PVC Alternatives 041411

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PVC Alternatives

Project

Co-Chairs:
Scott OConnell, Cisco
Jim Arnold, iNEMI

April 2011
Background
iNEMI PVC Alternatives project was proposed at the September
2008 iNEMI Sustainability Summit, approved by the Board
Project chairs Scott OConnell, Cisco & Jim Arnold, iNEMI

The project is focused on 2 areas:


Phase 1 - Cradle-to-grave Life cycle assessment (LCA) comparing
PVC and PVC-free cables - WE ARE HERE TODAY

Phase 2 - Technical evaluation of PVC alternatives electrical,


mechanical, safety

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Companies and Organizations Participating
in the Project Statement of Work (SOW)
OEMs Alcatel-Lucent, Cisco, Dell, IBM, Intel, Lenovo, HP

Cable Manufacturers Alpha Gary, BizLink, CordMaster, Hueson


Wire, Huntsman, NorthWire, TeknorApex, Tyco, Volex

Resin/Raw Material Manufacturers and Formulators BASF, Dow,


DSM, Dupont, TeknorApex, Exxon Mobil, SABIC

Safety Standards Organizations UL

LCA Consultants EarthShift, PE International

Universities, others Purdue, IST (Integrated Services Technology),


ITRI (Industrial Technology Research Institute), The Vinyl Institute

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Thrust Area:
Environment
TIG: PVC Alternatives Project May-11
ECE

Goal: Perform an Life Cycle Assessment of the electrical and mechanical


properties, and safety aspects of PVC alternatives for Power Cord Sets
Strategy Issues Graphics
Phase 1 Evaluate differences between PVC Industry migration to PVC-
with PVC-free compounds in the lifecycle of free materials
detachable US desktop power cord sets Sub-team formed to investigate
Phase 2 - Develop and conduct a test to gain a hot spots in the life cycle
better understanding of the electrical, using a screening LCA.
mechanical and safety aspects of PVC-free Current LCA models are limited
alternatives by lack of data on materials and
processes used in the
Project Lead: Scott OConnell, Cisco Systems manufacture of power cord sets
Project Co-Lead: Jim Arnold, iNEMI
Tactics Milestones and/or Deliverables Plan Actual
Research Project Information Define and Collect Data
Phase 1 - Conduct a cradle-to-grave Life Cycle Mar-10 Apr-10

Assessment (LCA) on PVC and PVC-free Go / No-Go Decision on LCA Study Aug-10 Sep-10
Alternatives for detachable US desktop power Investigate LCA models to determine limitations Dec-10 Jan-11
cord sets
Screening LCA to identify "hot spots" Apr-11

Phase 2 - Conduct performance testing of Project Reporting Jun-11

different PVC-free alternatives

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PVC Alternatives Project
Project Team Members

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What Has Been Done So Far?
Vinyl 2010 study on recovery of PVC (2003)
Emphasis on EOL aspects of mixed cable waste
http://www.ecvm.org/img/db/PE_Recovery_Options_final_140503.pdf
EU Commission study on PVC and replacement materials (2004)
Overview of publicly available LCAs, little information on PVC alternatives in electronic
applications
http://ec.europa.eu/enterprise/chemicals/sustdev/pvc_en.htm
USEPA PVC Alternatives Project (2008)
Focused on building and telecom wire, emphasis on base resins & additives (Pb vs
Pb-free)
http://www.epa.gov/dfe/pubs/projects/wire-cable/index.htm
HDPUG Halogen-Free Guideline (2008)
Includes a section on Cables, general information on PVC alternatives
www.hdpug.org
HDPUG PVC Alternatives Project (Ongoing)
Emphasis on supply chain readiness for PVC-free cables (all cable types)
MIT Life Cycle Analysis of Plastics for Clamshell Packaging: PVC & PET (2010)

Significant historical data on PVC (and additives); however little


data exists on non-PVC alternatives & additives
Typical Uses of PVC In Electronic Cables

Main Cable Configurations

SVE SPE-2

PVC alternatives developing for all cable applications:


Jacketing
Insulation
Strain Relief
Plugs
PHASE 1
LIFE CYCLE ASSESSMENT
(LCA)

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Phase 1 - LCA Project

Goal: Conduct a cradle-to-grave life cycle assessment on PVC and


PVC alternatives, emphasis on US desktop power cords. The
project should take into account the needs of electronic
product sectors represented by iNEMI membership.

1. Identify market segment & cable design/BOM requirements


2. Review & assess existing LCA studies for relevance in the
electronics sector
3. Identify candidate materials and develop life cycle inventory (LCI)
base resins + additives
4. Identify LCA parameters and LCA tool of choice (SimaPro, GaBi,
etc.)
5. Conduct the LCA may begin with a high-level screening
assessment to identify hot spots across the life cycle

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Current Resin Alternatives Identified for LCA

The goal of the LCAs is to represent the variety of


environmental specifications used across the industry for US
desktop power cords:

PVC #1 - Standard RoHS-compliant

PVC #2 - RoHS-compliant, phthalate-free (renewable or non-


renewable plasticizers)

Low Halogen - RoHS-compliant, phthalate-free, HFR & PVC-


free (TPE, TPU)
Phase I LCA Project
Goal conduct a pilot LCA within GaBi comparing PVC, TPE and TPU resins for use in
RoHS-compliant US desktop power cords. Use the pilot results to develop a model for
assessing different cord sets either independently and/or within the iNEMI PVC Alternatives
project.

Pilot LCA Details


Functional unit: RoHS-compliant US desktop power cord (6ft cable) made of PVC, TPE
and TPU resins
Scope: Raw material extraction thru end-of-life phases
Participants: Cisco, Alcatel-Lucent, Dow

Key assumptions:
Utilize existing data within GaBi
Utilize key assumptions developed by the iNEMI project team (cut off criteria, life span,
etc)

Expected results: produce an LCA model for the iNEMI PVC Alternatives project team
that identifies hot spots across the life cycle as well as data gaps for future work by the
NEMI project team
Identified GaBi Data Gaps

Materials Data Gaps Cable Manufacturing Data Gaps


PVC resin does not No plastic extrusion process
include additives (only injection molding)
(plasticizers, fillers)
Extrusion process is included
TPU and TPE resins are in Eco-Invent database
not included (only PE,
PU) Different extrusion & drying
processes for non-PVC resins

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Key Inputs from Power Cord Manufacturers
Similarities Between PVC and Non-PVC
Specific gravity and mass/thickness are similar for PVC and non-PVC resins used in power cord
cable jacketing
Cable jacketing extrusion process for PVC and non-PVC is done in the same factory location
Recycled content % and production waste generation

Differences Between PVC and Non-PVC


Sourcing of resins for cable manufacturing
For PVC, most source of resins are from China
For TPE, source of resins are from China and from USA
For TPU, source of resins are from Europe and from USA
Resin moisture content must be controlled for non-PVC (<0.02%) as too much moisture will affect the
mechanical & electrical properties of the cable after the extrusion process
Different parameters for extrusion and drying of PVC and non-PVC cable jacketing:

Resin Extrusion Temp Drying Conditions


PVC 120-180C 80C for 2H
TPU - glossy 140-230C 100C for 6H
TPU - matte 140-180C 90C for 3H
TPE 140-180C 90C for 3H

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Dow SUSTAIN Processing Guide
Conductor Barrel Temp:
PVC: 160-190oC
Conductor pre-heat
recommended
Non-PVC: 180-200oC

Line Speed
PVC: 80-100m/min
Non-PVC: 60-100 m/min
Desiccant drier

Drying Conditions:
PVC: 110oC @ 1hr
Non-PVC: 100-110oC @ 2hrs

* All data based on extrusion of SVE type cable on a 75mm extruder with screw CR 3:1 and L/D 25:1
Phase I LCA Project Next Steps

March 2011 - develop a screening LCA to identify hot


spots across the US desktop power cord life cycle

April 2011 - document the screening LCA results and


determine if a more detailed LCA is appropriate

May/June 2011 - produce Phase I project report

June 2011 - begin Phase II project

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Phase 2 - Technical Evaluation of PVC
Alternatives
Goal: Understand the electrical, mechanical and safety
aspects of PVC alternatives. Develop, manage, and
execute performance testing.

1. Develop an evaluation test matrix for PVC alternatives

2. Create a PVC alternatives global safety standards matrix,


emphasis on power cords

3. Manufacture PVC-free power cords (test samples) using


commercially-available resins

4. Assign teams to carry out completion of the testing per agreed-up


test matrix

5. Roll-up results for final report


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Questions?
Comments?

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