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    Additive 091 m1

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    Patel Hitendra
    Calcium oxide (lime) is a white or greyish powder that is slightly soluble in water. It is used as an alkali and dough conditioner in foods. Calcium oxide must contain at least 95% calcium oxide after ignition, with impurities limited to less than 10% loss on ignition, 3.6% magnesium and alkali salts, 1% acid insoluble matter, and maximum levels of barium, fluoride, and lead. It is assayed by igniting a sample, dissolving the residue, and titrating with a disodium ethylenediamine tetraacetate solution to determine the calcium oxide content.

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    Additive 091 m1

    Uploaded by

    Patel Hitendra
    44 views2 pages
    Calcium oxide (lime) is a white or greyish powder that is slightly soluble in water. It is used as an alkali and dough conditioner in foods. Calcium oxide must contain at least 95% calcium oxide after ignition, with impurities limited to less than 10% loss on ignition, 3.6% magnesium and alkali salts, 1% acid insoluble matter, and maximum levels of barium, fluoride, and lead. It is assayed by igniting a sample, dissolving the residue, and titrating with a disodium ethylenediamine tetraacetate solution to determine the calcium oxide content.

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    Calcium oxide (lime) is a white or greyish powder that is slightly soluble in water. It is used as an alkali and dough conditioner in foods. Calcium oxide must contain at least 95% calcium oxide after ignition, with impurities limited to less than 10% loss on ignition, 3.6% magnesium and alkali salts, 1% acid insoluble matter, and maximum levels of barium, fluoride, and lead. It is assayed by igniting a sample, dissolving the residue, and titrating with a disodium ethylenediamine tetraacetate solution to determine the calcium oxide content.

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    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    44 views2 pages

    Additive 091 m1

    Uploaded by

    Patel Hitendra
    Calcium oxide (lime) is a white or greyish powder that is slightly soluble in water. It is used as an alkali and dough conditioner in foods. Calcium oxide must contain at least 95% calcium oxide after ignition, with impurities limited to less than 10% loss on ignition, 3.6% magnesium and alkali salts, 1% acid insoluble matter, and maximum levels of barium, fluoride, and lead. It is assayed by igniting a sample, dissolving the residue, and titrating with a disodium ethylenediamine tetraacetate solution to determine the calcium oxide content.

    Copyright:

    © All Rights Reserved
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    of 2

    CALCIUM OXIDE

    Prepared at the 19th JECFA (1975), published in NMRS 55B (1976) and in
    FNP 52 (1992). Metals and arsenic specifications revised at the 59th JECFA
    (2002). An ADI Not limited was established at the 9th JECFA (1965).

    SYNONYMS

    Lime; INS No. 529

    DEFINITION
    Chemical names

    Calcium oxide

    C.A.S. number

    1305-78-8

    Chemical formula

    CaO

    Formula weight

    56.08

    Assay

    Not less than 95.0% after ignition

    DESCRIPTION

    Odourless, hard, white or greyish white masses or granules, or white to


    greyish white powder

    FUNCTIONAL USES Alkali, dough conditioner, yeast food


    CHARACTERISTICS
    IDENTIFICATION
    Solubility (Vol. 4)

    Slightly soluble in water, insoluble in ethanol, soluble in glycerol


    (Caution: Protect eyes when adding water)

    Reaction with water

    Moisten the sample with water; heat is generated


    (Caution: Protect eyes when adding water).

    Test for alkali

    The sample is alkaline to moistened litmus paper

    Test for calcium (Vol. 4)

    Passes test

    PURITY
    Loss on ignition (Vol. 4)

    Not more than 10% (1 g, about 800o to constant weight)

    Barium

    Not more than 0.03%


    Cautiously mix 1.5 g of the sample with 10 ml water, add 15 ml of dilute
    hydrochloric acid TS, dilute to 30 ml with water and filter. To 20 ml of the
    filtrate add 2 g of sodium acetate, 1 ml of dilute acetic acid TS and 0.5 ml of
    potassium chromate TS and allow to stand for 15 min. The turbidity of the

    solution is not greater than that of a control prepared by adding water to 0.3
    ml of barium standard solution (1.779 g barium chloride in 1000 ml of water)
    to make to 20 ml, adding 2 g of sodium acetate, 1 ml of dilute acetic acid TS
    and 0.5 ml of potassium chromate TS and allowing to stand for 15 min.
    Magnesium and alkali
    salts

    Not more than 3.6%


    Dissolve 500 mg of the sample in 30 ml of water and 15 ml of dilute
    hydrochloric acid TS. Heat the solution and boil for 1 min. Add rapidly 40 ml of
    oxalic acid TS and stir vigorously. Add 2 drops of methyl red TS and
    neutralize the solution with ammonia TS to precipitate the calcium completely.
    Heat the mixture on a steam bath for 1 h, cool, dilute to 100 ml with water, mix
    well and filter. To 50 ml of the filtrate carefully add 0.5 ml of concentrated
    sulfuric acid, evaporate to dryness and ignite to constant weight in a tared
    platinum crucible.

    Acid insoluble matter

    Not more than 1%


    Slake 5 g of the sample, mix with 100 ml of water and sufficient hydrochloric
    acid, added dropwise, to effect solution. Boil the solution, cool, add
    hydrochloric acid, if necessary, to make the solution distinctly acid, and filter
    through a tared crucible. Wash the residue with water until free of chlorides,
    dry at 105o for 1 h, cool, and weigh.

    Fluoride (Vol. 4)

    Not more than 50 mg/kg (Method I or III)

    Lead (Vol. 4)

    Not more than 2 mg/kg


    Determine using an atomic absorption technique appropriate to the specified
    level. The selection of sample size and method of sample preparation may be
    based on the principles of the method described in Volume 4, Instrumental
    Methods.

    METHOD OF
    ASSAY

    Ignite at approximately 800o about 1 g of the sample to constant weight,


    accurately weigh the residue and dissolve it in 20 ml of dilute hydrochloric
    acid TS. Cool the solution, dilute with water to 500 ml and mix. Pipet 50 ml of
    this solution into a suitable container and add 50 ml of water, then add 15 ml
    of sodium hydroxide TS, 40 mg of murexide indicator preparation and 3 ml of
    naphthol green TS, and titrate with 0.05 M disodium ethylenediamine
    tetraacetate until the solution is deep blue in colour. Each ml of 0.05 M
    disodium ethylenediamine tetraacetate is equivalent to 2.804 mg of CaO.

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