Lead Acid Battery
Lead Acid Battery
Lead Acid Battery
1. IDENTIFICATION
Product Name: Lead Acid Battery
Synonyms: SLI Battery
NOTE: The Johnson Controls sealed cell/battery is considered an article as defined by 29 CFR 1910.1200 (OSHA Hazard
Communication Standard). The information contained in this SDS is supplied at the customers request for
information only.
2. HAZARD(S) IDENTIFICATION
Health
Environmental
Category 2
Aquatic
Chronic 1
Acute Toxicity
(Oral/Dermal/Inhalation
Category 4
Aquatic
Acute 1
Skin Corrosion/Irritation
Category 1A
Eye Damage
Category 1
Reproductive
Category 1A
Carcinogenicity (lead)
Category 2A
Category 1A
Category 1A
Physical
Explosive Chemical
Division 1.3
Label Elements:
Health
Environmental
Hazard Statements
DANGER!
Causes severe skin burns and eye damage. Causes
serious eye damage.
May damage fertility or the unborn child if
ingested or inhaled.
May cause cancer if ingested or inhaled.
Causes damage to central nervous system, blood
and kidneys through prolonged or repeated
exposure.
Lead Acid Battery
Version #: 01 Issue Date: 04/01/2015
Physical
Precautionary Statements
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Wear protective gloves/protective clothing, eye protection/face protection.
Avoid breathing dust/fume/gas/mist/vapors/spray.
Use only outdoors or in a well-ventilated area.
Causes skin irritation, serious eye damage.
Contact with internal components may cause irritation or severe burns. Avoid
contact with internal acid.
Irritating to eyes, respiratory system, and skin.
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CAS No.:
7439-92-1
1309-60-0
7664-93-9
7446-14-2
% by Wt:
34
31
34
<1
Stop flow of material, contain/absorb small spills with dry sand, earth, and vermiculite. Do not use
combustible materials. If possible, carefully neutralize spilled electrolyte with soda ash, sodium
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Taken if Material is
Released or Spilled
Waste Disposal
Method
bicarbonate, lime, etc. Wear acid-resistant clothing, boots, gloves, and face shield. Do not allow discharge
of un-neutralized acid to sewer. Acid must be managed in accordance with approved local, state, and
federal requirements. Consult state environmental agency and/or federal EPA.
Dispose of as a hazardous waste. Dispose of in accordance with applicable local, state and federal
regulations.
Storage
Charging:
Other
Unless involved in recycling operations, do not breach the casing or empty the contents of the battery.
Handle carefully and avoid tipping, which may allow electrolyte leakage. There may be increasing risk of
electric shock from strings of connected batteries. Keep containers tightly closed when not in use. If
battery case is broken, avoid contact with internal components. Keep vent caps on and cover terminals to
prevent short circuits. Place cardboard between layers of stacked automotive batteries to avoid damage
and short circuits. Keep away from combustible materials, organic chemicals, reducing substances,
metals, strong oxidizers and water. Use banding or stretch wrap to secure items for shipping.
Store batteries under roof in cool, dry, well-ventilated areas separated from incompatible materials and
from activities that may create flames, spark, or heat. Store on smooth, impervious surfaces provided with
measures for liquid containment in the event of electrolyte spills. Keep away from metallic objects that
could bridge the terminals on a battery and create a dangerous short-circuit. Room ventilation is required
for batteries utilized for standby power generation. Never recharge batteries in an unventilated, enclosed
space.
There is a possible risk of electric shock from charging equipment and from strings of series connected
batteries, whether or not being charged. Shut-off power to chargers whenever not in use and before
detachment of any circuit connections. Batteries being charged will generate and release flammable
hydrogen gas. Charging space should be ventilated. Keep battery vent caps in position. Prohibit smoking
and avoid creation of flames and sparks nearby. Wear face and eye protection when near batteries being
charged.
Follow Manufacturers Recommendations regarding maximum recommended currents and operating
temperature range. Do not overcharge beyond the recommended upper charging voltage limit. Applying
pressure or deforming the battery may lead to disassembly followed by eye, skin and throat irritation.
Value
0.05 mg/m
0.05 mg/m
0.05 mg/m
Value
1 mg/m
Type
TWA
TWA
TWA
TWA
Value
0.05 mg/m
0.05 mg/m
0.05 mg/m
0.2 mg/m
Type
TWA
Value
0.05 mg/m
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Form
Thoracic Fractions
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Lead Oxide
Sulfuric Acid
1309-60-0
7664-93-9
Value
300 g/l
300 g/l
300 g/l
TWA
TWA
Determinant
Lead
Lead
Lead
0.05 mg/m
1 mg/m
Specimen
Blood
Blood
Blood
Sampling Time
*
*
*
Melting Point
Specific Gravity
(H2O = 1)
Flash Point
Evaporation Rate
(Butyl Acetate = 1)
Vapor Pressure
(mm Hg @ 20 C)
Manufactured article; no apparent odor. Electrolyte is a clear liquid with a sharp, penetrating,
pungent odor.
Not applicable.
Not applicable
Not applicable unless individual components exposed.
Battery Electrolyte (Acid) - 230 - 233.6 F (110 - 112 C)
Lead - 3191 F (1755 C)
Lead - 621.32 F (327.4 C)
1.215 to 1.350
498.2 F (259.0 C) Hydrogen
<1
Battery Electrolyte (Acid) 11.7
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Flammability
Upper/lower flammability
or explosive limits
Vapor Pressure
Vapor Density
Relative Density
Solubility
% Volatile by Weight
Partition coefficient
(n-octanol/water)
Auto-ignition temperature
Decomposition
temperature
Viscosity
Hydrogen
Not applicable.
3.4 (Air = 1) Battery Electrolyte (Acid)
1.21 - 1.3 Battery Electrolyte (Acid)
Lead and Lead dioxide are not soluble.
100 % Battery Electrolyte (Acid).
Not applicable unless individual components exposed.
Not applicable
1076 F (580 C) Hydrogen.
Not applicable
Not applicable
Hazardous Decomposition
Products
Hazardous Polymerization
Arsenic compounds: strong oxidizers; bromine azide. NOTE: hydrogen gas can react with inorganic
arsenic to form the highly toxic gas arsine
Electrolyte: Sulfur trioxide, carbon monoxide, sulfuric acid mist, sulfur dioxide, hydrogen sulfide.
Lead compounds: Temperatures above the melting point are likely to produce toxic metal fume,
vapor, or dust; contact with strong acid or base or presence of nascent hydrogen may generate
highly toxic arsine gas.
Will not occur.
Skin Contact
Sulfuric Acid: Breathing of sulfuric acid vapors or mists may cause severe respiratory irritation.
Lead Compounds: Inhalation of lead dust or fumes may cause irritation of upper respiratory tract
and lungs.
EXPOSURE IS NOT EXPECTED FOR PRODUCT UNDER NORMAL CONDITIONS OF USE.
Sulfuric Acid: Severe irritation, burns and ulceration.
Lead Compounds: Not absorbed through the skin.
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Skin Absorption
Eye Contact
Ingestion
Acute Effects
Chronic Effects
Sulfuric Acid: Possible erosion of tooth enamel, inflammation of nose, throat & bronchial tubes.
Lead Compounds: Anemia; neuropathy, particularly of the motor nerves, with wrist drop; kidney
damage; reproductive changes in males and females. Repeated exposure to lead and lead
compounds in the workplace may result in nervous system toxicity. Some toxicologists report
abnormal conduction velocities in persons with blood lead levels of 50 g/100 ml or higher. Heavy
lead exposure may result in central nervous system damage, encephalopathy and damage to the
blood-forming (hematopoietic) tissues.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE
Overexposure to sulfuric acid mist may cause lung damage and aggravate pulmonary conditions. Contact of sulfuric acid with skin
may aggravate diseases such as eczema and contact dermatitis. Lead and its compounds can aggravate some forms of kidney,
liver and neurologic diseases.
ADDITIONAL HEALTH DATA
All heavy metals, including the hazardous ingredients in this product, are taken into the body primarily by inhalation and
ingestion. Most inhalation problems can be avoided by adequate precautions such as ventilation and respiratory protection
covered in Section 8. Follow good personal hygiene to avoid inhalation and ingestion: wash hands, face, neck and arms
thoroughly before eating, smoking or leaving the work site. Keep contaminated clothing out of non-contaminated areas, or wear
cover clothing when in such areas. Restrict the use and presence of food, tobacco and cosmetics to non-contaminated areas.
Work clothes and work equipment used in contaminated areas must remain in designated areas and never taken home or
laundered with personal non-contaminated clothing. This product is intended for industrial use only and should be isolated from
children and their environment.
The 19th Amendment to EC Directive 67/548/EEC classified lead compounds, but not lead in metal form, as possibly toxic to
reproduction. Risk phrase 61: May cause harm to the unborn child, applies to lead compounds, especially soluble forms.
Toxicological Data
Constituents
Sulfuric Acid (CAS 7664-93-9)
Acute
Oral
LD50
Species
Test Results
Rat
2140 mg/kg
CARCINOGENICITY
Sulfuric Acid: The International Agency for Research on Cancer (IARC) has classified "strong inorganic acid mist containing sulfuric
acid" as a Category I carcinogen, a substance that is carcinogenic to humans. This classification does not apply to liquid forms of
sulfuric acid or sulfuric acid solutions contained within a battery. Inorganic acid mist (sulfuric acid mist) is not generated under
normal use of this product. Misuse of the product, such as overcharging, may result in the generation of sulfuric acid mist.
Lead Acid Battery
Version #: 01 Issue Date: 04/01/2015
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Lead Compounds: Lead is listed as a Group 2A- carcinogen, likely in animals at extreme doses. Per the guidance found in OSHA 29
CFR 1910.1200 Appendix F, this is approximately equivalent to GHS Category 1A. Proof of carcinogenicity in humans is lacking at
present.
IARC Monographs. Overall Evaluation of Carcinogenicity
Lead (CAS 7439-92-1)
2A Probably carcinogenic to humans.
Lead oxide (CAS 1309-60-0)
2A Probably carcinogenic to humans.
Lead sulfate (CAS 7446-14-2)
2A Probably carcinogenic to humans.
NTP Report on Carcinogens
Lead oxide (CAS 1309-60-0)
Reasonably Anticipated to be a Human Carcinogen.
Lead sulfate (CAS 7446-14-2)
Reasonably Anticipated to be a Human Carcinogen.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
Reproductive toxicity
Specific target organ
toxicity single exposure
Specific target organ
toxicity repeated exposure
Aspiration hazard
Lead: May cause damage to organs (blood, central nervous system) through prolonged or
repeated exposure.
Not classified.
Environmental toxicity
Sulfuric Acid
Lead
Additional Information
Lead is very persistent in soil and sediments. No data on environmental degradation. Mobility of
metallic lead between ecological compartments is slow. Bioaccumulation of lead occurs in aquatic
and terrestrial animals and plants but little bioaccumulation occurs through the food chain. Most
studies include lead compounds and not elemental lead
Aquatic Toxicity:
24-hr LC50, freshwater fish (Brachydanio rerio): 82 mg/L
96 hr- LOEC, freshwater fish (Cyprinus carpio): 22 mg/L
48 hr LC50 (modeled for aquatic invertebrates): <1 mg/L, based on lead bullion
No known effects on stratospheric ozone depletion
Volatile organic compounds: 0% (by Volume)
Water Endangering Class (WGK): NA
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IMDG
Proper Shipping name
Packing group
Hazardous class
Label/Placard Required
UN Identification
Environmental Hazards
EmS
Reference
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01
NFPA Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3=Serious 4 = Severe
Disclaimer
Johnson Controls Battery Group, Inc. cannot anticipate all conditions under which this information
and its product, or the products of other manufacturers in combination with its product, may be
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used. It is the users responsibility to ensure safe conditions for handling, storage and disposal of
the product, and to assume liability for loss, injury, damage or expense due to improper use. The
information in the sheet was written based on the best knowledge and experience currently
available.
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