be a public safety hazard
outside the immediate area of the incident, and that
the following actions should be considered:
3.1.10
People should be warned to stay indoors with all doors

and windows closed, preferably in rooms upstairs
and facing away from the incident. Ignition sources
should be eliminated and any ventilation stopped.
3.1.11
Effects may spread beyond the immediate vicinity.

All non-essential personnel should be instructed to
move at least 250 metres away from the incident.
3.1.12
Police and Fire and Rescue Service incident commanders

should consult each other and with a product
expert, or with a source of product expertise.
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3.1.13
The possible need for subsequent evacuation should be

considered, but it should be remembered that in most cases
it will be safer to remain in a building than to evacuate.
Situations where evacuation may be necessary include
the following:
EXAMPLES
ASSESSMENT
1.i. Smoke from product fire
1.
Nuisance effects will last

several hours. Smoke
or gas concentrations
in open air are
unpleasant but shortterm exposure is not
likely to be dangerous.
which is allowed to burn

out. (Often safest and
least environmentally
damaging option.)
1.ii. Small/low concentration
long lasting toxic

emission.
2.
A larger long lasting

toxic gas emission
which will be carried
towards an inhabited
area after a predicted
wind change not due
for at least two hours.
2.
Area considered for

evacuation will not be
exposed to significant
danger for at least an
hour, preferably longer.
3.
Evacuation of people
from an isolated house
in the country may be
feasible, possibly using
additional BA sets.
3.
Downwind area is very

sparsely populated and
resources are available
to protect people during
their evacuation.
4.i. Righting a loaded road
4.
Area considered for

evacuation could be
exposed to danger
as a result of actions
necessary to restore
normality at a time
determined by the
recovery team.
tanker or rail tank

wagon, especially one
carrying a liquefied gas.
4.ii. Recovering or clearing
petrol from drains.

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Section 4
Numerical List of
Dangerous Goods
4.1
Explanation of headings in Numerical List
4.1.1
The headings provided in each column of this Section are

defined below:
Column 1: United Nations (UN) Number

4.1.2
The identification number shown in the first column of the

list is that allocated by the United Nations and contained
in the Recommendations on the Transport of Dangerous
Goods Model Regulations (seventeenth revised edition).
These entries can also be found in the Regulations Concerning
the International Carriage of Dangerous Goods by Rail [RID]
(2013) and in the European Agreement Concerning the
International Carriage Dangerous Goods by Road [ADR] (2013).
4.1.3
Certain United Nations numbers carry more than one entry,

each having a differing EAC, e.g. UN. 1866 and UN 1986. In
these cases the substances are carried in differing forms whose
properties pose different hazards and require separate EACs.
4.1.4
Many United Nations numbers carry the abbreviation N.O.S.

This abbreviation denotes Not Otherwise Specified. These
numbers are used for substances or articles which do not
have a discrete entry in the list of UN numbers and represent
the hazard or hazards the substance or article possesses,
e.g. UN 2929 Toxic Liquid, Flammable, Organic, N.O.S.
4.1.5
The List in this Section is displayed in UN number order. If only

the substance name is known, the UN number can be found by
reference to the alphabetical list of substances in Section 5.
Numerical list of dangerous goods 23
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Column 2: Substance
4.1.6
The names of substances in the second column of the list are by

Proper Shipping Names. Where more than one EAC is allocated
to a single UN number, the allocation of EAC is identified by
the packing group following the Proper Shipping Name.
4.1.7
The alphabetical list of substances in Section 5 indicate the

appropriate UN number for that substance. Substances shown in
BOLD CAPITAL TYPE in this list indicate the Proper Shipping
Name. Normal type indicates an alternative name with the
appropriate UN number under which the substance will appear
in this Section.
Column 3: Emergency Action Code (EAC)

4.1.8
Emergency Action Codes (commonly known as Hazchem codes)

are designed to be used by the emergency services in conjunction
with Emergency Action Code Cards, which are intended to be
carried by emergency service personnel. The cards indicate the
action that may be necessary (except additional personal
protection (APP) and the use of alcohol resistant foam) during
the first few minutes of an incident.
Column 4: Advice on Additional Personal

Protection (APP)
4.1.9
These codes appear as A or B in the List.

Note:These codes do not appear on vehicle placards or on the
Emergency Action Code Cards. Whenever an APP code is assigned
to a substance, further information shall be sought from the
appropriate authority who have access to this information, e.g.
fire and rescue service control.
4.1.10
Code letter A:Indicates that fire kit as specified in paragraph

3.1.4 with gas-tight chemical protective clothing as specified
in paragraph 4.1.11 should be worn. The fire kit is intended
to protect against one or more of the following additional
hazards which are indicated in the List by the appropriate
character(s) in brackets, following the A, as shown below:
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(c)
Liquefied gas with a boiling point below -20C
(fg) Flammable gas

(fl)
Flammable liquid
(cf) Liquefied flammable gas with a boiling point below -20C

(h)
The substance may be carried above 100C
(co) Oxidising gas with a boiling point below -20C

(!)
The substance may have a particularly deleterious effect on

chemical protective clothing
Where a thermal hazard is present [A(c), A(cf), A(co), and A(h)]

suitable thermal resistant gloves should be worn, such as those
conforming to BS EN511:2006 or BS EN407:2004.
4.1.11
Code letter B:The chemical protective clothing should be

gas-tight conforming to BS EN 943 part 2 in combination
with the breathing apparatus specified in paragraph 3.1.4.
Column 5: Hazards
4.1.12
This is sub-divided to show the primary hazard of the substance,

which determines the Class into which the substance is assigned,
and, where appropriate, the subsidiary risks. The classifications
identified are those adopted by the United Nations Committee of
Experts on the Transport of Dangerous Goods and on the Globally
Harmonised System of Classification and Labelling of Chemicals,
and are as follows:
Class 1 Explosives (Note: not included in this document)
Class 2.1 Flammable gases
Class 2.2 Non-flammable, non-toxic gases
Class 2.3 Toxic gases
Class 3 Flammable liquids and desensitised liquid explosives
Class 4.1 F lammable solids, self-reactive substances and solid
desensitised explosives
Class 4.2 Substances liable to spontaneous combustion
Class 4.3 S ubstances which in contact with water emit
flammable gases
Class 5.1 Oxidising substances
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Class 5.2 Organic peroxides

Class 6.1 Toxic substances
Class 6.2 Infectious substances
Class 7 Radioactive material
Class 8 Corrosive substances
Class 9 Miscellaneous dangerous substances and articles
Note:In this column the number following a decimal point
always indicates a sub-division of a class.
Column 6: Hazard Identification Number (HIN)

4.1.3
The HIN consists of two or three figures. In general, the figures

indicate the following hazards:
2
Emissions of gas due to pressure or to chemical reaction
Flammability of liquids (vapours) and gases or

self-heating liquids
Flammability of solids or self-heating solids
Oxidizing (fire-intensifying) effect
Toxicity (or risk of infection)
Radioactivity
Corrosivity
Risk of spontaneous, violent reaction
Note:Spontaneous violent reaction within the meaning of figure

9 includes the possibility of the risk of explosion, disintegration
and polymerization reaction with the release of considerable heat
or flammable and/or toxic gases.
4.1.14
Doubling of a figure indicates an intensification of that

particular hazard.
4.1.15
Where the hazard associated with a substance can be adequately

indicated by a single figure, this is followed by zero.
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4.1.16
The following combinations of figures, however, have a special

meaning: 22, 323, 333, 362, 382, 423, 44, 446, 462, 482, 539,
606, 623, 642, 823, 842 90 and 99. See below.
4.1.17
If the letter X prefixes a hazard identification number, this

indicates that the substance will react dangerously with water.
For these substances, water may only be used with the approval
of experts.
4.1.18
The hazard identification numbers have the following meanings:

20
Asphyxiant gas or gas with no subsidiary risk
22
Refrigerated liquefied gas, Asphyxiant
223
Refrigerated liquefied gas, flammable
225
Refrigerated liquefied gas, oxidising (fire intensifying)
23
Flammable gas
239
Flammable gas, which can spontaneously lead to violent reaction
25
Oxidising (fire-intensifying) gas
26
Toxic gas
263
Toxic gas, flammable
265
Toxic gas, oxidising (fire-intensifying)
268
Toxic gas, corrosive
30
Flammable liquid (flash-point between 23C and 60C inclusive) or

flammable liquid or solid in the molten state with a flash point above
60C, heated to a temperature equal to or above its flash point, or
self-heating liquid
323
Flammable liquid which reacts with water, emitting flammable gases
X323
Flammable liquid which reacts dangerously with water, emitting

flammable gases*
33
Highly flammable liquid (flash-point below 23C)
333
Pyrophoric liquid
X333
Pyrophoric liquid, which reacts dangerously with water*
336
Highly flammable liquid, toxic
338
Highly flammable liquid, corrosive
X338
Highly flammable liquid, corrosive, which reacts dangerously with water*
339
Highly flammable liquid which can spontaneously lead to

violent reaction
* Water not to be used except by approval of experts
Book 1.indb 27
04/04/2013 15:31
36
Flammable liquid (flash-point between 23C and 60C inclusive),

slightly toxic or self-heating liquid toxic
362
Flammable liquid, toxic, which reacts with water, emitting

flammable gases
X362
Flammable liquid, toxic, which reacts dangerously with water, emitting

flammable gases*
368
Flammable liquid, toxic, corrosive
38
Flammable liquid (flash-point between 23C and 60C inclusive),

slightly corrosive or self-heating liquid, corrosive
382
Flammable liquid, corrosive, which reacts with water, emitting

flammable gases
X382
Flammable liquid, corrosive, which reacts dangerously with water,

emitting flammable gases*
39
Flammable liquid, which can spontaneously lead to violent reaction
40
Flammable solid, or self-reactive substance, or self-heating substance
423
Solid which reacts with water, emitting flammable gas, or flammable

solid which reacts with water, emitting flammable gases or self-heating
solid which reacts with water, emitting flammable gases*
X423
Solid which reacts dangerously with water, emitting flammable gases,

or flammable solid which reacts dangerously with water, emitting
flammable gases, or self-heating solid which reacts dangerously with
water, emitting flammable gases*
43
Spontaneously flammable (Pyrophoric) solid
X432
Spontaneously flammable (pyrophoric) solid which reacts dangerously

with water, emitting flammable gases*
44
Flammable solid, in the molten state at an elevated temperature
446
Flammable solid, toxic in the molten state, at an elevated temperature
46
Flammable or self-heating solid, toxic
462
Toxic solid which reacts with water, emitting flammable gases
X462
Solid which reacts dangerously with water, emitting toxic gases*
48
Flammable or self-heating solid, corrosive
482
Corrosive solid which reacts with water, emitting corrosive gases
X482
Solid which reacts dangerously with water, emitting corrosive gases*
50
Oxidising (fire-intensifying) substance
539
Flammable organic peroxide
55
Strongly oxidising (fire-intensifying) substance
556
Strongly oxidising (fire-intensifying) substance, toxic
Book 1.indb 28
04/04/2013 15:31
558
Strongly oxidising (fire-intensifying) substance, corrosive
559
Strongly oxidising (fire-intensifying) substance, which can

spontaneously lead to violent reaction
56
Oxidising substance (fire-intensifying), toxic
568
Oxidising substance (fire-intensifying), toxic, corrosive
58
Oxidising substance (fire-intensifying), corrosive
59
Oxidising substance (fire-intensifying) which can spontaneously lead

to violent reaction
60
Toxic or slightly toxic substance
606
Infectious substance
623
Toxic liquid, which reacts with water, emitting flammable gases
63
Toxic substance, flammable (flash-point between 23C and

60C inclusive)
638
Toxic substance, flammable (flash-point between 23C and 60C

inclusive), corrosive
639
Toxic substance, flammable (flash-point not above 60C inclusive),

which can spontaneously lead to violent reaction
64
Toxic solid, flammable or self-heating
642
Toxic solid, which reacts with water, emitting flammable gases
65
Toxic substance, oxidising (fire-intensifying)
66
Highly toxic substance
663
Highly toxic substance, flammable (flash-point not above

60C inclusive)
664
Highly Toxic substance, flammable or self-heating
665
Highly toxic substance, oxidising (fire-intensifying)
668
Highly toxic substance, corrosive
X668
Highly toxic substance, corrosive, which reacts dangerously with water
669
Highly toxic substance which can spontaneously lead to a

violent reaction
68
Toxic substance, corrosive
69
Toxic or slightly toxic substance, which can spontaneously lead to

violent reaction
70
Radioactive material
78
Radioactive material, corrosive
80
Corrosive or slightly corrosive substance
Book 1.indb 29
04/04/2013 15:31
X80
Corrosive or slightly corrosive substance, which reacts dangerously

with water*
823
Corrosive liquid which reacts with water, emitting flammable gases
83
Corrosive or slightly corrosive substance, flammable (flash-point

between 23C and 60C inclusive)
X83

between 23C and 60C inclusive), which reacts dangerously with
water*
839

between 23C and 60C inclusive), which can spontaneously lead to
violent reaction
X839

between 23C and 60C inclusive), which can spontaneously lead to
violent reaction and which reacts dangerously with water*
84
Corrosive solid, flammable or self-heating
842
Corrosive solid which reacts with water, emitting flammable gases
85
Corrosive or slightly corrosive substance, oxidising (fire-intensifying)
856
Corrosive or slightly corrosive substance, oxidising (fire-intensifying)

and toxic
86
Corrosive or slightly corrosive substance, toxic
88
Highly corrosive substance
X88
Highly corrosive substance, which reacts dangerously with water*
883
Highly corrosive substance, flammable (flash-point between 23C and

60C inclusive)
884
Highly corrosive solid, flammable or self-heating
885
Highly corrosive substance, oxidising (fire-intensifying)
886
Highly corrosive substance, toxic
X886
Highly corrosive substance, toxic which reacts dangerously with water*
89
Corrosive or slightly corrosive substance, which can spontaneously

lead to violent reaction
90
Environmentally hazardous substance; miscellaneous dangerous

substances
99
Miscellaneous dangerous substance carried at an elevated temperature
Book 1.indb 30
04/04/2013 15:31
List of Dangerous Goods

UN
No
Substance
EAC
APP
Hazards
Class
HIN
Sub
Risks
1001
ACETYLENE, DISSOLVED
2SE
2.1
239
1002
AIR, COMPRESSED
2T
2.2
20
1003
AIR, REFRIGERATED LIQUID
2P
A(co)
1004
UN No. no longer in use

A(c)
1005
AMMONIA, ANHYDROUS
2RE
1006
ARGON, COMPRESSED
2T
1007
2.2
5.1
2.3
2.2
225
268
20
1008
BORON TRIFLUORIDE
2RE
1009
BROMOTRIFLUOROMETHANE
(REFRIGERANT GAS R 13B1)
2TE
2.2
20
1010
BUTADIENES, STABILIZED or
BUTADIENES AND HYDROCARBON
MIXTURE, STABILIZED
2YE
2.1
239
1011
BUTANE
2YE
2.1
23
1012
BUTYLENES MIXTURE or
1-BUTYLENE or cis-2-BUTYLENE or
trans-2-BUTYLENE
2YE
2.1
23
1013
CARBON DIOXIDE
2T
2.2
20
1014
1015
1016
CARBON MONOXIDE,
COMPRESSED
2SE
2.3
2.1
263
1017
CHLORINE
2XE
2.3
8, 5.1
265
1018
CHLORODIFLUOROMETHANE
(REFRIGERANT GAS R 22)
2TE
2.2
20
1019
1020
CHLOROPENTAFLUOROETHANE
2TE
2.2
20
1021
1-CHLORO-1,2,2,2TETRAFLUOROETHANE
2TE
2.2
20
A(c)
2.3
268
Book 1.indb 31
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1022
CHLOROTRIFLUOROMETHANE
2TE
2.2
1023
COAL GAS, COMPRESSED
2SE
2.3
2.1
263
1024
1025
1026
CYANOGEN
2PE
2.3
2.1
263
1027
CYCLOPROPANE
2YE
2.1
23
1028
DICHLORODIFLUOROMETHANE
2TE
2.2
20
1029
DICHLOROFLUOROMETHANE
2TE
2.2
20
1030
1,1-DIFLUOROETHANE
(REFRIGERANT GAS R 152a)
2YE
2.1
23
1031
1032
DIMETHYLAMINE, ANHYDROUS
2PE
2.1
23
1033
DIMETHYL ETHER
2YE
2.1
23
1034
1035
ETHANE
2YE
2.1
23
1036
ETHYLAMINE
2PE
2.1
23
Class
A(cf)
A(fg)
A(fg)
HIN
Sub
Risks
20
1037
ETHYL CHLORIDE
2YE
2.1
23
1038
ETHYLENE, REFRIGERATED LIQUID
2YE
2.1
223
1039
ETHYL METHYL ETHER
2SE
2.1
23
1040
2PE
ETHYLENE OXIDE or ETHYLENE
OXIDE WITH NITROGEN up to a total
pressure of 1MPa (10bar) at 50C
1041
ETHYLENE OXIDE AND CARBON

DIOXIDE MIXTURE with more
than9% but not more than 87%
ethylene oxide
1042
1043
FERTILIZER AMMONIATING
SOLUTION with free ammonia
2RE (1)
1044
FIRE EXTINGUISHERS with

compressed or liquefied gas
(1)
1045
FLUORINE, COMPRESSED
2PE (1)
A(fg)
2SE
2.3
2.1
2.1
263
239
2.2
2.2
2.3
5.1, 8
(1) Not applicable to the carriage of dangerous goods under RID or ADR
Book 1.indb 32
04/04/2013 15:31
UN
No
Substance
1046
HELIUM, COMPRESSED
1047
1048
HYDROGEN BROMIDE,
ANHYDROUS
EAC
APP
Hazards
Class
2T
2RE
2.2
A(c)
2.3
HIN
Sub
Risks
20
268
268
1049
HYDROGEN, COMPRESSED
2SE
1050
HYDROGEN CHLORIDE,
ANHYDROUS
2RE
A(c)
2.3
1051
HYDROGEN CYANIDE, STABILIZED

containing less than 3% water
2WE (1)
A(fl)
6.1
1052
HYDROGEN FLUORIDE,
ANHYDROUS
2XE
6.1
886
1053
HYDROGEN SULPHIDE
2WE
A(cf)
2.3
2.1
263
1054
2.1
23
1055
ISOBUTYLENE
2YE
2.1
23
1056
KRYPTON, COMPRESSED
2TE
2.2
20
1057
LIGHTERS or LIGHTER REFILLS

containing flammable gas
(1)
2.1
1058
LIQUEFIED GASES, non-flammable,

charged with nitrogen, carbon dioxide
or air
2TE
2.2
20
1059
1060
METHYLACETYLENE AND
2YE
PROPADIENE MIXTURE, STABILIZED
2.1
239
1061
METHYLAMINE, ANHYDROUS
2PE
A(fg)
2.1
23
1062
METHYL BROMIDE with not more

than 2% chloropicrin
2XE
2.3
26
1063
METHYL CHLORIDE (REFRIGERANT

GAS R 40)
2YE
2.1
23
1064
METHYL MERCAPTAN
2WE
1065
NEON, COMPRESSED
2T
A(fg)
2.3
2.1
2.2
263
20
1066
NITROGEN, COMPRESSED
2T
1067
DINITROGEN TETROXIDE
(NITROGEN DIOXIDE)
2PE
2.3
5.1, 8
1068
1069
NITROSYL CHLORIDE
2RE (1)
2.3
2.2
20
265
Book 1.indb 33
04/04/2013 15:31
UN
No
Substance
EAC
1070
NITROUS OXIDE
2P
1071
OIL GAS, COMPRESSED
2SE
1072
OXYGEN, COMPRESSED
2S
1073
OXYGEN, REFRIGERATED LIQUID
2P
1074
1075
PETROLEUM GASES, LIQUEFIED
APP
A(co)
A(co)
2YE
Hazards
HIN
Class
Sub
Risks
2.2
5.1
25
2.3
2.1
263
2.2
5.1
25
2.2
5.1
225
2.1
23
1076
PHOSGENE
2XE
1077
PROPYLENE
2YE
2.1
23
1078
REFRIGERANT GAS, N.O.S.
2TE
2.2
20
2.3
268
1079
SULPHUR DIOXIDE
2RE
1080
SULPHUR HEXAFLUORIDE
2TE
2.2
20
1081
TETRAFLUOROETHYLENE,
STABILIZED
2SE
2.1
239
1082
TRIFLUOROCHLOROETHYLENE,
STABILIZED
2WE
A(cf)
2.3
1083
TRIMETHYLAMINE, ANHYDROUS
2PE
A(fg)
2.1
23
1084
1085
VINYL BROMIDE, STABILIZED
2YE
2.1
239
1086
VINYL CHLORIDE, STABILIZED
2YE
2.1
239
2.3
2.1
268
263
1087
VINYL METHYL ETHER, STABILIZED
2YE
2.1
239
1088
ACETAL
l3YE
33
1089
ACETALDEHYDE
l2YE
33
1090
ACETONE
l2YE
33
1091
ACETONE OILS
l2YE
33
1092
ACROLEIN, STABILIZED
l2WE
6.1
663
1093
ACRYLONITRILE, STABILIZED
l3WE
A(fl)
6.1
336
1094
to
1097
UN Nos. no longer in use
1098
ALLYL ALCOHOL
l2WE
A(fl)
6.1
663
1099
ALLYL BROMIDE
2WE
A(fl)
6.1
336
1100
ALLYL CHLORIDE
3YE
6.1
336
Book 1.indb 34
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1101
to
1103
1104
AMYL ACETATES
l3Y
30
1105
PENTANOLS, packing group II
l3YE
33
1105
PENTANOLS, packing group III
l3Y
30
Class
HIN
Sub
Risks
1106
AMYLAMINE, packing group II
l2WE
A(fl)
338
1106
AMYLAMINE, packing group III
l2W
A(fl)
38
1107
AMYL CHLORIDE
3YE
33
1108
1-PENTENE (n-AMYLENE)
3YE
33
1109
AMYL FORMATES
3Y
30
1110
n-AMYL METHYL KETONE
3Y
30
33
1111
AMYL MERCAPTAN
3WE
1112
AMYL NITRATE
3Y
30
1113
AMYL NITRITE
3YE
33
1114
BENZENE
3WE
33
1115
to
1119
1120
BUTANOLS, packing group II
l2YE
33
1120
BUTANOLS, packing group III
l2Y
30
1121
1122
A(fl)
A(fl)
1123
BUTYL ACETATES, packing group II
3YE
33
1123
BUTYL ACETATES, packing group III
3Y
30
1124
1125
n-BUTYLAMINE
l2WE
1126
1-BROMOBUTANE
2YE
33
1127
CHLOROBUTANES
3YE
33
1128
n-BUTYL FORMATE
l3YE
33
1129
BUTYRALDEHYDE
l3YE
33
1130
CAMPHOR OIL
3Y
30
A(fl)
338
Book 1.indb 35
04/04/2013 15:31
UN
No
Substance
EAC
1131
CARBON DISULPHIDE
1132
1133
ADHESIVES containing flammable

liquid, packing groups I & II
l3YE
33
1133

liquid, packing group III
l3Y
30
1133

liquid (having a flash point below
23C and viscous according to ADR
2.2.3.1.4), packing group III
l3YE
33
1134
CHLOROBENZENE
2Y
30
1135
ETHYLENE CHLOROHYDRIN
l2W
A(fl)
6.1
1136
COAL TAR DISTILLATES,

FLAMMABLE, packing group II
3WE
A(fl)
33
1136

FLAMMABLE, packing group III
3W
A(fl)
30
1137
1138
1139
COATING SOLUTION, packing

groups I & II
l3YE
33
1139
COATING SOLUTION, packing

group III
l3Y
30
1139
COATING SOLUTION (having a

flash point below 23C and viscous
according to ADR 2.2.3.1.4), packing
group III
l3YE
33
1140
to
1142
1143
CROTONALDEHYDE or
CROTONALDEHYDE, STABILIZED
l2WE
1144
CROTONYLENE
3YE
339
1145
CYCLOHEXANE
3YE
33
2WE
APP
A(fl)
A(fl)
Hazards
Class
Sub
Risks
6.1
6.1
HIN
336
663
663
1146
CYCLOPENTANE
3YE
33
1147
DECAHYDRONAPHTHALENE
3Y
30
1148
DIACETONE ALCOHOL, packing

group II
l2YE
33
Book 1.indb 36
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1148
DIACETONE ALCOHOL, packing

group III
l2Y
30
1149
DIBUTYL ETHERS
3Y
30
1150
1,2-DICHLOROETHYLENE
2YE
33
1151
1152
DICHLOROPENTANES
3Y
30
1153
ETHYLENE GLYCOL DIETHYL ETHER,

packing group II
l3YE
33
1153
ETHYLENE GLYCOL DIETHYL ETHER,

packing group III
l3Y
30
1154
DIETHYLAMINE
l2WE
1155
DIETHYL ETHER (ETHYL ETHER)
l3YE
33
1156
DIETHYL KETONE
l3YE
33
1157
DIISOBUTYL KETONE
3Y
30
1158
DIISOPROPYLAMINE
l3WE
1159
DIISOPROPYL ETHER
3YE
1160
DIMETHYLAMINE AQUEOUS
SOLUTION
l2WE
1161
DIMETHYL CARBONATE
3YE
Class
A(fl)
A(fl)
3
A(fl)
HIN
Sub
Risks
338
338
33
338
33
1162
DIMETHYLDICHLOROSILANE
4WE
A(fl)
X338
1163
DIMETHYLHYDRAZINE,
UNSYMMETRICAL
l2WE
A(fl)
6.1
3, 8
663
1164
DIMETHYL SULPHIDE
3YE
33
1165
DIOXANE
l2YE
33
1166
DIOXOLANE
l2YE
33
1167
DIVINYL ETHER, STABILIZED
3YE
339
1168
1169
EXTRACTS, AROMATIC, LIQUID,

packing group II
3YE
33
1169

packing group III
3Y
30
Book 1.indb 37
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1169

(having a flash point below 23C and
viscous according to ADR 2.2.3.1.4),
packing group III
l3YE
33
1170
ETHANOL (ETHYL ALCOHOL)

or ETHANOL SOLUTION (ETHYL
ALCOHOL SOLUTION), packing
group II
l2YE
33
1170
ETHANOL (ETHYL ALCOHOL)

or ETHANOL SOLUTION (ETHYL
ALCOHOL SOLUTION), packing
group III
l2Y
30
1171
ETHYLENE GLYCOL MONOETHYL

ETHER
l2Y
30
1172

ETHER ACETATE
l2Y
30
1173
ETHYL ACETATE
l3YE
33
1174
1175
ETHYLBENZENE
3YE
33
1176
ETHYL BORATE
l3YE
33
1177
2-ETHYLBUTYL ACETATE
3Y
30
1178
2-ETHYLBUTYRALDEHYDE
3YE
33
Class
HIN
Sub
Risks
1179
ETHYL BUTYL ETHER
3YE
33
1180
ETHYL BUTYRATE
3Y
30
1181
ETHYL CHLOROACETATE
2W
1182
ETHYL CHLOROFORMATE
l3WE
A(fl)
6.1
3, 8
663
1183
ETHYLDICHLOROSILANE
4WE
A(fl)
4.3
3, 8
X338
1184
ETHYLENE DICHLORIDE
2YE
6.1
336
1185
ETHYLENEIMINE, STABILIZED
l2WE
6.1
663
1186
1187
1188
ETHYLENE GLYCOL MONOMETHYL

ETHER
l2Y
30
1189
ETHYLENE GLYCOL MONOMETHYL

ETHER ACETATE
l2Y
30
A(fl)
A(fl)
6.1
63
Book 1.indb 38
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1190
ETHYL FORMATE
l2YE
33
1191
OCTYL ALDEHYDES
3Y
30
1192
ETHYL LACTATE
l2Y
30
1193
ETHYL METHYL KETONE

(METHYL ETHYL KETONE)
l2YE
33
1194
ETHYL NITRITE SOLUTION
l2WE
1195
ETHYL PROPIONATE
l3YE
Class
A(fl)
HIN
Sub
Risks
6.1
336
33
1196
ETHYLTRICHLOROSILANE
4WE
1197
EXTRACTS, FLAVOURING, LIQUID,

packing group II
3YE
33
1197
EXTRACTS, FLAVOURING, LIQUID,

packing group III
3Y
30
1197
EXTRACTS, FLAVOURING, LIQUID

packing group III
l3YE
33
1198
FORMALDEHYDE SOLUTION,
FLAMMABLE
l2W
1199
FURALDEHYDES
1200
1201
FUSEL OIL, packing group II
A(fl)
A(fl)
X338
38
l3Y
6.1
63
l2YE
33
1201
FUSEL OIL, packing group III
l2Y
30
1202
GAS OIL or DIESEL FUEL or

HEATING OIL, LIGHT
3Y
30
1203
MOTOR SPIRIT or GASOLINE or

PETROL
3YE
33
1204
NITROGLYCERIN SOLUTION IN
ALCOHOL with not more than 1%
nitroglycerin
l2YE (1)
1205
1206
HEPTANES
3YE
33
1207
HEXALDEHYDE
3Y
30
1208
HEXANES
3YE
33
1209
Book 1.indb 39
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1210
PRINTING INK, flammable or

PRINTING INK RELATED MATERIAL
(including printing ink thinning or
reducing compound), flammable,
packing groups I & II
l3YE
33
1210

reducing compound), flammable,
packing group III
l3Y
30
1210

reducing compound), flammable
packing group III
l3YE
33
1211
1212
ISOBUTANOL (ISOBUTYL
ALCOHOL)
l3Y
30
Class
1213
ISOBUTYL ACETATE
3YE
1214
ISOBUTYLAMINE
l2WE
1215
1216
ISOOCTENES
1217
1218
1219
3
A(fl)
HIN
Sub
Risks
33
8
338
3YE
33
ISOPRENE, STABILIZED
3YE
339
ISOPROPANOL (ISOPROPYL
ALCOHOL)
l2YE
33
1220
ISOPROPYL ACETATE
l3YE
1221
ISOPROPYLAMINE
l2WE
1222
ISOPROPYL NITRATE
3YE (1)
3
A(fl)
33
8
338
1223
KEROSENE
3Y
30
1224
KETONES, LIQUID, N.O.S., packing

group II
l3YE
33
1224
KETONES, LIQUID, N.O.S., packing

group III
l3Y
30
Book 1.indb 40
04/04/2013 15:31
UN
No
Substance
EAC
1225
to
1227
1228
MERCAPTANS, LIQUID,
FLAMMABLE, TOXIC, N.O.S. or
MERCAPTAN MIXTURE, LIQUID,
FLAMMABLE, TOXIC, N.O.S.
3WE
1229
MESITYL OXIDE
l3Y
APP
A(fl)
Hazards
Class
Sub
Risks
6.1
HIN
336/36
30
1230
METHANOL
l2WE
1231
METHYL ACETATE
l2YE
33
1232
A(fl)
6.1
336
1233
METHYLAMYL ACETATE
3Y
30
1234
METHYLAL
l2YE
33
1235
METHYLAMINE, AQUEOUS
SOLUTION
l2WE
1236
1237
METHYL BUTYRATE
l3YE
1238
METHYL CHLOROFORMATE
1239
METHYL CHLOROMETHYL ETHER
1240
1241
1242
1243
A(fl)
338
2WE
A(fl)
6.1
3, 8
663
3WE
A(fl)
6.1
663
METHYLDICHLOROSILANE
4WE
A(fl)
4.3
3, 8
X338
METHYL FORMATE
l2YE
33
33
1244
METHYLHYDRAZINE
l2WE
1245
METHYL ISOBUTYL KETONE
l3YE
33
1246
METHYL ISOPROPENYL KETONE,

STABILIZED
3YE
339
1247
METHYL METHACRYLATE
MONOMER, STABILIZED
3YE
339
1248
METHYL PROPIONATE
3YE
33
1249
METHYL PROPYL KETONE
l3YE
1250
METHYLTRICHLOROSILANE
4WE
A(fl)
X338
1251
METHYL VINYL KETONE,

STABILIZED
l2WE
A(fl)
6.1
3, 8
639
A(fl)
6.1
3, 8
663
33
Book 1.indb 41
04/04/2013 15:31
UN
No
Substance
1252
to
1258
EAC
2WE
APP
Hazards
Class
Sub
Risks
6.1
1259
NICKEL CARBONYL
1260
1261
NITROMETHANE
l2Y(1)
A(fl)
HIN
663
1262
OCTANES
3YE
33
1263
PAINT (including paint, lacquer,

enamel, stain, shellac, varnish, polish,
liquid filler and liquid lacquer base)
or PAINT RELATED MATERIAL
(including paint thinning or reducing
compound), packing groups I & II
l3YE
33
1263

compound), packing group III
l3Y
30
1263

liquid filler and liquid lacquer base) or
PAINT RELATED MATERIAL
compound) (having a flash point below
l3YE
33
1264
PARALDEHYDE
l2Y
30
1265
PENTANES, liquid
3YE
33
1266
PERFUMERY PRODUCTS with

flammable solvents, packing group
II
l3YE
33
1266

flammable solvents, packing groupIII
l3Y
30
1266

flammable solvents (having a flash
point below 23C and viscous
group III
l3YE
33
1267
PETROLEUM CRUDE OIL, packing

groups I & II
3WE
33
A(fl)
Book 1.indb 42
04/04/2013 15:31
UN
No
Substance
EAC
1267
PETROLEUM CRUDE OIL, packing

group III
3W
1268
PETROLEUM DISTILLATES, N.O.S.

or PETROLEUM PRODUCTS, N.O.S.,
1268

or PETROLEUM PRODUCTS, N.O.S.,
packing group III
1269
to
1271
1272
PINE OIL
1273
1274
APP
Hazards
Class
A(fl)
HIN
Sub
Risks
30
3YE
33
3Y
30
3Y
30
n-PROPANOL (PROPYL ALCOHOL,

NORMAL), packing group II
l2YE
33
1274
n-PROPANOL (PROPYL ALCOHOL,

NORMAL), packing group III
l2Y
30
1275
PROPIONALDEHYDE
l2YE
33
1276
n-PROPYL ACETATE
l2YE
33
1277
PROPYLAMINE
l2WE
1278
1-CHLOROPROPANE
3YE
33
1279
1,2-DICHLOROPROPANE
2YE
33
1280
PROPYLENE OXIDE
l3YE
33
1281
PROPYL FORMATES
l3YE
33
1282
PYRIDINE
l2WE
33
1283
to
1285
1286
ROSIN OIL, packing group II
33
3YE
A(fl)
A(fl)
338
1286
ROSIN OIL, packing group III
3Y
30
1286
ROSIN OIL (having a flash point below

3YE
33
1287
RUBBER SOLUTION, packing

group II
3YE
33
1287
RUBBER SOLUTION, packing group III 3Y
30
Book 1.indb 43
04/04/2013 15:31
UN
No
Substance
EAC
1287
RUBBER SOLUTION (having a

flash point below 23C and viscous
group III
3YE
1288
SHALE OIL, packing group II
3WE
APP
Hazards
Class
HIN
Sub
Risks
33
A(fl)
33
1288
SHALE OIL, packing group III
3W
A(fl)
1289
SODIUM METHYLATE SOLUTION

in alcohol, packing group II
l2WE
A(fl)
338
1289
SODIUM METHYLATE SOLUTION

in alcohol, packing group III
l2W
A(fl)
38
1290
1291
1292
TETRAETHYL SILICATE
3Y
30
1293
TINCTURES, MEDICINAL, packing

group II
l2YE
33
1293
TINCTURES, MEDICINAL, packing

group III
l2Y
30
1294
TOLUENE
3YE
33
30
1295
TRICHLOROSILANE
4WE
A(fl)
4.3
3, 8
X338
1296
TRIETHYLAMINE
l2WE
A(fl)
338
1297
TRIMETHYLAMINE, AQUEOUS
SOLUTION, not more than 50%
trimethylamine, by mass, packing
groups I & II
l2WE
A(fl)
338
1297
SOLUTION, not more than 50%
trimethylamine, by mass, packing
group III
l2W
A(fl)
38
1298
TRIMETHYLCHLOROSILANE
4WE
A(fl)
X338
1299
TURPENTINE
3Y
30
1300
TURPENTINE SUBSTITUTE, packing

group II
3YE
33
1300
TURPENTINE SUBSTITUTE, packing

group III
3Y
30
1301
VINYL ACETATE, STABILIZED
l3YE
339
1302
VINYL ETHYL ETHER, STABILIZED
3YE
339
Book 1.indb 44
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1303
VINYLIDENE CHLORIDE, STABILIZED 2YE
339
1304
VINYL ISOBUTYL ETHER,

STABILIZED
3YE
339
1305
VINYLTRICHLOROSILANE
4WE
1306
WOOD PRESERVATIVES, LIQUID,

packing group II
l3YE
33
1306
WOOD PRESERVATIVES, LIQUID,

packing group III
l3Y
30
1306
WOOD PRESERVATIVES, LIQUID

packing group III
l3YE
33
1307
XYLENES, packing group II
3YE
33
Class
A(fl)
HIN
Sub
Risks
X338
1307
XYLENES, packing group III
3Y
30
1308
ZIRCONIUM SUSPENDED IN A
FLAMMABLE LIQUID, packing
groups I & II
3YE
33
1308
FLAMMABLE LIQUID, packing
group III
3Y
30
4Y
4.1
40
1309
ALUMINIUM POWDER, COATED
1310
AMMONIUM PICRATE, WETTED

1W (1)
with not less than 10% water, by mass
1311
1312
BORNEOL
1Z
4.1
4.1
40
1313
CALCIUM RESINATE
1Z
4.1
40
1314
CALCIUM RESINATE, FUSED
1Z
4.1
40
1315
to
1317
1318
COBALT RESINATE, PRECIPITATED
1Z
4.1
40
1319
1320
DINITROPHENOL, WETTED with not

less than 15% water, by mass
1W (1)
4.1
6.1
1321
DINITROPHENOLATES, WETTED
1W (1)
4.1
6.1
Book 1.indb 45
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1322
DINITRORESORCINOL, WETTED
1W (1)
4.1
1323
FERROCERIUM
1Z
4.1
1324
FILMS, NITROCELLULOSE BASE,

gelatin coated, except scrap
1Z
1325
FLAMMABLE SOLID, ORGANIC,

N.O.S.
1Z
4.1
40
1326
HAFNIUM POWDER, WETTED with

not less than 25% water
1Z
4.1
40
1327
HAY, STRAW or BHUSA
1Z (1)
4.1
1Z
4.1
40
4.1
40
Class
(1)
HIN
Sub
Risks
40
4.1
1328
HEXAMETHYLENETETRAMINE
1329
1330
MANGANESE RESINATE
1Z
1331
MATCHES, STRIKE ANYWHERE
1Z
1332
METALDEHYDE
1Z
1333
CERIUM, slabs, ingots or rods
1Z
1334
NAPHTHALENE, CRUDE or
NAPHTHALENE, REFINED
1Z
4.1
1335
1336
NITROGUANIDINE (PICRITE),
WETTED with not less than 20%
water, by mass
1W (1)
4.1
1337
NITROSTARCH, WETTED with not

1W (1)
4.1
1338
PHOSPHORUS, AMORPHOUS
1Z
4.1
40
1339
PHOSPHORUS HEPTASULPHIDE,
free from yellow and white
phosphorus
4Y
4.1
40
1340
PHOSPHORUS PENTASULPHIDE,
phosphorus
4W
4.3
1341
PHOSPHORUS SESQUISULPHIDE,
phosphorus
4Y
4.1
40
1342
1343
PHOSPHORUS TRISULPHIDE, free

from yellow and white phosphorus
4Y
4.1
40
(1)
4.1
4.1
(1)
40
4.1
40
4.1
423
Book 1.indb 46
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1344
TRINITROPHENOL (PICRIC ACID),

water, by mass
1W (1)
4.1
1345
RUBBER SCRAP or RUBBER

SHODDY, powdered or granulated
1Z
4.1
40
1346
SILICON POWDER, AMORPHOUS
1Z
4.1
40
1347
SILVER PICRATE, WETTED with not

1W (1)
4.1
1348
SODIUM DINITRO-o-CRESOLATE,
water, by mass
1W (1)
4.1
1349
SODIUM PICRAMATE, WETTED with 1W (1)

not less than 20% water, by mass
4.1
1350
SULPHUR
1Z
4.1
40
1351
1352
TITANIUM POWDER, WETTED, with

not less than 25% water
1Z
4.1
40
1353
FIBRES or FABRICS IMPREGNATED

WITH WEAKLY NITRATED
NITROCELLULOSE, N.O.S.
1Z (1)
4.1
1354
TRINITROBENZENE, WETTED with

1W (1)
4.1
1355
TRINITROBENZOIC ACID, WETTED

1W (1)
4.1
1356
TRINITROTOLUENE (TNT), WETTED 1W (1)

4.1
1357
UREA NITRATE, WETTED with not

1W (1)
4.1
1358
ZIRCONIUM POWDER, WETTED

with not less than 25% water
1Z
4.1
1359
1360
CALCIUM PHOSPHIDE
4WE (1)
4.3
1361
CARBON, animal or vegetable origin
1Y
4.2
Class
HIN
Sub
Risks
6.1
40
6.1
40
1362
CARBON, ACTIVATED
1Y
4.2
40
1363
COPRA
1Y
4.2
40
1364
COTTON WASTE, OILY
1Y
4.2
40
Book 1.indb 47
04/04/2013 15:31
UN
No
Substance
1365
COTTON, WET
1366
to
1368
1369
p-NITROSODIMETHYLANILINE
1370
1371
1372
EAC
APP
Hazards
Class
HIN
Sub
Risks
1Y
4.2
40
1Y
4.2
40
FIBRES, ANIMAL or FIBRES,

VEGETABLE burnt, wet or damp
1Y(1)
4.2
1373
FIBRES or FABRICS, ANIMAL or

VEGETABLE or SYNTHETIC, N.O.S.
with oil
1Y
4.2
40
1374
FISH MEAL (FISH SCRAP),

UNSTABILIZED
1Y
4.2
40
1375
1376
IRON OXIDE, SPENT or IRON

SPONGE, SPENT obtained from coal
gas purification
1Y
4.2
40
1377
1378
METAL CATALYST, WETTED with a

visible excess of liquid
1Y
4.2
40
1379
PAPER, UNSATURATED OIL

TREATED, incompletely dried
(including carbon paper)
1Y
4.2
40
1380
PENTABORANE
4W
4.2
6.1
333
1381
PHOSPHORUS, WHITE or YELLOW,

DRY or UNDER WATER or IN
SOLUTION
1WE
4.2
6.1
46
1382
POTASSIUM SULPHIDE,
ANHYDROUS or POTASSIUM
SULPHIDE with less than 30% water
of crystallization
1W
4.2
40
1383
PYROPHORIC METAL, N.O.S. or

PYROPHORIC ALLOY, N.O.S.
4Y
4.2
43
1384
SODIUM DITHIONITE (SODIUM

HYDROSULPHITE)
1S
4.2
40
Book 1.indb 48
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1385
SODIUM SULPHIDE, ANHYDROUS

or SODIUM SULPHIDE with less than
30% water of crystallization
1W
4.2
40
1386
SEED CAKE with more than 1.5% oil

and not more than 11% moisture
1Y
4.2
40
1387
WOOL WASTE, WET
1Y(1)
4.2
1388
1389
ALKALI METAL AMALGAM, LIQUID
4W
4.3
Class
HIN
Sub
Risks
X323
1390
ALKALI METAL AMIDES
4W
4.3
423
1391
ALKALI METAL DISPERSION

or ALKALINE EARTH METAL
DISPERSION
4W
4.3
X323
1392
ALKALINE EARTH METAL

AMALGAM, LIQUID
4W
4.3
X323
1393
ALKALINE EARTH METAL ALLOY,

N.O.S.
4W
4.3
423
1394
ALUMINIUM CARBIDE
4W
4.3
423
1395
ALUMINIUM FERROSILICON
POWDER
4W
4.3
1396
ALUMINIUM POWDER, UNCOATED
4W
1397
ALUMINIUM PHOSPHIDE
4WE
1398
ALUMINIUM SILICON POWDER,

UNCOATED
4Y
4.3
423
1399
1400
BARIUM
4W
4.3
423
6.1
4.3
(1)
4.3
462
423
6.1
1401
CALCIUM
4W
4.3
423
1402
CALCIUM CARBIDE
4W
4.3
X423/
423
1403
CALCIUM CYANAMIDE with more

than 0.1% calcium carbide
4W
4.3
423
1404
CALCIUM HYDRIDE
4W (1)
4.3
1405
CALCIUM SILICIDE
4W
4.3
423
1406
1407
CAESIUM
4W
4.3
X423
Book 1.indb 49
04/04/2013 15:31
UN
No
Substance
1408
FERROSILICON with 30% or more

but less than 90% silicon
1409
EAC
APP
Hazards
HIN
Class
Sub
Risks
4W
4.3
6.1
METAL HYDRIDES, WATERREACTIVE, N.O.S., packing group I
4W (1)
4.3
1409
METAL HYDRIDES, WATERREACTIVE, N.O.S., packing group II
4W
4.3
1410
LITHIUM ALUMINIUM HYDRIDE
4W (1)
1411
LITHIUM ALUMINIUM HYDRIDE,

ETHEREAL
4WE
1412
1413
LITHIUM BOROHYDRIDE
4W (1)
4.3
1414
LITHIUM HYDRIDE
4W (1)
4.3
1415
LITHIUM
4W
4.3
X423
1416
1417
LITHIUM SILICON
4W
4.3
423
1418
MAGNESIUM POWDER or
MAGNESIUM ALLOYS POWDER,
packing group I
4W
1418
MAGNESIUM POWDER or
MAGNESIUM ALLOYS POWDER,
packing groups II & III
1419
(1)
462
423
4.3
A(fl)
4.3
4.3
4.2
4W
4.3
4.2
MAGNESIUM ALUMINIUM
PHOSPHIDE
4WE (1)
4.3
6.1
1420
POTASSIUM METAL ALLOYS,

LIQUID
4W
4.3
X323
1421
ALKALI METAL ALLOY, LIQUID,

N.O.S.
4W
4.3
X323
1422
POTASSIUM SODIUM ALLOYS,

LIQUID
4W
4.3
X323
1423
RUBIDIUM
4W
4.3
X423
1424
1425
1426
SODIUM BOROHYDRIDE
4W (1)
4.3
1427
SODIUM HYDRIDE
4W
4.3
1428
SODIUM
4W
(1)
(1)
4.3
423
X423
Book 1.indb 50
04/04/2013 15:31
UN
No
Substance
1429
1430
EAC
APP
Hazards
Class
Sub
Risks
1431
SODIUM METHYLATE
1W
4.2
1432
SODIUM PHOSPHIDE
4WE (1)
4.3
6.1
1433
STANNIC PHOSPHIDES
4WE (1)
4.3
6.1
1434
HIN
48
1435
ZINC ASHES
4Y
4.3
1436
ZINC POWDER or ZINC DUST,

packing group I
4W (1)
4.3
4.2
1436
ZINC POWDER or ZINC DUST,

4W
4.3
4.2
1437
ZIRCONIUM HYDRIDE
4Y
4.1
40
423
423
1438
ALUMINIUM NITRATE
1Z
5.1
50
1Y
5.1
50
1Y
5.1
50
1Z
5.1
50
1439
AMMONIUM DICHROMATE
1440
1441
1442
AMMONIUM PERCHLORATE
1443
1444
AMMONIUM PERSULPHATE
1445
BARIUM CHLORATE, SOLID
1Y
5.1
6.1
56
1446
BARIUM NITRATE
1Y
5.1
6.1
56
1447
BARIUM PERCHLORATE, SOLID
1Y
5.1
6.1
56
1448
BARIUM PERMANGANATE
1Y
5.1
6.1
56
1449
BARIUM PEROXIDE
1Y
5.1
6.1
56
1450
BROMATES, INORGANIC, N.O.S.
1Y
5.1
50
1451
CAESIUM NITRATE
1Z
5.1
50
1452
CALCIUM CHLORATE
1Y
5.1
50
1453
CALCIUM CHLORITE
1Y
5.1
50
1454
CALCIUM NITRATE
1Z
5.1
50
1455
CALCIUM PERCHLORATE
1Y
5.1
50
1456
CALCIUM PERMANGANATE
1Y
5.1
50
Book 1.indb 51
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1457
CALCIUM PEROXIDE
1Y
5.1
50
1458
CHLORATE AND BORATE MIXTURE
1Y
5.1
50
1459
CHLORATE AND MAGNESIUM

CHLORIDE MIXTURE, SOLID
1Y
5.1
50
1460
1461
CHLORATES, INORGANIC, N.O.S.
1Y
5.1
50
1462
CHLORITES, INORGANIC, N.O.S.
1Y
5.1
50
1463
CHROMIUM TRIOXIDE,
ANHYDROUS
1W
5.1
1464
1465
DIDYMIUM NITRATE
1Z
5.1
50
1466
FERRIC NITRATE
1Z
5.1
50
1Z
5.1
50
Class
HIN
Sub
Risks
6.1, 8
568
1467
GUANIDINE NITRATE
1468
1469
LEAD NITRATE
1Y
5.1
6.1
56
1470
LEAD PERCHLORATE, SOLID
1Y
5.1
6.1
56
1471
LITHIUM HYPOCHLORITE, DRY or

LITHIUM HYPOCHLORITE MIXTURE
1W
5.1
1472
LITHIUM PEROXIDE
1Y
5.1
50
1473
MAGNESIUM BROMATE
1Y
5.1
50
1474
MAGNESIUM NITRATE
1Z
5.1
50
50
1475
MAGNESIUM PERCHLORATE
1Y
5.1
50
1476
MAGNESIUM PEROXIDE
1Y
5.1
50
1477
NITRATES, INORGANIC, N.O.S.
1Y
5.1
50
1478
1479
OXIDISING SOLID, N.O.S., packing

group I
1Y (1)
5.1
1479
OXIDISING SOLID, N.O.S., packing

groups II & III
1Y
5.1
50
1480
1481
PERCHLORATES, INORGANIC,
N.O.S.
1Y
5.1
50
Book 1.indb 52
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1482
PERMANGANATES, INORGANIC,
N.O.S.
1Y
5.1
50
1483
PEROXIDES, INORGANIC, N.O.S.
1Y
5.1
50
1484
POTASSIUM BROMATE
1Y
5.1
50
Class
HIN
Sub
Risks
1485
POTASSIUM CHLORATE
1Y
5.1
50
1486
POTASSIUM NITRATE
1Z
5.1
50
1487
POTASSIUM NITRATE AND SODIUM 1Y

NITRITE MIXTURE
5.1
50
1488
POTASSIUM NITRITE
5.1
50
1Y
1489
POTASSIUM PERCHLORATE
1Y
5.1
50
1490
POTASSIUM PERMANGANATE
1Y
5.1
50
1491
POTASSIUM PEROXIDE
1W (1)
5.1
1492
POTASSIUM PERSULPHATE
1Z
5.1
50
1493
SILVER NITRATE
1Y
5.1
50
1494
SODIUM BROMATE
1Y
5.1
50
1495
SODIUM CHLORATE
1Y
5.1
50
1Y
5.1
50
1496
SODIUM CHLORITE
1497
1498
SODIUM NITRATE
1Z
5.1
50
1499
SODIUM NITRATE AND POTASSIUM 1Z

NITRATE MIXTURE
5.1
50
1Z
5.1
1Y
5.1
50
50
1500
SODIUM NITRITE
1501
1502
SODIUM PERCHLORATE
1503
SODIUM PERMANGANATE
1Y
5.1
1504
SODIUM PEROXIDE
1W (1)
5.1
1505
SODIUM PERSULPHATE
1Z
5.1
6.1
56
50
1506
STRONTIUM CHLORATE
1Y
5.1
50
1507
STRONTIUM NITRATE
1Z
5.1
50
1508
STRONTIUM PERCHLORATE
1Y
5.1
50
1509
STRONTIUM PEROXIDE
1Y
5.1
50
1510
TETRANITROMETHANE
2W
6.1
5.1
665
Book 1.indb 53
04/04/2013 15:31
UN
No
Substance
1511
UREA HYDROGEN PEROXIDE
1512
ZINC AMMONIUM NITRITE
EAC
APP
Hazards
Class
Sub
Risks
1X
5.1
1Y
5.1
HIN
58
50
1513
ZINC CHLORATE
1Y
5.1
50
1514
ZINC NITRATE
1Y
5.1
50
1515
ZINC PERMANGANATE
1Y
5.1
50
1516
ZINC PEROXIDE
1Y
5.1
50
1517
ZIRCONIUM PICRAMATE, WETTED 1W

1518
to
1540
1541
ACETONE CYANOHYDRIN,
STABILIZED
1542
1543
1544
ALKALOIDS, SOLID, N.O.S. or

ALKALOID SALTS, SOLID, N.O.S.
2X
1545
ALLYL ISOTHIOCYANATE,
STABILIZED
3WE
1546
AMMONIUM ARSENATE
2Z
1547
ANILINE
l3X
6.1
60
1548
ANILINE HYDROCHLORIDE
2X
6.1
60
1549
ANTIMONY COMPOUND,
INORGANIC, SOLID, N.O.S.
2Z
6.1
60
1550
ANTIMONY LACTATE
2Z
6.1
60
6.1
60
6.1
66
l2X
1551
ANTIMONY POTASSIUM TARTRATE 2Z
1552
1553
ARSENIC ACID, LIQUID
4.1
(1)
2X
A(fl)
6.1
669
6.1
66/60
6.1
6.1
639
60
1554
ARSENIC ACID, SOLID
2Z
6.1
60
1555
ARSENIC BROMIDE
2Z
6.1
60
1556
ARSENIC COMPOUND, LIQUID,

N.O.S., inorganic, including:
Arsenates, n.o.s., Arsenites, n.o.s.,
Arsenic sulphides, n.o.s., packing
group I
2X
6.1
66
Book 1.indb 54
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1556

Arsenic sulphides, n.o.s., packing
groups II & III
2X
6.1
60
1557
ARSENIC COMPOUND, SOLID,

Arsenic sulphides, n.o.s.
2X
6.1
66/60
1558
ARSENIC
2Z
6.1
60
1559
ARSENIC PENTOXIDE
2Z
6.1
60
1560
ARSENIC TRICHLORIDE
2X
6.1
66
Class
HIN
Sub
Risks
1561
ARSENIC TRIOXIDE
2X
6.1
60
1562
ARSENICAL DUST
2Z
6.1
60
1563
1564
BARIUM COMPOUND, N.O.S.
2Z
6.1
60
1565
BARIUM CYANIDE
2X
6.1
66
1566
BERYLLIUM COMPOUND, N.O.S.
2Z
6.1
60
2Z
6.1
4.1
64
6.1
63
1567
BERYLLIUM POWDER
1568
1569
BROMOACETONE
1570
BRUCINE
2X
6.1
1571
BARIUM AZIDE, WETTED with not

1W (1)
4.1
1572
CACODYLIC ACID
2Z
6.1
60
1573
CALCIUM ARSENATE
2Z
6.1
60
1574
CALCIUM ARSENATE AND

CALCIUM ARSENITE MIXTURE,
SOLID
2Z
6.1
60
1575
CALCIUM CYANIDE
2X
6.1
66
1576
1577
CHLORODINITROBENZENES,
LIQUID
2X
6.1
60
1578
CHLORONITROBENZENES, SOLID
2X
6.1
60
2W
A(fl)
66
6.1
Book 1.indb 55
04/04/2013 15:31
UN
No
Substance
EAC
1579
4-CHLORO-o-TOLUIDINE
HYDROCHLORIDE, SOLID
2X
1580
CHLOROPICRIN
2XE
1581
CHLOROPICRIN AND METHYL

BROMIDE MIXTURE with more than
2% chloropicrin
1582
APP
Hazards
Class
HIN
Sub
Risks
6.1
60
6.1
66
2XE
2.3
26

CHLORIDE MIXTURE
2XE
A(c)
2.3
26
1583
CHLOROPICRIN MIXTURE, N.O.S.,

packing group I
2XE
6.1
66
1583
CHLOROPICRIN MIXTURE, N.O.S.,

2X
6.1
60
1584
1585
COPPER ACETOARSENITE
2Z
6.1
60
1586
COPPER ARSENITE
2Z
6.1
60
1587
COPPER CYANIDE
2X
6.1
60
1588
CYANIDES, INORGANIC, SOLID,

N.O.S.
2X
6.1
66/60
1589
CYANOGEN CHLORIDE, STABILIZED 2XE (1)
1590
DICHLOROANILINES, LIQUID
2X
6.1
60
1591
o-DICHLOROBENZENE
2Z
6.1
60
1592
1593
DICHLOROMETHANE
2Z
6.1
60
1594
DIETHYL SULPHATE
2X
6.1
60
1595
DIMETHYL SULPHATE
l3XE
2.3
6.1
668
1596
DINITROANILINES
2X
6.1
60
1597
DINITROBENZENES, LIQUID
2X
6.1
60
1598
DINITRO-o-CRESOL
2X
6.1
60
1599
DINITROPHENOL SOLUTION
2X
1600
DINITROTOLUENES, MOLTEN
2W
1601
DISINFECTANT, SOLID, TOXIC,

N.O.S.
2X
A(h)
6.1
60
6.1
60
6.1
66/60
Book 1.indb 56
04/04/2013 15:31
UN
No
Substance
EAC
1602
DYE, LIQUID, TOXIC, N.O.S. or DYE,

INTERMEDIATE, LIQUID, TOXIC,
N.O.S., packing group I
2X
1602
DYE, LIQUID, TOXIC, N.O.S. or DYE,

INTERMEDIATE, LIQUID, TOXIC,
N.O.S., packing groups II & III
2X
APP
Hazards
Class
HIN
Sub
Risks
6.1
66
6.1
60
1603
ETHYL BROMOACETATE
2W
A(fl)
6.1
63
1604
ETHYLENEDIAMINE
l2W
A(fl)
83
1605
ETHYLENE DIBROMIDE
2X
6.1
66
1606
FERRIC ARSENATE
2X
6.1
60
1607
FERRIC ARSENITE
2X
6.1
60
1608
FERROUS ARSENATE
2X
6.1
60
1609
1610
1611
HEXAETHYL TETRAPHOSPHATE
2X
6.1
60
1612
AND COMPRESSED GAS MIXTURE
2RE
2.3
26
1613
HYDROCYANIC ACID, AQUEOUS

SOLUTION (HYDROGEN CYANIDE,
AQUEOUS SOLUTION) with not more
than 20% hydrogen cyanide
l2WE
A(fl)
6.1
1614
HYDROGEN CYANIDE, STABILIZED,

containing less than 3% water and
absorbed in a porous inert material
2WE (1)
A(fl)
6.1
1615
1616
LEAD ACETATE
2Z
6.1
60
1617
LEAD ARSENATES
2Z
6.1
60
2Z
6.1
60
2Z
6.1
60
1618
LEAD ARSENITES
1619
1620
LEAD CYANIDE
663
1621
LONDON PURPLE
2X
6.1
60
1622
MAGNESIUM ARSENATE
2Z
6.1
60
1623
MERCURIC ARSENATE
2X
6.1
60
1624
MERCURIC CHLORIDE
2X
6.1
60
Book 1.indb 57
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1625
MERCURIC NITRATE
2X
6.1
60
1626
MERCURIC POTASSIUM CYANIDE
2X
6.1
66
2X
6.1
60
Class
HIN
Sub
Risks
1627
MERCUROUS NITRATE
1628
1629
MERCURY ACETATE
2X
6.1
60
1630
MERCURY AMMONIUM CHLORIDE
2X
6.1
60
2X
6.1
60
2X
6.1
60
2X
6.1
60
1631
MERCURY BENZOATE
1632
1633
1634
MERCURY BROMIDES
1635
1636
MERCURY CYANIDE
1637
MERCURY GLUCONATE
2X
6.1
60
1638
MERCURY IODIDE
2X
6.1
60
1639
MERCURY NUCLEATE
2X
6.1
60
1640
MERCURY OLEATE
2X
6.1
60
1641
MERCURY OXIDE
2X
6.1
60
1642
MERCURY OXYCYANIDE,
DESENSITIZED
2X
6.1
60
1643
MERCURY POTASSIUM IODIDE
2X
6.1
60
1644
MERCURY SALICYLATE
2X
6.1
60
1645
MERCURY SULPHATE
2X
6.1
60
1646
MERCURY THIOCYANATE
2X
6.1
60
1647
METHYL BROMIDE AND ETHYLENE

DIBROMIDE MIXTURE, LIQUID
2X
6.1
66
1648
ACETONITRILE
l2YE
33
1649
MOTOR FUEL ANTI-KNOCK

MIXTURE
2WE
6.1
66
1650
beta-NAPHTHYLAMINE, SOLID
2Z
6.1
60
1651
NAPHTHYLTHIOUREA
2Z
6.1
60
1652
NAPHTHYLUREA
2X
6.1
60
1653
NICKEL CYANIDE
2X
6.1
60
Book 1.indb 58
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1654
NICOTINE
2X
6.1
60
1655
NICOTINE COMPOUND, SOLID,

N.O.S. or NICOTINE PREPARATION,
SOLID, N.O.S.
2X
6.1
66/60
1656
NICOTINE HYDROCHLORIDE,
LIQUID or SOLUTION
2X
6.1
60
1657
NICOTINE SALICYLATE
2X
6.1
60
1658
NICOTINE SULPHATE, SOLUTION
2X
6.1
60
Class
1659
NICOTINE TARTRATE
2X
1660
NITRIC OXIDE, COMPRESSED
2PE (1)
1661
NITROANILINES (o-,m-,p-)
2X
6.1
B
2.3
6.1
HIN
Sub
Risks
60
5.1, 8
60
1662
NITROBENZENE
2X
6.1
60
1663
NITROPHENOLS (o-,m-,p-)
2X
6.1
60
1664
NITROTOLUENES, LIQUID
2X
6.1
60
1665
NITROXYLENES, LIQUID
2X
6.1
60
1666
to
1668
1669
PENTACHLOROETHANE
2Z
1670
PERCHLOROMETHYL MERCAPTAN
2XE
1671
PHENOL, SOLID
2X
6.1
60
6.1
66
6.1
60
1672
PHENYLCARBYLAMINE CHLORIDE
2XE
6.1
66
1673
PHENYLENEDIAMINES (o-,m-,p-)
2X
6.1
60
1674
PHENYLMERCURIC ACETATE
2X
6.1
60
1675
1676
1677
POTASSIUM ARSENATE
2X
6.1
60
1678
POTASSIUM ARSENITE
2X
6.1
60
1679
POTASSIUM CUPROCYANIDE
2X
6.1
60
1680
POTASSIUM CYANIDE, SOLID
2X
6.1
66
1681
1682
Book 1.indb 59
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1683
SILVER ARSENITE
2Z
6.1
60
1684
SILVER CYANIDE
2X
6.1
60
Class
HIN
Sub
Risks
1685
SODIUM ARSENATE
2X
6.1
60
1686
SODIUM ARSENITE, AQUEOUS

SOLUTION
2X
6.1
60
1687
SODIUM AZIDE
2XE (1)
6.1
1688
SODIUM CACODYLATE
2X
6.1
60
1689
SODIUM CYANIDE, SOLID
2X
6.1
66
1690
SODIUM FLUORIDE, SOLID
2Z
6.1
60
1691
STRONTIUM ARSENITE
2Z
6.1
60
1692
STRYCHNINE or STRYCHNINE SALTS 2X
6.1
66
1693
TEAR GAS SUBSTANCE, LIQUID,

2XE
6.1
66
1693

N.O.S., packing group II
2XE
6.1
60
1694
BROMOBENZYL CYANIDES, LIQUID
2XE
6.1
66
1695
CHLOROACETONE, STABILIZED
l2WE
A(fl)
6.1
1696
1697
CHLOROACETOPHENONE, SOLID
2Z
6.1
60
1698
DIPHENYLAMINE CHLOROARSINE
2XE
6.1
66
1699
DIPHENYLCHLOROARSINE, LIQUID
2XE
6.1
66
1700
TEAR GAS CANDLES
2X
1701
XYLYL BROMIDE, LIQUID
2XE
6.1
60
1702
1,1,2,2-TETRACHLOROETHANE
2X
6.1
60
1703
1704
TETRAETHYL
DITHIOPYROPHOSPHATE
2X
6.1
60
1705
1706
(1)
6.1
3, 8
663
4.1
1707
THALLIUM COMPOUND, N.O.S.
2Z
6.1
60
1708
TOLUIDINES, LIQUID
l3X
6.1
60
1709
2,4-TOLUYLENEDIAMINE, SOLID
2X
6.1
60
Book 1.indb 60
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1710
TRICHLOROETHYLENE
2Z
6.1
60
1711
XYLIDINES, LIQUID
2X
6.1
60
1712
ZINC ARSENATE, ZINC ARSENITE

or ZINC ARSENATE AND ZINC
ARSENITE MIXTURE
2Z
6.1
60
1713
ZINC CYANIDE
2X
6.1
66
1714
ZINC PHOSPHIDE
4WE
1715
ACETIC ANHYDRIDE
l3W
1716
ACETYL BROMIDE
4W
Class
(1)
A(fl)
HIN
Sub
Risks
4.3
6.1
83
80
1717
ACETYL CHLORIDE
4WE
1718
BUTYL ACID PHOSPHATE
2X
80
1719
CAUSTIC ALKALI LIQUID, N.O.S.
2R
80
1720
1721
1722
ALLYL CHLOROFORMATE
l3WE
A(fl)
6.1
3, 8
668
1723
ALLYL IODIDE
2WE
A(fl)
338
1724
ALLYLTRICHLOROSILANE,
STABILIZED
4W
A(fl)
X839
1725
ALUMINIUM BROMIDE,
ANHYDROUS
4W
80
1726
ALUMINIUM CHLORIDE,
ANHYDROUS
4W
80
1727
AMMONIUM
HYDROGENDIFLUORIDE, SOLID
2X
80
1728
AMYLTRICHLOROSILANE
4W
X80
1729
ANISOYL CHLORIDE
4W
80
1730
ANTIMONY PENTACHLORIDE,
LIQUID
4WE
X80
1731
ANTIMONY PENTACHLORIDE
SOLUTION
4WE
80
A(fl)
1732
ANTIMONY PENTAFLUORIDE
4W
1733
ANTIMONY TRICHLORIDE
4W
1734
6.1
X338
86
80
Book 1.indb 61
04/04/2013 15:31
UN
No
Substance
1735
1736
BENZOYL CHLORIDE
EAC
APP
Hazards
Class
4W
HIN
Sub
Risks
80
1737
BENZYL BROMIDE
2X
6.1
68
1738
BENZYL CHLORIDE
2X
6.1
68
1739
BENZYL CHLOROFORMATE
2X
1740
HYDROGENDIFLUORIDES, SOLID,
N.O.S.
2X
88
80
1741
BORON TRICHLORIDE
2WE
1742
BORON TRIFLUORIDE ACETIC ACID

COMPLEX, LIQUID
2X
80
1743
BORON TRIFLUORIDE PROPIONIC

ACID COMPLEX, LIQUID
2X
80
1744
BROMINE or BROMINE SOLUTION
2XE
6.1
886
1745
BROMINE PENTAFLUORIDE
4WE
A(!)
5.1
6.1, 8
568
2.3
268
1746
BROMINE TRIFLUORIDE
4WE
A(!)
5.1
6.1, 8
568
1747
BUTYLTRICHLOROSILANE
4W
A(fl)
X83
1748
CALCIUM HYPOCHLORITE, DRY

or CALCIUM HYPOCHLORITE
MIXTURE, DRY with more than 39%
available chlorine (8.8% available
oxygen)
1W
5.1
50
1749
CHLORINE TRIFLUORIDE
2WE
2.3
5.1, 8
265
1750
CHLOROACETIC ACID SOLUTION
2X
6.1
68
1751
CHLOROACETIC ACID, SOLID
2X
6.1
68
1752
CHLOROACETYL CHLORIDE
2XE
6.1
668
X80
X88
A(!)
1753
CHLOROPHENYLTRICHLOROSILANE
4W
1754
CHLOROSULPHONIC ACID (with or

without sulphur trioxide)
4WE
1755
CHROMIC ACID SOLUTION
2X
80
1756
CHROMIC FLUORIDE, SOLID
2X
80
1757
CHROMIC FLUORIDE SOLUTION
2X
1758
CHROMIUM OXYCHLORIDE
4WE
1759
CORROSIVE SOLID, N.O.S.
2X
1760
CORROSIVE LIQUID, N.O.S.,

packing group I
2X
80
X88
88/80
88
Book 1.indb 62
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1760
CORROSIVE LIQUID, N.O.S.,

2X
1761
CUPRIETHYLENEDIAMINE
SOLUTION
2X
1762
CYCLOHEXENYLTRICHLOROSILANE
4W
X80
1763
CYCLOHEXYLTRICHLOROSILANE
4W
X80
Class
HIN
Sub
Risks
80
6.1
86
1764
DICHLOROACETIC ACID
2X
80
1765
DICHLOROACETYL CHLORIDE
4W
X80
1766
DICHLOROPHENYLTRICHLOROSILANE
4W
X80
1767
DIETHYLDICHLOROSILANE
4W
1768
DIFLUOROPHOSPHORIC ACID,
ANHYDROUS
2X
80
1769
DIPHENYLDICHLOROSILANE
4W
X80
1770
DIPHENYLMETHYL BROMIDE
2X
80
4W
X80
80
A(fl)
1771
DODECYLTRICHLOROSILANE
1772
1773
FERRIC CHLORIDE, ANHYDROUS
2X
1774
FIRE EXTINGUISHER CHARGES,

corrosive liquid
(1)
X83
1775
FLUOROBORIC ACID
2X
80
1776
FLUOROPHOSPHORIC ACID,
ANHYDROUS
2X
80
1777
FLUOROSULPHONIC ACID
4WE
88
1778
FLUOROSILICIC ACID
2X
80
1779
FORMIC ACID with more than 85%

acid by mass
l2W
A(fl)
83
1780
FUMARYL CHLORIDE
4W
80
1781
HEXADECYLTRICHLOROSILANE
4W
X80
1782
HEXAFLUOROPHOSPHORIC ACID
2X
80
1783
HEXAMETHYLENEDIAMINE
SOLUTION
2X
80
1784
HEXYLTRICHLOROSILANE
4W
X80
1785
Book 1.indb 63
04/04/2013 15:31
UN
No
Substance
EAC
1786
HYDROFLUORIC ACID AND

SULPHURIC ACID MIXTURE
2W
1787
HYDRIODIC ACID
2R
80
1788
HYDROBROMIC ACID
2R
80
1789
HYDROCHLORIC ACID
2R
1790
HYDROFLUORIC ACID with

more than 60% hydrogen fluoride,
packing group I
2W
1790
HYDROFLUORIC ACID with not more 2X

than 60% hydrogen fluoride, packing
group II
APP
Hazards
Class
Sub
Risks
6.1
8
B
HIN
886
80
6.1
886
6.1
86
1791
HYPOCHLORITE SOLUTION
2X
80
1792
IODINE MONOCHLORIDE, SOLID
4WE
80
1793
ISOPROPYL ACID PHOSPHATE
2X
80
1794
LEAD SULPHATE with more than

3% free acid
2X
80
1795
1796
NITRATING ACID MIXTURE with

more than 50% nitric acid, packing
group I
2P
1796
NITRATING ACID MIXTURE with not

more than 50% nitric acid, packing
group II
2R
1797
1798
NITROHYDROCHLORIC ACID
2P (1)
1799
NONYLTRICHLOROSILANE
4W
X80
1800
OCTADECYLTRICHLOROSILANE
4W
X80
5.1
885
80
1801
OCTYLTRICHLOROSILANE
4W
1802
PERCHLORIC ACID with not more

than 50% acid, by mass
2P
1803
PHENOLSULPHONIC ACID, LIQUID
2X
80
1804
PHENYLTRICHLOROSILANE
4W
X80
X80
5.1
85
1805
PHOSPHORIC ACID, SOLUTION
2R
80
1806
PHOSPHORUS PENTACHLORIDE
4W
80
1807
PHOSPHORUS PENTOXIDE
2X
80
Book 1.indb 64
04/04/2013 15:31
UN
No
Substance
EAC
APP
1808
PHOSPHORUS TRIBROMIDE
4WE
1809
PHOSPHORUS TRICHLORIDE
4WE
B
B
Hazards
Class
HIN
Sub
Risks
X80
6.1
668
1810
PHOSPHORUS OXYCHLORIDE
4WE
6.1
X668
1811
POTASSIUM
2X
6.1
86
1812
POTASSIUM FLUORIDE, SOLID
2X
6.1
60
1813
POTASSIUM HYDROXIDE, SOLID
2W
80
1814
POTASSIUM HYDROXIDE
SOLUTION
2R
80
1815
PROPIONYL CHLORIDE
l3WE
A(fl)
338
1816
PROPYLTRICHLOROSILANE
4W
A(fl)
X83
1817
PYROSULPHURYL CHLORIDE
4WE
X80
1818
SILICON TETRACHLORIDE
4WE
X80
1819
SODIUM ALUMINATE SOLUTION
2R
80
1820
to
1822
1823
SODIUM HYDROXIDE, SOLID
2W
80
1824
SODIUM HYDROXIDE SOLUTION
2R
80
1825
SODIUM MONOXIDE
2W
1826
NITRATING ACID MIXTURE, SPENT,

with more than 50% nitric acid,
packing group I
2W
1826
NITRATING ACID MIXTURE, SPENT,

with not more than 50% nitric acid,
packing groupII
2X
80
1827
STANNIC CHLORIDE, ANHYDROUS
4WE
X80
8
B
80
5.1
885
1828
SULPHUR CHLORIDES
4WE
X88
1829
SULPHUR TRIOXIDE, STABILIZED
4WE
X88
1830
SULPHURIC ACID with more than

51% acid
2P
80
1831
SULPHURIC ACID, FUMING
4WE
6.1
X886
1832
SULPHURIC ACID, SPENT
2W
80
1833
SULPHUROUS ACID
2R
80
Book 1.indb 65
04/04/2013 15:31
UN
No
Substance
EAC
1834
SULPHURYL CHLORIDE
4WE
1835
TETRAMETHYLAMMONIUM
HYDROXIDE SOLUTION
2X
1836
THIONYL CHLORIDE
4WE
1837
THIOPHOSPHORYL CHLORIDE
4WE
1838
TITANIUM TETRACHLORIDE
4WE
1839
TRICHLOROACETIC ACID
2X
APP
Hazards
Class
Sub
Risks
6.1
HIN
X668
80
X88
6.1
X80
8
X668
80
1840
ZINC CHLORIDE SOLUTION
2X
80
1841
ACETALDEHYDE AMMONIA
2Z
90
1842
1843
AMMONIUM DINITRO-oCRESOLATE, SOLID
2X
6.1
60
1844
1845
CARBON DIOXIDE, SOLID (dry ice) 2T (1)
1846
CARBON TETRACHLORIDE
2Z
6.1
60
1847
POTASSIUM SULPHIDE, HYDRATED

with not less than 30% water of
crystallisation
2X
80
1848
PROPIONIC ACID with not less than

10% and less than 90% acid by mass
l2W
80
1849
SODIUM SULPHIDE, HYDRATED

2X
80
1850

2X
6.1
60
43
1851
MEDICINE, LIQUID, TOXIC, N.O.S.
1852
1853
1854
BARIUM ALLOYS, PYROPHORIC
4Y
4.2
1855
CALCIUM, PYROPHORIC or
CALCIUM ALLOYS, PYROPHORIC
4W (1)
4.2
1856
RAGS, OILY
1Y(1)
4.2
1857
TEXTILE WASTE, WET
1Y
4.2
1858
HEXAFLUOROPROPYLENE
2TE
1859
SILICON TETRAFLUORIDE
2PE
(1)
2.2
B
2.3
20
8
268
Book 1.indb 66
04/04/2013 15:31
UN
No
Substance
1860
VINYL FLUORIDE, STABILIZED
1861
EAC
APP
Hazards
Class
2YE
HIN
Sub
Risks
2.1
239
1862
ETHYL CROTONATE
3YE
33
1863
FUEL, AVIATION, TURBINE ENGINE,

3YE
33
1863
FUEL, AVIATION, TURBINE ENGINE,

packing group III
3Y
30
1864
1865
n-PROPYL NITRATE
3YE (1)
1866
RESIN SOLUTION, flammable,

l3YE
33
1866
RESIN SOLUTION, flammable,

packing group III
l3Y
30
1866
RESIN SOLUTION, flammable (having

a flash point below 23C and viscous
group III
l3YE
33
1867
1868
DECABORANE
1X
4.1
1869
MAGNESIUM or MAGNESIUM
ALLOYS with more than 50%
magnesium in pellets, turnings or
ribbons
1Z
4.1
1870
POTASSIUM BOROHYDRIDE
4W (1)
4.3
6.1
46
40
1871
TITANIUM HYDRIDE
1Y
4.1
1872
LEAD DIOXIDE
1X
5.1
6.1
56
1873
PERCHLORIC ACID with more than

50% but not more than 72% acid,
by mass
2P
5.1
558
1874
to
1883
1884
BARIUM OXIDE
2Z
6.1
60
1885
BENZIDINE
2Z
6.1
60
40
1886
BENZYLIDENE CHLORIDE
2Z
6.1
60
1887
BROMOCHLOROMETHANE
2X
6.1
60
Book 1.indb 67
04/04/2013 15:31
UN
No
Substance
EAC
1888
CHLOROFORM
2Z
1889
CYANOGEN BROMIDE
2XE
1890
1891
ETHYL BROMIDE
2W
1892
ETHYLDICHLOROARSINE
2XE
1893
APP
Hazards
Class
6.1
6.1
HIN
Sub
Risks
60
8
668
6.1
60
6.1
66
1894
PHENYLMERCURIC HYDROXIDE
2X
6.1
60
1895
PHENYLMERCURIC NITRATE
2X
6.1
60
1896
1897
TETRACHLOROETHYLENE
2Z
6.1
60
1898
ACETYL IODIDE
4W
80
1899
to
1901
1902
DIISOOCTYL ACID PHOSPHATE
2X
80
1903
DISINFECTANT, LIQUID,
CORROSIVE, N.O.S., packing group I
2X
88
1903
CORROSIVE, N.O.S.,
2X
80
1904
1905
SELENIC ACID
2X
88
1906
SLUDGE ACID
2W
80
1907
SODA LIME with more than 4%

sodium hydroxide
2X
80
1908
CHLORITE SOLUTION
2X
80
1909
1910
CALCIUM OXIDE
2X (1)
1911
DIBORANE
2PE
1912
METHYL CHLORIDE AND

METHYLENE CHLORIDE MIXTURE
2YE
(1)
8
A(fg)
2.3
2.1
2.1
23
1913
NEON, REFRIGERATED LIQUID
2T
2.2
22
1914
BUTYL PROPIONATES
3Y
30
Book 1.indb 68
04/04/2013 15:31
UN
No
Substance
EAC
1915
CYCLOHEXANONE
l3Y
1916
2,2-DICHLORODIETHYL ETHER
l3W
APP
Hazards
Class
3
A(fl)
6.1
HIN
Sub
Risks
30
3
63
1917
ETHYL ACRYLATE, STABILIZED
l3WE
339
1918
ISOPROPYLBENZENE
3Y
30
1919
METHYL ACRYLATE, STABILIZED
3WE
339
1920
NONANES
3Y
30
1921
PROPYLENEIMINE, STABILIZED
l2WE
A(fl)
6.1
336
1922
PYRROLIDINE
l2WE
A(fl)
338
1923
CALCIUM DITHIONITE (CALCIUM

HYDROSULPHITE)
1S
1924
to
1927
1928
METHYL MAGNESIUM BROMIDE IN 4WE

ETHYL ETHER
1929
POTASSIUM DITHIONITE
(POTASSIUM HYDROSULPHITE)
1930
1931
4.2
A(fl)
4.3
40
X323
1S
4.2
40
ZINC DITHIONITE (ZINC

HYDROSULPHITE)
2Z
90
1Y
4.2
40
6.1
66
1932
ZIRCONIUM SCRAP
1933
1934
1935
CYANIDE SOLUTION, N.O.S.,

packing group I
2X
1935
CYANIDE SOLUTION, N.O.S.,

2X
6.1
60
1936
1937
1938
BROMOACETIC ACID SOLUTION
2X
80
1939
PHOSPHORUS OXYBROMIDE
4W
80
1940
THIOGLYCOLIC ACID
2X
80
1941
DIBROMODIFLUOROMETHANE
2Z
90
1942
AMMONIUM NITRATE
1Z
5.1
50
Book 1.indb 69
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1943
1944
MATCHES, SAFETY (book, card or

strike on box)
1Z (1)
4.1
1945
MATCHES, WAX VESTA
1Z (1)
4.1
1946
to
1949
1950
AEROSOLS
(1)
Class
HIN
Sub
Risks
(3)
1951
ARGON, REFRIGERATED LIQUID
2T
2.2
22
1952

DIOXIDE MIXTURE with not more
than 9% ethylene oxide
2T
2.2
20
1953
COMPRESSED GAS, TOXIC,

FLAMMABLE, N.O.S.
2PE
1954
COMPRESSED GAS, FLAMMABLE,

N.O.S.
2SE
1955
COMPRESSED GAS, TOXIC, N.O.S.
2RE
1956
COMPRESSED GAS, N.O.S.
2TE
A(fg)
2.3
2.1
263
2.1
23
2.3
26
2.2
20
1957
DEUTERIUM, COMPRESSED
2SE
2.1
23
1958
1,2-DICHLORO-1,1,2,2TETRAFLUOROETHANE
2TE
2.2
20
1959
1,1-DIFLUOROETHYLENE
2YE
2.1
239
1960
1961
ETHANE, REFRIGERATED LIQUID
2YE
2.1
223
1962
ETHYLENE
2SE
2.1
23
1963
HELIUM, REFRIGERATED LIQUID
2T
2.2
22
1964
HYDROCARBON GAS MIXTURE,

COMPRESSED, N.O.S.
2SE
2.1
23
1965

LIQUEFIED, N.O.S.
2YE
2.1
23
1966
HYDROGEN, REFRIGERATED LIQUID 2YE
2.1
223
1967
INSECTICIDE GAS, TOXIC, N.O.S.
2XE
2.3
26
1968
INSECTICIDE GAS, N.O.S.
2TE
2.2
20
A(c)
(1) Not applicable to the carriage of dangerous goods under RID or ADR (3) Various
Book 1.indb 70
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1969
ISOBUTANE
2YE
2.1
23
1970
KRYPTON, REFRIGERATED LIQUID
2TE
2.2
22
1971
METHANE, COMPRESSED or
NATURAL GAS, COMPRESSED with
high methane content
2SE
2.1
23
1972
METHANE, REFRIGERATED LIQUID

or NATURAL GAS, REFRIGERATED
LIQUID with high methane content
2YE
2.1
223
1973
CHLORODIFLUOROMETHANE AND
MIXTURE with fixed boiling
point, with approximately
49% chlorodifluoromethane
(REFRIGERANT GAS R502)
2TE
2.2
20
1974
CHLORODIFLUOROBROMOMETHANE
(REFRIGERANT GAS R 12B1)
2TE
2.2
20
1975
NITRIC OXIDE AND DINITROGEN

TETROXIDE MIXTURE (NITRIC
OXIDE AND NITROGEN DIOXIDE
MIXTURE)
2PE (1)
1976
OCTAFLUOROCYCLOBUTANE
(REFRIGERANT GAS RC 318)
2TE
2.2
20
1977
NITROGEN, REFRIGERATED LIQUID
2T
2.2
22
1978
PROPANE
2YE
2.1
23
1979
to
1981
1982
TETRAFLUOROMETHANE
2TE
2.2
20
1983
1-CHLORO-2,2,22TE
TRIFLUOROETHANE (REFRIGERANT
GAS R 133a)
2.2
20
1984
TRIFLUOROMETHANE
2.2
20
1985
1986
ALCOHOLS, FLAMMABLE, TOXIC,

N.O.S., packing groups I & II
l3WE
A(fl)
6.1
336
1986
ALCOHOLS, FLAMMABLE, TOXIC,

N.O.S., packing group III
l3W
A(fl)
6.1
36
Class
2T
2.3
HIN
Sub
Risks
5.1, 8
Book 1.indb 71
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
1987
ALCOHOLS, N.O.S., packing group II
l3YE
33
1987
ALCOHOLS, N.O.S., packing

group III
l3Y
30
1988
ALDEHYDES, FLAMMABLE, TOXIC,

l3WE
A(fl)
6.1
336
1988
ALDEHYDES, FLAMMABLE, TOXIC,

l3W
A(fl)
6.1
36
1989
ALDEHYDES, N.O.S., packing

groups I & II
l3YE
33
1989
ALDEHYDES, N.O.S., packing

group III
l3Y
30
Class
HIN
Sub
Risks
1990
BENZALDEHYDE
3Z
1991
CHLOROPRENE, STABILIZED
l3YE
6.1
336
1992
FLAMMABLE LIQUID, TOXIC,

l3WE
A(fl)
6.1
336
1992

l3W
A(fl)
6.1
36
1993
FLAMMABLE LIQUID, N.O.S.,

l3YE
33
1993
FLAMMABLE LIQUID, N.O.S.,

packing group III
l3Y
30
1993
FLAMMABLE LIQUID, N.O.S. (having

a flash point below 23C and viscous
group III
l3YE
33
1994
IRON PENTACARBONYL
2WE
A(fl)
6.1
1995
to
1998
1999
TARS, LIQUID, including road oils, and 2WE

cutback bitumens, packing group II
A(fl)
33
1999
TARS, LIQUID, including road oils, and 2W

cutback bitumens, packing group III
A(fl)
30
1999
TARS, LIQUID, including road oils, and 2WE

cutback bitumens (having a flash point
below 23C and viscous according to
ADR 2.2.3.1.4), packing group III
A(fl)
33
90
663
Book 1.indb 72
04/04/2013 15:31
UN
No
Substance
EAC
2000
CELLULOID in block, rods, rolls,

sheets, tubes, etc., except scrap
2001
COBALT NAPHTHENATES, POWDER 1Z
2002
CELLULOID, SCRAP
2003
2004
MAGNESIUM DIAMIDE
2005
2006
PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S.
2007
2008
APP
Hazards
Class
1Z (1)
1Y
HIN
Sub
Risks
4.1
4.1
40
4.2
(1)
1Y
4.2
1Y(1)
4.2
ZIRCONIUM POWDER, DRY
4Y
4.2
43/40
2009
ZIRCONIUM, DRY, finished sheets,

strip or coiled wire
1Y
4.2
40
2010
MAGNESIUM HYDRIDE
4WE (1)
4.3
(1)
40
2011
MAGNESIUM PHOSPHIDE
4WE
4.3
6.1
2012
POTASSIUM PHOSPHIDE
4WE (1)
4.3
6.1
2013
STRONTIUM PHOSPHIDE
4WE
4.3
6.1
2014
HYDROGEN PEROXIDE, AQUEOUS

SOLUTION with not less than 20%
but not more than 60% hydrogen
peroxide (stabilized as necessary)
2P
5.1
58
2015

SOLUTION, STABILIZED with more
than 60% hydrogen peroxide
2P
5.1
559
2016
AMMUNITION, TOXIC,
NONEXPLOSIVE
2X (1)
6.1
2017
AMMUNITION, TEAR-PRODUCING,
NON-EXPLOSIVE
2XE (1)
6.1
2018
CHLOROANILINES, SOLID
2X
6.1
60
2019
CHLOROANILINES, LIQUID
2X
6.1
60
(1)
2020
CHLOROPHENOLS, SOLID
2X
6.1
60
2021
CHLOROPHENOLS, LIQUID
2X
6.1
60
2022
CRESYLIC ACID
3X
6.1
68
2023
EPICHLOROHYDRIN
l3W
6.1
63
A(fl)
Book 1.indb 73
04/04/2013 15:31
UN
No
Substance
EAC
2024
MERCURY COMPOUND, LIQUID,

2X
2024

2025
APP
Hazards
Class
HIN
Sub
Risks
6.1
66
2X
6.1
60
MERCURY COMPOUND, SOLID,

N.O.S.
2X
6.1
66/60
2026
PHENYLMERCURIC COMPOUND,
N.O.S.
2X
6.1
66/60
2027
SODIUM ARSENITE, SOLID
2Z
6.1
60
2028
BOMBS, SMOKE, NON-EXPLOSIVE

2X
with corrosive liquid, without initiating
device
2029
HYDRAZINE, ANHYDROUS
l2WE (1)
A(fl)
3, 6.1
2030
HYDRAZINE AQUEOUS SOLUTION

with more than 37% hydrazine by
mass, packing group I
l2X
6.1
886
2030
HYDRAZINE AQUEOUS SOLUTION

with more than 37% hydrazine by
mass, packing groups II & III
6.1
86
2031
NITRIC ACID, other than red fuming,

with more than 70% nitric acid
2P
5.1
885
2031

with at least 65%, but not more than
70% nitric acid
2R
5.1
85
2031

with less than 65% nitric acid
2R
2032
NITRIC ACID, RED FUMING
2PE
(1)
l2X
80
5.1, 6.1 856
2033
POTASSIUM MONOXIDE
2W
80
2034
HYDROGEN AND METHANE

MIXTURE, COMPRESSED
2SE
2.1
23
2035
1,1,1-TRIFLUOROETHANE
2YE
2.1
23
2036
XENON
2TE
2.2
2037
RECEPTACLES, SMALL,
CONTAINING GAS (GAS
CARTRIDGES)
(1)
2038
DINITROTOLUENES, LIQUID
2X
6.1
20
(3)
60
(1) Not applicable to the carriage of dangerous goods under RID or ADR (3) Various
Book 1.indb 74
04/04/2013 15:31
UN
No
Substance
2039
to
2043
EAC
APP
Hazards
Class
HIN
Sub
Risks
2044
2,2-DIMETHYLPROPANE
2YE
2.1
23
2045
ISOBUTYRALDEHYDE (ISOBUTYL
ALDEHYDE)
l2YE
33
2046
CYMENES
3Y
30
2047
DICHLOROPROPENES, packing
groupII
2YE
33
2047
DICHLOROPROPENES, packing
groupIII
2Y
30
2048
DICYCLOPENTADIENE
3Y
30
2049
DIETHYLBENZENE
3Y
30
2050
DIISOBUTYLENE, ISOMERIC
COMPOUNDS
3YE
33
2051
2-DIMETHYLAMINOETHANOL
l2W
A(fl)
83
2052
DIPENTENE
3Y
30
2053
METHYL ISOBUTYL CARBINOL
l3Y
30
2054
MORPHOLINE
l2W
2055
STYRENE MONOMER, STABILIZED
3Y
2056
TETRAHYDROFURAN
l2YE
33
2057
TRIPROPYLENE, packing group II
3YE
33
2057
TRIPROPYLENE, packing group III
3Y
30
A(fl)
8
3
883
39
2058
VALERALDEHYDE
3YE
33
2059
NITROCELLULOSE SOLUTION,
FLAMMABLE, packing groups I & II
l2YE
33
2059
NITROCELLULOSE SOLUTION,
FLAMMABLE, packing group III
l2Y
30
2060
to
2066
2067
AMMONIUM NITRATE BASED

FERTILIZER
1Z
5.1
50
2068
to
2070
Book 1.indb 75
04/04/2013 15:31
UN
No
Substance
2071

FERTILIZER
2072
2073
EAC
APP
Hazards
Class
HIN
Sub
Risks
1Z (1)
AMMONIA SOLUTION, relative

density less than 0.880 at 15C in
water, with more than 35% but not
more than 50% ammonia
2RE
2.2
20
2074
ACRYLAMIDE, SOLID
2X
6.1
60
2075
CHLORAL, ANHYDROUS,
STABILIZED
2X
6.1
69
2076
CRESOLS, LIQUID
l2X
6.1
68
2077
alpha-NAPHTHYLAMINE
2Z
6.1
60
2078
TOLUENE DIISOCYANATE
2Z
6.1
60
2079
DIETHYLENETRIAMINE
2X
80
2080
to
2185
2186
HYDROGEN CHLORIDE,
REFRIGERATED LIQUID
2RE (1)
2187
CARBON DIOXIDE, REFRIGERATED

LIQUID
2T
2188
ARSINE
2PE (1)
A(cf)
2.3
2.1
A(c)
2.3
2.2
22
2189
DICHLOROSILANE
2WE
A(fg)
2.3
2.1, 8
2190
OXYGEN DIFLUORIDE,
COMPRESSED
2PE (1)
2.3
5.1, 8
2191
SULPHURYL FLUORIDE
2XE
A(c)
2.3
2192
GERMANE
2PE
A(cf)
2.3
2193
HEXAFLUOROETHANE
2TE
2194
SELENIUM HEXAFLUORIDE
2RE (1)
A(c)
2.3
2195
TELLURIUM HEXAFLUORIDE
2RE (1)
A(c)
2.3
2196
TUNGSTEN HEXAFLUORIDE
2WE
2.3
26
2.1
2.2
(1)
263
263
20
2197
HYDROGEN IODIDE, ANHYDROUS
2RE
A(c)
2.3
2198
PHOSPHORUS PENTAFLUORIDE
2RE (1)
2.3
2199
PHOSPHINE
2PE (1)
A(cf)
2.3
2.1
268
Book 1.indb 76
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2200
PROPADIENE, STABILIZED
2YE
2201
NITROUS OXIDE, REFRIGERATED

LIQUID
2P
A(co)
2.2
5.1
2202
HYDROGEN SELENIDE,
ANHYDROUS
2WE (1)
A(cf)
2.3
2.1
2203
SILANE
2SE
Class
HIN
Sub
Risks
2.1
239
2.1
225
23
2204
CARBONYL SULPHIDE
2PE
2205
ADIPONITRILE
l3X
6.1
60
2206
ISOCYANATES, TOXIC, N.O.S. or

ISOCYANATE SOLUTION, TOXIC,
N.O.S.
2X
6.1
60
2207
2208
CALCIUM HYPOCHLORITE
MIXTURE, DRY with more than
10% but not more than 39%
available chlorine
1X
5.1
50
2209
FORMALDEHYDE SOLUTION with

not less than 25% formaldehyde
l2X
80
2210
MANEB or MANEB PREPARATION

with not less than 60% maneb
1Y
4.2
2211
POLYMERIC BEADS, EXPANDABLE,

evolving flammable vapour
2Y
90
2212
BLUE ASBESTOS (crocidolite) or

BROWN ASBESTOS (amosite,
mysorite)
2X
90
2213
PARAFORMALDEHYDE
1Z
4.1
40
2214
PHTHALIC ANHYDRIDE with more

than 0.05% of maleic anhydride
2X
80
2215
MALEIC ANHYDRIDE
2X
80
2216
FISH MEAL (FISH SCRAP),

STABILIZED
1Z
2217
SEED CAKE with not more than 1.5%

oil and not more than 11% moisture
1Y
2218
ACRYLIC ACID, STABILIZED
l2W
2219
ALLYL GLYCIDYL ETHER
l2Y
2220
A(cf)
(1)
2.3
2.1
4.3
4.2
A(fl)
8
3
263
40
40
3
839
30
Book 1.indb 77
04/04/2013 15:31
UN
No
Substance
2221
2222
ANISOLE
2223
2224
EAC
APP
Hazards
Class
HIN
Sub
Risks
3Y
30
BENZONITRILE
3Z
6.1
60
2225
BENZENESULPHONYL CHLORIDE
2X
80
2226
BENZOTRICHLORIDE
2X
80
2227
n-BUTYL METHACRYLATE,
STABILIZED
3W
A(fl)
39
2228
to
2231
2232
2-CHLOROETHANAL
l2XE
6.1
66
2233
CHLOROANISIDINES
2X
6.1
60
2234
CHLOROBENZOTRIFLUORIDES
2Y
30
2235
CHLOROBENZYL CHLORIDES,
LIQUID
2Z
6.1
60
2236
3-CHLORO-4-METHYLPHENYL
ISOCYANATE, LIQUID
2X
6.1
60
2237
CHLORONITROANILINES
2X
6.1
60
2238
CHLOROTOLUENES
3Y
30
2239
CHLOROTOLUIDINES, SOLID
2X
6.1
60
2240
CHROMOSULPHURIC ACID
2W
88
2241
CYCLOHEPTANE
3YE
33
2242
CYCLOHEPTENE
3YE
33
2243
CYCLOHEXYL ACETATE
3Y
30
2244
CYCLOPENTANOL
3Y
30
2245
CYCLOPENTANONE
l3Y
30
2246
CYCLOPENTENE
3YE
33
2247
n-DECANE
3Y
2248
DI-n-BUTYLAMINE
l3W
2249
DICHLORODIMETHYL ETHER,
SYMMETRICAL
l3WE
2250
DICHLOROPHENYL ISOCYANATES
2X
(1)
30
A(fl)
A(fl)
6.1
6.1
83
60
Book 1.indb 78
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2251
BICYCLO[2.2.1] HEPTA-2, 5-DIENE, 3YE

STABILIZED (2,5-NORBORNADIENE,
STABILIZED)
2252
1,2-DIMETHOXYETHANE
l2YE
33
2253
N,N-DIMETHYLANILINE
3Z
6.1
60
2254
MATCHES, FUSEE
1Z (1)
4.1
2255
2256
CYCLOHEXENE
3YE
33
2257
POTASSIUM
4W
4.3
X423
2258
1,2-PROPYLENEDIAMINE
l2W
2259
TRIETHYLENETETRAMINE
2X
2260
TRIPROPYLAMINE
3W
Class
3
A(fl)
339
8
A(fl)
HIN
Sub
Risks
83
80
38
2261
XYLENOLS, SOLID
2X
6.1
60
2262
DIMETHYLCARBAMOYL CHLORIDE
4W
80
2263
DIMETHYLCYCLOHEXANES
3YE
33
2264
N,N-DIMETHYLCYCLOHEXYLAMINE
l3W
2265
N,N-DIMETHYLFORMAMIDE
l2Y
2266
DIMETHYL-N-PROPYLAMINE
l2WE
2267
DIMETHYL THIOPHOSPHORYL
CHLORIDE
2X
2268
2269
3,3-IMINODIPROPYLAMINE
l2X
2270
ETHYLAMINE, AQUEOUS
but not more than 70% ethylamine
l2PE
2271
ETHYL AMYL KETONE
3Y
30
2272
N-ETHYLANILINE
3Z
6.1
60
2273
2-ETHYLANILINE
3X
6.1
60
A(fl)
83
A(fl)
338
6.1
68
338
30
8
A(fl)
80
2274
N-ETHYL-N-BENZYLANILINE
2X
6.1
60
2275
2-ETHYLBUTANOL
3Y
30
2276
2-ETHYLHEXYLAMINE
l2W
A(fl)
2277
ETHYL METHACRYLATE,
STABILIZED
3WE
A(fl)
38
339
Book 1.indb 79
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2278
n-HEPTENE
3YE
33
2279
HEXACHLOROBUTADIENE
2X
6.1
60
Class
HIN
Sub
Risks
2280
HEXAMETHYLENEDIAMINE, SOLID
2X
80
2281
HEXAMETHYLENE DIISOCYANATE
2Z
6.1
60
2282
HEXANOLS
3Y
30
2283
ISOBUTYL METHACRYLATE,
STABILIZED
3W
A(fl)
39
2284
ISOBUTYRONITRILE
l3WE
A(fl)
6.1
336
2285
ISOCYANATOBENZOTRIFLUORIDES
l3W
A(fl)
6.1
63
2286
PENTAMETHYLHEPTANE
3Y
30
2287
ISOHEPTENE
3YE
33
2288
ISOHEXENE
3YE
33
2289
ISOPHORONEDIAMINE
2X
80
2290
ISOPHORONE DIISOCYANATE
2Z
6.1
60
2291
LEAD COMPOUND, SOLUBLE,

N.O.S.
2Z
6.1
60
2292
2293
4-METHOXY-4-METHYLPENTAN-2ONE
3Y
30
2294
N-METHYLANILINE
3X
6.1
60
2295
METHYL CHLOROACETATE
2W
A(fl)
6.1
663
2296
METHYLCYCLOHEXANE
3YE
33
2297
METHYLCYCLOHEXANONE
l3Y
30
2298
METHYLCYCLOPENTANE
3YE
33
2299
METHYL DICHLOROACETATE
2X
6.1
60
2300
2-METHYL-5-ETHYLPYRIDINE
3Z
6.1
60
2301
2-METHYLFURAN
3YE
33
2302
5-METHYLHEXAN-2-ONE
l3Y
30
2303
ISOPROPENYLBENZENE
3Y
30
2304
NAPHTHALENE, MOLTEN
1Y
4.1
44
2305
NITROBENZENESULPHONIC ACID
2X
80
Book 1.indb 80
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2306
NITROBENZOTRIFLUORIDES,
LIQUID
2X
6.1
60
2307
3-NITRO-4CHLOROBENZOTRIFLUORIDE
2X
6.1
60
2308
NITROSYLSULPHURIC ACID, LIQUID 2X
X80
2309
OCTADIENES
3YE
33
2310
PENTANE-2,4-DIONE
l2Y
2311
PHENETIDINES
2X
6.1
60
2312
PHENOL, MOLTEN
l3X
6.1
60
l2W
30
Class
HIN
Sub
Risks
6.1
36
2313
PICOLINES
2314
2315
POLYCHLORINATED BIPHENYLS,
LIQUID
2X
90
2316
SODIUM CUPROCYANIDE, SOLID
2X
6.1
66
2317
SODIUM CUPROCYANIDE
SOLUTION
2X
6.1
66
2318
SODIUM HYDROSULPHIDE with less

than 25% water of crystallization
1Y
4.2
40
A(fl)
2319
TERPENE HYDROCARBONS, N.O.S.
3Y
30
2320
TETRAETHYLENEPENTAMINE
2X
80
2321
TRICHLOROBENZENES, LIQUID
2X
6.1
60
2322
TRICHLOROBUTENE
2Z
6.1
60
2323
TRIETHYL PHOSPHITE
3Y
30
2324
TRIISOBUTYLENE
3Y
30
2325
1,3,5-TRIMETHYLBENZENE
3Y
30
2326
TRIMETHYLCYCLOHEXYLAMINE
2X
80
2327
TRIMETHYLHEXAMETHYLENEDIAMINES 2X
80
2328
TRIMETHYLHEXAMETHYLENE
DIISOCYANATE
6.1
60
2Z
2329
TRIMETHYL PHOSPHITE
3Y
30
2330
UNDECANE
3Y
30
2331
ZINC CHLORIDE, ANHYDROUS
2X
80
2332
ACETALDEHYDE OXIME
l2Y
30
Book 1.indb 81
04/04/2013 15:31
UN
No
Substance
EAC
2333
ALLYL ACETATE
l3YE
2334
ALLYLAMINE
l2WE
APP
A(fl)
Hazards
HIN
Class
Sub
Risks
6.1
336
6.1
663
2335
ALLYL ETHYL ETHER
3WE
A(fl)
6.1
336
2336
ALLYL FORMATE
3WE
A(fl)
6.1
336
2337
PHENYL MERCAPTAN
3WE
A(fl)
6.1
663
2338
BENZOTRIFLUORIDE
2YE
33
2339
2-BROMOBUTANE
2YE
33
2340
2-BROMOETHYL ETHYL ETHER
l2YE
33
2341
1-BROMO-3-METHYLBUTANE
2Y
30
2342
BROMOMETHYLPROPANES
2YE
33
2343
2-BROMOPENTANE
2YE
33
2344
BROMOPROPANES, packing group II
2YE
33
2344
BROMOPROPANES, packing
group III
2Y
30
2345
3-BROMOPROPYNE
2YE
33
2346
BUTANEDIONE
l2YE
33
2347
BUTYL MERCAPTAN
l3WE
A(fl)
33
3W
A(fl)
39
2348
BUTYL ACRYLATES, STABILIZED
2349
2350
BUTYL METHYL ETHER
3YE
33
2351
BUTYL NITRITES, packing group II
l3YE
33
2351
BUTYL NITRITES, packing group III
l3Y
30
2352
BUTYL VINYL ETHER, STABILIZED
l3YE
339
2353
BUTYRYL CHLORIDE
l3WE
A(fl)
338
2354
CHLOROMETHYL ETHYL ETHER
l3WE
A(fl)
6.1
336
2355
2356
2-CHLOROPROPANE
2357
CYCLOHEXYLAMINE
l2W
2358
CYCLOOCTATETRAENE
3YE
2359
DIALLYLAMINE
l2WE
A(fl)
6.1, 8
338
2360
DIALLYL ETHER
l3WE
A(fl)
6.1
336
3YE
3
A(fl)
33
3
83
33
Book 1.indb 82
04/04/2013 15:31
UN
No
Substance
EAC
2361
DIISOBUTYLAMINE
3WE
2362
1,1-DICHLOROETHANE
2YE
APP
A(fl)
Hazards
Class
Sub
Risks
HIN
38
33
2363
ETHYL MERCAPTAN
3WE
33
2364
n-PROPYLBENZENE
3Y
30
2365
2366
DIETHYL CARBONATE
3Y
30
A(fl)
2367
alpha-METHYLVALERALDEHYDE
3YE
33
2368
alpha-PINENE
3Y
30
2369
2370
1-HEXENE
3YE
33
2371
ISOPENTENES
3YE
33
2372
1,2-DI-(DIMETHYLAMINO) ETHANE
l2YE
33
2373
DIETHOXYMETHANE
l2YE
33
2374
3,3-DIETHOXYPROPENE
l3YE
33
2375
DIETHYL SULPHIDE
3WE
33
2376
2,3-DIHYDROPYRAN
l2YE
33
2377
1,1-DIMETHOXYETHANE
l2YE
33
2378
2-DIMETHYLAMINOACETONITRILE
3WE
A(fl)
6.1
336
2379
1,3-DIMETHYLBUTYLAMINE
3WE
A(fl)
338
2380
DIMETHYLDIETHOXYSILANE
l2YE
2381
DIMETHYL DISULPHIDE
3WE
A(fl)
6.1
336
2382
DIMETHYLHYDRAZINE,
SYMMETRICAL
l2WE
A(fl)
6.1
663
2383
DIPROPYLAMINE
l2WE
A(fl)
338
A(fl)
33
2384
DI-n-PROPYL ETHER
3YE
33
2385
ETHYL ISOBUTYRATE
l3YE
33
2386
1-ETHYLPIPERIDINE
3WE
A(fl)
338
2387
FLUOROBENZENE
3YE
33
2388
FLUOROTOLUENES
3YE
33
2389
FURAN
3YE
33
2390
2-IODOBUTANE
2YE
33
Book 1.indb 83
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2391
IODOMETHYLPROPANES
2YE
33
2392
IODOPROPANES
2Y
30
2393
ISOBUTYL FORMATE
l3YE
33
2394
ISOBUTYL PROPIONATE
3Y
30
2395
ISOBUTYRYL CHLORIDE
l3WE
A(fl)
338
2396
METHACRYLALDEHYDE,
STABILIZED
l2WE
A(fl)
6.1
336
2397
3-METHYLBUTAN-2-ONE
l3YE
33
2398
METHYL tert-BUTYL ETHER
l3YE
33
2399
1-METHYLPIPERIDINE
l2WE
2400
METHYL ISOVALERATE
l3YE
A(fl)
A(fl)
33
33
Class
A(fl)
2401
PIPERIDINE
l2WE
2402
PROPANETHIOLS
l3WE
2403
ISOPROPENYL ACETATE
l3YE
HIN
Sub
Risks
338
33
883
2404
PROPIONITRILE
l2WE
2405
ISOPROPYL BUTYRATE
3Y
2406
ISOPROPYL ISOBUTYRATE
3YE
2407
ISOPROPYL CHLOROFORMATE
l3WE
2408
2409
ISOPROPYL PROPIONATE
3YE
2410
1,2,3,6-TETRAHYDROPYRIDINE
l2WE
A(fl)
2411
BUTYRONITRILE
l3WE
A(fl)
2412
TETRAHYDROTHIOPHENE
3WE
A(fl)
33
2413
TETRAPROPYL ORTHOTITANATE
l2Y
30
3WE
33
33
2414
THIOPHENE
2415
2416
TRIMETHYL BORATE
(1)
A(fl)
A(fl)
6.1
30
33
6.1
3, 8
A(fl)
l3YE
33
33
6.1
2417
CARBONYL FLUORIDE
2PE
2.3
2418
SULPHUR TETRAFLUORIDE
2PE (1)
A(c)
2.3
2419
BROMOTRIFLUOROETHYLENE
2YE
2420
HEXAFLUOROACETONE
2WE
2.1
A(c)
336
2.3
336
268
23
8
268
Book 1.indb 84
04/04/2013 15:31
UN
No
Substance
EAC
2421
NITROGEN TRIOXIDE
2PE (1)
2422
OCTAFLUOROBUT-2-ENE
2TE
2.2
20
2423
2424
OCTAFLUOROPROPANE
2TE
2.2
20
2425
2426
AMMONIUM NITRATE, LIQUID

(hot concentrated solution)
1Y
5.1
59
2427
POTASSIUM CHLORATE, AQUEOUS

SOLUTION
2Y
5.1
50
2428
SODIUM CHLORATE, AQUEOUS

SOLUTION
2Y
5.1
50
2429
CALCIUM CHLORATE, AQUEOUS

SOLUTION
2Y
5.1
50
2430
ALKYL PHENOLS, SOLID, N.O.S.

(including C2-C12 homologues)
2X
88/80
2431
ANISIDINES
2Z
6.1
60
2432
N, N-DIETHYLANILINE
l3X
6.1
60
2433
CHLORONITROTOLUENES, LIQUID
2X
6.1
60
2434
DIBENZYLDICHLOROSILANE
4W
X80
X80
33
X80
2435
ETHYLPHENYLDICHLOROSILANE
4W
2436
THIOACETIC ACID
l2WE
2437
METHYLPHENYLDICHLOROSILANE
4W
2438
TRIMETHYLACETYL CHLORIDE
l3WE
APP
A(fl)
A(fl)
Hazards
Class
Sub
Risks
2.3
5.1, 8
6.1
3, 8
HIN
663
2439
SODIUM HYDROGENDIFLUORIDE
2X
80
2440
STANNIC CHLORIDE
PENTAHYDRATE
2X
80
2441
TITANIUM TRICHLORIDE,
PYROPHORIC or TITANIUM
TRICHLORIDE MIXTURE,
PYROPHORIC
4WE (1)
4.2
2442
TRICHLOROACETYL CHLORIDE
4W
X80
2443
VANADIUM OXYTRICHLORIDE
4WE
80
2444
VANADIUM TETRACHLORIDE
4WE
X88
Book 1.indb 85
04/04/2013 15:31
UN
No
Substance
2445
2446
NITROCRESOLS, SOLID
EAC
APP
Hazards
Class
2X
2447
PHOSPHORUS, WHITE, MOLTEN
1WE
2448
SULPHUR, MOLTEN
1Y
2449
2450
6.1
A(h)
4.2
HIN
Sub
Risks
60
6.1
4.1
446
44
2451
NITROGEN TRIFLUORIDE
2S
2.2
2452
ETHYL ACETYLENE, STABILIZED
2YE
2.1
239
2453
ETHYL FLUORIDE (REFRIGERANT

GAS R 161)
2YE
2.1
23
2454
METHYL FLUORIDE (REFRIGERANT

GAS R 41)
2YE
2.1
23
2455
METHYL NITRITE
2PE (1)
2.2
2456
2-CHLOROPROPENE
3YE
33
2457
2,3-DIMETHYLBUTANE
3YE
33
2458
HEXADIENES
3YE
33
5.1
25
2459
2-METHYL-1-BUTENE
3YE
33
2460
2-METHYL-2-BUTENE
3YE
33
2461
METHYLPENTADIENE
3YE
33
2462
2463
ALUMINIUM HYDRIDE
4WE (1)
4.3
2464
BERYLLIUM NITRATE
1Y
5.1
2465
DICHLOROISOCYANURIC ACID,
DRY or DICHLOROISOCYANURIC
ACID SALTS
1W
5.1
2466
POTASSIUM SUPEROXIDE
1W (1)
5.1
2467
2468
TRICHLOROISOCYANURIC ACID,
DRY
1W
5.1
50
2469
ZINC BROMATE
1Z
5.1
50
2470
PHENYLACETONITRILE, LIQUID
2X
6.1
60
2471
OSMIUM TETROXIDE
2X
6.1
66
6.1
56
50
Book 1.indb 86
04/04/2013 15:31
UN
No
Substance
2472
2473
SODIUM ARSANILATE
EAC
APP
Hazards
Class
2Z
HIN
Sub
Risks
6.1
60
2474
THIOPHOSGENE
2X
6.1
66
2475
VANADIUM TRICHLORIDE
2X
80
2476
2477
METHYL ISOTHIOCYANATE
l3WE
A(fl)
6.1
663
2478
ISOCYANATES, FLAMMABLE,
TOXIC, N.O.S. or ISOCYANATE
SOLUTION, FLAMMABLE, TOXIC,
l3WE
A(fl)
6.1
336
2478
TOXIC, N.O.S. or ISOCYANATE
SOLUTION, FLAMMABLE, TOXIC,
l3W
A(fl)
6.1
36
2479
2480
METHYL ISOCYANATE
l3WE
A(fl)
6.1
663
2481
ETHYL ISOCYANATE
l3WE
A(fl)
6.1
663
2482
n-PROPYL ISOCYANATE
l3WE
A(fl)
6.1
663
2483
ISOPROPYL ISOCYANATE
l3WE
A(fl)
6.1
663
2484
tert-BUTYL ISOCYANATE
l3WE
A(fl)
6.1
663
2485
n-BUTYL ISOCYANATE
l3W
A(fl)
6.1
663
2486
ISOBUTYL ISOCYANATE
l3WE
A(fl)
6.1
663
2487
PHENYL ISOCYANATE
l3W
A(fl)
6.1
663
2488
CYCLOHEXYL ISOCYANATE
l3W
A(fl)
6.1
663
2489
2490
DICHLOROISOPROPYL ETHER
2Z
6.1
60
2491
ETHANOLAMINE or
ETHANOLAMINE SOLUTION
2X
80
2492
2493
HEXAMETHYLENEIMINE
2494
l2WE
A(fl)
338
A(!)
5.1
6.1, 8
568
2495
IODINE PENTAFLUORIDE
4WE
2496
PROPIONIC ANHYDRIDE
l3X
80
Book 1.indb 87
04/04/2013 15:31
UN
No
Substance
2497
2498
1,2,3,6-TETRAHYDROBENZALDEHYDE
2499
2500
2501
2502
EAC
APP
Hazards
Class
HIN
Sub
Risks
l3Y
30
TRIS(1-AZIRIDINYL) PHOSPHINE
OXIDE SOLUTION
2X
6.1
60
VALERYL CHLORIDE
4W
A(fl)
83
2503
ZIRCONIUM TETRACHLORIDE
2X
80
2504
TETRABROMOETHANE
2Z
6.1
60
2505
AMMONIUM FLUORIDE
2X
6.1
60
2506
AMMONIUM HYDROGEN
SULPHATE
2X
80
2507
CHLOROPLATINIC ACID, SOLID
2X
80
2508
MOLYBDENUM PENTACHLORIDE
2X
80
2509
POTASSIUM HYDROGEN SULPHATE 2X
80
2510
2511
2-CHLOROPROPIONIC ACID
2X
80
2512
AMINOPHENOLS (o-,m-,p-)
2X
6.1
60
2513
BROMOACETYL BROMIDE
4W
X80
2514
BROMOBENZENE
2Y
30
2515
BROMOFORM
2X
6.1
60
2516
CARBON TETRABROMIDE
2Z
6.1
60
2517
1-CHLORO-1, 1-DIFLUOROETHANE
(REFRIGERANT GAS R 142b)
2YE
2.1
23
3Z
6.1
60
30
2518
1,5,9-CYCLODODECATRIENE
2519
2520
CYCLOOCTADIENES
3Y
2521
DIKETENE, STABILIZED
l3W
2522
2-DIMETHYLAMINOETHYL
METHACRYLATE
l2W
6.1
69
2523
2524
ETHYL ORTHOFORMATE
l3Y
30
A(fl)
6.1
663
Book 1.indb 88
04/04/2013 15:31
UN
No
Substance
EAC
APP
2525
ETHYL OXALATE
l3Z
2526
FURFURYLAMINE
l2W
A(fl)
A(fl)
Hazards
Class
2527
ISOBUTYL ACRYLATE, STABILIZED
3W
2528
ISOBUTYL ISOBUTYRATE
3Y
2529
ISOBUTYRIC ACID
l2W
2530
2531
METHACRYLIC ACID, STABILIZED
2532
2533
6.1
A(fl)
HIN
Sub
Risks
60
8
38
39
30
38
3W
89
METHYL TRICHLOROACETATE
2Z
6.1
60
2534
METHYLCHLOROSILANE
2WE
A(fg)
2.3
2.1, 8
263
2535
4-METHYLMORPHOLINE
(N-METHYLMORPHOLINE)
l2WE
A(fl)
338
2536
METHYLTETRAHYDROFURAN
l2YE
33
2537

1Z
4.1
40
2538
NITRONAPHTHALENE
2539
2540
2541
TERPINOLENE
3Y
30
2542
TRIBUTYLAMINE
3X
6.1
60
2543
2544
2545
HAFNIUM POWDER, DRY, packing

group I
1Y(1)
4.2
2545
HAFNIUM POWDER, DRY, packing

groups II & III
1Y
4.2
2546
TITANIUM POWDER, DRY, packing

group I
1Y(1)
4.2
2546
TITANIUM POWDER, DRY, packing

groups II & III
1Y
4.2
2547
SODIUM SUPEROXIDE
1W (1)
2548
CHLORINE PENTAFLUORIDE
2WE
(1)
40
40
5.1
A(!)
2.3
5.1, 8
Book 1.indb 89
04/04/2013 15:31
UN
No
Substance
2549
to
2551
2552
HEXAFLUOROACETONE HYDRATE,
LIQUID
EAC
APP
Hazards
Class
HIN
Sub
Risks
2X
6.1
60
33
2553
2554
METHYLALLYL CHLORIDE
3WE
2555
NITROCELLULOSE WITH WATER

(not less than 25% water, by mass)
1Z
(1)
4.1
2556
NITROCELLULOSE WITH ALCOHOL 1Y(1)

(not less than 25% alcohol, by mass,
and not more than 12.6% nitrogen, by
dry mass)
4.1
2557
NITROCELLULOSE, with not more

than 12.6% nitrogen, by dry mass,
MIXTURE WITH or WITHOUT
PLASTICIZER, WITH or WITHOUT
PIGMENT
1Z (1)
4.1
2558
EPIBROMOHYDRIN
l2W
2559
2560
2-METHYLPENTAN-2-OL
l3Y
30
2561
3-METHYL-1-BUTENE
3YE
33
2562
2563
2564
TRICHLOROACETIC ACID SOLUTION 2X
80
2X
80
2X
6.1
60
A(fl)
6.1
663
2565
DICYCLOHEXYLAMINE
2566
2567
SODIUM PENTACHLOROPHENATE
2568
2569
2570
CADMIUM COMPOUND
2X
6.1
66/60
2571
ALKYLSULPHURIC ACIDS
2X
80
2572
PHENYLHYDRAZINE
l3X
6.1
2573
THALLIUM CHLORATE
1Y
5.1
60
6.1
56
Book 1.indb 90
04/04/2013 15:31
UN
No
Substance
2574
TRICRESYL PHOSPHATE with more

than 3% ortho isomer
2575
2576
2577
EAC
APP
Hazards
Class
HIN
Sub
Risks
2X
6.1
60
PHOSPHORUS OXYBROMIDE,
MOLTEN
1X
80
PHENYLACETYL CHLORIDE
4W
80
2578
PHOSPHORUS TRIOXIDE
2X
80
2579
PIPERAZINE
2X
80
2580
ALUMINIUM BROMIDE SOLUTION
2X
80
2581
ALUMINIUM CHLORIDE SOLUTION
2X
80
2582
FERRIC CHLORIDE SOLUTION
2X
80
2583
ALKYLSULPHONIC ACIDS, SOLID or 2X

ARYLSULPHONIC ACIDS, SOLID with
more than 5% free sulphuric acid
80
2584
2X
ALKYLSULPHONIC ACIDS, LIQUID
or ARYLSULPHONIC ACIDS, LIQUID
with more than 5% free sulphuric acid
80
2585
ALKYLSULPHONIC ACIDS, SOLID or 2X

ARYLSULPHONIC ACIDS, SOLID with
not more than 5% free
sulphuric acid
80
2586
ALKYLSULPHONIC ACIDS, LIQUID

or ARYLSULPHONIC ACIDS, LIQUID
with not more than 5% free
sulphuric acid
2X
80
2587
BENZOQUINONE
2Z
6.1
60
2588
PESTICIDE, SOLID, TOXIC, N.O.S.
2X
6.1
66/60
2589
VINYL CHLOROACETATE
3W
2590
WHITE ASBESTOS (chrysotile,

actinolite, anthophyllite, tremolite)
2X
90
2591
XENON, REFRIGERATED LIQUID
2TE
2.2
22
2592
to
2598
A(fl)
6.1
63
Book 1.indb 91
04/04/2013 15:31
UN
No
Substance
EAC
2599
CHLOROTRIFLUOROMETHANE AND 2TE

TRIFLUOROMETHANE AZEOTROPIC
MIXTURE with approximately
60% chlorotrifluoromethane
2600
APP
Hazards
Class
HIN
Sub
Risks
2.2
20
2601
CYCLOBUTANE
2YE
2.1
23
2602
AND 1,1-DIFLUOROETHANE
AZEOTROPIC MIXTURE
with approximately 74%
dichlorodifluoromethane
2TE
2.2
20
2603
CYCLOHEPTATRIENE
3WE
A(fl)
6.1
336
2604
BORON TRIFLUORIDE DIETHYL

ETHERATE
4WE
A(fl)
883
2605
METHOXYMETHYL ISOCYANATE
3WE
A(fl)
6.1
663
A(fl)
6.1
663
2606
METHYL ORTHOSILICATE
3WE
2607
ACROLEIN DIMER, STABILIZED
l2Y
39
2608
NITROPROPANES
l3Y
30
2609
TRIALLYL BORATE
2X
2610
TRIALLYLAMINE
3W
A(fl)
38
2611
PROPYLENE CHLOROHYDRIN
l2W
A(fl)
6.1
63
2612
METHYL PROPYL ETHER
l3YE
33
2613
2614
METHALLYL ALCOHOL
l2Y
30
2615
ETHYL PROPYL ETHER
l3YE
33
2616
TRIISOPROPYL BORATE, packing

group II
l3YE
33
2616
TRIISOPROPYL BORATE, packing

groupIII
l3Y
30
2617
METHYLCYCLOHEXANOLS,
flammable
l3Y
30
2618
VINYLTOLUENES, STABILIZED
3Y
39
2619
BENZYLDIMETHYLAMINE
3W
6.1
A(fl)
60
83
Book 1.indb 92
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2620
AMYL BUTYRATES
l3Y
30
2621
ACETYL METHYL CARBINOL
l2Y
30
Class
HIN
Sub
Risks
2622
GLYCIDALDEHYDE
l2WE
2623
FIRELIGHTERS, SOLID with

flammable liquid
1Z (1)
4.1
2624
MAGNESIUM SILICIDE
4W
4.3
423
2625
2626
CHLORIC ACID, AQUEOUS

SOLUTION with not more than
10% chloric acid
2P
5.1
50
2627
NITRITES, INORGANIC, N.O.S.
1Y
5.1
50
A(fl)
6.1
336
2628
POTASSIUM FLUOROACETATE
2X
6.1
66
2629
SODIUM FLUOROACETATE
2X
6.1
66
2630
SELENATES or SELENITES
2X
6.1
66
2631
to
2641
2642
FLUOROACETIC ACID
2X
6.1
66
2643
METHYL BROMOACETATE
2X
2644
METHYL IODIDE
2X
2645
PHENACYL BROMIDE
2X
6.1
60
6.1
66
6.1
60
2646
HEXACHLOROCYCLOPENTADIENE
2X
6.1
66
2647
MALONONITRILE
2X
6.1
60
2648
1,2-DIBROMOBUTAN-3-ONE
2X
6.1
60
2649
1,3-DICHLOROACETONE
2X
6.1
60
2650
1,1-DICHLORO-1-NITROETHANE
2X
6.1
60
2651
4,4-DIAMINODIPHENYLMETHANE
2Z
6.1
60
2652

2X
6.1
60
2653
BENZYL IODIDE
2654
2655
POTASSIUM FLUOROSILICATE
2X
6.1
60
2656
QUINOLINE
2X
6.1
60
Book 1.indb 93
04/04/2013 15:31
UN
No
Substance
2657
SELENIUM DISULPHIDE
2658
EAC
APP
Hazards
Class
2Z
HIN
Sub
Risks
6.1
60
2659
SODIUM CHLOROACETATE
2Z
6.1
60
2660
NITROTOLUIDINES (mono)
2X
6.1
60
2661
HEXACHLOROACETONE
2Z
6.1
60
2662
2663
2664
DIBROMOMETHANE
2Z
6.1
60
2665
2666
2667
BUTYLTOLUENES
3X
6.1
60
2668
CHLOROACETONITRILE
2W
A(fl)
6.1
663
2669
CHLOROCRESOLS SOLUTION
2Z
6.1
60
2670
CYANURIC CHLORIDE
2X
80
2671
AMINOPYRIDINES (o-,m-,p-)
2X
6.1
60
2672

density between 0.880 and 0.957 at
15C in water, with more than 10%
but not more than 35% ammonia
2R
80
2673
2-AMINO-4-CHLOROPHENOL
2X
6.1
60
2674
SODIUM FLUOROSILICATE
2X
6.1
60
2675
2676
STIBINE
2PE (1)
2677
RUBIDIUM HYDROXIDE SOLUTION
2R
A(fg)
2.3
2.1
80
2678
RUBIDIUM HYDROXIDE
2W
80
2679
LITHIUM HYDROXIDE SOLUTION
2R
80
2680
LITHIUM HYDROXIDE
2X
80
2681
CAESIUM HYDROXIDE SOLUTION
2R
80
2682
CAESIUM HYDROXIDE
2W
80
2683
AMMONIUM SULPHIDE SOLUTION
l2W
A(fl)
3, 6.1
86
2684
3-DIETHYLAMINOPROPYLAMINE
l2W
A(fl)
38
N,N-DIETHYLETHYLENEDIAMINE
l2W
A(fl)
83
2685
Book 1.indb 94
04/04/2013 15:31
UN
No
Substance
EAC
APP
2686
2-DIETHYLAMINOETHANOL
l2W
2687
DICYCLOHEXYLAMMONIUM
NITRITE
1Z
4.1
40
2688
1-BROMO-3-CHLOROPROPANE
2X
6.1
60
2689
GLYCEROL alphaMONOCHLOROHYDRIN
2X
6.1
60
A(fl)
Hazards
Class
Sub
Risks
HIN
83
2690
N,n-BUTYLIMIDAZOLE
2X
6.1
60
2691
PHOSPHORUS PENTABROMIDE
4W
80
2692
BORON TRIBROMIDE
4WE
X88
2693
BISULPHITES, AQUEOUS
SOLUTION, N.O.S.
2X
80
2694
to
2697
2698
TETRAHYDROPHTHALIC
ANHYDRIDES with more than
0.05% of maleic anhydride
2X
80
2699
TRIFLUOROACETIC ACID
2X
88
2700
to
2704
2705
1-PENTOL
2X
80
2706
2707
DIMETHYLDIOXANES, packing
groupII
l3YE
33
2707
DIMETHYLDIOXANES, packing
groupIII
l3Y
30
2708
2709
BUTYLBENZENES
3Y
30
3Y
30
2710
DIPROPYL KETONE
2711
2712
2713
ACRIDINE
2X
6.1
60
2714
ZINC RESINATE
1Z
4.1
40
2715
ALUMINIUM RESINATE
1Z
4.1
40
Book 1.indb 95
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2716
1,4-BUTYNEDIOL
2X
6.1
60
2717
CAMPHOR, synthetic
1Z
4.1
40
2718
2719
BARIUM BROMATE
1W
5.1
2720
CHROMIUM NITRATE
1Z
5.1
50
2721
COPPER CHLORATE
1Y
5.1
50
Class
HIN
Sub
Risks
6.1
56
2722
LITHIUM NITRATE
1Z
5.1
50
2723
MAGNESIUM CHLORATE
1Y
5.1
50
2724
MANGANESE NITRATE
1Z
5.1
50
2725
NICKEL NITRATE
1Z
5.1
50
2726
NICKEL NITRITE
1Z
5.1
50
2727
THALLIUM NITRATE
1Y
6.1
5.1
65
2728
ZIRCONIUM NITRATE
1Z
5.1
50
2729
HEXACHLOROBENZENE
2Z
6.1
60
2730
NITROANISOLES, LIQUID
2Z
6.1
60
2731
2732
NITROBROMOBENZENES, LIQUID
2X
6.1
60
2733
AMINES, FLAMMABLE, CORROSIVE,

N.O.S. or POLYAMINES,
FLAMMABLE, CORROSIVE, N.O.S.,
l2WE
A(fl)
338
2733
AMINES, FLAMMABLE, CORROSIVE,

N.O.S. or POLYAMINES,
FLAMMABLE, CORROSIVE, N.O.S.,
packing group III
l2W
A(fl)
38
2734
AMINES, LIQUID, CORROSIVE,

FLAMMABLE, N.O.S. or
POLYAMINES, LIQUID, CORROSIVE,
FLAMMABLE, N.O.S.
l2W
A(fl)
883/83
2735

N.O.S. or POLYAMINES, LIQUID,
2X
88
2735

N.O.S. or POLYAMINES, LIQUID,
CORROSIVE, N.O.S., packing
groupsII& III
2X
80
Book 1.indb 96
04/04/2013 15:31
UN
No
Substance
2736
2737
EAC
APP
Hazards
Class
HIN
Sub
Risks
2738
N-BUTYLANILINE
2Z
6.1
60
2739
BUTYRIC ANHYDRIDE
l3X
80
2740
n-PROPYL CHLOROFORMATE
l3WE
2741
BARIUM HYPOCHLORITE with more

than 22% available chlorine
1Y
2742
CHLOROFORMATES, TOXIC,
CORROSIVE, FLAMMABLE, N.O.S.
l3W
2743
n-BUTYL CHLOROFORMATE
2744
CYCLOBUTYL CHLOROFORMATE
2745
CHLOROMETHYL
CHLOROFORMATE
2746
2747
A(fl)
6.1
3, 8
668
5.1
6.1
56
A(fl)
6.1
3, 8
638
l3W
A(fl)
6.1
3, 8
638
l3W
A(fl)
6.1
3, 8
638
2X
6.1
68
PHENYL CHLOROFORMATE
2X
6.1
68
tert-BUTYLCYCLOHEXYL
CHLOROFORMATE
2X
6.1
60
2748
2-ETHYLHEXYL CHLOROFORMATE
2X
6.1
2749
TETRAMETHYLSILANE
3YE
33
2750
1,3-DICHLOROPROPANOL-2
2X
6.1
60
2751
DIETHYLTHIOPHOSPHORYL
CHLORIDE
4W
80
68
2752
1,2-EPOXY-3-ETHOXYPROPANE
3Y
30
2753
N-ETHYLBENZYLTOLUIDINES,
LIQUID
2X
6.1
60
2754
N-ETHYLTOLUIDINES
3X
6.1
60
2755
2756
2757
CARBAMATE PESTICIDE, SOLID,

TOXIC
2X
6.1
66/60
2758
CARBAMATE PESTICIDE, LIQUID,

FLAMMABLE, TOXIC, flash point less
than 23C
l3WE
2759
ARSENICAL PESTICIDE, SOLID,

TOXIC
2X
A(fl)
6.1
6.1
336
66/60
Book 1.indb 97
04/04/2013 15:31
UN
No
Substance
EAC
2760
ARSENICAL PESTICIDE, LIQUID,

than 23C
l3WE
2761
ORGANOCHLORINE PESTICIDE,
SOLID, TOXIC
2X
2762
LIQUID, FLAMMABLE, TOXIC, flash
point less than 23C
l3WE
2763
TRIAZINE PESTICIDE, SOLID, TOXIC
2X
2764
TRIAZINE PESTICIDE, LIQUID,

than 23C
l3WE
2765
to
2770
2771
THIOCARBAMATE PESTICIDE,
SOLID, TOXIC
2X
2772
point less than 23C
l3WE
2773
2774
2775
COPPER BASED PESTICIDE, SOLID,

TOXIC
2X
2776
COPPER BASED PESTICIDE, LIQUID,

than 23C
l3WE
2777
MERCURY BASED PESTICIDE,

SOLID, TOXIC
2X
2778

point less than 23C
l3WE
2779
SUBSTITUTED NITROPHENOL
PESTICIDE, SOLID, TOXIC
2X
2780
PESTICIDE, LIQUID, FLAMMABLE,
TOXIC, flash point less than 23C
l3WE
2781
BIPYRIDILIUM PESTICIDE, SOLID,

TOXIC
2X
APP
A(fl)
Hazards
Class
Sub
Risks
6.1
6.1
A(fl)
6.1
6.1
6.1
6.1
336
66/60
6.1
6.1
A(fl)
336
66/60
6.1
A(fl)
336
66/60
6.1
A(fl)
336
66/60
6.1
6.1
A(fl)
336
66/60
6.1
A(fl)
HIN
336
66/60
6.1
336
66/60
Book 1.indb 98
04/04/2013 15:31
UN
No
Substance
EAC
2782
BIPYRIDILIUM PESTICIDE, LIQUID,

than 23C
l3WE
2783
ORGANOPHOSPHORUS PESTICIDE,
SOLID, TOXIC
2X
2784
point less than 23C
l3WE
APP
A(fl)
Hazards
Class
Sub
Risks
6.1
6.1
A(fl)
HIN
336
66/60
6.1
336
2785
4-THIAPENTANAL
2X
6.1
60
2786
ORGANOTIN PESTICIDE, SOLID,

TOXIC
2X
6.1
66/60
2787
ORGANOTIN PESTICIDE, LIQUID,

than 23C
l3WE
A(fl)
2788
ORGANOTIN COMPOUND, LIQUID,

2X
6.1
66
2788
ORGANOTIN COMPOUND, LIQUID,

2X
6.1
60
2789
ACETIC ACID, GLACIAL or ACETIC

ACID SOLUTION, more than 80%
acid, by mass
l2P
2790
ACETIC ACID SOLUTION, more

than 10% but not more than 80%
acid, by mass
l2R
2791
2792
2793
A(fl)
6.1
336
83
80
FERROUS METAL BORINGS,

1Y
SHAVINGS, TURNINGS or CUTTINGS
in a form liable to selfheating
4.2
40
2794
BATTERIES, WET, FILLED WITH

ACID, electric storage
2R
80
2795

ALKALI, electric storage
2R
80
2796
SULPHURIC ACID with not more than 2R

51% acid or BATTERY FLUID, ACID
80
2797
BATTERY FLUID, ALKALI
2R
80
2798
PHENYLPHOSPHORUS DICHLORIDE 2X
80
Book 1.indb 99
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2799
PHENYLPHOSPHORUS
THIODICHLORIDE
2W
80
2800
BATTERIES, WET, NON-SPILLABLE,

electric storage
2R
80
2801
DYE, LIQUID, CORROSIVE, N.O.S.

or DYE INTERMEDIATE, LIQUID,
2X
88
2801
DYE, LIQUID, CORROSIVE, N.O.S.

or DYE INTERMEDIATE, LIQUID,
CORROSIVE, N.O.S., packing
groups II & III
2X
80
2802
COPPER CHLORIDE
2X
80
2Z
80
4.3
423
Class
2803
GALLIUM
2804
2805
LITHIUM HYDRIDE, FUSED SOLID
4W
2806
LITHIUM NITRIDE
4W
2807
MAGNETIZED MATERIAL
2Z (1)
2808
HIN
Sub
Risks
4.3
(1)
2809
MERCURY
2X
2810
TOXIC LIQUID, ORGANIC, N.O.S.,

packing group I
2X
2810
TOXIC LIQUID, ORGANIC, N.O.S.,

2X
2811
TOXIC SOLID, ORGANIC, N.O.S.
2X
2812
SODIUM ALUMINATE, SOLID
2X
2813
WATER-REACTIVE SOLID, N.O.S.
4W
4.3
2814
INFECTIOUS SUBSTANCE,
AFFECTING HUMANS
2XE (1)
6.2
2814
2XE (1)
AFFECTING HUMANS, in refrigerated
nitrogen
2814
AFFECTING HUMANS (animal
material only)
2XE
6.2
606
2815
N-AMINOETHYLPIPERAZINE
l2X
80
8
B
6.1
86
6.1
66
6.1
60
6.1
66/60
(1)
A(c)
6.2
X423/
423
2.2
Book 1.indb 100
04/04/2013 15:31
UN
No
Substance
2816
2817
EAC
APP
Hazards
HIN
Class
Sub
Risks
AMMONIUM
2X
HYDROGENDIFLUORIDE SOLUTION
6.1
86
2818
AMMONIUM POLYSULPHIDE
SOLUTION
2X
6.1
86
2819
AMYL ACID PHOSPHATE
2X
2820
BUTYRIC ACID
l2X
80
2821
PHENOL SOLUTION
2X
6.1
60
2822
2-CHLOROPYRIDINE
2X
6.1
60
2X
80
2823
CROTONIC ACID, SOLID
2824
2825
2826
ETHYL CHLOROTHIOFORMATE
2827
2828
2829
CAPROIC ACID
2W
A(fl)
2X
80
83
80
2830
LITHIUM FERROSILICON
4W
4.3
423
2831
1,1,1-TRICHLOROETHANE
2Z
6.1
60
2832
2833
2834
PHOSPHOROUS ACID
2X
80
2835
SODIUM ALUMINIUM HYDRIDE
4W
4.3
423
2836
2837
BISULPHATES, AQUEOUS
SOLUTION
2R
80
2838
VINYL BUTYRATE, STABILIZED
3YE
339
2839
ALDOL
l2X
6.1
60
2840
BUTYRALDOXIME
l3W
A(fl)
2841
DI-n-AMYLAMINE
l3W
A(fl)
2842
NITROETHANE
l3Y
30
2843
2844
CALCIUM MANGANESE SILICON
4Y
4.3
423
30
6.1
36
Book 1.indb 101
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2845
PYROPHORIC LIQUID, ORGANIC,

N.O.S.
l3W
4.2
2846
PYROPHORIC SOLID, ORGANIC,

N.O.S.
4Y(1)
4.2
2847
2848
2849
3-CHLOROPROPANOL-1
l2X
6.1
60
2850
PROPYLENE TETRAMER
3Y
30
2851
BORON TRIFLUORIDE DIHYDRATE
4W
80
2852
DIPICRYL SULPHIDE, WETTED with

1W
Class
(1)
HIN
Sub
Risks
333
4.1
2853
MAGNESIUM FLUOROSILICATE
2Z
6.1
60
2854
AMMONIUM FLUOROSILICATE
2Z
6.1
60
2855
ZINC FLUOROSILICATE
2Z
6.1
60
2Z
6.1
60
2856
FLUOROSILICATES, N.O.S.
2857
REFRIGERATING MACHINES
2Z (1)
containing non-flammable, non-toxic
gases or ammonia solutions (UN 2672)
2.2
2858
1Z
ZIRCONIUM, DRY, coiled wire,
finished metal sheets, strip (thinner
than 254 microns but not thinner than
18 microns)
4.1
40
2859
AMMONIUM METAVANADATE
2Z
6.1
60
2860
2861
AMMONIUM POLYVANADATE
2X
6.1
60
2862
VANADIUM PENTOXIDE, non-fused

form
2X
6.1
60
2863
SODIUM AMMONIUM VANADATE
2X
6.1
60
2864
POTASSIUM METAVANADATE
2X
6.1
60
2865
HYDROXYLAMINE SULPHATE
2X
80
2866
to
2868
2869
TITANIUM TRICHLORIDE MIXTURE
4W
80
2870
ALUMINIUM BOROHYDRIDE
4W
4.2
4.3
X333
Book 1.indb 102
04/04/2013 15:31
UN
No
Substance
2870
ALUMINIUM BOROHYDRIDE IN
DEVICES
2871
2872
EAC
APP
Hazards
HIN
Class
Sub
Risks
4W (1)
4.2
4.3
ANTIMONY POWDER
2X
6.1
60
DIBROMOCHLOROPROPANES
2X
6.1
60
2873
DIBUTYLAMINOETHANOL
2Z
6.1
60
2874
FURFURYL ALCOHOL
l2X
6.1
60
2875
HEXACHLOROPHENE
2X
6.1
60
2Z
6.1
60
4.1
40
2876
RESORCINOL
2877
2878
TITANIUM SPONGE GRANULES or

TITANIUM SPONGE POWDERS
4Y
2879
SELENIUM OXYCHLORIDE
4WE
2880
CALCIUM HYPOCHLORITE,
HYDRATED, or CALCIUM
HYPOCHLORITE, HYDRATED
MIXTURE with not less than 5.5%
but not more than 16% water
1W
5.1
50
2881
METAL CATALYST, DRY
4Y
4.2
43/40
2882
to
2899
2900
AFFECTING ANIMALS only
2X (1)
6.2
2900
AFFECTING ANIMALS only (animal
material only)
2X
6.2
2900
AFFECTING ANIMALS only, in
refrigerated liquid nitrogen
2X (1)
A(c)
6.1
X886
606
6.2
2.2
5.1, 8
2901
BROMINE CHLORIDE
2WE
A(c)
2.3
2902
PESTICIDE, LIQUID, TOXIC, N.O.S.,

packing group I
2X
6.1
66
2902
PESTICIDE, LIQUID, TOXIC, N.O.S.,

2X
6.1
60
2903
PESTICIDE, LIQUID, TOXIC,

FLAMMABLE, N.O.S.
l3W
A(fl)
6.1
265
663/63
Book 1.indb 103
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
2904
CHLOROPHENOLATES, LIQUID or
PHENOLATES, LIQUID
2X
80
2905
CHLOROPHENOLATES, SOLID or
PHENOLATES, SOLID
2X
80
2906
2907
ISOSORBIDE DINITRATE MIXTURE

with not less than 60% lactose,
mannose, starch or calcium hydrogen
phosphate
1Z (1)
4.1
2908
RADIOACTIVE MATERIAL,
EXCEPTED PACKAGE EMPTY
PACKAGING
(2)
2909
EXCEPTED PACKAGE ARTICLES
MANUFACTURED FROM NATURAL
URANIUM or DEPLETED URANIUM
or NATURAL THORIUM
(2)
2910
EXCEPTED PACKAGE LIMITED
QUANTITY OF MATERIAL
(2)
2911
EXCEPTED PACKAGE
INSTRUMENTS or ARTICLES
(2)
2912
RADIOACTIVE MATERIAL, LOW

SPECIFIC ACTIVITY (LSA-I),
non-fissile or fissile excepted
(2)
70
2913
RADIOACTIVE MATERIAL, SURFACE

CONTAMINATED OBJECTS (SCO-I or
SCO-II), non-fissile or fissile excepted
(2)
70
2914
2915
RADIOACTIVE MATERIAL, TYPE A

PACKAGE, non-special form,
(2)
70
2916
RADIOACTIVE MATERIAL, TYPE B

(U) PACKAGE, non-fissile or fissile
excepted
(2)
70
2917
RADIOACTIVE MATERIAL, TYPE B

(M) PACKAGE, non-fissile or fissile
excepted
(2)
70
2918
Class
HIN
Sub
Risks
(1) Not applicable to the carriage of dangerous goods under RID or ADR (2) Radioactive material
Book 1.indb 104
04/04/2013 15:31
UN
No
Substance
EAC
2919
TRANSPORTED UNDER SPECIAL
ARRANGEMENT, non-fissile or fissile
excepted
(2)
2920
CORROSIVE LIQUID, FLAMMABLE,

N.O.S.
l3W
2921
CORROSIVE SOLID, FLAMMABLE,

N.O.S.
2X
2922
CORROSIVE LIQUID, TOXIC, N.O.S.,

packing group I
2X
2922
CORROSIVE LIQUID, TOXIC, N.O.S.,

2X
APP
Hazards
Class
7
A(fl)
HIN
Sub
Risks
70
883/83
4.1
884/84
6.1
886
6.1
86
2923
CORROSIVE SOLID, TOXIC, N.O.S.
2X
6.1
886/86
2924
FLAMMABLE LIQUID, CORROSIVE,

l3WE
A(fl)
338
2924
FLAMMABLE LIQUID, CORROSIVE,

l3W
A(fl)
38
2925
FLAMMABLE SOLID, CORROSIVE,

ORGANIC, N.O.S.
1W
4.1
48
2926
FLAMMABLE SOLID, TOXIC,

ORGANIC, N.O.S.
1X
4.1
6.1
46
2927
TOXIC LIQUID, CORROSIVE,

ORGANIC, N.O.S., packing group I
2XE
6.1
668
2927

ORGANIC, N.O.S., packing group II
2X
6.1
68
2928
TOXIC SOLID, CORROSIVE,

ORGANIC, N.O.S.
2X
6.1
668/68
2929
TOXIC LIQUID, FLAMMABLE,

ORGANIC, N.O.S.
l3W
6.1
663/63
2930
TOXIC SOLID, FLAMMABLE,

ORGANIC, N.O.S.
2X
6.1
4.1
664/64
2Z
6.1
60
l3Y
30
2931
VANADYL SULPHATE
2932
2933
METHYL 2-CHLOROPROPIONATE
A(fl)
2934
ISOPROPYL 2-CHLOROPROPIONATE 3Y
30
2935
ETHYL 2-CHLOROPROPIONATE
3Y
30
2936
THIOLACTIC ACID
l2X
6.1
60
(2) Radioactive material
Book 1.indb 105
04/04/2013 15:31
UN
No
Substance
2937
alpha-METHYLBENZYL ALCOHOL,
LIQUID
2938
2939
2940
9-PHOSPHABICYCLONONANES
(CYCLOOCTADIENE PHOSPHINES)
EAC
APP
Hazards
Class
HIN
Sub
Risks
2Z
6.1
60
1Y
4.2
40
2941
FLUOROANILINES
2X
6.1
60
2942
2-TRIFLUOROMETHYLANILINE
2X
6.1
60
2943
TETRAHYDROFURFURYLAMINE
l2Y
30
2944
2945
N-METHYLBUTYLAMINE
l2WE
2946
2-AMINO-5DIETHYLAMINOPENTANE
2X
6.1
60
2947
ISOPROPYL CHLOROACETATE
3Y
30
A(fl)
338
2948
2X
6.1
60
2949
SODIUM HYDROSULPHIDE,
HYDRATED with not less than 25%
water of crystallization
2X
80
4Y
4.3
423
1Y(1)
4.1
2950
MAGNESIUM GRANULES, COATED
2951
to
2955
2956
5-tert-BUTYL-2,4,6-TRINITRO-mXYLENE (MUSK XYLENE)
2957
to
2964
2965
BORON TRIFLUORIDE DIMETHYL

ETHERATE
4WE
A(fl)
4.3
3, 8
382
2966
THIOGLYCOL
2X
6.1
60
2967
SULPHAMIC ACID
2X
80
2968
MANEB, STABILIZED or MANEB

PREPARATION, STABILIZED against
self-heating
4Y
4.3
423
Book 1.indb 106
04/04/2013 15:31
UN
No
Substance
2969
CASTOR BEANS or CASTOR MEAL

or CASTOR POMACE or CASTOR
FLAKE
2970
to
2976
2977
EAC
APP
Hazards
Class
HIN
Sub
Risks
2Z
URANIUM HEXAFLUORIDE, FISSILE
(2)
78
2978
URANIUM HEXAFLUORIDE,
(2)
78
2979
to
2982
2983
ETHYLENE OXIDE AND PROPYLENE

OXIDE MIXTURE, not more than
30% ethylene oxide
l2WE
6.1
336
2984

but less than 20% hydrogen peroxide
(stabilized as necessary)
2R
2985
CHLOROSILANES, FLAMMABLE,
CORROSIVE, N.O.S.
4WE
A(fl)
X338
2986
CHLOROSILANES, CORROSIVE,
FLAMMABLE, N.O.S.
4W
A(fl)
X83
2987
N.O.S.
4W
2988
CHLOROSILANES,
WATER-REACTIVE, FLAMMABLE,
CORROSIVE, N.O.S.
4WE
A(fl)
90
5.1
50
8
A(fl)
4.3
X80
3, 8
X338
2989
LEAD PHOSPHITE, DIBASIC
1Z
4.1
2990
LIFE-SAVING APPLIANCES,
SELF-INFLATING
2Z (1)
2991

TOXIC, FLAMMABLE, flash point not
less than 23C
l3W
A(fl)
6.1
2992

TOXIC, packing group I
2X
6.1
66
2992

TOXIC, packing groups II & III
2X
6.1
60
40
663/63
Book 1.indb 107
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
HIN
2993

less than 23C
l3W
2994

2X
2994

2X
2995
LIQUID, TOXIC, FLAMMABLE,
flash point not less than 23C
l3W
A(fl)
6.1
2996
LIQUID, TOXIC, packing group I
2X
6.1
66
2996
2X
LIQUID, TOXIC, packing groups II & III
6.1
60
2997

less than 23C
l3W
A(fl)
6.1
2998

2X
6.1
66
2998

2X
6.1
60
2999
to
3004
3005
l3W
A(fl)
6.1
3006
2X
6.1
66
3006
2X
6.1
60
3007
3008
3009

less than 23C
l3W
A(fl)
6.1
3010

2X
6.1
Class
Sub
Risks
A(fl)
6.1
6.1
66
6.1
60
3
663/63
663/63
663/63
663/63
663/63
66
Book 1.indb 108
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3010

2X
3011

l3W
A(fl)
6.1
3012

2X
6.1
66
3012

2X
6.1
60
3013
FLAMMABLE, flash point not less
than 23C
l3W
A(fl)
6.1
3014
PESTICIDE, LIQUID, TOXIC, packing
group I
2X
6.1
66
3014
groups II & III
2X
6.1
60
3015

less than 23C
l3W
A(fl)
6.1
3016

2X
6.1
66
3016

2X
6.1
60
3017
l3W
A(fl)
6.1
3018
2X
6.1
66
3018
ORGANOPHOSPHORUS PESTICIDE, 2X
6.1
60
3019

less than 23C
l3W
A(fl)
6.1
3020

2X
6.1
66
3020

2X
6.1
60
Class
HIN
Sub
Risks
6.1
60
3
663/63
663/63
663/63
663/63
663/63
Book 1.indb 109
04/04/2013 15:31
UN
No
Substance
EAC
3021

TOXIC, N.O.S., flash point less than
23C
l3WE
3022
1,2-BUTYLENE OXIDE, STABILIZED
l2YE
3023
2-METHYL-2-HEPTANETHIOL
3024
APP
Hazards
HIN
Class
Sub
Risks
A(fl)
6.1
336
3WE
A(fl)
6.1
663
COUMARIN DERIVATIVE PESTICIDE,

LIQUID, FLAMMABLE, TOXIC,
flash point less than 23C
l3WE
A(fl)
6.1
336
3025
COUMARIN DERIVATIVE PESTICIDE,

l3W
A(fl)
6.1
663/63
3026
COUMARIN DERIVATIVE PESTICIDE, 2X

6.1
66
3026

6.1
60
3027

SOLID, TOXIC
6.1
66/60
3028
BATTERIES, DRY, CONTAINING

POTASSIUM HYDROXIDE SOLID,
electric storage
80
3029
to
3047
3048
ALUMINIUM PHOSPHIDE PESTICIDE 4W
6.1
642
3049
to
3053
3054
CYCLOHEXYL MERCAPTAN
3WE
30
3055
2-(2-AMINOETHOXY)ETHANOL
2X
80
2X
3056
n-HEPTALDEHYDE
3Y
3057
TRIFLUOROACETYL CHLORIDE
2XE
3058
to
3063
3064
NITROGLYCERIN, SOLUTION IN
ALCOHOL with more than 1% but not
more than 5% nitroglycerin
339
3
A(c)
l2YE (1)
2.3
30
8
268
Book 1.indb 110
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3065
ALCOHOLIC BEVERAGES, with more

than 70% alcohol by volume
l2YE
33
3065
ALCOHOLIC BEVERAGES, with more

alcohol by volume
l2Y
30
3066

(including paint-thinning or reducing
compound)
2X
80
3067
to
3069
3070
ETHYLENE OXIDE AND

MIXTURE with not more than 12.5%
ethylene oxide
2TE
2.2
20
3071
MERCAPTANS, LIQUID,
TOXIC, FLAMMABLE, N.O.S. or
TOXIC, FLAMMABLE, N.O.S.
l3WE
3072
LIFE-SAVING APPLIANCES NOT

SELF-INFLATING containing
dangerous goods as equipment
2Z (1)
l3W
Class
3073
VINYLPYRIDINES, STABILIZED
3074
to
3076
3077
ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, SOLID, N.O.S.
2Z
A(fl)
6.1
HIN
Sub
Risks
63
3, 8
638
A(fl)
6.1
90
3078
CERIUM, turnings or gritty powder
4W
3079
METHACRYLONITRILE, STABILIZED
l3WE
A(fl)
6.1
663
3080
ISOCYANATES, TOXIC,
FLAMMABLE, N.O.S.
l3W
A(fl)
6.1
63
3081
3082
ENVIRONMENTALLY HAZARDOUS
SUBSTANCE, LIQUID, N.O.S.
4.3
l3Z
423
90
Book 1.indb 111
04/04/2013 15:31
UN
No
Substance
EAC
3083
PERCHLORYL FLUORIDE
2WE
3084
CORROSIVE SOLID, OXIDISING,

N.O.S.
3085
APP
Hazards
HIN
Class
Sub
Risks
2.3
5.1
265
2W
5.1
885/85
OXIDISING SOLID, CORROSIVE,

1W (1)
5.1
3085

1W
5.1
58
3086
TOXIC SOLID, OXIDISING, N.O.S.
2W
6.1
5.1
665/65
3087
OXIDISING SOLID, TOXIC, N.O.S.,

packing group I
1W
5.1
6.1
3087
OXIDISING SOLID, TOXIC, N.O.S.,

1W
5.1
6.1
3088
SELF-HEATING SOLID, ORGANIC,

N.O.S.
1Y
4.2
40
3089
METAL POWDER, FLAMMABLE,

N.O.S.
4Y
4.1
40
3090
LITHIUM METAL BATTERIES

(including lithium alloy batteries)
4W (1)
3091

CONTAINED IN EQUIPMENT
or LITHIUM METAL BATTERIES
PACKED WITH EQUIPMENT
4W (1)
3092
1-METHOXY-2-PROPANOL
l2Y
3093
CORROSIVE LIQUID, OXIDISING,

2W
3093

3094
A(co)
(1)
3
B
56
30
5.1
885
2W
5.1
85
CORROSIVE LIQUID,
WATER-REACTIVE, N.O.S.
4W
4.3
823
3095
CORROSIVE SOLID, SELF-HEATING,

N.O.S.
2W
4.2
884/84
3096
CORROSIVE SOLID,
4W
4.3
842
3097
FLAMMABLE SOLID, OXIDISING,

N.O.S.
1Y(1)
4.1
5.1
3098
OXIDISING LIQUID, CORROSIVE,

N.O.S.
2W (1)
5.1
Book 1.indb 112
04/04/2013 15:31
UN
No
Substance
3099
OXIDISING LIQUID, TOXIC, N.O.S.
3100
EAC
APP
Hazards
HIN
Class
Sub
Risks
2W (1)
5.1
6.1
OXIDISING SOLID, SELF-HEATING,

N.O.S.
1W
5.1
4.2
3101
ORGANIC PEROXIDE TYPE B,

LIQUID
2WE (1)
5.2
3102
ORGANIC PEROXIDE TYPE B, SOLID
1WE (1)
5.2
3103
ORGANIC PEROXIDE TYPE C,

LIQUID
2WE
(1)
5.2
3104
ORGANIC PEROXIDE TYPE C, SOLID 1WE (1)
5.2
3105
ORGANIC PEROXIDE TYPE D,

LIQUID
2WE (1)
5.2
3106
ORGANIC PEROXIDE TYPE D, SOLID 1WE (1)
5.2
3107
ORGANIC PEROXIDE TYPE E,

LIQUID
2W
(1)
5.2
3108
ORGANIC PEROXIDE TYPE E, SOLID
1W (1)
5.2
3109
ORGANIC PEROXIDE TYPE F, LIQUID 2W
5.2
539
3110
ORGANIC PEROXIDE TYPE F, SOLID
1W
5.2
539
3111
ORGANIC PEROXIDE TYPEB,

LIQUID, TEMPERATURE
CONTROLLED
2WE (1)
5.2
3112
ORGANIC PEROXIDE TYPE B, SOLID, 1WE (1)

TEMPERATURE CONTROLLED
5.2
3113
ORGANIC PEROXIDE TYPEC,

LIQUID, TEMPERATURE
CONTROLLED
2WE (1)
5.2
3114
ORGANIC PEROXIDE TYPE C, SOLID, 1WE (1)

5.2
3115
ORGANIC PEROXIDE TYPED,

LIQUID, TEMPERATURE
CONTROLLED
2WE (1)
5.2
3116
ORGANIC PEROXIDE TYPE D, SOLID, 1WE (1)

5.2
3117
ORGANIC PEROXIDE TYPEE,

LIQUID, TEMPERATURE
CONTROLLED
2W (1)
5.2
3118
ORGANIC PEROXIDE TYPE E, SOLID, 1W (1)

5.2
(1)
Book 1.indb 113
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3119
ORGANIC PEROXIDE TYPEF,

LIQUID, TEMPERATURE
CONTROLLED
2W
5.2
539
3120
ORGANIC PEROXIDE TYPE F, SOLID, 1W

5.2
539
3121
OXIDISING SOLID,
4W (1)
5.1
4.3
3122
TOXIC LIQUID, OXIDISING, N.O.S.,

packing group I
2WE
6.1
5.1
665
3122
TOXIC LIQUID, OXIDISING, N.O.S.,

packing group II
2WE
6.1
5.1
65
3123
TOXIC LIQUID, WATER-REACTIVE,

N.O.S.
4W
6.1
4.3
623
3124
TOXIC SOLID, SELF-HEATING,

N.O.S.
2W
6.1
4.2
664/64
3125
TOXIC SOLID, WATER-REACTIVE,

N.O.S.
4W
6.1
4.3
642
3126
SELF-HEATING SOLID, CORROSIVE,

ORGANIC, N.O.S.
1W
4.2
48
3127
SELF-HEATING SOLID, OXIDISING,

N.O.S.
1W (1)
4.2
5.1
3128
SELF-HEATING SOLID, TOXIC,

ORGANIC, N.O.S.
1W
4.2
6.1
46
3129
WATER-REACTIVE LIQUID,
CORROSIVE, N.O.S.
4W
4.3
X382/
382
3130
WATER-REACTIVE LIQUID, TOXIC,

N.O.S.
4W
4.3
6.1
X362/
362
3131
WATER-REACTIVE SOLID,
CORROSIVE, N.O.S.
4W
4.3
X482/
482
3132
FLAMMABLE, N.O.S., packing
group I
4W (1)
4.3
4.1
3132
FLAMMABLE, N.O.S., packing
groups II & III
4W
4.3
4.1
3133
OXIDISING, N.O.S.
4W (1)
4.3
5.1
3134
WATER-REACTIVE SOLID, TOXIC,

4W (1)
4.3
6.1
Class
HIN
Sub
Risks
423
Book 1.indb 114
04/04/2013 15:31
UN
No
Substance
3134

3135
EAC
APP
Hazards
Class
Sub
Risks
4W
4.3
6.1
SELF-HEATING, N.O.S., packing
group I
4W (1)
4.3
4.2
3135
SELF-HEATING, N.O.S., packing
groups II & III
4W
4.3
4.2
3136
TRIFLUOROMETHANE,
REFRIGERATED LIQUID
2T
2.2
3137
OXIDISING SOLID, FLAMMABLE,

N.O.S.
1W (1)
5.1
3138
ETHYLENE, ACETYLENE
2YE
AND PROPYLENE MIXTURE,
REFRIGERATED LIQUID containing
at least 71.5% ethylene with not more
than 22.5% acetylene and not more
than 6% propylene
2.1
3139
OXIDISING LIQUID, N.O.S.
2Y(1)
5.1
3140
ALKALOIDS, LIQUID, N.O.S. or

ALKALOID SALTS, LIQUID, N.O.S.,
packing group I
2X
3140
ALKALOIDS, LIQUID, N.O.S. or

ALKALOID SALTS, LIQUID, N.O.S.,
3141
HIN
462
423
22
4.1
223
6.1
66
2X
6.1
60
ANTIMONY COMPOUND,
INORGANIC, LIQUID, N.O.S.
2Z
6.1
60
3142
DISINFECTANT, LIQUID, TOXIC,

2X
6.1
66
3142

2X
6.1
60
3143
DYE, SOLID, TOXIC, N.O.S. or DYE

INTERMEDIATE, SOLID, TOXIC,
N.O.S.
2X
6.1
66/60
3144
NICOTINE COMPOUND, LIQUID,

LIQUID, N.O.S., packing group I
2X
6.1
66
3144
NICOTINE COMPOUND, LIQUID,

2X
LIQUID, N.O.S., packing groups II & III
6.1
60
Book 1.indb 115
04/04/2013 15:31
UN
No
Substance
EAC
3145
ALKYLPHENOLS, LIQUID, N.O.S.

(including C2-C12 homologues),
packing group I
2X
3145

(including C2-C12 homologues),
3146
APP
Hazards
Class
HIN
Sub
Risks
88
2X
80
ORGANOTIN COMPOUND, SOLID,

N.O.S.
2X
6.1
66/60
3147
DYE, SOLID, CORROSIVE, N.O.S.

or DYE INTERMEDIATE, SOLID,
CORROSIVE, N.O.S.
2X
88/80
3148
WATER-REACTIVE LIQUID, N.O.S.
4W
4.3
X323/
323
3149
HYDROGEN PEROXIDE AND

2P
PEROXYACETIC ACID MIXTURE with
acid(s), water and not more than 5%
peroxyacetic acid, STABILIZED
5.1
3150
DEVICES, SMALL, HYDROCARBON

GAS POWERED or HYDROCARBON
GAS REFILLS FOR SMALL DEVICES
with release device
2YE (1)
2.1
3151
POLYHALOGENATED BIPHENYLS,
LIQUID or POLYHALOGENATED
TERPHENYLS, LIQUID
2X
90
3152
SOLID or POLYHALOGENATED
TERPHENYLS, SOLID
2X
90
3153
PERFLUORO (METHYL VINYL

ETHER)
2YE
2.1
23
3154
PERFLUORO (ETHYL VINYL ETHER)
2YE
2.1
23
58
3155
PENTACHLOROPHENOL
2X
6.1
3156
COMPRESSED GAS, OXIDISING,

N.O.S.
2S
2.2
5.1
25
3157
LIQUEFIED GAS, OXIDISING, N.O.S.
2PE
2.2
5.1
25
3158
GAS, REFRIGERATED LIQUID, N.O.S. 2TE
2.2
22
3159
1,1,1,2-TETRAFLUOROETHANE
2TE
2.2
20
3160
LIQUEFIED GAS, TOXIC,

FLAMMABLE, N.O.S.
2WE
A(co)
A(cf)
2.3
60
2.1
263
Book 1.indb 116
04/04/2013 15:31
UN
No
Substance
EAC
3161
LIQUEFIED GAS, FLAMMABLE,

N.O.S.
2YE
3162
LIQUEFIED GAS, TOXIC, N.O.S.
2XE
3163
LIQUEFIED GAS, N.O.S.
3164
APP
Hazards
Class
HIN
Sub
Risks
2.1
23
2.3
26
2TE
2.2
20
ARTICLES, PRESSURISED,
PNEUMATIC or HYDRAULIC
(containing non-flammable gas)
2T
2.2
3165
AIRCRAFT HYDRAULIC POWER

UNIT FUEL TANK (containing a
mixture of anhydrous hydrazine and
methylhydrazine) (M86 fuel)
l2WE (1)
3166
ENGINE, INTERNAL COMBUSTION

or VEHICLE, FLAMMABLE
GAS POWERED or VEHICLE,
FLAMMABLE LIQUID POWERED or
ENGINE, FUEL CELL, FLAMMABLE
GAS POWERED or ENGINE, FUEL
CELL, FLAMMABLE LIQUID
POWERED or VEHICLE, FUEL CELL,
FLAMMABLE GAS POWERED or
VEHICLE, FUEL CELL, FLAMMABLE
LIQUID POWERED
2YE (1)
3167
GAS SAMPLE, NON-PRESSURISED,

FLAMMABLE, N.O.S., not
refrigerated liquid
2YE (1)
2.1
3168

TOXIC, FLAMMABLE, N.O.S., not
refrigerated liquid
2WE (1)
A(fg)
2.3
3169

TOXIC, N.O.S., not refrigerated liquid
2XE (1)
2.3
3170
ALUMINIUM SMELTING
BY-PRODUCTS or ALUMINIUM
REMELTING BY-PRODUCTS
4W
4.3
3171
BATTERY-POWERED VEHICLE or
BATTERY-POWERED EQUIPMENT
4W (1)
3172
TOXINS, EXTRACTED FROM LIVING

SOURCES, LIQUID, N.O.S., packing
group I
2X
3172

SOURCES, LIQUID, N.O.S., packing
groups II & III
2X
A(c)
(1)
A(fl)
6.1, 8
2.1
423
6.1
66
6.1
60
Book 1.indb 117
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3173
3174
TITANIUM DISULPHIDE
1Y
4.2
40
3175
SOLIDS CONTAINING FLAMMABLE

LIQUID, N.O.S.
1Z
4.1
40
3176

MOLTEN, N.O.S.
1Y
4.1
44
3177
3178
FLAMMABLE SOLID, INORGANIC,

N.O.S.
1Z
4.1
40
3179

INORGANIC, N.O.S.
1X
4.1
6.1
46
3180
FLAMMABLE SOLID, CORROSIVE,

INORGANIC, N.O.S.
1X
4.1
48
3181
METAL SALTS OF ORGANIC

1Z
COMPOUNDS, FLAMMABLE, N.O.S.
4.1
40
3182
METAL HYDRIDES, FLAMMABLE,

N.O.S.
1Z
4.1
40
3183
SELF-HEATING LIQUID, ORGANIC,

N.O.S.
l3W
4.2
30
3184
SELF-HEATING LIQUID, TOXIC,

ORGANIC, N.O.S.
l3W
4.2
6.1
36
3185
SELF-HEATING LIQUID, CORROSIVE,

ORGANIC, N.O.S.
l3W
4.2
38
3186
SELF-HEATING LIQUID, INORGANIC,

N.O.S.
l3W
4.2
3187

INORGANIC, N.O.S.
l3W
4.2
6.1
36
3188
SELF-HEATING LIQUID, CORROSIVE,

INORGANIC, N.O.S.
l3W
4.2
38
3189
METAL POWDER, SELF-HEATING,

N.O.S.
1Y
4.2
40
3190
SELF-HEATING SOLID, INORGANIC,

N.O.S.
1Y
4.2
40
3191

INORGANIC, N.O.S.
1W
4.2
6.1
46
3192
SELF-HEATING SOLID, CORROSIVE,

INORGANIC, N.O.S.
1W
4.2
48
Class
HIN
Sub
Risks
30
Book 1.indb 118
04/04/2013 15:31
UN
No
Substance
3193
3194
PYROPHORIC LIQUID, INORGANIC,

N.O.S.
3195
to
3199
3200
PYROPHORIC SOLID, INORGANIC,

N.O.S.
3201
to
3204
3205
EAC
APP
Hazards
Class
HIN
Sub
Risks
2W
4.2
333
4W
4.2
43

ALCOHOLATES, N.O.S.
1Y
4.2
40
3206
ALKALI METAL ALCOHOLATES,

SELF-HEATING, CORROSIVE, N.O.S.
1W
4.2
3207
3208
METALLIC SUBSTANCE,
WATER-REACTIVE, N.O.S., packing
group I
4W (1)
4.3
3208
METALLIC SUBSTANCE,
WATER-REACTIVE, N.O.S., packing
groups II & III
4W
4.3
3209
METALLIC SUBSTANCE,
WATER-REACTIVE, SELF-HEATING,
4W (1)
4.3
4.2
3209
METALLIC SUBSTANCE,
WATER-REACTIVE, SELF-HEATING,
4W
4.3
4.2
3210
CHLORATES, INORGANIC,
AQUEOUS SOLUTION, N.O.S.
2Y
5.1
50
3211
2Y
5.1
50
3212
HYPOCHLORITES, INORGANIC,
N.O.S.
1W
5.1
50
3213
BROMATES, INORGANIC, AQUEOUS

SOLUTION, N.O.S.
2Y
5.1
50
3214
2Y
5.1
50
3215
PERSULPHATES, INORGANIC, N.O.S. 1Z
5.1
50
48
423
423
Book 1.indb 119
04/04/2013 15:31
UN
No
Substance
3216
PERSULPHATES, INORGANIC,
3217
3218
EAC
APP
Hazards
Class
HIN
Sub
Risks
2Z
5.1
50
NITRATES, INORGANIC, AQUEOUS

SOLUTION, N.O.S.
2Y
5.1
50
3219
NITRITES, INORGANIC, AQUEOUS

SOLUTION, N.O.S.
2Y
5.1
50
3220
PENTAFLUOROETHANE
2TE
2.2
20
3221
SELF-REACTIVE LIQUID TYPE B
2WE (1)
4.1
3222
SELF-REACTIVE SOLID TYPE B
1WE (1)
4.1
3223
SELF-REACTIVE LIQUID TYPE C
2WE (1)
4.1
3224
SELF-REACTIVE SOLID TYPE C
1WE
(1)
4.1
3225
SELF-REACTIVE LIQUID TYPE D
2WE
(1)
4.1
3226
SELF-REACTIVE SOLID TYPE D
1WE (1)
4.1
3227
SELF-REACTIVE LIQUID TYPE E
2W
(1)
4.1
3228
SELF-REACTIVE SOLID TYPE E
1W
(1)
3229
SELF-REACTIVE LIQUID TYPE F
2W
3230
SELF-REACTIVE SOLID TYPE F
1W
3231
4.1
4.1
40
4.1
40
SELF-REACTIVE LIQUID TYPE B,

2WE
(1)
4.1
3232
SELF-REACTIVE SOLID TYPE B,

1WE (1)
4.1
3233
SELF-REACTIVE LIQUID TYPE C,

2WE (1)
4.1
3234
SELF-REACTIVE SOLID TYPE C,

1WE (1)
4.1
3235
SELF-REACTIVE LIQUID TYPE D,

2WE (1)
4.1
3236
SELF-REACTIVE SOLID TYPE D,

1WE (1)
4.1
3237
SELF-REACTIVE LIQUID TYPE E,

2W (1)
4.1
3238
SELF-REACTIVE SOLID TYPE E,

1W (1)
4.1
Book 1.indb 120
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3239
SELF-REACTIVE LIQUID TYPE F,

2W
4.1
40
3240
SELF-REACTIVE SOLID TYPE F,

1W
4.1
40
3241
2-BROMO-2-NITROPROPANE1,3DIOL
1Y(1)
4.1
3242
AZODICARBONAMIDE
1Y
4.1
40
3243
SOLIDS CONTAINING TOXIC

LIQUID, N.O.S.
2X
6.1
60
3244
SOLIDS CONTAINING CORROSIVE

LIQUID, N.O.S.
2X
80
3245
GENETICALLY MODIFIED
MICROORGANISMS or
ORGANISMS
2Z (1)
3245
MICROORGANISMS or
ORGANISMS, in refrigerated liquid
nitrogen
2Z (1)
2.2
3246
METHANESULPHONYL CHLORIDE
2XE
6.1
3247
SODIUM PEROXOBORATE,
ANHYDROUS
1Y
3248
MEDICINE, LIQUID, FLAMMABLE,

TOXIC, N.O.S., packing group II
l3WE
A(fl)
6.1
336
3248
MEDICINE, LIQUID, FLAMMABLE,

TOXIC, N.O.S., packing group III
l3W
A(fl)
6.1
36
3249
MEDICINE, SOLID, TOXIC, N.O.S.
2X
3250
CHLOROACETIC ACID, MOLTEN
2W
3251
3252
Class
5.1
6.1
668
50
6.1
A(h)
HIN
Sub
Risks
60
8
68
ISOSORBIDE-5-MONONITRATE
1Y
(1)
4.1
DIFLUOROMETHANE
2YE
2.1
23
3253
DISODIUM TRIOXOSILICATE
2X
80
3254
TRIBUTYLPHOSPHANE
3W
4.2
333
3255
tert-BUTYL HYPOCHLORITE
2WE
(1)
4.2
Book 1.indb 121
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3256
ELEVATED TEMPERATURE LIQUID,

2Y
FLAMMABLE, N.O.S. with flash point
above 60C, at or above its
flash point
30
3257

N.O.S., at or above 100C and below
its flash point (including molten
metals, molten salts, etc.), filled at a
temperature higher than 190C
2Y
99
3257

N.O.S., at or above 100C and below
its flash point (including molten
metals, molten salts, etc.), filled at or
below 190C
2Y
99
3258
ELEVATED TEMPERATURE SOLID,

N.O.S., at or above 240C
1Y
99
3259
AMINES, SOLID, CORROSIVE,

N.O.S. or POLYAMINES, SOLID,
CORROSIVE, N.O.S.
2X
88/80
3260
CORROSIVE SOLID, ACIDIC,

INORGANIC, N.O.S.
2X
88/80
3261

ORGANIC, N.O.S.
2X
88/80
3262
CORROSIVE SOLID, BASIC,

INORGANIC, N.O.S.
2X
88/80
3263

ORGANIC, N.O.S.
2X
88/80
3264
CORROSIVE LIQUID, ACIDIC,

INORGANIC, N.O.S., packing group I
2X
88
3264

INORGANIC, N.O.S., packing
groupsII & III
2X
80
3265

2X
88
3265

ORGANIC, N.O.S., packing
groupsII & III
2X
80
3266
CORROSIVE LIQUID, BASIC,

2X
88
Class
HIN
Sub
Risks
Book 1.indb 122
04/04/2013 15:31
UN
No
Substance
EAC
3266

INORGANIC, N.O.S., packing
groups II & III
2X
3267

2X
3267

ORGANIC, N.O.S., packing
groups II & III
3268
APP
Hazards
Class
HIN
Sub
Risks
80
88
2X
80
AIR BAG INFLATORS or AIR

BAG MODULES or SEAT-BELT
PRETENSIONERS
2Z (1)
3269
POLYESTER RESIN KIT
l2YE (1)
3270
NITROCELLULOSE MEMBRANE
FILTERS
1Z
4.1
3271
ETHERS, N.O.S., packing group II
3YE
33
3271
ETHERS, N.O.S., packing group III
3Y
30
3272
ESTERS, N.O.S., packing group II
l3YE
33
3272
ESTERS, N.O.S., packing group III
l3Y
3273
NITRILES, FLAMMABLE, TOXIC,

N.O.S.
3WE
A(fl)
6.1
336
3274
ALCOHOLATES SOLUTION, N.O.S.,

in alcohol
l3WE
A(fl)
338
3275
NITRILES, TOXIC, FLAMMABLE,

N.O.S.
3W
A(fl)
6.1
663/63
3276
NITRILES, LIQUID, TOXIC, N.O.S.,

packing group I
2X
6.1
66
3276
NITRILES, LIQUID, TOXIC, N.O.S.,

2X
6.1
60
3277
CORROSIVE, N.O.S.
2X
6.1
3278
ORGANOPHOSPHORUS
COMPOUND, LIQUID, TOXIC,
N.O.S., packing groupI
2X
3278
ORGANOPHOSPHORUS
2X
(1)
30
68
6.1
66
6.1
60
Book 1.indb 123
04/04/2013 15:31
UN
No
Substance
EAC
3279
ORGANOPHOSPHORUS
COMPOUND, TOXIC, FLAMMABLE,
N.O.S.
l3W
3280
ORGANOARSENIC COMPOUND,
LIQUID, N.O.S., packing group I
2X
3280
2X
LIQUID, N.O.S., packing groups II & III
3281
METAL CARBONYLS, LIQUID,

2X
3281

2X
3282
ORGANOMETALLIC COMPOUND,
LIQUID, TOXIC, N.O.S., packing
groupI
2X
3282
LIQUID, TOXIC, N.O.S., packing
groups II & III
3283
SELENIUM COMPOUND, SOLID,

N.O.S.
APP
Hazards
HIN
Class
Sub
Risks
A(fl)
6.1
6.1
66
6.1
60
6.1
66
6.1
60
6.1
66
2X
6.1
60
2X
6.1
66/60
663/63
3284
TELLURIUM COMPOUND, N.O.S.
2X
6.1
66/60
3285
VANADIUM COMPOUND, N.O.S.
2X
6.1
66/60
3286

CORROSIVE, N.O.S.
l3WE
A(fl)
3287
TOXIC LIQUID, INORGANIC, N.O.S.,

packing group I
2X
6.1
66
3287
TOXIC LIQUID, INORGANIC, N.O.S.,

2X
6.1
60
3288
TOXIC SOLID, INORGANIC, N.O.S.
2X
3289

2X
3289
6.1, 8
6.1
B
368
66/60
6.1
668

2X
INORGANIC, N.O.S., packing group II
6.1
68
3290

INORGANIC, N.O.S.
2X
6.1
668/68
3291
CLINICAL WASTE, UNSPECIFIED,

N.O.S. or (BIO) MEDICAL WASTE,
N.O.S. or REGULATED MEDICAL
WASTE, N.O.S.
2X
6.2
606
Book 1.indb 124
04/04/2013 15:31
UN
No
Substance
EAC
APP
3291

N.O.S. or (BIO) MEDICAL WASTE,
WASTE, N.O.S., in refrigerated liquid
nitrogen
2X (1)
3292
BATTERIES, CONTAINING SODIUM,

or CELLS, CONTAINING SODIUM
4W (1)
4.3
3293
HYDRAZINE, AQUEOUS SOLUTION

with not more than 37% hydrazine,
by mass
l2X
6.1
3294
HYDROGEN CYANIDE, SOLUTION

IN ALCOHOL with not more than
45% hydrogen cyanide
l2WE
3295
HYDROCARBONS, LIQUID, N.O.S.,

3YE
33
3295
HYDROCARBONS, LIQUID, N.O.S.,

packing group III
3Y
30
3296
HEPTAFLUOROPROPANE
2T
2.2
20
3297
ETHYLENE OXIDE AND

CHLOROTETRAFLUOROETHANE
MIXTURE with not more than 8.8%
ethylene oxide
2TE
2.2
20
3298
ETHYLENE OXIDE AND

PENTAFLUOROETHANE MIXTURE
with not more than 7.9% ethylene
oxide
2TE
2.2
20
3299
ETHYLENE OXIDE AND

TETRAFLUOROETHANE MIXTURE
with not more than 5.6% ethylene
oxide
2TE
2.2
20
3300

DIOXIDE MIXTURE with more than
87% ethylene oxide
2PE
3301
CORROSIVE LIQUID, SELF-HEATING, 2W

3301
3302
A(c)
A(fl)
Hazards
Class
Sub
Risks
6.2
2.2
6.1
HIN
60
663
A(cf)
2.3
2.1
263
4.2
884
CORROSIVE LIQUID, SELF-HEATING, 2W

4.2
84
ACRYLATE
6.1
2X
60
Book 1.indb 125
04/04/2013 15:31
UN
No
Substance
EAC
3303

OXIDISING, N.O.S.
2PE
3304

CORROSIVE, N.O.S.
3305
APP
Hazards
HIN
Class
Sub
Risks
2.3
5.1
265
2RE
2.3
268

FLAMMABLE, CORROSIVE, N.O.S.
2PE
A(fg)
2.3
2.1, 8
263
3306

OXIDISING, CORROSIVE, N.O.S.
2PE
2.3
5.1, 8
265
3307
LIQUEFIED GAS, TOXIC, OXIDISING, 2WE

N.O.S.
A(co)
2.3
5.1
265
3308

CORROSIVE, N.O.S.
2XE
A(c)
2.3
268
3309

2WE
A(cf)
2.3
2.1, 8
263
3310
LIQUEFIED GAS, TOXIC, OXIDISING, 2WE

CORROSIVE, N.O.S.
A(co)
2.3
5.1, 8
265
3311
GAS, REFRIGERATED LIQUID,

OXIDISING, N.O.S.
2PE
A(co)
2.2
5.1
225
3312

FLAMMABLE, N.O.S.
2YE
2.1
223
3313
ORGANIC PIGMENTS,
SELF-HEATING
1Y
4.2
40
3314
PLASTICS MOULDING COMPOUND

in dough, sheet or extruded rope
form, evolving flammable vapour
2Y (1)
90
3315
CHEMICAL SAMPLE, TOXIC
2X (1)
3316
CHEMICAL KIT or FIRST AID KIT
2Z (1)
3317
2-AMINO-4,6-DINITROPHENOL,
water, by mass
1W (1)
4.1
3318

density less than 0.880 at 15C in
water, with more than 50% ammonia
2RE
3319
NITROGLYCERIN MIXTURE,
1Y(1)
DESENSITIZED, SOLID, N.O.S. with
more than 2% but not more than 10%
nitroglycerin, by mass
6.1
2.3
268
4.1
Book 1.indb 126
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3320
SODIUM BOROHYDRIDE AND

SODIUM HYDROXIDE SOLUTION,
with not more than 12% sodium
borohydride and not more than 40%
sodium hydroxide by mass
2X
80
3321

SPECIFIC ACTIVITY (LSA-II),
non-fissile or fissile-excepted
(2)
70
3322

SPECIFIC ACTIVITY (LSA-III),
non-fissile or fissile-excepted
(2)
70
3323
RADIOACTIVE MATERIAL, TYPE C

PACKAGE, non-fissile or
fissile-excepted
(2)
70
3324

SPECIFIC ACTIVITY (LSA-II), FISSILE
(2)
70
3325

SPECIFIC ACTIVITY, (LSA-III),
FISSILE
(2)
70
3326
RADIOACTIVE MATERIAL, SURFACE

CONTAMINATED OBJECTS
(SCO-I or SCO-II), FISSILE
(2)
70
3327

PACKAGE, FISSILE, non-special form
(2)
70
3328
RADIOACTIVE MATERIAL, TYPE

B(U) PACKAGE, FISSILE
(2)
70
3329

B(M) PACKAGE, FISSILE
(2)
70
3330
RADIOACTIVE MATERIAL, TYPE C

PACKAGE, FISSILE
(2)
70
3331
ARRANGEMENT, FISSILE
(2)
70
3332

PACKAGE, SPECIAL FORM,
(2)
70
3333

PACKAGE, SPECIAL FORM, FISSILE
(2)
70
3334
AVIATION REGULATED LIQUID,

N.O.S.
2Z (1)
Class
HIN
Sub
Risks
Book 1.indb 127
04/04/2013 15:31
UN
No
Substance
EAC
3335
AVIATION REGULATED SOLID,

N.O.S.
2Z (1)
3336
MERCAPTANS, LIQUID,
FLAMMABLE, N.O.S.
3WE
APP
Hazards
Class
HIN
Sub
Risks
9
A(fl)
33/30
3337
REFRIGERANT GAS R 404A
2TE
2.2
20
3338
REFRIGERANT GAS R 407A
2TE
2.2
20
3339
REFRIGERANT GAS R 407B
2TE
2.2
20
3340
REFRIGERANT GAS R 407C
2TE
2.2
20
3341
THIOUREA DIOXIDE
1Y
4.2
40
3342
XANTHATES
1Y
4.2
40
3343
DESENSITIZED, LIQUID,
FLAMMABLE, N.O.S. with not more
than 30% nitroglycerin, by mass
l2Y(1)
3344
PENTAERYTHRITE TETRANITRATE
(PENTAERYTHRITOL
TETRANITRATE; PETN) MIXTURE,
DESENSITIZED, SOLID, N.O.S. with
more than 10% but not more than
20% PETN, by mass
1Y(1)
4.1
3345
PHENOXYACETIC ACID DERIVATIVE

2X
6.1
3346

TOXIC, flash point less than 23C
l3WE
A(fl)
6.1
336
3347

than 23C
l3W
A(fl)
6.1
663/63
3348

group I
2X
6.1
66
3348

groups II & III
2X
6.1
60
3349
PYRETHROID PESTICIDE, SOLID,

TOXIC
2X
6.1
66/60
66/60
Book 1.indb 128
04/04/2013 15:31
UN
No
Substance
EAC
3350
PYRETHROID PESTICIDE, LIQUID,

than 23C
l3WE
3351

less than 23C
3352
APP
Hazards
HIN
Class
Sub
Risks
A(fl)
6.1
336
l3W
A(fl)
6.1
663/63

2X
6.1
66
3352

2X
6.1
60
3353
3354
INSECTICIDE GAS, FLAMMABLE,

N.O.S.
2YE
2.1
23
3355
INSECTICIDE GAS, TOXIC,

FLAMMABLE, N.O.S.
2WE
3356
OXYGEN GENERATOR, CHEMICAL
1Y(1)
5.1
3357
DESENSITIZED, LIQUID, N.O.S.
with not more than 30% nitroglycerin,
by mass
l2Y
3358
REFRIGERATING MACHINES
containing flammable, non-toxic,
liquefied gas
2YE (1)
2.1
3359
FUMIGATED CARGO TRANSPORT

UNIT
2Z (1)
3360
FIBRES, VEGETABLE, DRY
1Z (1)
4.1
3361
CHLOROSILANES, TOXIC,
CORROSIVE, N.O.S.
4W
3362
4WE
A(fl)
3363
DANGEROUS GOODS IN
MACHINERY or DANGEROUS
GOODS IN APPARATUS
1Z (1)
3364
TRINITROPHENOL (PICRIC ACID),

WETTED, with not less than 10%
water by mass
1W (1)
4.1
3365
TRINITROCHLOROBENZENE (PICRYL 1W (1)

CHLORIDE), WETTED, with not less
than 10% water by mass
4.1
A(cf)
(1)
2.3
2.1
263
6.1
68
6.1
3, 8
638
Book 1.indb 129
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3366
TRINITROTOLUENE (TNT), WETTED, 1W (1)

with not less than 10% water by mass
4.1
3367
TRINITROBENZENE, WETTED, with

not less than 10% water by mass
1W (1)
4.1
3368
TRINITROBENZOIC ACID, WETTED,

with not less than 10% water by mass
1W (1)
4.1
3369
water by mass
1W (1)
4.1
3370
UREA NITRATE, WETTED, with not

less than 10% water by mass
1W (1)
4.1
3371
2-METHYLBUTANAL
3YE
33
3372
3373
BIOLOGICAL SUBSTANCE,
CATEGORY B
2X
6.2
606
3374
ACETYLENE, SOLVENT FREE
2SE (1)
2.1
3375
AMMONIUM NITRATE EMULSION

or SUSPENSION or GEL, intermediate
for blasting explosives
1Y
5.1
3376
4-NITROPHENYLHYDRAZINE, with
1W (1)
4.1
3377
SODIUM PERBORATE
MONOHYDRATE
1Z
5.1
50
3378
SODIUM CARBONATE
PEROXYHYDRATE
1Y
5.1
50
3379
DESENSITIZED EXPLOSIVE, LIQUID,

N.O.S.
l3YE (1)
3380
DESENSITIZED EXPLOSIVE, SOLID,

N.O.S.
1W (1)
4.1
3381
TOXIC BY INHALATION LIQUID,

N.O.S. with an LC50 lower than or
equal to 200ml/m3 and saturated
vapour concentration greater than or
equal to 500 LC50
2XE
6.1
66
3382

equal to 1000ml/m3 and saturated
equal to 10 LC50
2XE
6.1
66
Class
HIN
Sub
Risks
6.1
50
Book 1.indb 130
04/04/2013 15:31
UN
No
Substance
EAC
3383

FLAMMABLE, N.O.S. with an LC50
lower than or equal to 200ml/m3 and
saturated vapour concentration greater
than or equal to 500 LC50
l3WE
3384

FLAMMABLE, N.O.S. with an LC50
3385

WATER-REACTIVE, N.O.S. with an
LC50 lower than or equal to 200ml/m3
and saturated vapour concentration
greater than or equal to 500 LC50
APP
Hazards
HIN
Class
Sub
Risks
A(fl)
6.1
663
l3WE
A(fl)
6.1
663
4WE
6.1
4.3
623
3386
4WE
WATER-REACTIVE, N.O.S. with an
LC50 lower than or equal to 1000ml/
m3 and saturated vapour concentration
6.1
4.3
623
3387
2WE
OXIDISING, N.O.S. with an LC50
6.1
5.1
665
3388
2WE
OXIDISING, N.O.S. with an LC50
6.1
5.1
665
3389
2XE
CORROSIVE, N.O.S. with an LC50
6.1
668
3390
2XE
CORROSIVE, N.O.S. with an LC50
6.1
668
3391
ORGANOMETALLIC SUBSTANCE,
SOLID, PYROPHORIC
4Y
4.2
43
3392
LIQUID, PYROPHORIC
4Y
4.2
333
Book 1.indb 131
04/04/2013 15:31
UN
No
Substance
3393
SOLID, PYROPHORIC,
WATER-REACTIVE
3394
EAC
APP
Hazards
HIN
Class
Sub
Risks
4W
4.2
4.3
X432
LIQUID, PYROPHORIC,
WATER-REACTIVE
4W
4.2
4.3
X333
3395
SOLID, WATER-REACTIVE
4W
4.3
3396
SOLID, WATER-REACTIVE,
FLAMMABLE
4W
4.3
4.1
X423/
423
3397
SELF-HEATING
4W
4.3
4.2
X423/
423
3398
LIQUID, WATER-REACTIVE
4W
4.3
3399
LIQUID, WATER-REACTIVE,
FLAMMABLE
4W
3400
SOLID, SELF-HEATING
2Y
4.2
40
3401
ALKALI METAL AMALGAM, SOLID
4W
4.3
X423
3402

AMALGAM, SOLID
4W
4.3
X423
A(fl)
4.3
X423/
423
X323/
323
3
X323/
323
3403
POTASSIUM METAL ALLOYS, SOLID 4W
4.3
X423
3404

SOLID
4W
4.3
X423
3405
BARIUM CHLORATE SOLUTION
2Y
5.1
6.1
56
3406
BARIUM PERCHLORATE SOLUTION
2Y
5.1
6.1
56
3407

CHLORIDE MIXTURE SOLUTION
2Y
5.1
50
3408
LEAD PERCHLORATE SOLUTION
2Y
5.1
3409
CHLORONITROBENZENES, LIQUID
2X
6.1
60
3410
HYDROCHLORIDE SOLUTION
2X
6.1
60
3411
beta-NAPHTHYLAMINE SOLUTION
2Z
6.1
60
6.1
56
Book 1.indb 132
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3412
FORMIC ACID with not less than 10%

but not more than 85% acid
by mass
l2X
80
3412
FORMIC ACID with not less than 5%

but less than 10% acid by mass
2X
80
3413
POTASSIUM CYANIDE SOLUTION,

packing group I
2X
6.1
66
3413
POTASSIUM CYANIDE SOLUTION,

2X
6.1
60
3414
SODIUM CYANIDE SOLUTION,

packing group I
2X
6.1
66
3414
SODIUM CYANIDE SOLUTION,

2X
6.1
60
3415
SODIUM FLUORIDE SOLUTION
2Z
6.1
60
3416
CHLOROACETOPHENONE, LIQUID
2Z
6.1
60
Class
HIN
Sub
Risks
3417
XYLYL BROMIDE, SOLID
2X
6.1
60
3418
2,4-TOLUYLENEDIAMINE
SOLUTION
2X
6.1
60
3419
BORON TRIFLUORIDE ACETIC ACID

COMPLEX, SOLID
2X
80
3420

ACID COMPLEX, SOLID
2X
80
3421
POTASSIUM HYDROGEN
DIFLUORIDE SOLUTION
2X
3422
POTASSIUM FLUORIDE SOLUTION
2X
6.1
60
3423
TETRAMETHYLAMMONIUM
HYDROXIDE, SOLID
2X
80
3424
AMMONIUM DINITRO-oCRESOLATE, SOLUTION
2X
6.1
60
6.1
86
3425
BROMOACETIC ACID, SOLID
2X
80
3426
ACRYLAMIDE SOLUTION
2X
6.1
60
3427
CHLOROBENZYL CHLORIDES, SOLID 2X
6.1
60
3428
3-CHLORO-4-METHYLPHENYL
ISOCYANATE, SOLID
6.1
60
2X
3429
CHLOROTOLUIDINES, LIQUID
2X
6.1
60
3430
XYLENOLS, LIQUID
2X
6.1
60
Book 1.indb 133
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3431
NITROBENZOTRIFLUORIDES, SOLID
2X
6.1
60
3432
SOLID
2X
90
3433

2X
6.1
60
Class
HIN
Sub
Risks
3434
NITROCRESOLS, LIQUID
3435
3436
HEXAFLUOROACETONE HYDRATE,
SOLID
2X
6.1
60
3437
CHLOROCRESOLS, SOLID
2Z
6.1
60
3438
alpha-METHYLBENZYL ALCOHOL,
SOLID
2Z
6.1
60
3439
NITRILES, SOLID, TOXIC, N.O.S.
2X
3440
SELENIUM COMPOUND, LIQUID,

2X
3440

3441
3442
6.1
66/60
6.1
66
2X
6.1
60
CHLORODINITROBENZENES, SOLID
2X
6.1
60
DICHLOROANILINES, SOLID
2X
6.1
60
3443
DINITROBENZENES, SOLID
2X
6.1
60
3444
NICOTINE HYDROCHLORIDE, SOLID 2X
6.1
60
3445
NICOTINE SULPHATE, SOLID
6.1
60
2X
3446
NITROTOLUENES, SOLID
2X
6.1
60
3447
NITROXYLENES, SOLID
2X
6.1
60
3448
TEAR GAS SUBSTANCE, SOLID,

N.O.S.
2X
6.1
66/60
3449
BROMOBENZYL CYANIDES, SOLID
2X
6.1
66
3450
DIPHENYLCHLOROARSINE, SOLID
2X
6.1
66
3451
TOLUIDINES, SOLID
2X
6.1
60
3452
XYLIDINES, SOLID
2X
6.1
60
3453
PHOSPHORIC ACID, SOLID
2X
80
3454
DINITROTOLUENES, SOLID
2X
6.1
60
3455
CRESOLS, SOLID
2X
6.1
3456
NITROSYLSULPHURIC ACID, SOLID
2X
68
X80
Book 1.indb 134
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3457
CHLORONITROTOLUENES, SOLID
2X
6.1
60
3458
NITROANISOLES, SOLID
2Z
6.1
60
Class
HIN
Sub
Risks
3459
NITROBROMOBENZENES, SOLID
2X
6.1
60
3460
SOLID
2X
6.1
60
3461
3462

SOURCES, SOLID, N.O.S.
2X
6.1
66/60
3463
PROPIONIC ACID with not less than

90% acid by mass
l2W
3464
ORGANOPHOSPHORUS
COMPOUND, SOLID, TOXIC, N.O.S.
2X
6.1
66/60
3465
SOLID, N.O.S.
2X
6.1
66/60
3466
METAL CARBONYLS, SOLID, N.O.S.
2X
6.1
66/60
3467
SOLID, TOXIC, N.O.S.
2X
6.1
66/60
3468
HYDROGEN IN A METAL
2SE (1)
HYDRIDE STORAGE SYSTEM or
HYDROGEN IN A METAL HYDRIDE
STORAGE SYSTEM CONTAINED
IN EQUIPMENT or HYDROGEN
IN A METAL HYDRIDE STORAGE
SYSTEMPACKED WITH EQUIPMENT
3469
PAINT, FLAMMABLE, CORROSIVE

(including paint, lacquer, enamel,
stain, shellac, varnish, polish, liquid
filler and liquid lacquer base) or PAINT
RELATED MATERIAL, FLAMMABLE,
CORROSIVE (including paint thinning
or reducing compound), packing
groups I & II
3469 PAINT, FLAMMABLE, CORROSIVE

RELATED MATERIAL, FLAMMABLE,
CORROSIVE (including paint thinning
or reducing compound), packing group
III
A(fl)
83
2.1
l3WE
A(fl)
338
l3W
A(fl)
38
Book 1.indb 135
04/04/2013 15:31
UN
No
Substance
EAC
APP
3470
PAINT, CORROSIVE, FLAMMABLE

RELATED MATERIAL, CORROSIVE,
FLAMMABLE (including paint thinning
or reducing compound)
l3W
3471
HYDROGENDIFLUORIDES
SOLUTION, N.O.S.
2X
3472
CROTONIC ACID, LIQUID
l2X
3473
FUEL CELL CARTRIDGES or FUEL

CELL CARTRIDGES CONTAINED
IN EQUIPMENT or FUEL CELL
CARTRIDGES PACKED WITH
EQUIPMENT, containing flammable
liquids
l2WE (1)
3474
1-HYDROXYBENZOTRIAZOLE
MONOHYDRATE
1W (1)
4.1
3475
ETHANOL AND GASOLINE

MIXTURE or ETHANOL AND
MOTOR SPIRIT MIXTURE or
ETHANOL AND PETROL MIXTURE,
with more than 10% ethanol
l3YE
3476

EQUIPMENT, containing waterreactive substances
4W (1)
4.3
3477

EQUIPMENT, containing corrosive
substances
2X (1)
3478

EQUIPMENT, containing liquefied
flammable gas
2Y(1)
2.1
A(fl)
Hazards
Sub
Risks
83
6.1
86
8
A(fl)
HIN
Class
80
33
Book 1.indb 136
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3479

EQUIPMENT, containing hydrogen in
metal hydride
2W (1)
2.1
3480
LITHIUM ION BATTERIES (including

lithium ion polymer batteries)
4W (1)
3481
LITHIUM ION BATTERIES

CONTAINED IN EQUIPMENT or
LITHIUM ION BATTERIES PACKED
WITH EQUIPMENT (including lithium
ion polymer batteries)
4W (1)
3482
ALKALI METAL DISPERSION,

FLAMMABLE or ALKALINE EARTH
METAL DISPERSION, FLAMMABLE
4WE
A(fl)
4.3
X323
3483

MIXTURE, FLAMMABLE
l3WE
A(fl)
6.1
663
3484
HYDRAZINE AQUEOUS SOLUTION,

FLAMMABLE with more than 37%
hydrazine, by mass
l2X
A(fl)
3, 6.1
886
3485
DRY, CORROSIVE or CALCIUM
HYPOCHLORITE MIXTURE, DRY,
CORROSIVE with more than 39%
available chlorine (8.8% available
oxygen)
1W
5.1
58
3486
MIXTURE, DRY, CORROSIVE with
more than 10% but not more than
39% available chlorine
1W
5.1
58
3487
HYDRATED, CORROSIVE or
HYDRATED MIXTURE, CORROSIVE
with not less than 5.5% but not more
than 16% water
1W
5.1
58
3488

with an LC50 lower than or equal to
200 ml/m and saturated vapour
concentration greater than or equal to
500 LC50
2WE
6.1
3, 8
663
Class
A(fl)
HIN
Sub
Risks
Book 1.indb 137
04/04/2013 15:31
UN
No
Substance
EAC
3489

10 LC50
2WE
3490

equal to 200 ml/m and saturated
equal to 500 LC50
3491
APP
Hazards
HIN
Class
Sub
Risks
A(fl)
6.1
3, 8
663
4WE
A(fl)
6.1
3, 4.3
623

equal to 10 LC50
4WE
A(fl)
6.1
3, 4.3
623
3492

500 LC50
2WE
A(fl)
6.1
8, 3
668
3493

10 LC50
2WE
A(fl)
6.1
8, 3
668
3494
PETROLEUM SOUR CRUDE OIL,

FLAMMABLE, TOXIC, packing groups
I & II
l3WE
A(fl)
6.1
336
3494

FLAMMABLE, TOXIC, packing group
III
l3W
A(fl)
6.1
36
3495
IODINE
2WE
6.1
86
3496
BATTERIES, NICKEL-METAL
HYDRIDE
2Y
3497
KRILL MEAL
1Y
4.2
40
3498
IODINE MONOCHLORIDE, LIQUID
2X
80
(1)
Book 1.indb 138
04/04/2013 15:31
UN
No
Substance
EAC
APP
Hazards
3499
CAPACITOR, electric double layer

(with an energy storage capacity
greater than 0.3Wh)
1Z (1)
3500
CHEMICAL UNDER PRESSURE,

N.O.S.
2ZE
2.2
20
3501

FLAMMABLE, N.O.S.
2YE
2.1
23
3502

TOXIC, N.O.S.
2XE
2.2
6.1
26
3503

CORROSIVE, N.O.S.
2XE
2.2
28
3504

2WE
A(fg)
2.1
6.1
263
3505

2WE
A(fg)
2.1
238
3506
MERCURY CONTAINED IN
MANUFACTURED ARTICLES
2X (1)
6.1
Class
HIN
Sub
Risks
Book 1.indb 139
04/04/2013 15:31
Book 1.indb 140
04/04/2013 15:31
Section 5
Alphabetical List of
Dangerous Goods
alphabetical list of dangerous goods 141
Book 1.indb 141
04/04/2013 15:31
Book 1.indb 142
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Accumulators, electric, see
2794
2795
2800
3028
3292
ACRIDINE
2713
ACROLEIN DIMER, STABILIZED
2607
ACROLEIN, STABILIZED
1092
ACRYLAMIDE, SOLID
2074
ACRYLAMIDE SOLUTION
3426
ACRYLIC ACID, STABILIZED
2218
ACRYLONITRILE, STABILIZED
1093
Actinolite, see
2590
Activated carbon, see
1362
Activated charcoal, see
1362
ADHESIVES, containing flammable

liquid
1133
ADIPONITRILE
2205
AEROSOLS
1950
AIR BAG INFLATORS
3268
AIR BAG MODULES
3268
AIR, COMPRESSED
1002
ACETAL
1088
ACETALDEHYDE
1089
ACETALDEHYDE AMMONIA
1841
ACETALDEHYDE OXIME
2332
ACETIC ACID, GLACIAL
2789

than 80% acid, by mass
2789

acid, by mass
2790
ACETIC ANHYDRIDE
1715
Acetoin, see
2621
ACETONE
1090
ACETONE CYANOHYDRIN,
STABILIZED
1541
ACETONE OILS
1091
Aircraft evacuation slides, see
2990
ACETONITRILE
1648
3165
ACETYL BROMIDE
1716
ACETYL CHLORIDE
1717
AIRCRAFT HYDRAULIC POWER

UNIT FUEL TANK (containing a
mixture of anhydrous hydrazine and
methylhydrazine) (M86 fuel)
ACETYLENE, DISSOLVED
1001
Aircraft survival kits, see
2990
AIR, REFRIGERATED LIQUID
1003
ACETYLENE, SOVLENT FREE
3374
Acetylene tetrabromide, see
2504
ALCOHOLATES SOLUTIONS,
N.O.S., in alcohol
3274
Acetylene tetrachloride, see
1702
Alcohol, denatured, see
ACETYL IODIDE
1898
1986
1987
ACETYL METHYL CARBINOL
2621
Alcohol, industrial, see
1986
1987
Acid butyl phosphate, see
1718
ALCOHOLS, N.O.S.
1987
Acid mixtures, hydrofluoric and

sulphuric, see
1786
ALCOHOLS, FLAMMABLE,
TOXIC, N.O.S.
1986
Acid mixtures, nitrating acid, see
1796
ALCOHOLIC BEVERAGES
3065
Acid mixtures, spent, nitrating acid,

see
1826
Aldehyde, see
1989
ALDEHYDES, N.O.S.
1989
Acraldehyde, inhibited, see
1092
Book 1.indb 143
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
ALDEHYDES, FLAMMABLE,
TOXIC, N.O.S.
1988
2584
ALDOL
2839
ALKYL SULPHONIC ACIDS,

LIQUID, with more than 5% free
sulphuric acid
ALKALI METAL ALCOHOLATES,

SELF-HEATING, CORROSIVE,
N.O.S.
3206

LIQUID, with not more than 5%
free sulphuric acid
2586
ALKALI METAL ALLOY, LIQUID,

N.O.S.
1421

SOLID, with more than 5% free
sulphuric acid
2583
ALKALI METAL AMALGAM,

LIQUID
1389
2585
ALKALI METAL AMALGAM,

SOLID
3401

SOLID, with not more than 5%
sulphuric acid
ALKYL SULPHURIC ACIDS
2571
ALKALI METAL AMIDES
1390
Allene, see
2200
ALKALI METAL DISPERSION
1391
ALLYL ACETATE
2333
ALKALI METAL DISPERSION,

FLAMMABLE
3482
ALLYL ALCOHOL
1098
Alkaline corrosive battery fluid, see
2797
ALLYLAMINE
2334

ALCOHOLATES, N.O.S.
3205
ALLYL BROMIDE
1099
ALLYL CHLORIDE
1100
ALKALINE EARTH METAL ALLOY,

N.O.S.
1393
Allyl chlorocarbonate, see
1722

AMALGAM, LIQUID
1392
ALLYL CHLOROFORMATE
1722
ALLYL ETHYL ETHER
2335

AMALGAM, SOLID
3402
ALLYL FORMATE
2336
ALLYL GLYCIDYL ETHER
2219

DISPERSION
1391
ALLYL IODIDE
1723

DISPERSION, FLAMMABLE
3482
ALLYL ISOTHIOCYANATE,
STABILIZED
1545
ALKALOIDS, LIQUID, N.O.S.
3140
ALLYLTRICHLOROSILANE,
STABILIZED
1724
ALKALOIDS, SOLID, N.O.S.
1544
Aluminium alkyl halides, liquid, see
3394
ALKALOID SALTS, LIQUID, N.O.S.
3140
Aluminium alkyl halides, solid, see
3393
ALKALOID SALTS, SOLID, N.O.S.
1544
Aluminium alkyl hydrides, see
3394
Alkyl aluminium halides, see
3394
Aluminium alkyls, see
3394

3145
ALUMINIUM BOROHYDRIDE
2870
ALKYLPHENOLS, SOLID, N.O.S.

2430
ALUMINIUM BOROHYDRIDE IN
DEVICES
2870
ALUMINIUM BROMIDE,
ANHYDROUS
1725
Book 1.indb 144
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
ALUMINIUM BROMIDE
SOLUTION
2580
2-AMINO-5-DIETHYLAMINOPENTANE
2946
ALUMINIUM CARBIDE
1394
3317
ALUMINIUM CHLORIDE,
ANHYDROUS
1726
2-AMINO-4,6-DINITROPHENOL,
water by mass
ALUMINIUM CHLORIDE
SOLUTION
2581
2-(2-AMINOETHOXY) ETHANOL
3055
N-AMINOETHYLPIPERAZINE
2815
Aluminium dross, see
3170
1-Amino-2-nitrobenzene, see
1661
ALUMINIUM FERROSILICON
POWDER
1395
1661
ALUMINIUM HYDRIDE
2463
1661
ALUMINIUM NITRATE
1438
AMINOPHENOLS (o-,m-,p-)
2512
ALUMINIUM PHOSPHIDE
1397
AMINOPYRIDINES (o-,m-,p-)
2671
ALUMINIUM PHOSPHIDE
PESTICIDES
3048
AMMONIA, ANHYDROUS
1005
2672
ALUMINIUM POWDER, COATED
1309
ALUMINIUM POWDER,
UNCOATED
1396

density (specific gravity) between
0.880 and 0.957 at 15C in water,
with more than 10% and not more
than 35% ammonia
ALUMINIUM RE-MELTING
BY-PRODUCTS
3170
2073
ALUMINIUM RESINATE
2715

density (specific gravity) less than
0.880 at 15C in water, with more
than 35% and not more than 50%
ammonia
ALUMINIUM SILICON POWDER,

UNCOATED
1398
3318
ALUMINIUM SMELTING
BY-PRODUCTS
3170

density (specific gravity) less than
0.880 at 15C in water, with more
than 50% ammonia
AMINES, FLAMMABLE,
CORROSIVE, N.O.S.
2733
AMMONIUM ARSENATE
1546
Ammonium bichromate, see
1439

N.O.S.
2735
Ammonium bifluoride solid, see
1727

FLAMMABLE, N.O.S.
2734
Ammonium bifluoride solution, see
2817
Ammonium bisulphate, see
2506
AMINES, SOLID, CORROSIVE,

N.O.S.
3259
Ammonium bisulphite solution, see
2693
AMMONIUM DICHROMATE
1439
AMMONIUM DINITRO-oCRESOLATE, SOLID
1843
Aminobenzene, see
1547
2-Aminobenzotrifluoride, see
2942
3-Aminobenzotrifluoride, see
2948
1125
AMMONIUM DINITRO-oCRESOLATE SOLUTION
3424
Aminobutane, see
2-AMINO-4-CHLOROPHENOL
2673
AMMONIUM FLUORIDE
2505
Book 1.indb 145
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
AMMONIUM FLUOROSILICATE
2854
2016
Ammonium hexafluorosilicate, see
2854
AMMUNITION, TOXIC,
NON-EXPLOSIVE without burster
or expelling charge, non-fused
AMMONIUMHYDROGEN
Amosite, see
2212
DIFLUORIDE, SOLID
1727
AMYL ACETATES
1104
AMMONIUMHYDROGEN
DIFLUORIDE SOLUTION
2817
AMYL ACID PHOSPHATE
2819
AMMONIUM HYDROGEN
SULPHATE
2506
Amyl aldehyde, see
2058
AMYLAMINE
1106
Ammonium hydrosulphide solution

(treat as ammonium sulphide
solution), see
2683
AMYL BUTYRATES
2620
AMYL CHLORIDE
1107
1108
AMMONIUM METAVANDATE
2859
n-Amylene, see
AMMONIUM NITRATE, with not

more than 2% total combustible
material
1942
AMYL FORMATES
1109
AMYL MERCAPTAN
1111
n-AMYL METHYL KETONE
1110
AMYL NITRATE
1112
AMYL NITRITE
1113
AMYLTRICHLOROSILANE
1728
Anaesthetic ether, see
1155
ANILINE
1547
Aniline chloride, see
1548
ANILINE HYDROCHLORIDE
1548
Aniline oil, see
1547
Aniline salt, see
1548
ANISIDINES
2431
ANISOLE
2222
ANISOYL CHLORIDE
1729
Anthophyllite, see
2590

FERTILIZER
2067
AMMONIUM NITRATE
EMULSION, intermediate for
blasting explosives
3375
AMMONIUM NITRATE GEL,

intermediate for blasting explosives
3375
AMMONIUM NITRATE LIQUID

(hot concentrated solution)
2426
AMMONIUM NITRATE
SUSPENSION, intermediate for
blasting explosives
3375
AMMONIUM PERCHLORATE
1442
Ammonium permanganate, see
1482
AMMONIUM PERSULPHATE
1444
AMMONIUM POLYSULPHIDE
SOLUTION
2818
AMMONIUM POLYVANADATE
2861
Antimonous chloride, see
1733
Ammonium silicofluoride, see
2854
3141
AMMONIUM SULPHIDE
SOLUTION
2683
ANTIMONY COMPOUND,
INORGANIC, LIQUID, N.O.S.
1549
Ammunition, lachrymatory, see
2017
ANTIMONY COMPOUND,
INORGANIC, SOLID, N.O.S.
AMMUNITION, TEAR-PRODUCING,
NON-EXPLOSIVE without burster
or expelling charge, non-fused
2017
Antimony hydride, see
2676
ANTIMONY LACTATE
1550
Book 1.indb 146
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Antimony (III) lactate, see
1550
1557
LIQUID
1730
ARSENIC COMPOUND, SOLID,

INORGANIC, N.O.S., including
Arsenates, n.o.s.; Arsenites, n.o.s.;
SOLUTION
1731
Arsenic (III) oxide, see
1561
ANTIMONY PENTAFLUORIDE
1732
Arsenic (V) oxide, see
1559
Antimony perchloride, liquid, see
1730
ARSENIC PENTOXIDE
1559
Arsenic sulphides, see
1556
ANTIMONY POTASSIUM
TARTRATE
1551
ARSENIC TRICHLORIDE
1560
ANTIMONY POWDER
2871
ARSENIC TRIOXIDE
1561
ANTIMONY TRICHLORIDE
1733
Arsenious chloride, see
1560
A.n.t.u., see
1651
Arsenites, n.o.s., liquid, see
1556
ARGON, COMPRESSED
1006
Arsenites, n.o.s., solid, see
1557
ARGON, REFRIGERATED LIQUID
1951
Arsenous chloride, see
1560
Arsenates, liquid, n.o.s., see
1556
ARSINE
2188
Arsenates, solid, n.o.s., see
1557
1558
ARTICLES PRESSURISED,
HYDRAULIC (containing
non-flammable gas)
3164
ARSENIC
ARSENIC ACID, LIQUID
1553
1554
ARTICLES PRESSURISED,
PNEUMATIC (containing
non-flammable gas)
3164
ARSENIC ACID, SOLID

ARSENICAL DUST
1562
1562

FLAMMABLE, TOXIC, flash point
less than 23C
2760
ARYLSULPHONIC ACIDS, LIQUID,

with more than 5% free sulphuric
acid
2584
Arsenical flue dust, see
2586

TOXIC, FLAMMABLE, flash point
23C or above
2993
ARYLSULPHONIC ACIDS, LIQUID,

sulphuric acid
2583

TOXIC
2994
ARYLSULPHONIC ACIDS, SOLID,

with more than 5% free sulphuric
acid
2585
ARSENICAL PESTICIDE, SOLID,

TOXIC
2759
ARYLSULPHONIC ACIDS, SOLID,

sulphuric acid
ARSENIC BROMIDE
1555
Asbestos, blue or brown, see
2212
Arsenic (III) bromide, see
1555
Asbestos, white, see
2590
Arsenic chloride, see
1560
Asphalt, see

INORGANIC, N.O.S., including:
Arsenates, n.o.s.; Arsenites, n.o.s.;
1556
1999
3256
3257
AVIATION REGULATED LIQUID,

N.O.S.
3334
Book 1.indb 147
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
AVIATION REGULATED SOLID,

N.O.S.
3335
BATTERIES, WET,
NON-SPILLABLE, electric, storage
2800
AZODICARBONAMIDE
3242
BATTERY FLUID, ACID
2796
BARIUM
1400
BATTERY FLUID, ALKALI
2797
BARIUM ALLOYS, PYROPHORIC
1854
BATTERY-POWERED EQUIPMENT
3171
BARIUM AZIDE, WETTED, with

1571
BATTERY-POWERED VEHICLE
3171
BENZALDEHYDE
1990
Barium binoxide, see
1449
BARIUM BROMATE
BENZENE
1114
2719
BARIUM CHLORATE, SOLID
BENZENESULPHONYL CHLORIDE
2225
1445
BARIUM CHLORATE SOLUTION
Benzenethiol, see
2337
3405
BARIUM COMPOUND, N.O.S.
BENZIDINE
1885
1564
BARIUM CYANIDE
Benzole, see
1114
1565
Benzolene, see
1268
Barium dioxide, see
1449
BARIUM HYPOCHLORITE, with

more than 22% available chlorine
BENZONITRILE
2224
2741
BENZOQUINONE
2587
BARIUM NITRATE
1446
Benzosulphochloride, see
2225
BARIUM OXIDE
1884
BENZOTRICHLORIDE
2226
BARIUM PERCHLORATE, SOLID
1447
BENZOTRIFLUORIDE
2338
BARIUM PERCHLORATE
SOLUTION
3406
BENZOYL CHLORIDE
1736
BENZYL BROMIDE
1737
BARIUM PERMANGANATE
1448
BENZYL CHLORIDE
1738
BARIUM PEROXIDE
1449
Benzyl chlorocarbonate, see
1739
Barium selenate, see
2630
BENZYL CHLOROFORMATE
1739
Barium selenite, see
2630
Benzyl cyanide, see
2470
Barium superoxide, see
1449
BENZYLDIMETHYLAMINE
2619
BATTERIES, CONTAINING
SODIUM
3292
BENZYLIDENE CHLORIDE
1886
BENZYL IODIDE
2653
BERYLLIUM COMPOUND, N.O.S.
1566
BERYLLIUM NITRATE
2464
BERYLLIUM POWDER
1567
BATTERIES, DRY, CONTAINING

POTASSIUM HYDROXIDE SOLID,
electric, storage
3028
BATTERIES, NICKEL-METAL
HYDRIDE
3496

ACID, electric, storage
2794
BHUSA
1327
2251

ALKALI, electric, storage
2795
BICYCLO[2.2.1]HEPTA-2,5DIENE, STABILIZED
Biflourides, n.o.s., see
1740
Book 1.indb 148
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
BIOLOGICAL SUBSTANCE,
CATEGORY B
3373

1743
(BIO) MEDICAL WASTE, N.O.S.
3291
3420
BIPYRIDILIUM PESTICIDE,
2782

ACID COMPLEX, SOLID
BROMATES, INORGANIC, N.O.S.
1450
flash point 23C or above
3213
3015
BROMATES, INORGANIC,
BROMINE
1744
LIQUID, TOXIC
3016
BROMINE CHLORIDE
2901
BROMINE PENTAFLUORIDE
1745
BIPYRIDILIUM PESTICIDE, SOLID,

TOXIC
2781
BROMINE SOLUTION
1744
BROMINE TRIFLUORIDE
1746
BROMOACETIC ACID, SOLID
3425
BROMOACETIC ACID SOLUTION
1938
BROMOACETONE
1569
omega-Bromoacetophenone, see
2645
BROMOACETYL BROMIDE
2513
BROMOBENZENE
2514
BROMOBENZYL CYANIDES,
LIQUID
1694
BROMOBENZYL CYANIDES,
SOLID
3449
1-BROMOBUTANE
1126
2-BROMOBUTANE
2339
BROMOCHLOROMETHANE
1887
1-BROMO-3-CHLOROPROPANE
2688
1-Bromo-2,3-epoxypropane, see
2558
Bromoethane, see
1891
2-BROMOETHYL ETHYL ETHER
2340
BROMOFORM
2515
Bromomethane, see
1062
1-BROMO-3-METHYLBUTANE
2341
BROMOMETHYLPROPANES
2342
2-BROMO-2-NITROPROPANE-1,
3-DIOL
3241
BISULPHATES, AQUEOUS
SOLUTION
2837
BISULPHITES, AQUEOUS
SOLUTION, N.O.S.
2693
Bitumen, see
1999
3256
3257
Bleaching powder, see
2208
BLUE ASBESTOS (crocidolite)
2212
BOMBS, SMOKE,
NON-EXPLOSIVE, with corrosive
liquid, without initiating device
2028
Borate and chlorate mixture, see
1458
BORNEOL
1312
BORON TRIBROMIDE
2692
BORON TRICHLORIDE
1741
BORON TRIFLUORIDE
1008
BORON TRIFLUORIDE ACETIC

1742
BORON TRIFLUORIDE ACETIC

ACID COMPLEX, SOLID
3419
BORON TRIFLUORIDE DIETHYL

ETHERATE
2604
BORON TRIFLUORIDE DIMETHYL

ETHERATE
2965
BORON TRIFLUORIDE
DIHYDRATE
2851
Book 1.indb 149
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
2-BROMOPENTANE
2343
sec-Butyl benzene, see
2709
BROMOPROPANES
2344
n-Butyl bromide, see
1126
3-BROMOPROPYNE
2345
n-Butyl chloride, see
1127
BROMOTRIFLUORO-ETHYLENE
2419
n-BUTYL CHLOROFORMATE
2743
BROMOTRIFLUOROMETHANE
1009
2212
tert-BUTYLCYCLOHEXYL
CHLOROFORMATE
2747
BROWN ASBESTOS (amosite,

mysorite)
1- BUTYLENE
1012
BRUCINE
1570
cis-2-BUTYLENE
1012
BUTADIENES, STABILIZED
1010
BUTYLENES
1012
BUTADIENES AND
HYDROCARBON MIXTURE,
STABILIZED
1010
1,2-BUTYLENE OXIDE,
STABILIZED
3022
BUTANE
Butyl ethers, see
1149
1011
BUTANEDIONE
Butyl ethyl ether, see
1179
2346
n-BUTYL FORMATE
1128
Butane-1-thiol, see
2347
tert-BUTYL HYPOCHLORITE
3255
Butan-2-ol, see
1120
BUTANOLS
N,n-BUTYLIMIDAZOLE
2690
1120
N,n-Butyliminazole, see
2690
1-Butanol, see
1120
n-BUTYL ISOCYANATE
2485
Butanol, secondary, see
1120
tert-BUTYL ISOCYANATE
2484
Butanol, tertiary, see
1120
Butyl lithium, see
3394
Butanone, see
1193
BUTYL MERCAPTAN
2347
2-Butenal, see
1143
1012
n-BUTYL METHACRYLATE,
STABILIZED
2227
Butene, see
But-1-ene-3-one, see
1251
BUTYL METHYL ETHER
2350
1, 2-Buteneoxide, see
3022
BUTYL NITRITES
2351
2-Buten-1-ol, see
2614
Butylphenols, liquid, see
3145
BUTYL ACETATES
1123
Butylphenols, solid, see
2430
Butyl acetate, secondary, see
1123
BUTYL PROPIONATES
1914
BUTYL ACID PHOSPHATE
1718
p-tert-Butyltoluene, see
2667
BUTYL ACRYLATES, STABILIZED
2348
BUTYLTOLUENES
2667
Butyl alcohols, see
1120
BUTYLTRICHLOROSILANE
1747
n-BUTYLAMINE
1125
2956
N-BUTYLANILINE
2738
5-tert-BUTYL-2,4,6-TRINITRO-mXYLENE
BUTYLBENZENES
2709
BUTYL VINYL ETHER,

STABILIZED
2352
Book 1.indb 150
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
But-1-yne, see
2452
CALCIUM DITHIONITE
1923
1,4-BUTYNEDIOL
2716
CALCIUM HYDRIDE
1404
2-Butyne-1, 4-diol, see
2716
Calcium hydrosulphite, see
1923
BUTYRALDEHYDE
1129
1748
BUTYRALDOXIME
2840
BUTYRIC ACID
2820
CALCIUM HYPOCHLORITE, DRY

or CALCIUM HYPOCHLORITE
MIXTURE, DRY, with more than
39% available chlorine (8.8%
available oxygen)
BUTYRIC ANHYDRIDE
2739
2710
BUTYRONITRILE
2411
DRY, CORROSIVE or CALCIUM
HYPOCHLORITE MIXTURE, DRY,
CORROSIVE
3485
Butyrone, see
Butyroyl chloride, see
2353
2353
CACODYLIC ACID
1572
CADMIUM COMPOUND
2570
HYDRATED or CALCIUM
HYPOCHLORITE, HYDRATED
MIXTURE, with not less than 5.5%
but not more than 16% water
2880
BUTYRYL CHLORIDE
CAESIUM
1407
HYDRATED, CORROSIVE
3487
CAESIUM HYDROXIDE
2682
2681
HYDRATED MIXTURE,
CORROSIVE
3487
CAESIUM HYDROXIDE
SOLUTION
CAESIUM NITRATE
1451
2208
Caffeine, see
1544
Cajeputene, see
2052
MIXTURE, DRY, with more than
10% but not more than 39%
available chlorine
CALCIUM
1401
MIXTURE, DRY, CORROSIVE
3486
CALCIUM ALLOYS, PYROPHORIC
1855
CALCIUM MANGANESE SILICON
2844
CALCIUM ARSENATE
1573
CALCIUM NITRATE
1454
CALCIUM ARSENATE AND

CALCIUM ARSENITE, MIXTURE,
SOLID
1574
CALCIUM OXIDE
1910
CALCIUM PERCHLORATE
1455
Calcium bisulphite solutions, see
2693
CALCIUM PERMANGANATE
1456
CALCIUM CARBIDE
1402
CALCIUM PEROXIDE
1457
CALCIUM CHLORATE
1452
CALCIUM PHOSPHIDE
1360
CALCIUM CHLORATE, AQUEOUS

SOLUTION
2429
CALCIUM, PYROPHORIC
1855
CALCIUM RESINATE
1313
CALCIUM CHLORITE
1453
CALCIUM RESINATE, FUSED
1314
CALCIUM CYANAMIDE, with

more than 0.1% calcium carbide
1403
Calcium selenate, see
2630
CALCIUM CYANIDE
1575
CALCIUM SILICIDE
1405
Book 1.indb 151
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Calcium silicon, see
1405
1016
Calcium superoxide, see
1457
CARBON MONOXIDE,
COMPRESSED
Camphanone, see
2717
Carbon oxysulphide, see
2204
CAMPHOR OIL
1130
CARBON TETRABROMIDE
2516
CAMPHOR, synthetic
2717
CARBON TETRACHLORIDE
1846
CAPACITOR, electric double layer

(with an energy storage capacity
greater than 0.3Wh)
3499
Carbonyl chloride, see
1076
CARBONYL FLUORIDE
2417
CAPROIC ACID
CARBONYL SULPHIDE
2204
2829

less than 23C
Casingead gasolene, see
1203
2758
2969

23C or above
2991
CASTOR BEANS or CASTOR

MEAL or CASTOR POMACE or
CASTOR FLAKE
CAUSTIC ALKALI LIQUID, N.O.S.
1719
Caustic potash, see
1814

TOXIC
2992
Caustic soda, see
1824
CARBAMATE PESTICIDE, SOLID,

TOXIC
2757
Caustic soda liquor, see
1824
CELLS, CONTAINING SODIUM
3292
Carbolic acid, see
1671
2312
2821
CELLULOID in blocks, rods, rolls,

sheets, tubes, etc., except scrap
2000
CARBON, ACTIVATED
1362
CELLULOID, SCRAP
2002
CARBON, animal or vegetable

origin
1361
Cement, see
1133
CERIUM, slabs, ingots, or rods
1333
Carbon bisulphide, see
1131
CERIUM, turnings or gritty powder
3078
Carbon, black, animal or vegetable

origin, see
1361
Cer mishmetall, see
1323
Charcoal, activated, see
1362
CARBON DIOXIDE
1013
Charcoal, non-activated, see
1361
Carbon dioxide and ethylene oxide

mixtures, see
1041
1952
3300
CHEMICAL KIT
3316
CHEMICAL SAMPLE, TOXIC
3315
CARBON DIOXIDE,
REFRIGERATED LIQUID
2187

N.O.S.
3500
CARBON DIOXIDE, SOLID
1845
1131

FLAMMABLE, N.O.S.
3501
CARBON DISULPHIDE
Carbonic anhydride, see
1013
1845
2187

TOXIC, N.O.S.
3502

CORROSIVE, N.O.S.
3503
Book 1.indb 152
04/04/2013 15:31
Substance
UN
No
Substance
UN
No

3504
CHLOROANILINES, SOLID
2018

FLAMMABLE, CORROSIVE,
N.O.S.
3505
CHLOROANISIDINES
2233
CHLOROBENZENE
1134
CHLOROBENZOTRIFLUORIDES
2234
Chile saltpetre, see
1498
2075
LIQUID
2235
CHLORAL, ANHYDROUS,
STABILIZED
1458
SOLID
3427
CHLORATE AND BORATE

MIXTURE
1-Chloro-3-bromopropane, see
2688

CHLORIDE MIXTURE, SOLID
1459
1-Chlorobutane, see
1127
2-Chlorobutane, see
1127
CHLOROBUTANES
1127
CHLOROCRESOLS, SOLID
3437
CHLOROCRESOLS SOLUTION
2669
1974

CHLORIDE MIXTURE SOLUTION
3407
CHLORATES, INORGANIC, N.O.S.
1461
CHLORATES, INORGANIC,
3210
CHLORODIFLUOROBROMOMETHANE
CHLORIC ACID AQUEOUS

SOLUTION, with not more than
10% chloric acid
2626
1-CHLORO-1, 1-DIFLUOROETHANE 2517
CHLORINE
1017
CHLORINE PENTAFLUORIDE
2548
CHLORINE TRIFLUORIDE
1749
CHLORITES, INORGANIC, N.O.S.
1462
CHLORITE SOLUTION
1908
Chloroacetaldehyde, see
2232
CHLOROACETIC ACID, MOLTEN
3250
CHLOROACETIC ACID, SOLID
1751
CHLOROACETIC ACID SOLUTION
1750
CHLOROACETONE, STABILIZED
1695
CHLOROACETONITRILE
2668
CHLOROACETOPHENONE,
LIQUID
3416
CHLOROACETOPHENONE, SOLID
CHLOROACETYL CHLORIDE
CHLOROANILINES, LIQUID
2019
1018
AND CHLOROPENTAFLUOROETHANE MIXTURE, with fixed
boiling point, with approximately
49% chlorodifluoromethane
1973
3-Chloro-1,2-dihydroxypropane, see
2689
Chlorodimethyl ether, see
1239
LIQUID
1577
SOLID
3441
2-CHLOROETHANAL
2232
Chloroethane, see
1037
Chloroethane nitrile, see
2668
2-Chloroethanol, see
1135
1697
CHLOROFORM
1888
1752
CHLOROFORMATES, TOXIC
CORROSIVE, FLAMMABLE,
N.O.S.
2742
Book 1.indb 153
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
CORROSIVE, N.O.S.
3277
CHLOROPLATINIC ACID, SOLID
2507
CHLOROPRENE, STABILIZED
Chloromethane, see
1063
1991
1-CHLOROPROPANE
1-Chloro-3-methylbutane, see
1107
1278
2-Chloro-2-methylbutane, see
1107
2-CHLOROPROPANE
2356
CHLOROMETHYL
CHLOROFORMATE
2745
3-Chloro-propanediol-1,2 see
2689
3-CHLOROPROPANOL-1
2849
Chloromethyl cyanide, see
2668
2-CHLOROPROPENE
2456
CHLOROMETHYL ETHYL ETHER
2354
3-Chloropropene, see
1100
Chloromethyl methyl ether, see
1239
3-Chloroprop-1-ene, see
1100
3-CHLORO-4METHYLPHENYLISOCYANATE,
LIQUID
2236
2-CHLOROPROPIONIC ACID
2511
2-CHLOROPYRIDINE
2822
3-CHLORO-4METHYLPHENYLISOCYANATE,
SOLID
3428
N.O.S.
2987
2554
FLAMMABLE, N.O.S.
2986
3-Chloro-2-methylprop-1-ene, see
CHLORONITROANILINES
2237
CHLOROSILANES, FLAMMABLE,
CORROSIVE, N.O.S.
2985
CHLORONITROBENZENES,
LIQUID
3409
CHLORONITROBENZENES, SOLID
1578
CHLORONITROTOLUENES,
LIQUID
2433
CHLORONITROTOLUENES, SOLID
3457
1020
CHLOROPHENOLATES, LIQUID
2904
CHLOROPHENOLATES, SOLID
2905
CHLOROPHENOLS, LIQUID
2021
CHLOROPHENOLS, SOLID
2020
CORROSIVE, N.O.S.
3361
N.O.S.
3362
CHLOROSILANES,
CORROSIVE, N.O.S.
2988
CHLOROSULPHONIC ACID, (with

or without sulphur trioxide)
1754
1-CHLORO-1,2,2,2TETRAFLUORO-ETHANE
1021
CHLOROPHENYLTRICHLOROSILANE 1753
CHLOROTOLUENES
2238
CHLOROPICRIN
1580
1579

BROMIDE MIXTURE, with more
1581
HYDROCHLORIDE, SOLID
HYDROCHLORIDE SOLUTION
3410

CHLORIDE MIXTURE
1582
CHLOROTOLUIDINES, LIQUID
3429
CHLOROPICRIN MIXTURE, N.O.S.
CHLOROTOLUIDINES, SOLID
2239
1583
Book 1.indb 154
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
1-CHLORO-2,2,2,-TRIFLUOROETHANE
1983
Coal tar naphtha, see
1268
Chlorotrifluoroethylene, see
1082
Coal tar oil, see
1136
COATING SOLUTION
1022
1139
AND TRIFLUOROMETHANE
AZEOTROPIC MIXTURE,
chlorotrifluoromethane
2599
COBALT NAPHTHENATES,
POWDER
2001
COBALT RESINATE,
PRECIPITATED
1318
Cocculus, see
Chromic acid, solid, see
1463
3172
3462
CHROMIC ACID SOLUTION
1755
Collodion cottons, see
Chromic anhydride, solid, see
1463
CHROMIC FLUORIDE, SOLID
1756
2059
2555
2556
2557
CHROMIC FLUORIDE SOLUTION
1757
COMPRESSED GAS,
FLAMMABLE, N.O.S.
1954
Chromic nitrate, see
2720
COMPRESSED GAS, N.O.S.
1956
Chromium (VI) dichloride dioxide,

see
1758
COMPRESSED GAS, OXIDISING,

N.O.S.
3156
Chromium (III) fluoride, see
1756
2720

CORROSIVE, N.O.S.
3304
CHROMIUM NITRATE
CHROMIUM OXYCHLORIDE
1758
3305
CHROMIUM TRIOXIDE,
ANHYDROUS
1463

N.O.S.
2240

FLAMMABLE, N.O.S.
1953
CHROMOSULPHURIC ACID
Chrysotile, see
2590
2052

N.O.S.
1955
Cinene, see
Cinnamene, see
2055

3306
Cinnamol, see
2055
3291

OXIDISING, N.O.S.
3303

N.O.S. or MEDICAL WASTE,
WASTE, N.O.S.
COPPER ACETOARSENITE
1585
COPPER ARSENITE
1586

N.O.S. or MEDICAL WASTE,
WASTE, N.O.S., in refrigerated
liquid nitrogen
3291
Copper (II) arsenite, see
1586
COPPER BASED PESTICIDE,

2776
COAL GAS, COMPRESSED
1023

LIQUID, TOXIC
3010

FLAMMABLE
1136
Book 1.indb 155
04/04/2013 15:31
Substance
UN
No
Substance
UN
No

3009
CORROSIVE SOLID,
FLAMMABLE, N.O.S.
2921

SOLID, TOXIC
CORROSIVE SOLID, N.O.S.
1759
2775
3084
COPPER CHLORATE
2721
CORROSIVE SOLID, OXIDISING,

N.O.S.
2721
CORROSIVE SOLID,
SELF-HEATING, N.O.S.
3095
Copper (II) chlorate, see

COPPER CHLORIDE
2802
2923
COPPER CYANIDE
1587
CORROSIVE SOLID, TOXIC,

N.O.S.
Copper selenate, see
2630
CORROSIVE SOLID,
3096
Copper selenite, see
2630
COTTON WASTE, OILY
1364
COPRA
1363
COTTON, WET
1365

INORGANIC, N.O.S.
3264
3024

ORGANIC, N.O.S.
3265
COUMARIN DERIVATIVE
PESTICIDE, LIQUID,
less than 23C

INORGANIC, N.O.S.
3266
3025

ORGANIC, N.O.S.
3267
COUMARIN DERIVATIVE
FLAMMABLE, flash point 23C or
above
2920
COUMARIN DERIVATIVE
PESTICIDE, LIQUID, TOXIC
3026
CORROSIVE LIQUID,
FLAMMABLE, N.O.S.
1760
COUMARIN DERIVATIVE
3027
CORROSIVE LIQUID, N.O.S.

N.O.S.
3093
Creosote, see
2810
Creosote salts, see
1334
CORROSIVE LIQUID,
3301
CRESOLS, LIQUID
2076
CORROSIVE LIQUID, TOXIC,

N.O.S.
2922
CRESOLS, SOLID
3455
CRESYLIC ACID
2022
CORROSIVE LIQUID,
3094
Crocidolite, see
2212

INORGANIC, N.O.S.
3260
CROTONALDEHYDE or
CROTONALDEHYDE, STABILIZED
1143

ORGANIC, N.O.S.
3261
CROTONIC ACID, LIQUID
3472
CROTONIC ACID, SOLID
2823

INORGANIC, N.O.S.
3262
Crotonic aldehyde, stabilized, see
1143

ORGANIC, N.O.S.
3263
CROTONYLENE
1144
Crude naphtha, see
1268
Book 1.indb 156
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Cumene, see
1918
CYCLOHEXYLAMINE
2357
Cupric chlorate, see
2721
CYCLOHEXYL ISOCYANATE
2488
CUPRIETHYLENEDIAMINE
SOLUTION
1761
CYCLOHEXYL MERCAPTAN
3054
Cut backs, see
1999
3256
3257
CYCLOHEXYLTRICHLOROSILANE
1763
Cyclooctadiene phosphines, see
2940
CYCLOOCTADIENES
2520
CYANIDE SOLUTION, N.O.S.
1935
CYCLOOCTATETRAENE
2358
CYANIDES, INORGANIC, SOLID,

N.O.S.
1588
CYCLOPENTANE
1146
CYCLOPENTANOL
2244
CYCLOPENTANONE
2245
CYCLOPENTENE
2246
CYCLOPROPANE
1027
CYMENES
2046
2046
Cyanides, organic, flammable, toxic,

n.o.s., see
3273
Cyanides, organic, toxic, n.o.s., see
3276
3439
Cyanides, organic, toxic, flammable,

n.o.s., see
3275
Cyanoacetonitrile, see
2647
Cymol, see
CYANOGEN
1026
3363
CYANOGEN BROMIDE
1889
DANGEROUS GOODS IN
APPARATUS
CYANOGEN CHLORIDE,
STABILIZED
1589
DANGEROUS GOODS IN
MACHINERY
3363
CYANURIC CHLORIDE
2670
Deanol, see
2051
CYCLOBUTANE
2601
DECABORANE
1868
CYCLOBUTYL CHLOROFORMATE
2744
DECAHYDRONAPHTHALENE
1147
1,5,9-CYCLODODECATRIENE
2518
Decalin, see
1147
CYCLOHEPTANE
2241
n-DECANE
2247
CYCLOHEPTATRIENE
2603
DESENSITIZED EXPLOSIVE,
LIQUID, N.O.S.
3379
1,3,5-Cyloheptatriene, see
2603
2242
DESENSITIZED EXPLOSIVE,
SOLID, N.O.S.
3380
CYCLOHEPTENE
1,4-Cyclohexadienedione, see
2587
DEUTERIUM, COMPRESSED
1957
3150
CYCLOHEXANE
1145
Cyclohexanethiol, see
3054
DEVICES, SMALL,
HYDROCARBON GAS POWERED,
with release device
CYCLOHEXANONE
1915
DIACETONE ALCOHOL
1148
CYCLOHEXENE
2256
DIALLYLAMINE
2359
CYCLOHEXENYLTRICHLOROSILANE
1762
DIALLYL ETHER
2360
CYCLOHEXYL ACETATE
2243
4,4-DIAMINODIPHENYLMETHANE
2651
Book 1.indb 157
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
1,2-Diaminoethane, see
1604
1,2-DICHLOROETHYLENE
1150
Diaminopropylamine, see
2269
Di(2-chloroethyl) ether, see
1916
DI-n-AMYLAMINE
2841
DICHLOROFLUOROMETHANE
1029
Dibenzopyridine, see
2713
alpha-Dichlorohydrin, see
2750
DIBENZYLDICHLOROSILANE
2434
1911
DICHLOROISOCYANURIC ACID,
DRY or DICHLOROISOCYANURIC
ACID SALTS
2465
DIBORANE
1,2-DIBROMOBUTAN-3-ONE
2648
DICHLOROISOPROPYL ETHER
2490
DIBROMOCHLOROPROPANES
2872
DICHLOROMETHANE
1593
1,2-Dibromo-3-chloropropane, see
2872
1,1-DICHLORO-1-NITROETHANE
2650
DIBROMODIFLUOROMETHANE
1941
DICHLOROPENTANES
1152
DIBROMOMETHANE
2664
Dichlorophenols, see
DI-n-BUTYLAMINE
2248
2020
2021
DIBUTYLAMINOETHANOL
2873
DICHLOROPHENYL
ISOCYANATES
2250
2-Dibutylaminoethanol, see
2873
2873
DICHLOROPHENYLTRICHLOROSILANE
1766
N,N-Di-n-butylaminoethanol, see
DIBUTYL ETHERS
1149
1,2-DICHLOROPROPANE
1279
DICHLOROACETIC ACID
1764
1,3-Dichloro-2-propanone, see
2649
1,3-DICHLOROACETONE
2649
1,3-DICHLOROPROPANOL-2
2750
DICHLOROACETYL CHLORIDE
1765
DICHLOROPROPENES
2047
DICHLOROANILINES, LIQUID
1590
DICHLOROSILANE
2189
DICHLOROANILINES, SOLID
3442
1958
o-DICHLOROBENZENE
1591
1,2-DICHLORO-1,1,2,
2-TETRAFLUOROETHANE
2,2-DICHLORODIETHYL ETHER
1916
Dichloro-s-triazine-2,4,6-trione, see
2465
1028
1,4-Dicyanobutane, see
2205
AND DIFLUOROETHANE
AZEOTROPIC MIXTURE,
dichlorodifluoromethane
2602
Dicycloheptadiene, see
2251
DICYCLOHEXYLAMINE
2565
Dicyclohexylamine nitrite, see
2687
3070
DICYCLOHEXYLAMMONIUM
NITRITE
2687
Dichlorodifluoromethane and
ethylene oxide mixture, see
DICYCLOPENTADIENE
2048
DICHLORODIMETHYL ETHER,
SYMMETRICAL
2249
1,2-DI-(DIMETHYLAMINO)
ETHANE
2372
1,1-DICHLOROETHANE
2362
DIDYMIUM NITRATE
1465
1,2-Dichloroethane, see
1184
DIESEL FUEL
1202
Book 1.indb 158
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
1,1-Diethoxyethane, see
1088
3338
1,2-Diethoxyethane, see
1153
DIETHOXYMETHANE
2373
3,3-DIETHOXYPROPENE
2374
Difluoromethane,
pentafluoroethane, and 1,1,1,2tetrafluoroethane azeotropic
mixture, with approximately
20% difluoromethane and 40%
pentafluoroethane, see
DIETHYLAMINE
1154
2686
3-DIETHYLAMINOPROPYLAMINE
2684
N,N-DIETHYLANILINE
2432
Difluoromethane,
pentafluoroethane, and
1,1,1,2-tetrafluoroethane azeotropic
3339
2-DIETHYLAMINOETHANOL
DIETHYLBENZENE
2049
1768
Diethylcarbinol, see
1105
DIFLUOROPHOSPHORIC ACID,
ANHYDROUS
DIETHYL CARBONATE
2366
2,3-DIHYDROPYRAN
2376
DIETHYLDICHLOROSILANE
1767
DIISOBUTYLAMINE
2361
Diethylenediamine, see
2579
DIISOBUTYLENE, ISOMERIC
COMPOUNDS
2050
DIETHYLENETRIAMINE
2079
alpha-Diisobutylene, see
2050
N,N-Diethylethanolamine, see
2686
beta-Diisobutylene, see
2050
DIETHYL ETHER
1155
DIISOBUTYL KETONE
1157
N,N-DIETHYLETHYLENEDIAMINE
2685
DIISOOCTYL ACID PHOSPHATE
1902
Di-(2-ethylhexyl) phosphoric acid,

see
1902
DIISOPROPYLAMINE
1158
DIETHYL KETONE
1156
DIISOPROPYL ETHER
1159
DIETHYL SULPHATE
1594
DIKETENE, STABILIZED
2521
DIETHYL SULPHIDE
2375
1,1-DIMETHOXYETHANE
2377
DIETHYLTHIOPHOSPHORYL
CHLORIDE
2751
1,2-DIMETHOXYETHANE
2252
Dimethoxystrychnine, see
1570
1032
Diethyl zinc, see
3394
DIMETHYLAMINE ANHYDROUS
2-4-Difluoroaniline, see
2941
1160
Difluorochloroethane, see
2517
DIMETHYLAMINE AQUEOUS
SOLUTION
1,1-DIFLUOROETHANE
1030
2-DIMETHYLAMINOACETONITRILE
2378
1,1-DIFLUOROETHYLENE
1959
2-DIMETHYLAMINOETHANOL
2051
DIFLUOROMETHANE
3252
3340
ACRYLATE
3302
Difluoromethane,
pentafluoroethane and
1,1,1,2-tetrafluoroethane azeotropic
METHACRYLATE
2522
N,N-DIMETHYLANILINE
2253
Book 1.indb 159
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Dimethylarsenic acid, see
1572
DINITRO-o-CRESOL
1598
N,N-Dimethylbenzylamine, see
2619
DINITROPHENOL SOLUTION
1599
2,3-DIMETHYLBUTANE
2457
2379
DINITROPHENOL, WETTED, with

1320
1,3-DIMETHYLBUTYLAMINE
DIMETHYLCARBAMOYL
CHLORIDE
2262
DINITROPHENOLATES, WETTED,
by mass
1321
DIMETHYL CARBONATE
1161
2263
DINITRORESORCINOL, WETTED,
by mass
1322
DIMETHYLCYCLOHEXANES
DINITROTOLUENES, LIQUID
2038
DINITROTOLUENES, MOLTEN
1600
DINITROTOLUENES, SOLID
3454
DIOXANE
1165
DIOXOLANE
1166
DIPENTENE
2052
N,N-DIMETHYLCYCLOHEXYLAMINE 2264
DIMETHYLDICHLOROSILANE
1162
DIMETHYLDIETHOXYSILANE
2380
DIMETHYLDIOXANES
2707
DIMETHYL DISULPHIDE
2381
Dimethylethanolamine, see
2051
DIMETHYL ETHER
1033
N,N-DIMETHYLFORMAMIDE
2265
DIMETHYLHYDRAZINE,
SYMMETRICAL
2382
DIMETHYLHYDRAZINE,
UNSYMMETRICAL
1163
1,1-Dimethylhydrazine, see
1163
N,N-Dimethyl-4-nitrosoaniline, see
1369
2,2-DIMETHYLPROPANE
2044
DIMETHYL-N-PROPYLAMINE
2266
DIMETHYL SULPHATE
1595
DIMETHYL SULPHIDE
1164
DIMETHYL THIOPHOSPHORYL
CHLORIDE
2267
Dimethyl zinc, see
3394
DINITROANILINES
1596
DINITROBENZENES, LIQUID
1597
DINITROBENZENES, SOLID
3443
Dinitrochlorobenzene, see
1577
DINITROGEN TETROXIDE
1067
DIPHENYLAMINE CHLORO-ARSINE 1698

DIPHENYLCHLOROARSINE, LIQUID
1699
DIPHENYLCHLOROARSINE, SOLID 3450

DIPHENYLDICHLOROSILANE
1769
DIPHENYLMETHYL BROMIDE
1770
DIPICRYL SULPHIDE, WETTED,

with not less than 10% water by
mass
2852
DIPROPYLAMINE
2383
Dipropylene triamine, see
2269
DI-n-PROPYL ETHER
2384
DIPROPYL KETONE
2710
CORROSIVE, N.O.S.
1903

N.O.S.
3142
DISINFECTANT, SOLID, TOXIC,

N.O.S.
1601
DISODIUM TRIOXOSILICATE
3253
DIVINYL ETHER, STABILIZED
1167
DODECYLTRICHLOROSILANE
1771
Book 1.indb 160
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Dry ice, see
1845
3077
DYE or DYE INTERMEDIATE,

LIQUID, CORROSIVE, N.O.S.
2801
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
SOLID, N.O.S.

LIQUID, TOXIC, N.O.S.
1602
EPIBROMOHYDRIN
2558
EPICHLOROHYDRIN
2023

SOLID, CORROSIVE, N.O.S.
3147
1,2-Epoxybutane, stabilized, see
3022

Epoxyethane, see
1040
3143
1,2-EPOXY-3-ETHOXYPROPANE
2752
2794
2795
2800
3028
2,3-Epoxy-1-propanal, see
2622
2,3-Epoxypropyl ethyl ether, see
2752
ESTERS, N.O.S.
3272
Electrolyte (acid or alkaline) for

batteries, see
2796
2797
ETHANE
1035
ELEVATED TEMPERATURE
LIQUID, FLAMMABLE, N.O.S.,
with flash point above 60C, at or
above its flash point
3256
ETHANE, REFRIGERATED LIQUID
1961
Ethanethiol, see
2363
ETHANOL or ETHANOL
SOLUTION
1170
LIQUID, N.O.S., at or above 100C
and below its flash point (including
molten metals, molten salts etc),
filled at a temperature higher than
190C
3257
ETHANOL AND GASOLINE

MIXTURE or ETHANOL AND
MOTOR SPIRIT or ETHANOL AND
PETROL MIXTURE with more than
10% ethanol
3475
LIQUID, N.O.S., at or above 100C
and below its flash point (including
molten metals, molten salts etc),
filled at or below 190C
3257
ETHANOLAMINE or
ETHANOLAMINE SOLUTION
2491
Ether, see
1155
ETHERS, N.O.S.
3271
2-Ethoxyethanol, see
1171
2-Ethoxyethyl acetate, see
1172
Ethoxy propane-1, see
2615
ETHYL ACETATE
1173
ETHYLACETYLENE, STABILIZED
2452
ETHYL ACRYLATE, STABILIZED
1917
Electric storage, batteries, see
ELEVATED TEMPERATURE SOLID,

N.O.S., at or above 240C
3258
Enamels, see
1263
3066
3469
3470
ENGINE, FUEL CELL,

FLAMMABLE GAS POWERED
3166
ENGINE, FUEL CELL,

FLAMMABLE LIQUID POWERED
3166
ETHYL ALCOHOL or ETHYL

ALCOHOL SOLUTION, see
1170
ENGINE, INTERNAL
COMBUSTION
3166
ETHYLAMINE
1036
2270
ENVIRONMENTALLY
HAZARDOUS SUBSTANCE,
LIQUID, N.O.S.
3082
ETHYLAMINE, AQUEOUS
SOLUTION, with not less than 50%
but not more than 70% ethylamine
Book 1.indb 161
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
ETHYL AMYL KETONE
2271
ETHYLENEDIAMINE
1604
N-ETHYLANILINE
2272
ETHYLENE DIBROMIDE
1605
2-ETHYLANILINE
2273
1175
Ethylene dibromide and methyl

bromide, liquid mixture, see
1647
ETHYLBENZENE
N-ETHYL-N-BENZYLANILINE
2274
ETHYLENE DICHLORIDE
1184
LIQUID
2753
ETHYLENE GLYCOL DIETHYL

ETHER
1153
SOLID
3460

ETHER
1171
ETHYL BORATE
1176

ETHER ACETATE
1172
ETHYL BROMIDE
1891
1603
ETHYLENE GLYCOL
MONOMETHYL ETHER
1188
ETHYL BROMOACETATE
2-ETHYLBUTANOL
2275
2-ETHYLBUTYL ACETATE
1177
ETHYL BUTYL ETHER
1179
2-ETHYLBUTYRALDEHYDE
1178
ETHYL BUTYRATE
1180
ETHYL CHLORIDE
1037
ETHYL CHLOROACETATE
1181
Ethyl chlorocarbonate, see
1182
ETHYL CHLOROFORMATE
1182
ETHYL-2-CHLOROPROPIONATE
2935
Ethyl-alpha-chloropropionate, see
2935
ETHYL CHLOROTHIOFORMATE
2826
ETHYL CROTONATE
1862
ETHYLDICHLOROARSINE
1892
ETHYLDICHLOROSILANE
1183
ETHYLENE, ACETYLENE
AND PROPYLENE MIXTURE,
REFRIGERATED LIQUID,
containing at least 71.5% ethylene,
with not more than 22.5%
acetylene and not more than 6%
propylene
3138
ETHYLENE CHLOROHYDRIN
1135
ETHYLENE
1962
ETHYLENE GLYCOL MONOMETHYL 1189

ETHER ACETATE
ETHYLENEIMINE, STABILIZED
1185
ETHYLENE OXIDE
1040

DIOXIDE MIXTURE, with more
3300

DIOXIDE MIXTURE, with more
ethylene oxide
1041

DIOXIDE MIXTURE, with not more
1952
ETHYLENE OXIDE AND

CHLOROTETRAFLUOROETHANE
MIXTURE, with not more than
8.8% ethylene oxide
3297
ETHYLENE OXIDE AND

12.5% ethylene oxide
3070
ETHYLENE OXIDE AND

PENTAFLUOROETHANE
7.9% ethylene oxide
3298
ETHYLENE OXIDE AND

PROPYLENE OXIDE MIXTURE,
with not more than 30% ethylene
oxide
2983
Book 1.indb 162
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
ETHYLENE OXIDE AND

TETRAFLUOROETHANE
5.6% ethylene oxide
3299
EXTRACTS, FLAVOURING,
LIQUID
1197
1373
ETHYLENE OXIDE WITH

NITROGEN, up to a total pressure
of 1MPa (10bar) at 50C
1040
FABRICS, ANIMAL, VEGETABLE

or SYNTHETIC, N.O.S., with oil
1353
ETHYLENE, REFRIGERATED
LIQUID
1038
FABRICS IMPREGNATED
FERRIC ARSENATE
1606
1607
Ethyl ether, see
1155
FERRIC ARSENITE
ETHYL FLUORIDE
2453
FERRIC CHLORIDE, ANHYDROUS
1773
ETHYL FORMATE
1190
FERRIC CHLORIDE SOLUTION
2582
2-ETHYLHEXYLAMINE
2276
FERRIC NITRATE
1466
2-ETHYLHEXYL
CHLOROFORMATE
2748
FERROCERIUM
1323
1408
Ethylidene chloride, see
2362
FERROSILICON, with 30% or more

but less than 90% silicon
ETHYL ISOBUTYRATE
2385
FERROUS ARSENATE
1608
ETHYL ISOCYANATE
2481
2793
ETHYL LACTATE
1192
ETHYL MERCAPTAN
2363
FERROUS METAL BORINGS,

SHAVINGS, TURNINGS, or
CUTTINGS, in a form liable to
self-heating
ETHYL METHACRYLATE,
STABILIZED
2277
FERTILIZER AMMONIATING
SOLUTION, with free ammonia
1043
ETHYL METHYL ETHER
1039
Fertilizers with ammonium nitrate,

n.o.s., see
2067
ETHYL METHYL KETONE
1193
1194
FIBRES, ANIMAL or VEGETABLE,

burnt, wet or damp
1372
ETHYL NITRITE SOLUTION

ETHYL ORTHOFORMATE
2524
FIBRES, ANIMAL, VEGETABLE or

SYNTHETIC, N.O.S. with oil
1373
ETHYL OXALATE
2525
2435
1-ETHYLPIPERIDINE
2386
FIBRES, IMPREGNATED
1353
ETHYLPHENYLDICHLOROSILANE
ETHYL PROPIONATE
1195
FIBRES, VEGETABLE, DRY
3360
ETHYL PROPYL ETHER
2615
Fillers, liquid, see
Ethyl silicate, see
1292
1263
3066
3469
3470
Ethyl sulphate, see
1594
2754
ETHYLTRICHLOROSILANE
1196
Films, nitrocellulose base, from

which gelatine has been removed,
film scrap, see
2002
N-ETHYLTOLUIDINES
EXTRACTS, AROMATIC, LIQUID
1169
FILMS, NITROCELLULOSE BASE,

gelatin coated, except scrap
1324
Book 1.indb 163
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
FIRE EXTINGUISHER CHARGES,

corrosive liquid
1774
FLUOROACETIC ACID
2642
FIRE EXTINGUISHERS, with

compressed or liquefied gas
FLUOROANILINES
1044
2941
2-Fluoroaniline, see
2941
4-Fluoroaniline, see
2941
FIRELIGHTERS, SOLID, with

flammable liquid
2623
o-Fluoroaniline, see
2941
FIRST AID KIT
3316
p-Fluoroaniline, see
2941
Fischer Tropsch gas, see
2600
FLUOROBENZENE
2387
FISH MEAL or FISH SCRAP,

STABILIZED
2216
FLUOROBORIC ACID
1775
Fluoroethane, see
2453
FISH MEAL or FISH SCRAP,

UNSTABILIZED
1374
Fluoroform, see
1984
Flammable gas in lighters, see
1057
Fluoromethane, see
2454
FLAMMABLE LIQUID,
CORROSIVE, N.O.S.
2924
FLUOROPHOSPHORIC ACID,
ANHYDROUS
1776
FLAMMABLE LIQUID, N.O.S.
1993
FLUOROSILICATES, N.O.S.
2856
FLUOROSILICIC ACID
1778

CORROSIVE, N.O.S.
3286
FLUOROSULPHONIC ACID
1777

N.O.S.
1992
FLUOROTOLUENES
2388
FLAMMABLE SOLID,
INORGANIC, N.O.S.
3178
FORMALDEHYDE SOLUTION, with

not less than 25% formaldehyde
2209
FLAMMABLE SOLID,
CORROSIVE, INORGANIC, N.O.S.
3180
FORMALDEHYDE SOLUTION,
FLAMMABLE
1198

INORGANIC, N.O.S.
3179
Formalin, see
1198
2209

N.O.S.
1325
Formamidine sulphinic acid, see
3341
1779
FLAMMABLE SOLID,
CORROSIVE, ORGANIC, N.O.S.
2925
FORMIC ACID, with more than

85% acid by mass
3412

MOLTEN, N.O.S.
3176
FORMIC ACID, with more than 5%

acid but not more than 85% acid
Formic aldehyde, see
FLAMMABLE SOLID, OXIDISING,

N.O.S.
3097
1198
2209
2-Formyl-3,4-dihydro-2H-pyran, see
2607

ORGANIC, N.O.S.
2926
FUEL, AVIATION, TURBINE

ENGINE
1863
Flue dusts, toxic, see
1562
Fluoric acid, see
1790
FLUORINE, COMPRESSED
1045
Book 1.indb 164
04/04/2013 15:31
Substance
UN
No
Substance
UN
No

EQUIPMENT, containing flammable
liquids
3473
GAS OIL
1202
GASOLINE
1203
Gasoline, casinghead, see
1203
3312

EQUIPMENT, containing
water-reactive substances
3476

FLAMMABLE, N.O.S.
N.O.S.
3158

OXIDISING, N.O.S.
3311

EQUIPMENT, containing corrosive
substance
3477

FLAMMABLE, N.O.S., not
refrigerated liquid
3167

TOXIC, N.O.S., not refrigerated
liquid
3169

EQUIPMENT, containing liquefied
flammable gas
3478

TOXIC, FLAMMABLE, N.O.S., not
refrigerated liquid
3168
3245

EQUIPMENT, containing hydrogen
in metal hydride
3479
GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY

MODIFIED ORGANISMS
GENETICALLY MODIFIED MICROORGANISMS or GENETICALLY
MODIFIED ORGANISMS, in
3245
Fumaroyl dichloride, see
1780
GERMANE
2192
FUMARYL CHLORIDE
1780
Germanium hydride, see
2192
FUMIGATED CARGO
TRANSPORT UNIT
3359
Glycerol-1, 3-dichlorohydrin, see
2750
2689
FURALDEHYDES
1199
GYLCEROL alpha-MONOCHLOROHYDRIN
FURAN
2389
Glyceryl trinitrate, see
1204
FURFURYL ALCOHOL
2874
GLYCIDALDEHYDE
2622
FURFURYLAMINE
2526
GUANIDINE NITRATE
1467
Furyl carbinol, see
2874
Gutta percha solution, see
1287
FUSEL OIL
1201
HAFNIUM POWDER, DRY
2545
GALLIUM
2803
HAFNIUM POWDER, WETTED,

1326
GAS CARTRIDGES, without a

release device, non-refillable, see
2037
HAY
1327
Gas drips, hydrocarbon, see
3295
HEATING OIL, LIGHT
1202
Book 1.indb 165
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Heavy Hydrogen, see
1957
2280
HELIUM, COMPRESSED
1046
HEXAMETHYLENEDIAMINE,
SOLID
HELIUM, REFRIGERATED LIQUID
1963
HEXAMETHYLENEDIAMINE
SOLUTION
1783
HEPTAFLUOROPROPANE
3296
3056
HEXAMETHYLENE
DIISOCYANATE
2281
n-HEPTALDEHYDE
n-Heptanal, see
3056
HEXAMETHYLENEIMINE
2493
HEPTANES
1206
HEXAMETHYLENETETRAMINE
1328
4-Heptanone, see
2710
Hexamine, see
1328
n-HEPTENE
2278
HEXANES
1208
HEXACHLOROACETONE
2661
Hexanoic acid, see
2829
HEXACHLOROBENZENE
2729
HEXANOLS
2282
HEXACHLOROBUTADIENE
2279
1-HEXENE
2370
Hexachloro-1,3-butadiene, see
2279
HEXYLTRICHLOROSILANE
1784
HEXACHLOROCYCLOPENTADIENE
2646
HYDRAZINE, ANHYDROUS
2029
2875
HYDRAZINE, AQUEOUS
SOLUTION, with not less than 37%
hydrazine by mass
2030
HEXACHLOROPHENE
Hexachloro-2-propanone, see
2661
1781
HEXADIENES
2458
HYDRAZINE, AQUEOUS
37% hydrazine by mass
3293
HEXADECYLTRICHLOROSILANE
1611
3484
AND COMPRESSED GAS
MIXTURE
1612
HYDRAZINE AQUEOUS
SOLUTION, FLAMMABLE with
more than 37% hydrazine, by mass
Hydrides, metal, water-reactive,
n.o.s., see
1409
HEXAFLUOROACETONE
2420
HYDRIODIC ACID
1787
HEXAFLUOROACETONE
HYDRATE, LIQUID
2552
Hydriodic acid, anhydrous, see
2197
HEXAFLUOROACETONE
HYDRATE, SOLID
3436
HYDROBROMIC ACID
1788
1964
HEXAFLUOROETHANE
2193

COMPRESSED, N.O.S.
1782

LIQUEFIED, N.O.S.
1965
HEXAFLUOROPHOSPHORIC ACID
HEXAFLUOROPROPYLENE
1858
3150
Hexahydrocresol, see
2617
HYDROCARBON GAS REFILLS

FOR SMALL DEVICES, with release
device
Hexahydromethyl phenol, see
2617
HYDROCARBONS, LIQUID N.O.S.
3295
HEXALDEHYDE
1207
HYDROCHLORIC ACID
1789
Book 1.indb 166
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
HYDROCYANIC ACID, AQUEOUS

SOLUTIONS, with not more than
20% hydrogen cyanide
1613
3468
Hydrofluoboric acid, see
1775
HYDROFLUORIC ACID
1790
HYDROFLUORIC ACID AND

SULPHURIC ACID MIXTURE
1786
HYDROGEN IN METAL
HYDRIDE STORAGE SYSTEM
or HYDROGEN IN A METAL
or HYDROGEN IN A METAL
1778
HYDROGEN IODIDE,
ANHYDROUS
2197
Hydrofluosilicic acid, see

Hydrogen arsenide, see
2188
Hydrogen iodide solution, see
1787
HYDROGEN BROMIDE,
ANHYDROUS
1048
HYDROGEN AND METHANE

MIXTURE, COMPRESSED
2034
Hydrogen bromide solution, see
1788
HYDROGEN CHLORIDE,
ANHYDROUS
1050
HYDROGEN PEROXIDE AND

3149
PEROXYACETIC ACID MIXTURE,
STABILIZED, with acid(s), water and
not more than 5% peroxyacetic acid
HYDROGEN CHLORIDE,
REFRIGERATED LIQUID
2186
HYDROGEN, COMPRESSED
1049
HYDROGEN CYANIDE, AQUEOUS

20% hyrdrogen cyanide
1613
HYDROGEN CYANIDE,
SOLUTION IN ALCOHOL, with not
more than 45% hydrogen cyanide
3294
HYDROGEN CYANIDE,
STABILIZED, containing less than
3% water and absorbed in a porous
inert material
1614
HYDROGEN CYANIDE,
STABILIZED, containing less than
3% material
1051
HYDROGENDIFLUORIDES,
SOLID, N.O.S.
HYDROGEN PEROXIDE,
AQUEOUS SOLUTION, with not
less than 8% but less than 20%
hydrogen peroxide (stabilized as
necessary)
2984
HYDROGEN PEROXIDE,
AQUEOUS SOLUTION, with not
less than 20% but not more than
60% hydrogen peroxide (stabilized
as necessary)
2014
HYDROGEN PEROXIDE,
STABILIZED or HYDROGEN
PEROXIDE AQUEOUS SOLUTION,
STABILIZED, with more than 60%
hydrogen peroxide
2015
HYDROGEN, REFRIGERATED
LIQUID
1966
1740
HYDROGEN SELENIDE,
ANHYDROUS
2202
HYDROGENDIFLUORIDES,
SOLUTION, N.O.S.
3471
Hydrogen silicide, see
2203
HYDROGEN SULPHIDE
1053
HYDROGEN FLUORIDE,
ANHYDROUS
1052
Hydroselenic acid, see
2202
Hydrosilicofluoric acid, see
1778
1-HYDROXYBENZOTRIAZOLE
MONOHYDRATE
3474
3-Hydroxybutan-2-one, see
2621
HYDROXYLAMINE SULPHATE
2865
Hydrogen fluoride solution, see
1790
Book 1.indb 167
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
1-Hydroxy-3-methyl-2-penten-4yne, see
2705
IODOPROPANES
2392
alpha-Iodotoluene, see
2653
3-Hydroxyphenol, see
2876
HYPOCHLORITE SOLUTION
I.p.d.i, see
2290
1791
HYPOCHLORITES, INORGANIC,
N.O.S.
Iron chloride anhydrous, see
1773
3212
Iron chloride solution, see
2582
1376
3,3-IMINODIPROPYLAMINE
2269
IRON OXIDE, SPENT
India rubber, see
1287
IRON PENTACARBONYL
1994
AFFECTING HUMANS
2814
Iron perchloride anhydrous, see
1773
Iron powder, pyrophoric, see
1383
AFFECTING HUMANS, in
2814
Iron sesquichloride anhydrous, see
1773
1376
AFFECTING HUMANS (animal
material only)
2814
IRON SPONGE, SPENT, obtained

from coal gas purification
Iron swarf, see
2793
AFFECTING ANIMALS only
2990
ISOBUTANE
1969
ISOBUTANOL
1212
AFFECTING ANIMALS only (animal
material only)
2990
Isobutene, see
1055
ISOBUTYL ACETATE
1213
AFFECTING ANIMALS only, in
liquid nitrogen
2990
ISOBUTYL ACRYLATE,
STABILIZED
2527
ISOBUTYL ALCOHOL
1212
Ink, printers, flammable, see
1210
ISOBUTYL ALDEHYDE
2045
INSECTICIDE GAS, N.O.S.
1968
ISOBUTYLAMINE
1214
INSECTICIDE GAS, FLAMMABLE,

N.O.S.
3354
ISOBUTYLENE
1055
INSECTICIDE GAS, TOXIC, N.O.S.
1967
ISOBUTYL FORMATE
2393
INSECTICIDE GAS, TOXIC,

FLAMMABLE, N.O.S.
3355
ISOBUTYL ISOBUTYRATE
2528
ISOBUTYL ISOCYANATE
2486
IODINE
3495
2283
IODINE MONOCHLORIDE,
LIQUID
3498
ISOBUTYL METHACRYLATE,
STABILIZED
ISOBUTYL PROPIONATE
2394
IODINE MONOCHLORIDE, SOLID
1792
ISOBUTYRALDEHYDE
2045
IODINE PENTAFLUORIDE
2495
ISOBUTYRIC ACID
2529
2-IODOBUTANE
2390
ISOBUTYRONITRILE
2284
Iodomethane, see
2644
ISOBUTYRYL CHLORIDE
2395
IODOMETHYLPROPANES
2391
Book 1.indb 168
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
TOXIC, N.O.S., or ISOCYANATE
SOLUTION, FLAMMABLE,
TOXIC, N.O.S.
2478
ISOPROPYL CHLOROACETATE
2947
ISOPROPYL CHLOROFORMATE
2407
2206
ISOPROPYL
2-CHLOROPROPIONATE
2934
ISOCYANATES, TOXIC, N.O.S., or

N.O.S.
Isopropyl-alpha-chloropropionate,
see
2934
ISOCYANATES, TOXIC,
FLAMMABLE, N.O.S., or
FLAMMABLE, N.O.S.
3080
Isopropyl ether, see
1159
Isopropylethylene, see
2561
ISOCYANATOBENZOTRIFLUORIDES
2285
Isopropyl formate, see
1281
3-Isocyanatomethyl-3,5,5trimethylcyclohexyl isocyanate, see
2290
ISOPROPYL ISOBUTYRATE
2406
ISOPROPYL ISOCYANATE
2483
Isododecane, see
2286
Isopropyl mercaptan, see
2402
ISOHEPTENE
2287
ISOPROPYL NITRATE
1222
ISOHEXENE
2288
ISOPROPYL PROPIONATE
2409
Isooctane, see
1262
Isopropyltoluene, see
2046
ISOOCTENE
1216
Isopropyltoluol, see
2046
Isopentane, see
1265
ISOSORBIDE-5-MONONITRATE
3251
ISOPENTENES
2371
2907
Isopentylamine, see
1106
Isopentyl nitrite, see
1113
ISOSORBIDE DINITRATE
MIXTURE, with not less than 60%
lactose, mannose, starch, or calcium
hydrogen phosphate
ISOPHORONEDIAMINE
2289
Isovaleraldehyde, see
2058
KEROSENE
1223
ISOPHORONE DIISOCYANATE
2290
ISOPRENE, STABILIZED
1218
ISOPROPANOL
1219
ISOPROPENYL ACETATE
2403
ISOPROPENYLBENZENE
2303
ISOPROPYL ACETATE
1220
ISOPROPYL ACID PHOSPHATE
1793
ISOPROPYL ALCOHOL
1219
ISOPROPYLAMINE
1221
ISOPROPYLBENZENE
1918
ISOPROPYL BUTYRATE
2405
Isopropyl chloride, see
2356
KETONES, LIQUID, N.O.S.
1224
Krill Meal
3497
KRYPTON, COMPRESSED
1056
KRYPTON, REFRIGERATED
LIQUID
1970
Lacquer base or lacquer chips,

nitrocellulose, dry, see
2557
Lacquer base or lacquer chips, plastic,

wet, with alcohol or solvent, see
1263
3066
3469
3470
LEAD ACETATE
1616
Lead (II) acetate, see
1616
LEAD ARSENATES
1617
Book 1.indb 169
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
LEAD ARSENITES
1618
3310
Lead chloride, solid, see
2291

LEAD COMPOUND, SOLUBLE,

N.O.S.
2291

OXIDISING, N.O.S.
3307
LEAD CYANIDE
1620

FLAMMABLE, N.O.S.
3160
Lead (II) cyanide, see
1620
LEAD DIOXIDE
1872
LEAD NITRATE
1469
Lead (II) Nitrate, see
1469
LEAD PERCHLORATE, SOLID
1470
LEAD PERCHLORATE SOLUTION
3408
Lead (II) perchlorate
LIQUEFIED GASES, non-flammable, 1058

charged with nitrogen, carbon
dioxide or air
Liquefied petroleum gas, see
1075
LITHIUM
1415
Lithium alkyls, liquid, see
3394
Lithium alkyls, solid, see
3393
1470
3408
LITHIUM ALUMINIUM HYDRIDE
1410
Lead peroxide, see
1872
LITHIUM ALUMINIUM HYDRIDE,
1411
LEAD PHOSPHITE, DIBASIC
2989
LITHIUM BOROHYDRIDE
1413
LEAD SULPHATE, with more than

3% free acid
1794
LITHIUM FERROSILICON
2830
LITHIUM HYDRIDE
1414
Lead tetraethyl, see
1649
LITHIUM HYDRIDE, FUSED SOLID
2805
Lead tetramethyl, see
1649
LITHIUM HYDROXIDE
2680
LIFE-SAVING APPLIANCES, NOT

SELF-INFLATING, containing
dangerous goods as equipment
3072
LITHIUM HYDROXIDE SOLUTION
2679
1471
LIFE-SAVING APPLIANCES,
SELF-INFLATING
2990
LITHIUM HYPOCHLORITE, DRY

or LITHIUM HYPOCHLORITE
MIXTURE
LIGHTERS or LIGHTER REFILLS,

containing flammable gas
1057
Lithium in cartouches, see
1415
3480
Limonene, inactive, see
2052

(including lithium ion polymer
batteries)
LIQUEFIED GAS, N.O.S.
3163
3161

CONTAINED IN EQUIPMENT or
LITHIUM ION BATTERIS PACKED
WITH EQUIPMENT
3481
LIQUEFIED GAS, FLAMMABLE,

N.O.S.
LIQUEFIED GAS, OXIDISING,
N.O.S.
3157

(including lithium alloy batteries)
3090
LIQUEFIED GAS, TOXIC, N.O.S.
3162
3308

N.O.S.
3309

or LITHIUM METAL BATTERIES
3091

CORROSIVE, N.O.S.
LITHIUM NITRATE
2722
Book 1.indb 170
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
LITHIUM NITRIDE
2806
MAGNESIUM SILICIDE
2624
LITHIUM PEROXIDE
1472
Magnesium silicofluoride, see
2853
Lithium silicide, see
1417
MAGNETIZED MATERIAL
2807
LITHIUM SILICON
1417
2215
L.n.g., see
1972
MALEIC ANHYDRIDE or MALEIC

ANHYDRIDE, MOLTEN
LONDON PURPLE
1621
Malonic dinitrile, see
2647
Malonodinitrile, see
2647
MALONONITRILE
2647
MANEB, STABILISED or MANEB

PREPARATIONS, STABILIZED
against self-heating
2968
MANEB or MANEB PREPARATION

with not less than 60% maneb
2210
Manganese ethylene-didithiocarbamate, see
2210
Manganese ethylene-1,2-didithiocarbamate, see
2210
L.p.g., see
1075
Lye, see
1823
Lythene, see
1268
MAGNESIUM or MAGNESIUM
ALLOYS, with more than 50%
magnesium in pellets, turnings
or ribbons
1869
Magnesium alkyls, see
3394
MAGNESIUM ALLOYS, POWDER
1418
MAGNESIUM ALUMINIUM
PHOSPHIDE
1419
MANGANESE NITRATE
2724
MAGNESIUM ARSENATE
1622
Manganese (II) nitrate, see
2724
Magnesium bisulphite solution, see
2693
MANGANESE RESINATE
1330
MAGNESIUM BROMATE
1473
Manganous nitrate, see
2724
MAGNESIUM CHLORATE
2723
MATCHES, FUSEE
2254
Magnesium chloride and chlorate

mixtures, see
1459
MATCHES, SAFETY, (book, card or

strike on box
1944
MAGNESIUM DIAMIDE
2004
MATCHES, STRIKE ANYWHERE
1331
Magnesium diphenyl, see
3393
MATCHES, WAX VESTA
1945
MAGNESIUM FLUOROSILICATE
2853
MEDICAL WASTE, N.O.S.
3291
MAGNESIUM GRANULES,
COATED, microns
2950
MEDICINE, LIQUID,
3248
MAGNESIUM HYDRIDE
2010
1474
MEDICINE, LIQUID, TOXIC,

N.O.S.
1851
MAGNESIUM NITRATE
MAGNESIUM PERCHLORATE
1475
MEDICINE, SOLID, TOXIC, N.O.S.
3249
MAGNESIUM PEROXIDE
1476
p-Mentha-1,8-diene, see
2052
MAGNESIUM PHOSPHIDE
2011
1228
MAGNESIUM POWDER
1418
Magnesium scrap, see
1869
MERCAPTANS, LIQUID,
FLAMMABLE, TOXIC, N.O.S., or
Book 1.indb 171
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
MERCAPTANS, LIQUID,
FLAMMABLE, N.O.S.
3336
MERCURY COMPOUND, SOLID,

N.O.S.
2025
3506
MERCAPTANS, LIQUID,
TOXIC, FLAMMABLE, N.O.S. or
TOXIC, FLAMMABLE, N.O.S.
MERCURY CONTAINED IN
MANUFACTURED ARTICLES
3071
MERCURY CYANIDE
1636
MERCURY GLUCONATE
1637
2-Mercaptoethanol, see
2966
MERCURY IODIDE
1638
2-Mercaptopropionic acid, see
2936
MERCURY NUCLEATE
1639
MERCURY OLEATE
1640
MERCURY OXIDE
1641
1642
MERCURIC ARSENATE
1623
MERCURIC CHLORIDE
1624
MERCURIC NITRATE
1625
MERCURY OXYCYANIDE,
DESENSITIZED
MERCURIC POTASSIUM CYANIDE
1626
MERCURY POTASSIUM IODIDE
1643
Mercuric sulphate, see
1645
MERCURY SALICYLATE
1644
Mercurol, see
1639
MERCURY SULPHATE
1645
Mercurous bisulphate, see
1645
MERCURY THIOCYANATE
1646
MERCUROUS NITRATE
1627
Mesitylene, see
2325
Mercurous sulphate, see
1645
MESITYL OXIDE
1229
MERCURY
2809
1629
MERCURY AMMONIUM
CHLORIDE
Metal alkyl halides, water-reactive,

n.o.s or metal aryl halides,
water-reactive, n.o.s., see
3394
MERCURY ACETATE
1630
3394

2778
Metal alkyl hydrides, water-reactive,

n.o.s or metal aryl hydrides,
water-reactive, n.o.s., see
3393

3011
Metal alkyls, water-reactive, n.o.s

or metal aryls, water-reactive,
n.o.s., see
3281

LIQUID, TOXIC
3012

N.O.S.
3466

SOLID, TOXIC
2777
METAL CARBONYLS, SOLID,

N.O.S.
METAL CATALYST, DRY
2881
METAL CATALYST, WETTED with

a visible excess of liquid
1378
METALDEHYDE
1332
METAL HYDRIDES, FLAMMABLE,

N.O.S.
3182
MERCURY BENZOATE
1631
Mercury bichloride, see
1624
MERCURY BROMIDES
1634

N.O.S.
2024
Book 1.indb 172
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
METAL HYDRIDES,
1409
METHYL ACETATE
1231
METAL POWDER, FLAMMABLE,

N.O.S.
METHYLACETYLENE AND
PROPADIENE MIXTURE,
STABILIZED
1060
3089
METAL POWDER, SELF-HEATING,

N.O.S.
3189
beta-Methyl acrolein, see
1143
METAL SALTS OF ORGANIC

COMPOUNDS, FLAMMABLE,
N.O.S.
3181
METHYL ACRYLATE, STABILIZED
1919
METHYLAL
1234
Methyl alcohol, see
1230
METALLIC SUBSTANCE,
3208
Methyl allyl alcohol, see
2614
METALLIC SUBSTANCE,
WATER-REACTIVE,
3209
METHYLALLYL CHLORIDE
2554
METHYLAMINE, ANHYDROUS
1061
METHACRYLALDEHYDE,
STABILIZED
2396
METHYLAMINE, AQUEOUS
SOLUTION
1235
METHACRYLIC ACID, STABILIZED
2531
METHYLAMYL ACETATE
1233
METHACRYLONITRILE,
STABILIZED
3079
Methyl amyl alcohol, see
2053
Methyl amyl ketone, see
1110
2294
METHALLYL ALCOHOL
2614
N-METHYLANILINE
Methanal, see
1198
2209
Methylated spirit, see
1986
1987
Methane and hydrogen mixture, see
2034
2937
METHANE, COMPRESSED
1971
alpha-METHYLBENZYL
ALCOHOL, LIQUID
METHANE, REFRIGERATED
LIQUID
1972
alpha-METHYLBENZYL
ALCOHOL, SOLID
3438
METHANESULPHONYL
CHLORIDE
3246
METHYL BROMIDE, with not more

1062
METHANOL
1230
Methyl bromide and chloropicrin

mixture, see
1581
2-Methoxyethyl acetate, see
1189
2605
METHYL BROMIDE AND

ETHYLENE DIBROMIDE
MIXTURE, LIQUID
1647
METHOXYMETHYL ISOCYANATE
4-METHOXY-4-METHYLPENTAN2-ONE
2293
METHYL BROMOACETATE
2643
1-Methoxy-2-nitrobenzene, see
2730
3458
2-METHYLBUTANAL
3371
3-METHYLBUTAN-2-ONE
2397
2730
3458
2-METHYL-1-BUTENE
2459
2730
2-METHYL-2-BUTENE
2460
1-METHOXY-2-PROPANOL
3092
3-METHYL-1-BUTENE
2561
N-METHYLBUTYLAMINE
2945
Book 1.indb 173
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
METHYL tert-BUTYL ETHER
2398
2-METHYL-5-ETHYLPYRIDINE
2300
METHYL BUTYRATE
1237
METHYL FLUORIDE
2454
METHYL CHLORIDE
1063
METHYL FORMATE
1243
Methyl chloride and chloropicrin

mixture, see
1582
2-METHYLFURAN
2301
METHYL CHLORIDE AND

METHYLENE CHLORIDE
MIXTURE
Methyl glycol, see
1188
1912
Methyl glycol acetate, see
1189
2-METHYL-2-HEPTANETHIOL
3023
METHYL CHLOROACETATE
2295
5-METHYLHEXAN-2-ONE
2302
Methyl chlorocarbonate, see
1238
METHYLHYDRAZINE
1244
Methyl chloroform, see
2831
METHYL IODIDE
2644
METHYL CHLOROFORMATE
1238
METHYL ISOBUTYL CARBINOL
2053
METHYL CHLOROMETHYL
ETHER
1239
METHYL ISOBUTYL KETONE
1245
METHYL 2-CHLOROPROPIONATE
2933
METHYL ISOCYANATE
2480
1246
Methyl alpha-chloropropionate, see
2933
METHYL ISOPROPENYL KETONE,

STABILIZED
METHYLCHLOROSILANE
2534
METHYL ISOTHIOCYANATE
2477
Methyl cyanide, see
1648
METHYL ISOVALERATE
2400
METHYLCYCLOHEXANE
2296
2617
METHYL MAGNESIUM BROMIDE

IN ETHYL ETHER
1928
METHYLCYCLOHEXANOLS,
flammable
METHYL MERCAPTAN
1064
METHYCYCLOHEXANONE
2297
2785
METHYLCYCLOPENTANE
2298
Methyl mercaptopropionaldehyde,
see
METHYL DICHLOROACETATE
2299
1247
METHYLDICHLOROSILANE
1242
METHYL METHACRYLATE
MONOMER, STABILIZED
2664
4-METHYLMORPHOLINE
(N-METHYLMORPHOLINE)
2535
Methylene bromide, see

Methylene chloride, see
1593
METHYL NITRITE
2455
Methylene chloride and methyl

chloride mixture, see
1912
METHYL ORTHOSILICATE
2606
METHYLPENTADIENE
2461
Methylene cyanide, see
2647
Methylpentanes, see
1208
p,p-Methylene dianiline, see
2651
2-METHYLPENTAN-2-OL
2560
Methylene dibromide, see
2664
4-Methylpentan-2-ol, see
2053
2,2-Methylene-di-(3,4,6trichlorophenol), see
2875
3-Methyl-2-penten-4-yn-1-ol, see
2705
Methyl ethyl ether, see
1039
2437
METHYL ETHYL KETONE
METHYLPHENYLDICHLOROSILANE
1193
Book 1.indb 174
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
2-Methyl-2-phenylpropane, see
2709
1974
1-METHYLPIPERIDINE
2399
Monochlorodifluoromonobromomethane, see
METHYL PROPIONATE
1248
1973
Methylpropylbenzene, see
2046
Monochloropentafluoroethane
and monochlorodifluoromethane
mixture, see
METHYL PROPYL ETHER
2612
Monoethylamine, see
1036
METHYL PROPYL KETONE
1249
Monopropylamine, see
1277
Methyl pyridines, see
2313
MONONITROTOLUIDINES
2660
Methylstyrene, see
2618
MORPHOLINE
2054
alpha-Methylstyrene, see
2303

MIXTURE
1649
Methyl sulphate, see
1595
1164

MIXTURE, FLAMMABLE
3483
Methyl sulphide, see

METHYLTETRAHYDROFURAN
2536
MOTOR SPIRIT
1203
METHYL TRICHLOROACETATE
2533
Muriatic acid, see
1789
METHYLTRICHLOROSILANE
1250
MUSK XYLENE
2956
alpha-METHYLVALERALDEHYDE
2367
Mysorite, see
2212
Methyl vinyl benzene, see
2618
Naphta, see
1268
METHYL VINYL KETONE,

STABILIZED
1251
Naphta, petroleum, see
1268
Naphta, solvent, see
1268
M.i.b.c., see
2053
NAPHTHALENE, CRUDE
1334
Mirbane oil, see
1662
NAPHTHALENE, MOLTEN
2304
Mixtures A, A01, A02, A0, A1, B1,

B2, B or C, see
1965
NAPHTHALENE, REFINED
1334
Mixture F1, F2 or F3, see
1078
alpha-NAPHTHYLAMINE
2077
MIXTURES OF 1.3-BUTADIENE
AND HYDROCARBONS,
STABILIZED
1010
beta-NAPHTHYLAMINE, SOLID
1650
beta-NAPHTHYLAMINE
SOLUTION
3411
Mixture P1 or P2, see
1060
NAPHTHYLTHIOUREA
1651
MOLYBDENUM PENTACHLORIDE
2508
1-Naphthylthiourea, see
1651
Monochloroacetic acid, see
1750
1751
NAPHTHYLUREA
1652
NATURAL GAS, COMPRESSED,

with high methane content
1971
NATURAL GAS, REFRIGERATED

LIQUID, with high methane content
1972
Neohexane, see
1208
NEON, COMPRESSED
1065
Monochlorobenzene, see
1134
Monochlorodifluoromethane, see
1018
Monochlorodifluoromethane and
monochloropentafluoroethane
mixture, see
1973
Book 1.indb 175
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
NEON, REFRIGERATED LIQUID
1913
NITRIC OXIDE, COMPRESSED
1660
Neothyl, see
2612
1975
NICKEL CARBONYL
1259
NITRIC OXIDE AND DINITROGEN

TETROXIDE MIXTURE
NICKEL CYANIDE
1653
NITRIC OXIDE AND NITROGEN

DIOXIDE, MIXTURE
1975
Nickel (II) cyanide, see
1653
2725
NITRILES, FLAMMABLE, TOXIC,

N.O.S.
3273
NICKEL NITRATE
Nickel (II) nitrate
2725
NITRILES, TOXIC, FLAMMABLE,

N.O.S.
3275
NICKEL NITRITE
2726
NITRILES, LIQUID, TOXIC, N.O.S.
3276
Nickel (II) nitrite, see
2726
NITRILES, SOLID, TOXIC, N.O.S.
3439
Nickelous nitrate, see
2725
NITRITES, INORGANIC, N.O.S.
2627
Nickelous nitrite, see
2726
1259
NITRITES, INORGANIC,
3219
Nickel tetracarbonyl, see

NICOTINE
1654
NITROANILINES (o-,m-,p-)
1661
NICOTINE COMPOUND,
LIQUID, N.O.S. or NICOTINE
PREPARATION, LIQUID, N.O.S.
3144
NITROANISOLES, LIQUID
2730
NITROANISOLES, SOLID
3458
NICOTINE COMPOUND,
SOLID, or SOLUTION, N.O.S. or
NICOTINE PREPARATION, SOLID,
or SOLUTION, N.O.S.
1655
NITROBENZENE
1662
Nitrobenzene bromide, see
2732
NITROBENZENESULPHONIC ACID
2305
LIQUID or SOLUTION
1656
Nitrobenzol, see
1662
SOLID
2306
3444
LIQUID
NICOTINE SALICYLATE
SOLID
3431
1657
NICOTINE SULPHATE, SOLID
3445
2732
NICOTINE SULPHATE SOLUTION
1658
NITROBROMOBENZENES,
LIQUID
NICOTINE TARTRATE
1659
NITROBROMOBENZENES, SOLID
3459
NITRATES, INORGANIC, N.O.S.
1477
2059
NITRATES, INORGANIC,
3218
NITROCELLULOSE SOLUTIONS,
FLAMMABLE, with not more than
12.6% nitrogen by dry mass, and
not more than 55% nitrocellulose
NITRATING ACID, MIXTURE
1796
3270
NITRATING ACID, MIXTURE,

SPENT
1826
NITROCELLULOSE MEMBRANE
FILTERS, with not more than
12.6% nitrogen by dry mass
2031
NITRIC ACID, RED FUMING
2032
NITROCELLULOSE, with not

more than 12.6% nitrogen by
dry mass, MIXTURE, WITHOUT
PLASTICIZER, WITH OR
WITHOUT PIGMENT
2557
NITRIC ACID, other than red

fuming nitric acid
Book 1.indb 176
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
NITROCELLULOSE with ALCOHOL,

not less than 25% alcohol
2556
NITRONAPHTHALENE
2538
NITROCELLULOSE WITH WATER

NITROPHENOLS (o-,m-,p-)
1663
2555
4-NITROPHENYLHYDRAZINE, with
3376
Nitrochlorobenzene, see
1578
3409
NITROPROPANES
2608
3-NITRO-4-CHLOROBENZOTRIFLUORIDE
2307
p-NITROSODIMETHYLANILINE
1369
1337
NITROCRESOLS, LIQUID
3434
NITROSTARCH, WETTED, with not

less than 20% water by mass
NITROCRESOLS, SOLID
2446
NITROSYL CHLORIDE
1069
NITROETHANE
2842
2308
NITROGEN, COMPRESSED
1066
NITROSYLSULPHURIC ACID,
LIQUID
Nitrogen dioxide, see
1067
NITROSYLSULPHURIC ACID,
SOLID
3456
NITROGEN, REFRIGERATED
LIQUID
1977
NITROTOLUENES, LIQUID
1664
NITROGEN TRIFLUORIDE
2451
NITROTOLUENES, SOLID
3446
NITROGEN TRIOXIDE
2421
NITROTOLUIDINES
2660
NITROGLYERIN MIXTURE,
N.O.S., with not more than 30%
nitroglycerin by mass
3357
NITROUS OXIDE
1070
NITROUS OXIDE, REFRIGERATED

LIQUID
2201
NITROXYLENES, LIQUID
1665
with more than 2% but not more
than 10% nitroglycerin by mass,
desensitised
3319
NITROXYLENES, SOLID
3447
Non-activated carbon, see
1361
NITROGLYCERINE MIXTURE,
FLAMMABLE, N.O.S., with not
more than 30% nitroglycerin by
mass
3343
Non-activated charcoal, see
1361
NONANES
1920
NONYLTRICHLOROSILANE
1799
1204
2,5-NORBORNADIENE,
STABILIZED
2251
NITROGLYCERIN SOLUTION IN
ALCOHOL, with not more than 1%
nitroglycerin
OCTADECYLTRICHLOROSILANE
1800
NITROGLYCERIN, SOLUTION, IN
ALCOHOL, with more than 1% but
not more than 5% nitroglycerin
3064
OCTADIENE
2309
OCTAFLUOROBUT-2-ENE
2422
OCTAFLUOROCYCLOBUTANE
1976
NITROGUANIDINE, WETTED, with

1336
OCTAFLUOROPROPANE
2424
NITROHYDROCHLORIC ACID
1798
OCTANES
1262
NITROMETHANE
1261
OCTYL ALDEHYDES,
1191
Nitromuriatic acid, see
1798
tert-Octyl mercaptan, see
3023
Book 1.indb 177
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
OCTYLTRICHLOROSILANE
1801
3109
Oenanthol, see
3056
ORGANIC PEROXIDE TYPE F,

LIQUID
OIL GAS, COMPRESSED
1071
3119
Oleum, see
1831

LIQUID, TEMPERATURE
CONTROLLED

LIQUID
3101
ORGANIC PEROXIDE TYPE F,

SOLID
3110
ORGANIC PEROXIDE TYPEB,

LIQUID, TEMPERATURE
CONTROLLED
3111

SOLID, TEMPERATURE
CONTROLLED
3120

SOLID
3102
ORGANIC PIGMENTS
SELF-HEATING
3313

SOLID,
3112
LIQUID, N.O.S.
3280

LIQUID
3103
SOLID, N.O.S.
3465

LIQUID, TEMPERATURE
CONTROLLED
3113
2762

SOLID
3104
2995

SOLID, TEMPERATURE
CONTROLLED
3114
LIQUID, TOXIC
2996

LIQUID
3105
SOLID, TOXIC
2761

LIQUID, TEMPERATURE
CONTROLLED
3115
LIQUID, TOXIC, N.O.S.
3282
3106
Organometallic compound, solid,

water-reactive, flammable, n.o.s.,
see
3396

SOLID
SOLID, TEMPERATURE
CONTROLLED
3116
3399

LIQUID
3107
Organometallic compound or
organometallic compound solution
or organometallic compound
dispersion, water-reactive,
flammable, n.o.s., see
3117
3467
ORGANIC PEROXIDE TYPEE,

LIQUID, TEMPERATURE
CONTROLLED
SOLID, PYROPHORIC
3391

SOLID
3108
LIQUID, PYROPHORIC
3392

SOLID,
3118
Book 1.indb 178
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
SOLID, PYROPHORIC,
WATER-REACTIVE
3393
ORGANOTIN COMPOUND,
SOLID, N.O.S.
3146
LIQUID, PYROPHORIC,
WATER-REACTIVE

less than 23C
2787
3394
SOLID, WATER-REACTIVE

23C or above
3019
3395
FLAMMABLE
3396

TOXIC
3020
SELF-HEATING
ORGANOTIN PESTICIDE, SOLID,

TOXIC
2786
3397
Orthophosphoric acid, see
1805
LIQUID, WATER-REACTIVE
3398
OSMIUM TETROXIDE
2471
3098
LIQUID, WATER-REACTIVE,
FLAMMABLE
3399
OXIDISING LIQUID, CORROSIVE,

N.O.S.
OXIDISING LIQUID, N.O.S.
3139
SOLID, SELF-HEATING
4000
OXIDISING LIQUID, TOXIC,

N.O.S.
3099
ORGANOPHOSPHORUS
COMPOUND, TOXIC,
FLAMMABLE, N.O.S.
3279

N.O.S.
3085
3278
OXIDISING SOLID, FLAMMABLE,

N.O.S.
3137
ORGANOPHOSPHORUS
N.O.S.
OXIDISING SOLID, N.O.S.
1479
ORGANOPHOSPHORUS
COMPOUND, SOLID, TOXIC,
N.O.S.
3464
OXIDISING SOLID, TOXIC, N.O.S.
3087
OXIDISING SOLID,
3100
ORGANOPHOSPHOROUS
PESTICIDE, LIQUID,
less than 23C
2784
OXIDISING SOLID,
3121
Oxirane, see
1040
ORGANOPHOSPHORUS
FLAMMABLE, flash point 23C or
above
3017
OXYGEN, COMPRESSED
1072
OXYGEN DIFLUORIDE,
COMPRESSED
2190
ORGANOPHOSPHORUS
3018
OXYGEN GENERATOR,
CHEMICAL
3356
ORGANOPHOSPHORUS
2783
OXYGEN, REFRIGERATED LIQUID
1073
1-Oxy-4-nitrobenzene, see
1663

3066
3469
3470
ORGANOTIN COMPOUND,
LIQUID, N.O.S.
2788
Book 1.indb 179
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
PAINT, CORROSIVE, FLAMMABLE

or PAINT RELATED MATERIAL,
CORROSIVE, FLAMMABLE
3470
PENTANES, liquid
1265
3-Pentanol, see
1105
PAINT, FLAMMABLE, CORROSIVE,

or PAINT RELATED MATERIAL,
FLAMMABLE, CORROSIVE
3469
n-Pentanol, see
1265
PENTANOLS
1105
PAINT RELATED MATERIAL

(including paint thinning or
reducing compound)
1263
3066
3469
3470
1-PENTENE
1108
1-PENTOL
2705
Pentyl nitrite, see
1113
Paint thinning and reducing

compound, see
1263
3066
3469
3470
N.O.S.
1481
3211
PAPER, UNSATURATED OIL

TREATED, incompletely dried
(includes carbon paper)
1379
PERCHLORIC ACID, with more

acid by mass
1873
Paraffin, see
1223
2213
PERCHLORIC ACID, with not more

than 50% acid by mass
1802
PARAFORMALDEHYDE
PARALDEHYDE
1264
Perchlorobenzene, see
2729
PCBs, LIQUID
2315
Perchlorocyclopentadiene, see
2646
PCBs, SOLID
3432
Perchloroethylene, see
1897
PENTABORANE
1380
1670
PENTACHLOROETHANE
1669
PERCHLOROMETHYL
MERCAPTAN
PENTACHLOROPHENOL
3155
PERCHLORYL FLUORIDE
3083
PENTAERYTHRITE
TETRANITRATE
(PENTAERYTHRITOL
TRETRANITRATE; PETN)
MIXTURE, DESENSITIZED, SOLID,
N.O.S., with more than 10% but
not more than 20% PETN by mass
3344
Perfluoroacetylchloride, see
3057
PERFLUORO (ETHYL VINYL

ETHER)
3154
PERFLUORO (METHYL VINYL

ETHER)
3153
Perfluoropropane, see
2424
PENTAFLUOROETHANE
3220
1266
Pentafluoroethane,
1,1,1-trifluoroethane, and
1,1,1,2- tetrafluoroethane azeotropic
mixture with approximately 44%
pentafluoroethane and 52%
1,1,1- triflluoroethane, see
3337
PERFUMERY PRODUCTS, with

flammable solvents
N.O.S.
1482
PENTAMETHYLHEPTANE
2286
Pentanal, see
2058
PENTANE-2,4-DIONE
2310
3214
PEROXIDES, INORGANIC, N.O.S.
1483
N.O.S.
3215
Book 1.indb 180
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
3216
3348

TOXIC, N.O.S., flash point less
than 23C
3021
PHENOXYACETIC ACID
DERIVATIVE PESTICIDE, LIQUID,
TOXIC
3347

FLAMMABLE, N.O.S., flash point
23C or above
2903
PHENOXYACETIC ACID
not less than 23C
3345

N.O.S.
2902
PHENOXYACETIC ACID
DERIVATIVE PESTICIDE, SOLID,
TOXIC
PESTICIDE, SOLID, TOXIC, N.O.S.
2588
PHENYLACETONITRILE LIQUID
2470
Pesticides, toxic, under compressed

gas, n.o.s., see
1950
PHENYLACETYL CHLORIDE
2577
Phenylamine, see
1547
PETROL
1203
1-Phenylbutane, see
2709
PETROLEUM CRUDE OIL
1267
2-Phenylbutane, see
2709
1268
1672
Petroleum ether, see
1268
PHENYLCARBYLAMINE
CHLORIDE
PETROLEUM GASES, LIQUEFIED
1075
PHENYL CHLOROFORMATE
2746
Phenyl cyanide, see
2224
PHENYLENEDIAMINES(o-,m-,p)
1673
Phenylethylene, see
2055
PHENYLHYDRAZINE
2572
PHENYL ISOCYANATE
2487
Phenylisocyanodichloride, see
1672
Petroleum naphtha, see
1268
Petroleum oil, see
1268
PETROLEUM PRODUCTS, N.O.S.
1268
Petroleum raffinate, see
1268
Petroleum spirit, see
1268

FLAMMABLE, TOXIC
3494
PHENYL MERCAPTAN
2337
PHENACYL BROMIDE
2645
PHENYLMERCURIC ACETATE
1674
PHENETIDINES
2311
PHENYLMERCURIC COMPOUND
2026
PHENOL, MOLTEN
2312
PHENYLMERCURIC HYDROXIDE
1894
PHENOL, SOLID
1671
PHENYLMERCURIC NITRATE
1895
PHENOL SOLUTION
2821
2904
PHENYLPHOSPHORUS
DICHLORIDE
2798
PHENOLATES, LIQUID
PHENOLATES, SOLID
2905
PHENYLPHOSPHORUS
THIODICHLORIDE
2799
PHENOLSULPHONIC ACID,
LIQUID
1803
2-Phenylpropene, see
2303
PHENOXYACETIC ACID
less than 23C
3346
PHENYLTRICHLOROSILANE
1804
PHOSGENE
1076
9-PHOSPHABICYCLONONANES
2940
Book 1.indb 181
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
PHOSPHINE
2199
1381
Phosphoretted hydrogen, see
2199
PHOSPHORUS, WHITE or
YELLOW, DRY or UNDER WATER
or IN SOLUTION
PHOSPHORIC ACID, SOLUTION
1805
Phosphoryl chloride, see
1810
PHOSPHORIC ACID, SOLID
3453
1807
PHTHALIC ANHYDRIDE, with

more than 0.05% maleic anhydride
2214
Phosphoric acid, anhydrous, see

PHOSPHOROUS ACID
2834
PICOLINE
2313
PHOSPHORUS, AMORPHOUS
1338
Picric Acid, Wetted, see
1344
3364
Phosphorus bromide, see
1808
Picrite, Wetted, see
1336
Phosphorus chloride, see
1809
Picrotoxin, see
PHOSPHORUS HEPTASULPHIDE,
phosphorus
1339
3172
3462
Picryl Chloride, Wetted, see
3365
PHOSPHORUS OXYBROMIDE
1939
alpha-PINENE
2368
PHOSPHORUS OXYBROMIDE,
MOLTEN
2576
PINE OIL
1272
PIPERAZINE
2579
PHOSPHORUS OXYCHLORIDE
1810
PIPERIDINE
2401
PHOSPHORUS PENTABROMIDE
2691
Privaloyl chloride, see
2438
PHOSPHORUS PENTACHLORIDE
1806
2198
PHOSPHORUS PENTASULPHIDE,
phosphorus
1340
PLASTICS MOULDING
COMPOUND in dough, sheet
or extruded rope form, evolving
flammable vapour
3314
PHOSPHORUS PENTAFLUORIDE,
PLASTICS, NITROCELLULOSEBASED, SELF-HEATING, N.O.S.
2006
PHOSPHORUS PENTOXIDE
1807
Polish, see
PHOSPHORUS SESQUISULPHIDE,
phosphorus
1341
1263
3066
3469
3470
Phosphorus (V) sulphide, free from

yellow and white phosphorus, see
1340
POLYAMINES, FLAMMABLE,
CORROSIVE, N.O.S.
2733
Phosphorus sulphochloride, see
1837
2735
PHOSPHORUS TRIBROMIDE
1808
POLYAMINES, LIQUID,
CORROSIVE, N.O.S.
PHOSPHORUS TRICHLORIDE
1809
POLYAMINES, LIQUID,
CORROSIVE, FLAMMABLE,N.O.S.
2734
PHOSPHORUS TRIOXIDE
2578
1343
POLYAMINES, SOLID,
CORROSIVE, N.O.S.
3259
PHOSPHORUS TRISULPHIDE, free

from yellow and white phosphorus
2447
LIQUID
2315
PHOSPHORUS, WHITE, MOLTEN
SOLID
3432
Book 1.indb 182
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
POLYESTER RESIN KIT
3269
3421
LIQUID or POLYHALOGENATED
TERPHENYLS, LIQUID
3151
POTASSIUM
HYDROGENDIFLUORIDE
SOLUTION
2509
SOLID or POLYHALOGENATED
TERPHENYLS, SOLID
3152
POTASSIUM HYDROGEN
SULPHATE
POTASSIUM HYDROSULPHITE
1929
POLYMERIC BEADS, EXPANDABLE,

evolving flammable vapour
Potassium hydroxide, liquid, see
1814
2211
POTASSIUM HYDROXIDE, SOLID
1813
Polystyrene beads, evolving

flammable vapour, see
2211
POTASSIUM HYDROXIDE
SOLUTION
1814
POTASSIUM
2257
1420
POTASSIUM ARSENATE

LIQUID
1677
POTASSIUM ARSENITE

SOLID
3403
1678
Potassium bifluoride, see
1811
POTASSIUM METAVANADATE
2864
Potassium bisulphate, see
2509
POTASSIUM MONOXIDE
2033
Potassium bisulphite solution, see
2693
POTASSIUM NITRATE
1486
POTASSIUM BOROHYDRIDE
1870
1484
Potassium nitrate and sodium

nitrate mixture, see
1499
POTASSIUM BROMATE
POTASSIUM CHLORATE
1485
POTASSIUM NITRATE and

SODIUM NITRITE MIXTURE
1487
POTASSIUM CHLORATE,
AQUEOUS SOLUTION
2427
POTASSIUM NITRITE
1488
POTASSIUM CUPROCYANIDE
1679
POTASSIUM PERCHLORATE
1489
POTASSIUM CYANIDE, SOLID
1680
POTASSIUM PERMANGANATE
1490
POTASSIUM CYANIDE SOLUTION
3413
POTASSIUM PEROXIDE
1491
Potassium dicyanocuprate (I), see
1679
POTASSIUM PERSULPHATE
1492
POTASSIUM DITHIONITE
1929
POTASSIUM PHOSPHIDE
2012
POTASSIUM FLUORIDE, SOLID
1812
Potassium selenate, see
2630
Potassium selenite, see
2630
Potassium silicofluoride, see
2655

LIQUID
1422

SOLID
3404
POTASSIUM SULPHIDE,
ANHYDROUS or POTASSIUM
SULPHIDE, with less than 30%
1382
POTASSIUM FLUORIDE
SOLUTION
3422
POTASSIUM FLUOROACETATE
2628
POTASSIUM FLUOROSILICATE
2655
Potassium hexafluorosilicate, see
2655
Potassium hydrate, see
1814
POTASSIUM
1811
Book 1.indb 183
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
POTASSIUM SULPHIDE,
HYDRATED, with not less than
1847
PROPYLENEIMINE, STABILIZED
1921
PROPYLENE OXIDE
1280
POTASSIUM SUPEROXIDE
2466
PROPYLENE TETRAMER
2850
Potassium tetracyanomercurate (II),

see
1626
Propylene trimer, see
2057
PROPYL FORMATES
1281
PRINTING INK, FLAMMABLE

or PRINTING INK RELATED
MATERIAL (including printing ink
thinning or reducing compound),
flammable
1210
1263
n-PROPYL ISOCYANATE
2482
Propyl mercaptan, see
2402
n-PROPYL NITRATE
1865
1816
PROPADIENE, STABILIZED
2200
PROPYLTRICHLOROSILANE
Propadiene and methyl acetylene

mixture, stabilized, see
1060
Pyrazine hexahydride, see
2579
3350
PROPANE
1978
PROPANETHIOLS
2402

less than 23C
n-PROPANOL
1274

TOXIC
3352
Propene, see
1077
1275

not less than 23C
3351
PROPIONALDEHYDE
PROPIONIC ACID, with not less
than 10% and less than 90% acid
by mass
1848
PYRETHROID PESTICIDE, SOLID,

TOXIC
3349
PROPIONIC ACID, with not less

than 90% acid by mass
3463
PYRIDINE
1282
PYROPHORIC ALLOY, N.O.S.
1383
PROPIONIC ANHYDRIDE
2496
2404
Pyrophoric organometallic
compound, water-reactive, n.o.s.,
liquid, see
3394
PROPIONITRILE
PROPIONYL CHLORIDE
1815
1276
Pyrophoric organometallic
compound, water-reactive, n.o.s.,
solid, see
3393
n-PROPYL ACETATE
Propyl alcohol, normal, see
1274
PROPYLAMINE
PYROPHORIC LIQUID,
INORGANIC, N.O.S.
3194
1277
n-PROPYLBENZENE
2364
2845
Propyl chloride, see
1278
PYROPHORIC LIQUID, ORGANIC,

N.O.S.
n-PROPYL CHLOROFORMATE
2740
PYROPHORIC METAL, N.O.S.
1383
PROPYLENE
1077
PYROPHORIC SOLID,
INORGANIC, N.O.S.
3200
PROPYLENE CHLOROHYDRIN
2611
2258
PYROPHORIC SOLID, ORGANIC,

N.O.S.
2846
1,2-PROPYLENEDIAMINE
Propylene dichloride, see
1279
PYROSULPHURYL CHLORIDE
1817
Book 1.indb 184
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Pyroxylin solution, see
2059
3331
PYRROLIDINE
1922
ARRANGEMENT, FISSILE
Quinol, see
2662
2656
Quinone, see
2587
ARRANGEMENT, non-fissile or
fissile excepted
2919
QUINOLINE
EXCEPTED PACKAGE ARTICLES
MANUFACTURED FROM
NATURAL DEPLETED URANIUM
or DEPLETED URANIUM or
NATURAL THORIUM
2909

A PACKAGE, FISSILE, non-special
form
3327

A PACKAGE, non-special for,
2915
EXCEPTED PACKAGE EMPTY
PACKAGING
2908

A PACKAGE, SPECIAL FORM,
FISSILE
3333
EXCEPTED PACKAGE
INSTRUMENTS or ARTICLES
2911

A PACKAGE, SPECIAL FORM,
3332
EXCEPTED PACKAGE LIMITED
QUANTITY OF MATERIAL
2910

B(M) PACKAGE, FISSILE
3329

SPECIFIC ACTIVITY (LSA-I),
2912

B(M) PACKAGE, non-fissile or
fissile excepted
2917

SPECIFIC ACTIVITY (LSA II),
FISSILE
3324

B(U) PACKAGE, FISSILE
3328
3321

B(U) PACKAGE, non-fissile or
fissile excepted
2916

SPECIFIC ACTIVITY (LSA -II),
3325

C PACKAGE, FISSILE
3330

SPECIFIC ACTIVITY (LSA III),
FISSILE
3323

SPECIFIC ACTIVITY (LSA III),
3322

C PACKAGE, non-fissile or fissile
excepted
2977
SURFACE CONTAMINATED
OBJECTS (SCO I or SCO II),
FISSILE
3326
URANIUM HEXFLUORIDE,
FISSILE
URANIUM HEXAFLUORIDE,
2978
SURFACE CONTAMINATED
OBJECTS (SCO I or SCO II),
2913
RAGS, OILY
1856
RECEPTACLES, SMALL,
CONTAINING GAS, without
release device, not refillable
2037
Book 1.indb 185
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Red phosphorus, see
1338
Refrigerant Gas R 1132a, see
1959
REFRIGERANT GAS, N.O.S.
1078
Refrigerant Gas R 1216, seee
1858
Refrigerant Gas R 12, see
1028
2422
Refrigerant Gas R 12b1, see
1974
Refrigerant Gas Rc 318, see
1976
1022
1009
REFRIGERATING MACHINES,
containing flammable, non-toxic,
liquefied gas
3358
Refrigerant Gas R 13b1,see

1982
1029
Refrigerant Gas R22, see
1018
REFRIGERATING MACHINES,
containing non-flammable,
non-toxic, gases or ammonia
solutions (UN 2672)
2857
1984
3252
REGULATED MEDICAL WASTE,

N.O.S.
3291

1063
RESIN SOLUTION, flammable
1866
2454
Resorcin, see
2876
1958
RESORCINOL
2876
1020
ROSIN OIL
1286
2193
RUBBER SCRAP or RUBBER

SHODDY, powdered or granulated
1345
1021
RUBBER SOLUTION
1287
3220
RUBIDIUM
1423
1983
RUBIDIUM HYDROXIDE
2678
3159
2677
Refrigerant Gas R 142b, see
2517
RUBIDIUM HYDROXIDE
SOLUTION
2035
Saltpetre, see
1486
Sand acid, see
1778
SEAT-BELT PRETENSIONERS
3268
SEED CAKE with more than 1.5%

oil and not more than 11% moisture
1386
SEED CAKE with not more than

1.5% oil and not more than 11%
moisture
2217
Seed expellers, see
1386
2217
1030
2453
2424
3296
3337
3338
Refrigerant Gas R 407b, see
3339
Refrigerant Gas R 407c, see
3340
SELENATES
2630
2602
SELENIC ACID
1905
1973
SELENITES
2630
2599
Book 1.indb 186
04/04/2013 15:31
Substance
UN
No

N.O.S.
3440
SELENIUM COMPOUND, SOLID,

N.O.S.
3283
SELENIUM DISULPHIDE
2657
SELENIUM HEXAFLUORIDE
2194
SELENIUM OXYCHLORIDE
2879
SELF-HEATING LIQUID,
3188
3185
INORGANIC, N.O.S.
3186
ORGANIC, N.O.S.
Substance
UN
No
SELF-REACTIVE LIQUID TYPE D,

3235
3227

3237
SELF-REACTIVE LIQUID TYPE F
3229
SELF-REACTIVE LIQUID TYPE F,

3239
SELF-REACTIVE SOLID TYPE B
3222
SELF-REACTIVE SOLID TYPE B,

3232
SELF-REACTIVE SOLID TYPE C
3224
3183
SELF-REACTIVE SOLID TYPE C,

3234

INORGANIC, N.O.S.
3187
SELF-REACTIVE SOLID TYPE D
3226
3236

ORGANIC, N.O.S.
3184
SELF-REACTIVE SOLID TYPE D,

SELF-REACTIVE SOLID TYPE E
3228
SELF-HEATING SOLID,
3126
SELF-REACTIVE SOLID TYPE E,

3238
SELF-HEATING SOLID,
INORGANIC, N.O.S.
3190
SELF-REACTIVE SOLID TYPE F
3230
SELF-HEATING SOLID,
3192
SELF-REACTIVE SOLID TYPE F,

3240

INORGANIC, N.O.S.
3191
SHALE OIL
1288
Shellac, see
SELF-HEATING SOLID, ORGANIC,

N.O.S.
3088
1263
3066
3469
3470
SELF-HEATING SOLID,
OXIDISING, N.O.S.
3127
SILANE
2203

ORGANIC, N.O.S.
3128
Silicofluoric acid, see
1778
Silicofluorides, n.o.s., see
2856
SELF-REACTIVE LIQUID TYPE B
3221
Silicon chloride, see
1818
SELF-REACTIVE LIQUID TYPE B,

3231
SILICON POWDER, AMORPHOUS
1346
SELF-REACTIVE LIQUID TYPE C
3223
SILICON TETRACHLORIDE
1818
SELF-REACTIVE LIQUID TYPE C,

3233
SILICON TETRAFLUORIDE
1859
SILVER ARSENITE
1683
SELF-REACTIVE LIQUID TYPE D
3225
SILVER CYANIDE
1684
Book 1.indb 187
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
SILVER NITRATE
1493
SODIUM CUPROCYANIDE, SOLID
2316
SILVER PICRATE, WETTED, with

1347
SODIUM CUPROCYANIDE
SOLUTION
2317
SLUDGE ACID
1906
SODIUM CYANIDE, SOLID
1689
SODA LIME, with more than 4%

sodium hydroxide
1907
SODIUM CYANIDE SOLUTION
3414
SODIUM
Sodium dicyanocuprate (I), solid,

see
2316
1428
SODIUM ALUMINATE, SOLID
2812
1819
Sodium dicyanocuprate (I), solution,

see
2317
SODIUM ALUMINATE SOLUTION

SODIUM ALUMINIUM HYDRIDE
2835
Sodium dimethylarsenate, see
1688
SODIUM AMMONIUM
VANADATE
2863
water by mass
3369
SODIUM ARSANILATE
2473
1685
water by mass
1348
SODIUM ARSENATE
SODIUM ARSENITE, AQUEOUS
SOLUTIONS
1686
Sodium dioxide, see
1504
1384
SODIUM ARSENITE, SOLID
2027
SODIUM DITHIONITE
SODIUM AZIDE
1687
SODIUM FLUORIDE, SOLID
1690
Sodium bifluoride, see
2439
SODIUM FLUORIDE SOLUTION
3415
Sodium binoxide, see
1504
SODIUM FLUOROACETATE
2629
Sodium bisulphite solution, see
2693
SODIUM FLUOROSILICATE
2674
SODIUM BOROHYDRIDE
1426
Sodium hexafluorosilicate, see
2674
SODIUM BOROHYDRIDE
AND SODIUM HYDROXIDE
12% sodium borohydride and not
more than 40% sodium hydroxide
by mass
3320
Sodium hydrate, see
1824
SODIUM HYDRIDE
1427
Sodium hydrogen
4-aminophenylarsenate, see
2473
SODIUM BROMATE
SODIUM HYDROGENDIFLUORIDE
2439
1494
SODIUM CACODYLATE
2318
1688
SODIUM CARBONATE
PEROXYHYDRATE
3378
with less than 25% water of
crystallization
2949
SODIUM CHLORATE
1495
HYDRATED, with not less than
SODIUM CHLORATE, AQUEOUS

SOLUTION
2428
SODIUM HYDROSULPHITE
1384
SODIUM CHLORITE
1496
SODIUM HYDROXIDE, SOLID
1823
SODIUM CHLOROACETATE
2659
SODIUM HYDROXIDE SOLUTION
1824
Book 1.indb 188
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
Sodium metasilicate pentahydrate,

see
3253
SOLIDS CONTAINING
FLAMMABLE LIQUID, N.O.S.
3175
SODIUM METHYLATE
1431
3243
SODIUM METHYLATE
SOLUTION, in alcohol
1289
SOLIDS CONTAINING TOXIC

LIQUID, N.O.S.
Solvents, flammable, n.o.s., see
1993
SODIUM MONOXIDE
1825
1992
SODIUM NITRATE
1498
Solvents, flammable, toxic, n.o.s.,

see
SODIUM NITRATE AND

POTASSIUM NITRATE MIXTURE
1499
Stain, see
SODIUM NITRITE
1500
1263
3066
3469
3470
Sodium nitrite and potassium nitrate

mixture, see
1487
STANNIC CHLORIDE,
ANHYDROUS
1827
SODIUM PENTACHLOROPHENATE
2567
STANNIC CHLORIDE
PENTAHYDRATE
2440
SODIUM PERBORATE
MONOHYDRATE
3377
STANNIC PHOSPHIDES
1433
SODIUM PERCHLORATE
1502
Steel swarf, see
2793
SODIUM PERMANGANATE
1503
STIBINE
2676
SODIUM PEROXIDE
1504
STRAW
1327
SODIUM PEROXOBORATE,
ANHYDROUS
3247
Strontium alloys, pyrophoric, see
1383
STRONTIUM ARSENITE
1691
SODIUM PERSULPHATE
1505
STRONTIUM CHLORATE
1506
SODIUM PHOSPHIDE
1432
Strontium dioxide, see
1509
SODIUM PICRAMATE, WETTED,

mass
1349
STRONTIUM NITRATE
1507
STRONTIUM PERCHLORATE
1508
Sodium potassium alloys, see
1422
STRONTIUM PEROXIDE
1509
Sodium selenate, see
2630
STRONTIUM PHOSPHIDE
2013
Sodium selenite, see
2630
2674
STRYCHNINE or STRYCHNINE
SALTS
1692
Sodium silicofluoride, see

SODIUM SULPHIDE,
ANHYDROUS or SODIUM
SULPHIDE, with less than 30%
1385
STYRENE MONOMER,
STABILIZED
2055
Substances liable to spontaneous

combustion, n.o.s., see
SODIUM SULPHIDE, HYDRATED,

1849
2845
2846
3194
3200
SODIUM SUPEROXIDE
2547
2780
SOLIDS CONTAINING
CORROSIVE LIQUID, N.O.S.
3244
PESTICIDE, LIQUID,
less than 23C
Book 1.indb 189
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
than 23C
3013

N.O.S.
1693
3448
TEAR GAS SUBSTANCE, SOLID,

N.O.S.
3014
TELLURIUM COMPOUND, N.O.S.
3284
2195
2779
TELLURIUM HEXAFLUORIDE
2967
TERPENE HYDROCARBONS,
N.O.S.
2319
SULPHAMIC ACID
SULPHUR
1350
TERPINOLENE
2541
SULPHUR CHLORIDES
1828
TETRABROMOETHANE
2504
Sulphur dichloride, see
1828
1,1,2,2-TETRACHLOROETHANE
1702
SULPHUR DIOXIDE
1079
TETRACHLOROETHYLENE
1897
SULPHUR HEXAFLUORIDE
1080
1704
SULPHUR, MOLTEN
TETRAETHYLDITHIOPYROPHOSPHATE
2448
TETRAETHYLENEPENTAMINE
2320
Sulphur monochloride, see
1828
Tetraethyl lead, see
1649
Sulphuretted hydrogen, see
1053
SULPHURIC ACID, with more than

51% acid
TETRAETHYL SILICATE
1292
1830
Tetraethyoxysilane, see
1292
Tetrafluorodichloroethane, see
1958
1,1,1,2-TETRAFLUOROETHANE
3159
TETRAFLUOROETHYLENE,
STABILIZED
1081
SULPHURIC ACID, with not more

than 51% acid
2796
SULPHURIC ACID, FUMING
1831
SULPHURIC ACID, SPENT
1832
Sulphuric and hydrofluoric acid

mixture, see
1786
TETRAFLUOROMETHANE,
1982
SULPHUROUS ACID
1833
1,2,3,6-TETRAHYDROBENZALDEHYDE
2498
SULPHUR TETRAFLUORIDE
2418
TETRAHYDROFURAN
2056
SULPHUR TRIOXIDE, STABILIZED
1829
TETRAHYDROFURFURYLAMINE
2943
SULPHURYL CHLORIDE
1834
Tetrahydro-1, 4-oxazine, see
2054
SULPHURYL FLUORIDE
2191
2698
Talcum with tremolite and/or

actinolite, see
2590
TETRAHYDROPHTHALIC
ANHYDRIDES, with more than
0.05% maleic anhydride
1,2,3,6-TERTRAHYDROPYRIDINE
2410
TARS, LIQUID, including road oils

and cutbacks bitumens
1999
TETRAHYDROTHIOPHENE
2412
2606
3423
Tartar, emetic, see
1551
Tetramethoxysilane, see
TEAR GAS CANDLES
1700
TETRAMETHYLAMMONIUM
HYDROXIDE, SOLID
Book 1.indb 190
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
TETRAMETHYLAMMONIUM
HYDROXIDE SOLUTION
1835
THIOUREA DIOXIDE
3341
Tetramethylene, see
2601
Tin (IV) chloride, anhydrous, see
1827
TETRAMETHYLENE CYANIDE
2205
Tin (IV) chloride pentahydrate, see
2440
Tetramethyl lead, see
1649
TINCTURES, MEDICINAL
1293
TETRAMETHYLSILANE
2749
Tin tetrachloride, see
1827
TETRANITROMETHANE
1510
TITANIUM DISULPHIDE
3174
TETRAPROPYL ORTHOTITANATE
TITANIUM HYDRIDE
2413
1871
TEXTILE WASTE, WET
TITANIUM POWDER, DRY
1857
2546
THALLIUM CHLORATE
2573
TITANIUM POWDER, WETTED,

1352
Thallium (I) chlorate, see
2573
1707
TITANIUM SPONGE GRANULES

or TITANIUM SPONGE POWDERS
2878
THALLIUM COMPOUND, N.O.S.

Thallium (I) nitrate, see
2727
TITANIUM TETRACHLORIDE
1838
THALLIUM NITRATE
2727
TITANIUM TRICHLORIDE
MIXTURE
2869
Thallous chlorate, see
2573
2785
TITANIUM TRICHLORIDE,
PYROPHORIC
2441
4-THIAPENTANAL
Thia-4-pentanal, see
2785
TITANIUM TRICHLORIDE
MIXTURE, PYROPHORIC
2441
THIOACETIC ACID
2436
TNT, wetted, see
1356
2772
Toe puffs, nitrocellulose base, see
1353
TOLUENE
1294
3005
TOLUENE DI-ISOCYANATE
2078
TOLUIDINES, LIQUID
1708
LIQUID, TOXIC
3006
TOLUIDINES, SOLID
3451
Toluol, see
1294
2771
THIOGLYCOL
Toluylene diisocyanate, see
2078
2966
THIOGLYCOLIC ACID
2,4-TOLUYLENEDIAMINE, SOLID
1709
1940
THIOLACTIC ACID
2,4-TOLUYLENEDIAMINE
SOLUTION
3418
2936
THIONYL CHLORIDE
1836
Tolyene diisocyanate, see
2078
THIOPHENE
2414
Tolylethylene, inhibited, see
2618
Thiophenol, see
2337
2474
THIOPHOSPHORYL CHLORIDE
1837

N.O.S., with an LC50 lower than or
equal to 200 ml/m3 and saturated
vapour concentration greater than
or equal to 500 LC50
3381
THIOPHOSGENE
Book 1.indb 191
04/04/2013 15:31
Substance
UN
No
Substance
UN
No

N.O.S., with an LC50 lower than or
or equal to 10 LC50
3382

OXIDISING, N.O.S., with an LC50
lower than or equal to 200 ml/m3
3387

CORROSIVE, N.O.S., with an LC50
3389

OXIDISING, N.O.S., with an LC50
3388

CORROSIVE, N.O.S., with an LC50
3390
3385

3492

WATER-REACTIVE, N.O.S., with
an LC50 lower than or equal to
200 ml/m3 and saturated vapour
concentration greater than or equal
to 500 LC50
3386

or equal to 10 LC50
3493

WATER-REACTIVE, N.O.S., with
an LC50 lower than or equal to
1000 ml/m3 and saturated vapour
concentration greater than or equal
to 10 LC50
3490

FLAMMABLE, N.O.S., with an LC50
3383

3491

FLAMMABLE, N.O.S., with an LC50
3384

or equal to 10 LC50
INORGANIC, N.O.S.
3289


ORGANIC, N.O.S.
2927
3488
TOXIC LIQUID, FLAMMABLE,

ORGANIC, N.O.S.
2929
TOXIC LIQUID, INORGANIC,

N.O.S.
3287

or equal to 10 LC50
3489
TOXIC LIQUID, ORGANIC, N.O.S.
2810
TOXIC LIQUID, OXIDISING,

N.O.S.
3122
TOXIC LIQUID, WATER-REACTIVE,

N.O.S.
3123
Book 1.indb 192
04/04/2013 15:31
Substance
UN
No
Substance
UN
No

INORGANIC, N.O.S.
3290
TRICHLOROACETYL CHLORIDE
2442

ORGANIC, N.O.S.
TRICHLOROBENZENES, LIQUID
2928
2321
TRICHLOROBUTENE
2322
1,1,1-TRICHLOROETHANE
2831
TOXIC SOLID, FLAMMABLE,

ORGANIC, N.O.S.
2930
TRICHLOROETHYLENE
1710
TOXIC SOLID, INORGANIC,

N.O.S.
3288
TRICHLOROISOCYANURIC ACID,
DRY
2468
TOXIC SOLID, SELF-HEATING,

N.O.S.
3124
Trichloronitromethane, see
1580
TOXIC SOLID, ORGANIC, N.O.S.
2811
TRICHLOROSILANE
1295
2468
TOXIC SOLID, OXIDISING, N.O.S.
3086
1,3,5-Trichloro-s-triazine-2,4,6trione, see
TOXIC SOLID, WATER-REACTIVE,

N.O.S.
3125
2,4,6-Trichloro-1,3,5-triazine, see
2670
TOXINS, EXTRACTED FROM

LIVING SOURCES, LIQUID, N.O.S.
3172
TRICRESYL PHOSPHATE, with

more than 3% ortho isomer
2574
TOXINS, EXTRACTED FROM

LIVING SOURCES, SOLID, N.O.S.
3462
TRIETHYLAMINE
1296
Triethyl borate, see
1176
Tremolite, see
2590
TRIETHYLENETETRAMINE
2259
TRIALLYLAMINE
2610
Triethyl orthoformate, see
2524
TRIALLYL BORATE
2609
TRIETHYL PHOSPHITE
2323
TRIAZINE PESTICIDE, LIQUID

less than 23C
2764
TRIFLUOROACETIC ACID
2699
TRIFLUOROACETYL CHLORIDE
3057
Trifluorobromoemethane, see
1009
Trifluorochloroethane, see
1983
TRIFLUOROCHLOROETHYLENE,
STABILIZED
1082
Trifluorochloromethane, see
1022
TRIAZINE PESTICIDE, LIQUID

23C or above
2997

TOXIC
2998
TRIAZINE PESTICIDE, SOLID,

TOXIC
2763
1,1,1-TRIFLUOROETHANE
2035
Tribromoborane, see
2692
TRIFLUOROMETHANE
1984
TRIBUTYLAMINE
2542
3136
TRIBUTYLPHOSPHANE
3254
TRIFLUOROMETHANE,
REFRIGERATED LIQUID
Trichloroacetaldehyde, see
2075
2942
2948
TRIISOBUTYLENE
2324
TRIISOPROPYL BORATE
2616
TRIMETHYLACETYL CHLORIDE
2438
1839
SOLUTION
2564
Trichloroaceticaldehyde, see
2075
Book 1.indb 193
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
TRIMETHYLAMINE,
ANHYDROUS
1083
1356
50% trimethylamine, by mass
1297
TRINITROTOLUENE (TNT),
water by mass
TRIPROPYLAMINE
2260
1,3,5-TRIMETHYLBENZENE
TRIPROPYLENE
2325
2057
TRIMETHYL BORATE
2416
Tropilidene, see
2603
TRIMETHYLCHLOROSILANE
1298
TRIS-(1-AZIRIDINYL) PHOSPHINE
OXIDE SOLUTION
2501
TRIMETHYLCYCLOHEXYLAMINE
2326
TUNGSTEN HEXAFLUORIDE
2196
Trimethylene chlorobromide, see
2688
TURPENTINE
1299
TRIMETHYLHEXAMETHYLENEDIAMINES
2327
TURPENTINE SUBSTITUTE
1300
TRIMETHYLHEXAMETHYLENE
DIISOCYANATE
UNDECANE
2328
2330
UREA HYDROGEN PEROXIDE
1511
2,4,4-Trimethylpentene-1, see
2050
3370
2,4,4-Trimethylpentene-2, see
2050
UREA NITRATE, WETTED, with

TRIMETHYL PHOSPHITE
2329
UREA NITRATE, WETTED, with

1357
TRINITROBENZENE, WETTED,
mass
3367
Valeral, see
2058
VALERALDEHYDE
2058
n-Valeraldehyde, see
2058
Valeric aldehyde, see
2058
VALERYL CHLORIDE
2502
VANADIUM COMPOUNDS,
N.O.S.
3285
Vanadium (IV) oxide suphate, see
2931
Vanadium oxysulphate, see
2931
VANADIUM OXYTRICHLORIDE
2443
VANADIUM PENTOXIDE,
non-fused form
2862
VANADIUM TETRACHLORIDE
2444
VANADIUM TRICHLORIDE
2475
VANADYL SULPHATE
2931
Varnish, see
1263
3066
3469
3470
TRINITROBENZENE, WETTED,
mass
1354
TRINITROBENZOIC ACID,
water by mass
3368
TRINITROBENZOIC ACID,
water by mass
1355
TRINITROCHLOROBENZENE,
water by mass
3365
TRINITROPHENOL, WETTED, with

3364
TRINITROPHENOL, (PICRIC ACID)

water by mass
1344
TRINITROTOLUENE, WETTED
mass
3366
Book 1.indb 194
04/04/2013 15:31
Substance
UN
No
Substance
UN
No
VEHICLE, FUEL CELL,

FLAMMABLE GAS POWERED
3166

N.O.S.
3134
VEHICLE, FUEL CELL,

FLAMMABLE LIQUID POWERED
3166
3135
VEHICLE, FLAMMABLE GAS

POWERED
3166
White arsenic, see
1561
VEHICLE, FLAMMABLE LIQUID

POWERED
3166
WHITE ASBESTOS (chrysotile,

actinolite, anthophyllite, tremolite)
2590
Viliaumite, see
1690
White spirit, see
1300
VINYL ACETATE, STABILIZED
1301
WOOD PRESERVATIVES, LIQUID
1306
Vinylbenzene, see
2055
WOOL WASTE, WET
1387
VINYL BROMIDE, STABILIZED
1085
XANTHATES
3342
VINYL BUTYRATE, STABILIZED
2838
XENON
2036
VINYL CHLORIDE, STABILIZED
1086
XENON, REFRIGERATED LIQUID
2591
VINYL CHLOROACETATE
2589
XYLENES
1307
VINYL ETHYL ETHER, STABILIZED
1302
XYLENOLS, LIQUID
3430
VINYL FLUORIDE, STABILIZED
1860
XYLENOLS, SOLID
2261
VINYLIDENE CHLORIDE,
STABILIZED
1303
XYLIDINES, LIQUID
1711
XYLIDINES, SOLID
3452
VINYL ISOBUTYL ETHER,

STABILIZED
1304
Xylols, see
1307
XYLYL BROMIDE, LIQUID
1701
VINYL METHYL ETHER,

STABILIZED
1087
XYLYL BROMIDE, SOLID
3417
ZINC AMMONIUM NITRATE
1512
ZINC ARSENATE
1712
ZINC ARSENITE
1712
ZINC ARSENATE AND ZINC

ARSENITE MIXTURE
1712
ZINC ASHES
1435
Zinc bisulphite solution, see
2693
ZINC BROMATE
2469
ZINC CHLORATE
1513
ZINC CHLORIDE, ANHYDROUS
2331
ZINC CHLORIDE SOLUTION
1840
VINYLPYRIDINES, STABILIZED
3073
VINYLTOLUENES, STABILIZED
2618
VINYLTRICHLOROSILANE
1305
CORROSIVE, N.O.S.
3129
WATER-REACTIVE LIQUID, N.O.S.
3148
TOXIC, N.O.S.
3130
CORROSIVE, N.O.S.
3131
FLAMMABLE, N.O.S.
3132
WATER-REACTIVE SOLID, N.O.S.
2813
ZINC CYANIDE
1713
3133
ZINC DITHIONITE
1931
OXIDISING, N.O.S.
Book 1.indb 195
04/04/2013 15:31
Substance
UN
No
ZINC DUST
1436
ZINC FLUOROSILICATE
2855
Zinc hexafluorosilicate, see
2855
ZINC HYDROSULPHITE
1931
ZINC NITRATE
1514
ZINC PERMANGANATE
1515
ZINC PEROXIDE
1516
ZINC PHOSPHIDE
1714
ZINC POWDER
1436
ZINC RESINATE
2714
Zinc selenate, see
2630
Zinc selenite, see
2630
Zinc silicofluoride, see
2855
ZIRCONIUM HYDRIDE
1437
ZIRCONIUM, DRY, coiled wire,

finished metal sheets, strip (thinner
than 254 microns but not thinner
than 18 microns)
2858
ZIRCONIUM, DRY, finished sheets,

strip or coiled wire
2009
ZIRCONIUM NITRATE
2728
ZIRCONIUM PICRAMATE,
water by mass
1517
ZIRCONIUM POWDER, DRY
2008
ZIRCONIUM POWDER, WETTED,

1358
ZIRCONIUM SCRAP
1932
FLAMMABLE LIQUID
1308
ZIRCONIUM TETRACHLORIDE
2503
Book 1.indb 196
04/04/2013 15:31
Acknowledgements
NCEC is indebted to all who have helped with the provision of information,
expertise and validation to assist with the production of this edition and
previous editions of this publication, in particular:
The Chief Fire and Rescue Adviser section at the Department for
Communities and Local Government (CLG)
Dennis Ricketts (formerly of CLG)
Association of Chief Police Officers
British Chemical Distributors Trade Association
British Compressed Gas Association
British Safety Industry Federation
Bureau Veritas
Chemical Industries Association
Chief Fire Officers Association
Department for Transport
Environment Agency
Fire Brigades Union
Fire Service College
Freight Transport Association
Greater Manchester Fire and Rescue Service
HazmatLINK Ltd
Health & Safety Executive
Her Majestys Fire Service Inspectorate for Scotland
Independent Consultant (Bob Cumberland)
Lancashire Fire and Rescue Service
Local Government Association
London Fire & Emergency Planning Authority
acknowledgements 197
Book 1.indb 197
04/04/2013 15:31
Liquefied Petroleum Gas Association

Ministry of Defence
Network Rail
Retained Firefighters Union
Road Haulage Association
United Kingdom Petroleum Industry
Association
United Utilities plc
Book 1.indb 198
04/04/2013 15:31
Dangerous Goods Emergency Action Code List 2013
www.tso.co.uk
8175 Dangerous Goods Cover v1_1.indd 1
25/02/2013 16:10

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Dangerous Goods Emergency Action Code List 2013

8175 Dangerous Goods Cover v1_1.indd 1

Published by TSO (The Stationery Office) and available from:

This document supersedes the Dangerous Goods Emergency

Duty holders are required to use this document for the

The assignment of emergency action codes and additional

This document is effective immediately in connection with the

Sections 4 and 5 of this Document will continue to be revised in

Section 2: Displaying Emergency Action Codes

Assigning Emergency Action Codes

Assigning Emergency Action Codes to multi-loads

E Public Safety Hazard

Section 4: Numerical List of Dangerous Goods

Explanation of headings in Numerical List

Column 1: United Nations (UN) Number

Column 3: Emergency Action Code (EAC)

Column 4: Advice on Additional Personal Protection (APP)

Column 6: Hazard Identification Number (HIN)

List of Dangerous Goods

Section 5: Alphabetical List of Dangerous Goods

Emergency Action codes (EACs), also known as Hazchem codes,

This document shall not be used for the purposes of markings on

This document contains all items listed by the United Nations

Introduction to the emergency action codes 7

For internal transport operations in Great Britain there are two

must display the Emergency Action (Hazchem) Code

Number (HIN) (see paragraphs 4.1.134.1.18).

Examples of these two systems are shown below. The requirements

Hazard Warning Panel

RID/ADR (Hazard Identification Number) orange coloured plate and placard

8 dangerous goods emergency action code list 2013

CLASS 1 Explosive substances or articles

Division 1.1, 1.2

CLASS 3 Flammable liquids

Introduction to the emergency action codes 9

CLASS 4.1 Flammable solids, self-reactive substances and

CLASS 4.2 Substances liable to spontaneous combustion

CLASS 5.1 Oxidising substances

CLASS 5.2 Organic peroxides

10 dangerous goods emergency action code list 2013

CLASS 6.1 Toxic substances

CLASS 6.2 Infectious substances

CLASS 7 Radioactive material

CLASS 8 Corrosive substance

CLASS 9 Miscellaneous dangerous substances and articles

dangerous goods emergency action code list 2009 11

Under the requirements of the 2011 and 2013 editions of ADR

Environmentally hazardous substance mark

Mark for elevated temperature substances

Dangerous goods packed in limited quantities

THIS UNIT IS UNDER FUMIGATION

Fumigation warning sign

12 dangerous goods emergency action code list 2013

Assigning Emergency Action Codes

Substances in Class 7, i.e. radioactive material, have not been

ADR 5.3.2.1.4 and RID 5.3.2.1.1 and 5.3.2.1.2 stipulate that

The prefix l will sometimes appear before the EAC in the

Displaying emergency action codes 13

Assigning Emergency Action Codes

The following procedure shall be used to assign EACs when each