Inter Conversions

INTERCONVERSIONS
1How will you bring about the following conversions?

(i) Ethanol to but-1-yne
(ii) Ethane to bromoethene
(iii) Propene to 1-nitropropane
(iv) Toluene to benzyl alcohol
(v) Propene to propyne
(vi) Ethanol to ethyl fluoride
(vii) Bromomethane to propanone
(iii)
(viii) But-1-ene to but-2-ene

(ix) 1-Chlorobutane to n-octane
(x) Benzene to biphenyl.
(i)
(iv)
(v)
(vi)
(ix)
(x)
(vii)
2How the following conversions can be carried out?

(i) Propene to propan-1-ol
(ii) Ethanol to but-1-yne
(viii)
(iii) 1-Bromopropane to 2-bromopropane

(iv) Toluene to benzyl alcohol
(v) Benzene to 4-bromonitrobenzene
(vi) Benzyl alcohol to 2-phenylethanoic acid
(vii) Ethanol to propanenitrile
(viii) Aniline to chlorobenzene
(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(x) 2-Methyl-1-propene to 2-chloro-2-methylpropane
(xi) Ethyl chloride to propanoic acid
(xii) But-1-ene to n-butyliodide
(xiii) 2-Chloropropane to 1-propanol
(xiv) Isopropyl alcohol to iodoform
(xv) Chlorobenzene to p-nitrophenol
(xvi) 2-Bromopropane to 1-bromopropane
(xvii) Chloroethane to butane
(xviii) Benzene to diphenyl
(xix) tert-Butyl bromide to isobutyl bromide
(xx) Aniline to phenylisocyanide
Answer (i)
(ii)
(iii)
(iv)
(v)
(ix)
(x)
(vi)
(xi)
(vii)
(xii)
(viii)
(xiii)
(xvi)
(xiv)
(xvii)
(xviii)
(xv)
(xix)
(iii) When ethyl magnesium chloride is treated with methanal, an

adduct is the produced which gives propan-1-ol on hydrolysis.
(xx)
Q3
How are the following conversions carried out?
(i) Propene Propan-2-ol

(ii)Benzyl chloride Benzyl alcohol
(iii) Ethyl magnesium chloride Propan-1-ol.
(iv) When methyl magnesium bromide is treated with propane, an

adduct is the product which gives 2-methylpropane-2-ol on hydrolysis.
(iv) Methyl magnesium bromide 2-Methylpropan-2-ol.

Answer
(i) If propene is allowed to react with water in the presence of an acid
as a catalyst, then propan-2-ol is obtained.
(ii) If benzyl chloride is treated with NaOH (followed by acidification)

then benzyl alcohol is produced.
Q4
Show how would you synthesise the following alcohols from

appropriate alkenes?
Q6
(i)
(ii)
The given alcohols can be synthesized by applying Markovnikovs

rule of acid-catalyzed hydration of appropriate alkenes.
(i)
(i)
(ii)
(ii)
Q5
Give names of the reagents to bring about the following

transformations:
(i) Hexan-1-ol to hexanal (ii) Cyclohexanol to cyclohexanone
(iii) p-Fluorotoluene to p-fluorobenzaldehyde
(iv) Ethanenitrile to ethanol (v) Allyl alcohol to propenal
(vi) But-2-ene to ethanol
A
(iii)
(iv)
Show how each of the following compound can be

converted into Ethylbenzene (ii) Acetophenone (iii)
Bromobenzene (iv) Phenylethene (Styrene)
Q7
Write chemical reactions to affect the following transformations:
(i) Butan-1-ol to butanoic acid
(ii) Benzyl alcohol to phenylethanoic acid
(iii) 3-Nitrobromobenzene to 3-nitrobenzoic acid
(iv) 4-Methylacetophenone to benzene-1,4-dicarboxylic acid
(v) Cyclohexene to hexane-1,6-dioic acid
(vi) Butanal to butanoic acid.
Q8
How will you convert ethanal into the following

compounds?
(i) Butane-1, 3-diol (ii) But-2-enal (iii) But-2-enoic acid
(i) On treatment with dilute alkali, ethanal produces 3hydroxybutanal gives butane-1, 3-diol on reduction.
(ii) On treatment with dilute alkali, ethanal gives 3-hydroxybutanal

which on heating produces but-2-enal.
(iii) When treated with Tollens reagent, But-2-enal produced in the

above reaction produces but-2-enoic acid .
Q9
How will you prepare the following compounds from

benzene? You may use any inorganic reagent and any
organic reagent having not more than one carbon atom
(i) Methyl benzoate (ii) m-Nitrobenzoic acid
(iii) p-Nitrobenzoic acid (iv) Phenylacetic acid

(v) p-Nitrobenzaldehyde.
(i)
(iv)
(ii)
(v)
(iii)
Q10How will you bring about the following conversions in not

more than two steps?
(i) Propanone to Propene
(ii) Benzoic acid to Benzaldehyde
(iii) Ethanol to 3-Hydroxybutanal
(iv) Benzene to m-Nitroacetophenone
(v)
(v) Benzaldehyde to Benzophenone

(vi) Bromobenzene to 1-Phenylethanol
(vii) Benzaldehyde to 3-Phenylpropan-1-ol
(viii) Benazaldehyde to -Hydroxyphenylacetic acid
(ix) Benzoic acid to m- Nitrobenzyl alcohol
(i)
(vi)
(ii)
(vii)
(iii)
(viii)
(iv)
(ix)
Q11 How will you convert? (i) Benzene into aniline (ii)
Benzene into N, N-dimethylaniline (iii) Cl(CH2)4Cl into hexan1, 6-diamine?
Answer
(ii)
(i)
(ii)
(iii)
Q13
Q12Convert (i) 3-Methylaniline into 3-nitrotoluene.

(ii) Aniline into 1,3,5 tribromobenzene.
Answer (i)
How will you convert:

(i) Ethanoic acid into methanamine
(ii) Hexanenitrile into 1-aminopentane
(iii) Methanol to ethanoic acid
(iv) Ethanamine into methanamine
(v) Ethanoic acid into propanoic acid
(vi) Methanamine into ethanamine
(vii) Nitromethane into dimethylamine

(viii) Propanoic acid into ethanoic acid
A (i)
(v)
(ii)
(vi)
(iii)
(vii)
(iv)
(viii)
Q14Accomplish the following conversions:

(i) Nitrobenzene to benzoic acid
(ii) Benzene to m-bromophenol
(iii) Benzoic acid to aniline
(ii)
(iv) Aniline to 2,4,6-tribromofluorobenzene

(v) Benzyl chloride to 2-phenylethanamine
(vi) Chlorobenzene to p-chloroaniline
(vii) Aniline to p-bromoaniline
(viii) Benzamide to toluene
(ix) Aniline to benzyl alcohol.
(i)
Answer
(iii)
(vi)
(iv)
(v)
(vii)
(viii)
(ix)

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INTERCONVERSIONS

1How will you bring about the following conversions?

(viii) But-1-ene to but-2-ene

2How the following conversions can be carried out?

(iii) 1-Bromopropane to 2-bromopropane

(ix) 2-Chlorobutane to 3, 4-dimethylhexane

(iii) When ethyl magnesium chloride is treated with methanal, an

How are the following conversions carried out?

(i) Propene Propan-2-ol

(iv) When methyl magnesium bromide is treated with propane, an

(iv) Methyl magnesium bromide 2-Methylpropan-2-ol.

(ii) If benzyl chloride is treated with NaOH (followed by acidification)

Show how would you synthesise the following alcohols from

The given alcohols can be synthesized by applying Markovnikovs

Give names of the reagents to bring about the following

Show how each of the following compound can be

How will you convert ethanal into the following

(ii) On treatment with dilute alkali, ethanal gives 3-hydroxybutanal

(iii) When treated with Tollens reagent, But-2-enal produced in the

How will you prepare the following compounds from

(iii) p-Nitrobenzoic acid (iv) Phenylacetic acid

Q10How will you bring about the following conversions in not

(iv) Benzene to m-Nitroacetophenone

(v) Benzaldehyde to Benzophenone

Q12Convert (i) 3-Methylaniline into 3-nitrotoluene.

How will you convert:

(vii) Nitromethane into dimethylamine

Q14Accomplish the following conversions:

(iv) Aniline to 2,4,6-tribromofluorobenzene

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