Energy Conversion and Management: Mohamed Y.E. Selim
Energy Conversion and Management: Mohamed Y.E. Selim
Energy Conversion and Management: Mohamed Y.E. Selim
Reducing the viscosity of Jojoba Methyl Ester diesel fuel and effects on diesel
engine performance and roughness
Mohamed Y.E. Selim *
Mech. Eng. Dept., UAE University, Al-Ain, Abu Dhabi 17555, United Arab Emirates
a r t i c l e
i n f o
Article history:
Received 23 October 2007
Received in revised form 8 August 2008
Accepted 14 March 2009
Available online 16 April 2009
Keywords:
Jojoba Methyl Ester (JME)
Diesel engine
Viscosity
Performance
a b s t r a c t
An experimental investigation has been carried out to test two approaches to reduce the viscosity of the
Jojoba Methyl Ester (JME) diesel fuel. The rst approach is the heating of the fuel to two temperatures of
50 and 70 C as compared to the base ambient temperature and to diesel fuel too. The second approach is
adding one chemical which is considered by its own as alternative and renewable fuel which is Diethyl
Ether (DEE). The viscosity has been reduced by both methods to close to diesel values. The performance of
a diesel engine using those fuels has been tested in a variable compression research engine Ricardo E6
with the engine speed constant at 1200 rpm. The measured parameters included the exhaust gas temperature, the ignition delay period, the maximum pressure rise rate, maximum pressure, and indicated mean
effective pressure and maximum heat release rate. The engine performance is presented and the effects of
both approaches are scrutinized.
2009 Elsevier Ltd. All rights reserved.
1. Introduction
In addition to diesels inherent energy efciency, use of renewable fuels can reduce petroleum consumption even further [1]. Diesel drivers have the option to ll up with blends of biodiesel a
domestically produced renewable fuel. Biodiesel fuels are derived
from a variety of biomass sources such as vegetable oil, animal
fat, and cooking oil. Biodiesel is made through a chemical process
called transesterication, where glycerin is separated from methyl
esters derived from the fat or oil. The methyl ester product is what
is known as biodiesel and must meet the standards set forth by the
American Society of Testing and Materials (ASTM) for fuel grade
biodiesel, specically ASTM D6751 (or EN14214 in Europe) [2].
Technically, any hydrocarbon distillate material derived from
biomass that meets the appropriate ASTM specication can be dened as diesel, or as biodiesel. Feedstocks for diesel fuels derived
from biomass include soybean [3], rape seed [46], and waste
cooking oils, along with animal fats [7]. Vegetable oils can be used
directly as diesel fuels, but their properties such as high viscosity
and low volatility cause durability problems in fuel systems [2,3,5].
Various processes convert biomass to diesel fuels. Among these
is transesterication of triglycerides, which produces esters. The
resulting fuel ts into the denition of biodiesel. Other processes
include hydrothermal processing, hydroprocessing, and indirect
liquefaction. These processes yield distillates that are not esters.
Biodiesel is dened as the mono alkyl esters of long-carbonchain fatty acids derived from renewable lipid feedstocks. It is produced by transesterication of triglycerides (fatty acids) contained
in oil-rich biomass and animal fats. The triglycerides can be converted to esters that have properties more compatible with petroleum diesel fuel. In the base-catalyzed transesterication process,
the triglycerides are reacted with an alcohol, either methanol or
ethanol, in the presence of an alkaline catalyst, normally potassium
hydroxide. This reaction forms methyl or ethyl esters, and glycerin
is a byproduct.
Use of biodiesel can also result in some reduction in fuel economy depending on the blend due to biodiesels slightly lower energy content. The primary concern is one of quality assurance.
While many people can produce biodiesel, the production of biodiesel that meets the ASTM standard is more difcult. As the percentage of biodiesel in the blend increases, the sensitivity to
quality of the biodiesel increases proportionately [8,9].
Of the several biodeisel sources that started to appear in the literature by the current author is Jojoba oils [1012]. It appears to be
rst published as a fuel in shock tube experiments [12], followed
by another article about diesel engine burning this fuel [11] and
it has been then used in a dual fuel engine [10]. Another article
has been also published from the same laboratory [13]. Jojoba oil
comes from very promising plant that lives for more than one hundred and fty years and has unique properties. This is due to many
factors [13] such as its high contents of oil per seed, its molecules
contains a carbon chain of 2022 carbon atoms and its chemical
stability. The plant itself is very promising for cultivation in hot
weather as it resists salinity and dryness. It gives acceptable
Table 1
Engine specications.
60
2
40
20
Model
Ricardo E6
Type
Bore stroke (mm)
Cycle
Compression ratio
Maximum power (kW)
Maximum speed (rpm)
Injection timing
production per acre and is currently used for cosmetics applications. The properties of Jojoba Methyl Ester (JME) are unique as
will be shown later. However, so far only the viscosity needs to
be reduced so that it will be accepted by fuel properties standards,
hence it should be reduced from more than 19 cSt. to lower than
7 cSt. All previous publications about this fuel were for high viscosity version and no work has been reported about the long term effects of the high fuel viscosity. The current high viscosity affects
negatively the injection, atomization and mixing process of the fuel
with air.
Atomization is the breakup of bulk liquid jets into small droplets by using an atomizer. Adequate atomization enhances mixing
and complete combustion in a direct injection (DI) engine and
therefore is an important factor in engine emission and efciency.
According to Lefebvre [14], the physical properties of a liquid fuel
that affect its atomization in a diesel engine are viscosity, density,
and surface tension. For a DI diesel injector at xed operating condition, use of fuel with higher viscosity delays atomization by suppressing the instabilities required for the fuel jet to breakup. An
increase in fuel density adversely affects atomization, whereas
higher fuel surface tension opposes the formation of droplets from
the liquid fuel [14]. Hence a suitable diesel fuel in a DI engine requires balanced values of viscosity, density, and surface tension,
for a given atomizer to function properly.
Therefore the objectives of the present work are to reduce the
viscosity of the Jojoba Methyl Ester so that its properties will be
acceptable by fuel properties standards and it is acceptable as a
good fuel for diesel engines. The reduction of viscosity will be carried out by different approaches to match the required viscosities
for diesel fuels. Two approaches are used here of heating the JME
fuel to different temperatures and the second is by adding very
low viscosity renewable fuel to the JME. The effect of using the
new reduced-viscosity fuel on a real diesel engine will also be
presented.
Pressure, bar
1782
-2
Combustion pressure
Pressure rise rate
0
-4
-40
-20
20
40
1783
has been placed inside the fuel injection pump to measure the temperature of liquid fuel inside the pump tray. Three temperatures
have been tested here which are the atmospheric temperature of
25 C, 50 C, and 70 C. The temperatures of 50 and 70 C are easily
achieved by the water cooling system in the vehicle. The fuel is
heated here by passing it through an electric heater compartment
connected to the fuel line.
The second method of reducing the viscosity of the JME is by
mixing it with a very low viscosity renewable fuel which is the
Diethyl Ether (DEE). The viscosity of DEE is about 0.23 cSt at
40 C compared to 19.2 cSt for JME. The DEE has been selected
on purpose for its favorable features. It has a renewable origin, outstanding cetane number, reasonable energy density, very low viscosity [18,19]. It is also a liquid at ambient conditions. Table 2
shows the properties of DEE as compared to JME fuel. Three different blends have been tested here which are: 5%, 10%, and 15% DEE
with JME. The results of both approaches are illustrated in Fig. 3.
60
Pressure, bar
40
30
20
10
Injection
TDC
0
-40
-20
20
40
Table 2
Fuels properties.
Test
JME
DEE
0.866
19.2
47.38
63.5
87
13
383
NA
0.713
0.23
33.9
>125
C2H5OC2H5
34.4
160
18
16
14
Viscosity, cP
50
Diesel, Load=14.6 Nm
Motoring
Combustion
12
10
8
6
4
2
Two methods have been tested here in the current work to reduce the viscosity of the JME from over 19 to lower than 7 cSt.
The rst method is by direct heating of the liquid fuel just before it goes to the fuel injection pump [3,5]. One thermocouple
D
ie
JM
E@ sel
25
JM
oC
E
@
40
JM
o
E@ C
55
JM
oC
E
@
70
oC
10
0%
D
JM
EE
E+
5%
JM
D
EE
E+
10
%
JM
D
EE
E+
15
%
D
EE
1784
Also the effect of adding the DEE to the JME may be shown in
Fig. 3. The selection of the DEE is made because of its very low viscosity and its renewable sources. It viscosity is about 0.18 cP and it
is mixed with JME at 5%, 10%, and 15%. The viscosity of the blend is
shown as compared to the heating process and diesel fuel too. It
may be seen that adding 5% DEE caused the viscosity to drop from
16.6 cP to 11.3 cP. Adding 10% of DEE reduced it to 7.7 cP and 15%
of DEE decreased it to 5.3 cP. Both 10% and 15% of DEE can then reduce the viscosity of the JME to the acceptable range.
The tested methods of changing the viscosity have proven to be
successful and reduced the viscosity of JME to acceptable range for
diesel fuels. It has been decided then that those fuels with reducedviscosity must be tested in a real diesel engine and the effect of the
design and operating parameters on the performance must be
made clear.
3.2. Effects on exhaust temperature
The effect of adding DEE and heating JME on the exhaust gas
temperature of the diesel engine may be seen in Figs. 4 and 5
Exhaust temperature, o C
500
400
300
200
100
0
100
200
300
400
500
The effects of adding DEE to JME and heating the JME may be
seen in Figs. 6 and 7, respectively. Fig. 6 depicts the effects of adding DEE to JME at 5%, 10%, and 15%. It may be seen that as the load
is increased the ignition delay period is decreased for all cases. This
is due to the higher amount of fuel injected and higher cycle temperatures that reduces the ignition delay period, i.e. the fuel becomes easier to self-ignite. It may be also noticed from Fig. 6 that
the JME has lower ignition delay period than diesel fuel as it has
higher cetane number or it is easier to self-ignite. Adding more
DEE to JME causes the ignition delay period to reduce more as
the DEE has much higher cetane number than JME and diesel
and it is much easier to self-ignite so adding up to 15% of it helps
burning the JME to ignite faster once injected in the compression
stroke. Also adding more DEE caused the viscosity of JME to reduce
and the JME fuel becomes more readily mixed with hot air and
achieve the self-ignition temperature faster.
Fig. 7 shows the effect of heating the JME to 50 and 70 C as
compared to JME at room temperature and diesel fuel. it may be
50
500
40
o
JME - 50 C
o
JME - 70 C
400
Exhaust temperature, o C
300
200
30
20
10
100
0
100
200
300
400
500
100
200
300
400
500
1785
50
Effect of heating on ID
Diesel fuel
JME - 25oC
JME - 50o C
40
JME - 70o C
30
seen from the gure that heating the JME to 50 then 70 C caused
the ignition delay period to reduce as the viscosity becomes smaller and the JME fuel mixes faster and better with hot air to achieve
the self-ignition temperature and self-ignite faster. The ignition delay period is then decreased. Therefore it is advantageous to heat it
as the delay period is reduced.
3.4. Effects on maximum pressure rise rate and maximum pressure
20
10
0
0
100
200
300
400
500
dP/d, bar/deg.
68
JME - 50C
64
JME - 70C
60
56
52
0
0
100
200
300
400
500
100
200
300
400
500
Fig. 8. Effect of adding DEE to JME the maximum pressure rise rate.
8
Effect of heating on (dP/d )max
Diesel fuel
JME - 25oC
JME - 50oC
Maximum pressure, bar
6
dP/d , bar/deg.
JME - 70oC
68
64
60
56
52
0
0
100
200
300
400
500
100
200
300
400
500
1786
injected fuel with less pressure rise rates. The effects of heating the
JME to 50 and 70 C on the maximum pressure rise rate may be
seen in Fig. 9. It ma y noticed that the maximum pressure for the
engine using JME at 25 C is less than that for diesel fuel. However,
heating the JME to higher temperatures did not change much the
maximum pressure rise rate. This is considered as good enough result as heating the JME already decreased the viscosity and here
did not change the combustion noise.
60
Figs. 10 and 11 show the effects of heating JME and adding DEE
on the maximum combustion pressure of the cycle. It may be noticed from Fig. 10 that heating the JME to higher temperatures of
50 and 70 C did not change the maximum pressure as the pressure
rise rate (above) did not change. The pressure rise rate did not
change so the maximum pressure would occur at similar crank angles around the top dead center with the same values. Adding 5%,
10% or 15% DEE to JME did not change also the maximum pressure
60
60
40
40
30
P, bar
P, bar
40
P, bar
50
20
20
Diesel
Torque=16.4 Nm
10
0
-40
-20
20
JME + 5% DEE
Torque=17.3 Nm
40
-40
20
JME - 70 C
Torque=17.2 Nm
-20
20
-40
40
(c)
60
20
40
(a)
-20
(e)
60
60
40
40
P, bar
P, bar
40
P, bar
50
30
20
20
0
0
20
40
-40
-20
20
40
-40
-20
20
(b)
(d)
(f)
60
40
P, bar
-20
JME - 50 C
Torque=18 Nm
10
-40
20
JME, ambient
Torque=16.5 Nm
20
JME + 15% DEE
Torque=16.7 Nm
0
-40
-20
20
40
(g)
Fig. 12. Typical pressurecrank angle diagram for all cases studied.
40
1787
40
20
Effect of heating on (HRR)max
Diesel fuel
JME, 25C
JME, 50C
JME, 70C
0
0
100
200
300
400
500
(HRR)max, J/deg.
60
40
20
600
Indicated mean effective pressure, kPa
(HRR)max, J/deg.
60
560
JME - 70C
520
480
440
100
200
300
400
500
100
200
300
400
500
1788
5. Adding DEE to the JME caused the maximum pressure rise rate
to decrease slightly than pure JME or pure diesel fuel.
6. Heating the JME did not change much the maximum pressure
rise rate.
7. The maximum combustion pressure slightly increased for
heated JME or when DEE is added to JME.
8. Heating the JME increased the maximum HRR at all load ranges
tested while adding DEE affected the (HRR)max in different ways
according to the load output.
9. Adding DEE to the Jojoba Methyl Ester or heating it resulted in
an increase in the indicated mean effective pressure or reducing
the mechanical efciency.
600
Effect of adding DEE imep
Diesel fuel
JME - 25C
JME + 5% DEE
JME + 10% DEE
JME + 15% DEE
560
520
480
References
440
0
100
200
300
400
500
4. Conclusions
From the experimental study carried out here, the following
conclusions may be summarized:
1. Heating the Jojoba Methyl Ester fuel with its high viscosity
helped to reduce the viscosity to its acceptable range for diesel
fuel.
2. Adding very low viscosity renewable oil such Diethyl Ether
helped the JME to reduce its viscosity to the acceptable range.
3. Heating the JME or adding DEE did not change the exhaust gas
temperature or other cycle temperatures.
4. Heating the JME or adding DEE reduced the ignition delay period for the JME.
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