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IR Tables

This document provides a table summarizing infrared absorption frequencies for common functional groups. It lists the type of vibration, frequency range in wavenumbers and micrometers, and intensity for various bonds including C-H, C=C, C≡C, C=O, O-H, N-H, C≡N, N=O, C-X and others. The table acts as a reference for interpreting infrared spectra by correlating absorption bands to specific bond vibrations.

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33 views

IR Tables

This document provides a table summarizing infrared absorption frequencies for common functional groups. It lists the type of vibration, frequency range in wavenumbers and micrometers, and intensity for various bonds including C-H, C=C, C≡C, C=O, O-H, N-H, C≡N, N=O, C-X and others. The table acts as a reference for interpreting infrared spectra by correlating absorption bands to specific bond vibrations.

Uploaded by

Ash
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Download as PDF, TXT or read online on Scribd
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Chemistry 303

Fall, 2016

IR Tables

APPENDICES

INFRA-RED GROUP ABSORPTION FREQUENCIES


XVHVIUHTXHQF\LJQRUHVILQJHUSULQWUHJLRQFP
TYPE OF VIBRATION
CH

FREQUENCY (cm-1)

WAVELENGTH ()

INTENSITY (1)

Alkanes

(stretch)

3000-2850

3.33-3.51

CH3

(bend)

1450 and 1375

6.90 and 7.27

CH2

(bend)

1465

6.83

Alkenes

(stretch)

3100-3000

3.23-3.33

(bend)

1700-1000

5.88-10.0

Aromatics

(stretch)

3150-3050

3.17-3.28

(out-of-plane bend)

1000-700

10.0-14.3

Alkyne

(stretch)

ca. 3300

ca.3.03

2900-2800

3.45-3.57

2800-2700

3.57-3.70

Aldehyde

CC

Alkane

C=C

Alkene

1680-1600

5.95-6.25

m-w

Aromatic

1600-1400

6.25-7.14

m-w

CC

Alkyne

2250-2100

4.44-4.76

m-w

C=O

not usually useful

Aldehyde

1740-1720

5.75-5.81

Ketone

1725-1705

5.80-5.87

Carboxylic acid

1725-1700

5.80-5.88

Ester

1750-1730

5.71-5.78

Amide

1700-1640

5.88-6.10

Anhydride

ca. 1810

ca. 5.52

ca. 1760

ca. 5.68

1800

5.55

1300-1000

7.69-10.0

Free

3650-3600

2.74-2.78

Acyl chloride
CO

Alcohols, Ethers, Esters,


Carboxylic acids

OH

Alcohols, Phenols

H-Bonded

3400-3200

2.94-3.12

Carboxylic acids (2)

3300-2500

3.03-4.00

NH

Primary and secondary amines

ca. 3500

ca. 2.86

CN

Nitriles

2260-2240

4.42-4.46

N=O

Nitro (RNO2)

1600-1500

6.25-6.67

1400-1300

7.14-7.69

Fluoride

1400-1000

7.14-10.0

Chloride

800-600

12.5-16.7

Bromide, Iodide

<600

>16.7

CX

___________________________________________________________________________________
(1) s = strong, m = medium and w = weak
(2) note that the -OH absorption of solid carboxylic acids which run as a nujol mull can be difficult to see as they maybe very broad

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