2130504
2130504
2130504
CHEMICAL ENGINEERING
PROCESS CALCULATION
SUBJECT CODE: 2130504
B.E. Semester: III
Prerequisite: None
Rationale: The prime objective of this subject is to clear fundamentals of chemical engineering in a
simple and forthright manner and to provide the broad background for applying these principles to
industrial and theoretical problems.
After learning the course the students should be able:
To understand the importance of stoichiometry material and energy balances
To deal with the laws of conservation of mass and energy
To apply principles of unit operations and chemical reaction engineering in problem solving
Course Contents:
Teaching Module
Sr. Topic
Hrs. Weightage
No.
1 Dimensions and units: 5 9
Dimensions and system of units, Fundamental and derived units,
Dimensional consistency, Dimensional equations, Different ways of
expressing units of quantities and physical constant, Unit conversion and its
significance
2 Basic chemical calculations: 7 13
Calculations for mole, molecular weight, equivalent weight, etc.,
Composition of gaseous mixtures, liquid mixtures, solid mixtures, etc.,
Ideal gas law & other equations of state and their applications, Dalton law,
Raoults law, Henrys law, Solutions and their properties
3 Material balance without chemical reactions: 8 15
Process flowsheet, Degree of freedom, Material balance with and without
recycle; Bypass and purge streams, Material balance around equipments
related to unit operations like absorber and stripper, distillation towers,
extractors, dryers, evaporators, etc. Material balance of unsteady state
operations.
4 Material balance involving chemical reactions: 10 18
Concept of limiting and excess reactants, percentage conversion, yield,
selectivity, etc., M aterial balance with chemical reactions - single and
multiple reactions, Material balance involving reactions with special
reference to fertilizers, petrochemicals, dyestuffs, electrochemical
industries, metallurgical industries, etc.
5 Energy balances: 9 17
Thermochemistry and 1st law of thermodynamics, Heat capacity of gases
and gaseous mixtures, liquids & solids, Sensible heat change in liquids &
gases, Enthalpy changes during phase transformation, Enthalpy changes
accompanied by chemical reactions, Standard heat of reaction, Adiabatic
reactions, Thermo-chemistry of mixing processes, Dissolution of solids,
etc.
6 Stoichiometry and Unit operations: 7 13
Distillation, Absorption and stripping, Extraction & leaching,
Crystallization, Psychrometric Operations, Drying, Evaporation etc.
7 Fuels and combustion: 8 15
Types of fuels, Calorific value of fuels, Problems on combustion of coal,
liquid fuels, gaseous fuels, etc., Proximate and ultimate analysis,
Combustion calculations, theoretical flame temperature, etc., Air
requirement and flue gases.
Reference Books:
1. Stoichiometry, B.I. Bhatt, S.M. Vora, McGraw Hill Publishing Company Limited, 4th edition,
2004.
2. Basic Principles & Calculations in Chemical Engineering, David M. Himmelblau, James B.
Riggs, PHI Learing Pvt. Ltd, 7th edition, 2006.
3. Elementary Principles of Chemical Processes, Richard M. Felder, Ronald W. Rousseau, Wiley,
3rd edition, 2004.
4. Chemical Process Principles Part-I: Material and Energy Balances, O.A.Hougen, K.M.Watson,
R.A.Ragatz, CBS Publishers New Delhi, 2nd edition, 2004.
5. Stoichiometry and Process Calculations, K.V. Narayanan, B. Lakshmikutty, Prentice-Hall of
India Pvt. Ltd., 2006.
6. Industrial Stoichiometry: Chemical Calculations of Manufacturing Processes, H.C.Lewis,
W.K.Lewis, A.H.Radasch, McGraw-Hill, 2nd edition, 1954.
Course Outcome:
After learning the course, the students should be able to:
Establish mathematical methodologies for the computation of material balances and energy
balances
Present an overview of industrial chemical processes.
Develop a fundamental understanding of the basic principles of chemical engineering processes
and calculations.
Examine and select pertinent data, and solve material and energy balance problems.
Give examples of important application of material balances in chemical engineering processes.
Evaluate their own solutions and those of others to find and correct errors.