80.

0%

70.0%

60.0% f(x) = 0.6353395071 exp( - 0.0113857885 x )

R² = 0.854205292

50.0%
A%

A%
40.0% Exponential (A
%)

30.0%

20.0%

10.0%

0.0%
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 25.00

f(x) = - 0.000507963x^2 + 0.1929704056x + 3.7930743168

20.00
R² = 0.8598937678
q (mg/g)

15.00
q
Polynomial (q)

10.00

5.00

0.00
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 0.0450

0.0400 f(x) = - 0.0002367131x + 0.0411229032

R² = 0.9373584664
0.0350
k (min-1)

0.0300

0.0250 k
Linear (k)
0.0200

0.0150

0.0100

0.0050

0.0000
0.00 20.00 40.00 60.00 80.00 100.00 120.00 140.00 160.00
Co (mg/L)
 140.00

f(x) = 0.000507963x^2 + 0.8070295944x - 3.7930743168

120.00 R² = 0.9970992446
Ce (mg/L)

100.00

80.00
Ce
Polynomial (Ce)
60.00

40.00

20.00

0.00
0.00 20.00 40.00 60.00Co (mg/L)
80.00 100.00120.00140.00160.00
 A4 A3 A2 A1 methylene blue 1st αραιωση 5:100 20
0.2941 -1.1677 1.6979 2.9839 2nd-3rd αραιωση 10:100 10
Pretreated Wheat Straw Diethylene glycol 160˚C 40 min H2O: Βρύσης4th-6th αραιωση 100:100 1

1 lt methylene blue αχυρο (g) 1.00

προσρόφηση σε θ=23C V (L) 1.00
ημερομηνια 11/25/2015
αραιώσεις 1000:1000 500:1000 200:1000 90:1000 50:1000
t (min) abs 1 abs 2 abs 3 abs 1 abs 2 abs 3 abs1 abs2 abs3 abs1 abs 2 abs3 abs1 abs 2 abs3
0 1.888 1.828 1.885 1.889 1.882 1.869 0.801 0.806 0.788 2.831 2.844 1.939 1.927
5 1.878 1.873 1.877 1.833 1.834 1.796 0.718 0.717 0.709 2.406 2.426 1.492 1.499
10 1.849 1.855 1.840 1.794 1.797 1.741 0.637 0.640 0.636 2.187 2.163 1.301 1.334
15 1.859 1.849 1.830 1.789 1.762 1.751 0.646 0.624 0.636 2.055 2.061 1.190 1.242
20 1.818 1.809 1.785 1.711 1.702 1.682 0.631 0.643 0.638 1.939 1.936 1.127 1.120
25 1.811 1.839 1.819 1.690 1.675 1.677 0.620 0.636 0.639 1.879 1.885 1.090 1.083
30 1.851 1.848 1.841 1.697 1.680 1.670 0.625 0.619 0.620 1.829 1.843 1.016 1.013
35 1.799 1.802 1.781 1.672 1.677 1.682 0.601 0.607 0.621 1.756 1.736 0.969 0.971
40 1.830 1.817 1.808 1.699 1.69 1.684 0.561 0.585 0.580 1.700 1.706 0.939 0.928
45 1.822 1.822 1.825 1.664 1.673 1.677 0.562 0.565 0.559 1.611 1.614 0.872 0.857
50 1.834 1.826 1.811 1.699 1.691 1.698 0.544 0.559 0.556 1.557 1.549 0.848 0.851
55 1.817 1.813 1.794 1.659 1.664 1.668 0.545 0.551 0.539 1.510 1.510 0.821 0.821
60 1.805 1.820 1.822 1.637 1.656 1.657 0.537 0.538 0.541 1.477 1.487 0.767 0.770
65 1.803 1.815 1.790 1.657 1.660 1.654 0.527 0.526 0.528 1.432 1.423 0.745 0.737
70 1.808 1.797 1.807 1.651 1.650 1.650 0.513 0.517 0.512 1.403 1.398 0.716 0.712
75 1.671 1.669 1.646 1.636 1.624 1.675 0.506 0.506 0.508 1.337 1.356 0.673 0.681
80 1.787 1.763 1.765 1.626 1.640 1.660 0.505 0.502 0.500 1.332 1.337 0.707 0.681
85 1.796 1.796 1.791 1.619 1.620 1.628 0.503 0.502 0.501 1.293 1.301 0.692 0.697
90 1.793 1.723 1.727 1.585 1.590 1.595 0.497 0.499 0.498 1.288 1.283 0.658 0.661
95 1.778 1.755 1.778 1.570 1.575 1.58 0.493 0.490 0.497 1.268 1.265 0.648 0.649

t (min) ABS Φ1 ABS Φ2 ABS Φ3 ABS Φ4 ABS Φ5 ABS Φ6

0 1.867 1.880 0.798 2.838 1.933 0.569
5 1.876 1.821 0.715 2.416 1.496 0.313
10 1.848 1.777 0.638 2.175 1.318 0.256
15 1.846 1.767 0.635 2.058 1.216 0.211
20 1.804 1.698 0.637 1.938 1.120 0.188
25 1.823 1.681 0.632 1.882 1.087 0.169
30 1.847 1.682 0.621 1.836 1.015 0.158
35 1.794 1.677 0.610 1.746 0.970 0.148
40 1.818 1.691 0.575 1.703 0.934 0.140
 45 1.823 1.671 0.562 1.613 0.865 0.141
50 1.824 1.696 0.553 1.553 0.850 0.135
55 1.808 1.664 0.545 1.510 0.821 0.136
60 1.816 1.650 0.539 1.482 0.769 0.125
65 1.803 1.657 0.527 1.428 0.741 0.130
70 1.804 1.650 0.514 1.401 0.714 0.124
75 1.662 1.645 0.507 1.347 0.677 0.118
80 1.772 1.642 0.502 1.335 0.694 0.116
85 1.794 1.622 0.502 1.297 0.695 0.130
90 1.748 1.590 0.498 1.286 0.660 0.126
95 1.770 1.575 0.493 1.267 0.649 0.128

t (min) C1 C2 C3 C4 C5 C6
0 149.27 75.26 29.90 14.53 7.78 2.06
5 150.13 72.47 26.50 10.67 5.83 1.07
10 147.47 70.46 23.39 9.09 5.09 0.86
15 147.28 70.00 23.30 8.43 4.68 0.69
20 143.36 66.92 23.38 7.81 4.29 0.61
25 145.12 66.14 23.15 7.54 4.16 0.55
30 147.34 66.21 22.73 7.32 3.87 0.51 αραιώσεις 1000 500 200 90 50 20
35 142.44 65.98 22.26 6.90 3.69 0.47 1000 1000 1000 1000 1000 1000
40 144.69 66.59 20.89 6.71 3.54 0.45 Co 156.0 78.0 31.2 14.0 7.8 3.1
45 145.12 65.73 20.35 6.32 3.26 0.45
50 145.18 66.81 19.99 6.07 3.20 0.43
55 143.73 65.40 19.67 5.89 3.08 0.43
60 144.44 64.80 19.42 5.77 2.87 0.40
65 143.24 65.11 18.96 5.54 2.76 0.41
70 143.36 64.82 18.44 5.43 2.65 0.39
75 130.65 64.59 18.15 5.21 2.50 0.37
80 140.40 64.46 17.98 5.16 2.57 0.37
85 142.47 63.61 17.97 5.01 2.57 0.41
90 138.23 62.23 17.81 4.96 2.43 0.40
95 140.28 61.59 17.63 4.89 2.38 0.41

t (min) T(oC) 1 T(oC) 2 T(oC) 3 T(oC) 4 T(oC) 5 T(oC) 6

0 23.0 23.0 23.0 23.0 23.0 23.0
5 23.0 23.0 23.0 23.0 23.0 23.0
10 23.0 23.0 23.0 23.0 23.0 23.0
15 23.0 23.0 23.0 23.0 23.0 23.0
 20 23.0 23.0 23.0 23.0 23.0 23.0
25 23.0 23.0 23.0 23.0 23.0 23.0
30 23.0 23.0 23.0 23.0 23.0 23.0
35 23.0 23.0 23.0 23.0 23.0 23.0
40 23.0 23.0 23.0 23.0 23.0 23.0
45 23.0 23.0 23.0 23.0 23.0 23.0
50 23.0 23.0 23.0 23.0 23.0 23.0
55 23.0 23.0 23.0 23.0 23.0 23.0
60 23.0 23.0 23.0 23.0 23.0 23.0
65 23.0 23.0 23.0 23.0 23.0 23.0
70 23.0 23.0 23.0 23.0 23.0 23.0
75 23.0 23.0 23.0 23.0 23.0 23.0
80 23.0 23.0 23.0 23.0 23.0 23.0
85 23.0 23.0 23.0 23.0 23.0 23.0
90 23.0 23.0 23.0 23.0 23.0 23.0
95 23.0 23.0 23.0 23.0 23.0 23.0
μ.ο. 23 23 23 66 66 23

t (min) pH 1 pH 2 pH 3 pH 4 pH 5 pH 6
0 8.00 8.00 8.00 8.00 8.00 8.00
5 8.00 8.00 8.00 8.00 8.00 8.00
10 8.00 8.00 8.00 8.00 8.00 8.00
15 8.00 8.00 8.00 8.00 8.00 8.00
20 8.00 8.00 8.00 8.00 8.00 8.00
25 8.00 8.00 8.00 8.00 8.00 8.00
30 8.00 8.00 8.00 8.00 8.00 8.00
35 8.00 8.00 8.00 8.00 8.00 8.00
40 8.00 8.00 8.00 8.00 8.00 8.00
45 8.00 8.00 8.00 8.00 8.00 8.00
50 8.00 8.00 8.00 8.00 8.00 8.00
55 8.00 8.00 8.00 8.00 8.00 8.00
60 8.00 8.00 8.00 8.00 8.00 8.00
65 8.00 8.00 8.00 8.00 8.00 8.00
70 8.00 8.00 8.00 8.00 8.00 8.00
75 8.00 8.00 8.00 8.00 8.00 8.00
80 8.00 8.00 8.00 8.00 8.00 8.00
85 8.00 8.00 8.00 8.00 8.00 8.00
90 8.00 8.00 8.00 8.00 8.00 8.00
95 8.00 8.00 8.00 8.00 8.00 8.00
μ.ο. 8 8 8 8 8 8
20:1000
abs1 abs 2 abs3
0.570 0.567
0.312 0.314
0.254 0.257
0.210 0.211
0.189 0.186
0.171 0.167
0.153 0.163
0.147 0.148
0.136 0.143
0.140 0.141
0.136 0.133
0.133 0.138
0.125 0.125
0.13 0.130
0.121 0.126
0.115 0.120
0.113 0.119
0.130 0.130
0.128 0.124
0.130 0.125
 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1 C=156 C=78 C=31 C=14
t (min) mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l mg/L mg/L mg/L mg/l
0 149.3 75.3 29.9 14.5 7.8 2.1 149.9 72.6 30.0 13.1 7.6 1.0 0.003932 -0.03662 0.002388 -0.10608
5 150.1 72.5 26.5 10.7 5.8 1.1 149.0 71.6 28.0 11.6 6.6 0.9 -0.00181 0.001795 0.115651 0.187271
10 147.5 70.5 23.4 9.1 5.1 0.9 148.1 70.6 26.3 10.3 5.8 0.8 0.015963 0.029498 0.219496 0.307874
15 147.3 70.0 23.3 8.4 4.7 0.7 147.3 69.7 24.9 9.3 5.2 0.7 0.017222 0.035762 0.222633 0.358093
20 143.4 66.9 23.4 7.8 4.3 0.6 146.5 69.0 23.7 8.5 4.6 0.6 0.043369 0.078261 0.219944 0.40554
25 145.1 66.1 23.1 7.5 4.2 0.5 145.8 68.2 22.7 7.8 4.2 0.6 0.03161 0.088957 0.227562 0.426195
30 147.3 66.2 22.7 7.3 3.9 0.5 145.0 67.6 21.8 7.3 3.8 0.5 0.016803 0.087951 0.241443 0.442829
35 142.4 66.0 22.3 6.9 3.7 0.5 144.3 67.0 21.1 6.8 3.6 0.5 0.049515 0.091168 0.257098 0.47428
40 144.7 66.6 20.9 6.7 3.5 0.4 143.7 66.4 20.5 6.4 3.3 0.5 0.034508 0.082709 0.303048 0.48887
45 145.1 65.7 20.4 6.3 3.3 0.4 143.0 65.9 20.0 6.1 3.1 0.5 0.03161 0.094579 0.320838 0.518829
50 145.2 66.8 20.0 6.1 3.2 0.4 142.4 65.4 19.6 5.9 3.0 0.4 0.031195 0.079678 0.332827 0.538076
55 143.7 65.4 19.7 5.9 3.1 0.4 141.8 65.0 19.2 5.7 2.9 0.4 0.040903 0.099184 0.343471 0.551809
60 144.4 64.8 19.4 5.8 2.9 0.4 141.3 64.6 18.9 5.5 2.8 0.4 0.036162 0.107362 0.351887 0.560685
65 143.2 65.1 19.0 5.5 2.8 0.4 140.7 64.2 18.7 5.4 2.7 0.4 0.044191 0.103178 0.367369 0.577835
70 143.4 64.8 18.4 5.4 2.6 0.4 140.2 63.9 18.4 5.3 2.6 0.4 0.043369 0.107163 0.384583 0.58628
75 130.7 64.6 18.2 5.2 2.5 0.4 139.7 63.6 18.3 5.2 2.6 0.4 0.12818 0.110345 0.394275 0.60309
80 140.4 64.5 18.0 5.2 2.6 0.4 139.2 63.3 18.1 5.1 2.5 0.4 0.063136 0.112132 0.399997 0.606814
85 142.5 63.6 18.0 5.0 2.6 0.4 138.8 63.1 18.0 5.1 2.5 0.4 0.049311 0.123806 0.400437 0.618428
90 138.2 62.2 17.8 5.0 2.4 0.4 138.3 62.9 17.9 5.0 2.5 0.4 0.077621 0.142848 0.405713 0.621984
95 140.3 61.6 17.6 4.9 2.4 0.4 137.9 62.6 17.8 5.0 2.4 0.4 0.063945 0.151623 0.411864 0.627854

Ce 128.0 60.4 17.3 4.8 2.3 0.4 14% 20% 42% 67% 70% 83%
Co 149.9 72.6 30.0 13.1 7.6 1.0
k 0.0083 0.0177 0.0340 0.0406 0.0417 0.0394
sum 167.0075 27.03749 16.62373 6.057775 1.724678 1.226325
n-p 18 18 18 18 18 18
s 3.046013 1.225595 0.96101 0.580123 0.309541 0.261016

Co Ce k q A%
149.86 128.04 0.0083 21.82 14.6%
72.60 60.36 0.0177 12.24 16.9%
29.97 17.27 0.0340 12.70 42.4%
13.13 4.79 0.0406 8.34 63.5%
7.62 2.34 0.0417 5.28 69.4%
0.98 0.36 0.0394 0.62 63.3%
C=7,8 C=3,1 C=156 C=78 C=31 C=14 C=7,8 C=3,1
mg/l mg/l mg/L mg/L mg/L mg/l mg/l mg/l D1 D2 D3 D4 D5 D6
-0.02164 -1.10288 0 0 0 0.419794 0.871353 0.995988 0.347278 7.069531 0.005122 1.940675 0.027178 1.168682
0.235464 -0.08887 0.005948 0.014256 0.066313 0.495554 0.885926 1.001846 1.351724 0.818381 2.186127 0.857318 0.63871 0.039262
0.331414 0.127736 0.011654 0.027307 0.122246 0.557051 0.897891 0.983715 0.417034 0.025295 8.493527 1.582937 0.522275 0.005928
0.38545 0.292978 0.017126 0.039254 0.169423 0.606969 0.907714 0.98243 0.000208 0.064265 2.542748 0.803049 0.229313 0.000103
0.43643 0.375809 0.022375 0.050191 0.209215 0.64749 0.915779 0.955755 9.899022 4.152884 0.103384 0.469825 0.112343 0.000892
0.45422 0.441573 0.027409 0.060203 0.242778 0.680381 0.9224 0.967752 0.396316 4.357569 0.207921 0.076264 0.001505 0.001926
0.492483 0.480296 0.032238 0.069368 0.271087 0.70708 0.927836 0.982858 5.350308 1.819948 0.789189 0.003702 0.000411 0.001634
0.516158 0.516985 0.036869 0.077758 0.294965 0.728752 0.932299 0.949485 3.591528 0.947683 1.287746 0.010237 0.015501 0.001796
0.535592 0.544754 0.041311 0.085439 0.315105 0.746344 0.935963 0.964795 1.039297 0.039279 0.130568 0.078188 0.043035 0.001737
0.57236 0.541292 0.045572 0.092471 0.332093 0.760624 0.938972 0.967752 4.377972 0.023433 0.113764 0.035427 0.013185 0.000236
0.580356 0.562028 0.049659 0.098907 0.346421 0.772216 0.941442 0.968175 7.655901 1.948906 0.165964 0.033117 0.042486 0.000285
0.595549 0.558579 0.053578 0.1048 0.358507 0.781625 0.943469 0.958271 3.608266 0.16623 0.203038 0.041144 0.045762 3.83E-06
0.623526 0.594671 0.057338 0.110194 0.3687 0.789262 0.945134 0.963108 10.0709 0.042271 0.253863 0.062754 0.01021 0.00043
0.638169 0.57752 0.060944 0.115132 0.377298 0.795462 0.946501 0.954917 6.303479 0.753167 0.088544 0.025385 0.005026 4.21E-05
0.652532 0.599803 0.064403 0.119653 0.38455 0.800494 0.947623 0.955755 9.935444 0.822146 9.57E-07 0.024911 0.000759 4.63E-05
0.672184 0.620274 0.06772 0.123791 0.390667 0.804579 0.948544 0.869233 82.09008 0.952902 0.011693 0.000696 0.004698 0.000394
0.66316 0.625377 0.070902 0.127579 0.395826 0.807895 0.9493 0.935589 1.354555 1.257631 0.015618 0.002537 0.001915 0.000364
0.662894 0.57752 0.073954 0.131047 0.400178 0.810587 0.949921 0.949694 13.63882 0.276361 6E-05 0.00182 0.006581 0.00106
0.681462 0.591246 0.076882 0.134222 0.403849 0.812772 0.950431 0.920812 0.01227 0.392198 0.003122 0.001665 0.001002 0.000528
0.687288 0.586104 0.079689 0.137128 0.406944 0.814545 0.95085 0.934764 5.567091 1.107405 0.02173 0.006124 0.002784 0.000974

167.0075 27.03749 16.62373 6.057775 1.724678 1.226325

 160.0

140.0
C (mg/L)

120.0 C=156 mg/L

C=78 mg/L
100.0 C=31 mg/L
C=14 mg/l
80.0 C=7,8 mg/l
C=3,1 mg/l
60.0 C=156 mg/L
C=78 mg/L
40.0 C=31 mg/L
C=14 mg/l

20.0 C=7,8 mg/l

C=3,1 mg/l

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 160.0

150.0
C (mg/L)

140.0

130.0
C=156
mg/L

120.0

110.0

100.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 80.0
75.0
C (mg/L)

70.0
65.0
60.0
55.0
C=78
mg/L
50.0
45.0
40.0
35.0
30.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 35.0

30.0
C (mg/L)

25.0

20.0

C=31
15.0 mg/L

10.0

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 16.0

14.0
C (mg/L)

12.0

10.0

8.0
C=14
mg/l
6.0

4.0

2.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.0

8.0

7.0
C (mg/L)

6.0

5.0

4.0 C=7,8
mg/l
3.0

2.0

1.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 2.5

2.0
C (mg/L)

1.5

C=3,1
1.0 mg/l

0.5

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 3.055536 2.701244 2.535562 2.275821 1.695472 0.531453
5 3.095265 2.493955 2.222382 1.772161 1.249978 -0.34608
10 2.966802 2.31233 1.811122 1.458564 1.014937 -0.70292
15 2.957042 2.266247 1.795633 1.292062 0.853338 -1.09912
20 2.729327 1.880653 1.808924 1.104333 0.672454 -1.37843
25 2.838193 1.754631 1.770805 1.010132 0.600752 -1.67392
30 2.960305 1.767185 1.697375 0.92724 0.42654 -1.9001
35 2.667339 1.726473 1.607528 0.748815 0.30126 -2.17515
40 2.812439 1.830156 1.284665 0.653835 0.185223 -2.4491
45 2.838193 1.68141 1.125037 0.424925 -0.07976 -2.41056
50 2.841824 1.864845 1.001015 0.244295 -0.14802 -2.6673
55 2.753164 1.617175 0.876335 0.092008 -0.29216 -2.61975
60 2.797447 1.491805 0.7654 -0.02039 -0.62834 -3.28495
65 2.721263 1.557906 0.522305 -0.28158 -0.86297 -2.91407
70 2.729327 1.49505 0.157038 -0.44053 -1.16324 -3.42924
75 0.960499 1.441865 -0.12832 -0.86052 -1.8156 -4.39443
80 2.514495 1.4107 -0.34513 -0.98338 -1.46319 -4.91384
85 2.669463 1.179059 -0.36393 -1.5072 -1.45449 -2.91407
90 2.321376 0.625338 -0.62209 -1.74393 -2.38549 -3.19908
95 2.504641 0.208485 -1.0427 -2.32543 -3.0438 -3.08259

Ce 128.037 60.35873 17.27257 4.789347 2.335013 0.359866

Co 149.8589 72.59813 29.96766 13.13218 7.619371 0.980212
ln(Co-Ce) 3.0829 2.5047 2.5412 2.1214 1.6648 -0.4775
k 0.0083 0.0177 0.0340 0.0406 0.0417 0.0394
R -0.5508 -0.9075 -0.9820 -0.9824 -0.9752 -0.8840
R^2 0.3033 0.8235 0.9644 0.9652 0.9511 0.7815
 4
C=156 mg/L
3 Linear
ln(C-Ce)

(C=156 mg/L)
2
C=78 mg/L
1 Linear (C=78
mg/L)
0 C=31 mg/L
0 50 100
-1 Linear (C=31
mg/L)
-2 C=14 mg/l
-3 Linear (C=14
mg/l)
-4 C=7,8 mg/l
-5 Linear (C=7,8
mg/l)
-6 C=3,1 mg/l
t (min)
ln(C-Ce) 3.5
3
2.5
2
1.5
1 C=156 mg/L
0.5
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5 C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100
t (min)
ln(C-Ce) 3
2.5
2
1.5
1
0.5
0
-0.5 C=31 mg/L
-1
-1.50 10 20 30 40 t 50 60 70 80 90 100
(min)
 3

2
ln(C-Ce)

-1
0 10 20 30 40 50 60 70 80 90 100
C=14 mg/l
-2

-3
t (min)
 2
ln(C-Ce)
1

-1
0 10 20 30 40 50 60 70 80 90 100
-2 C=7,8 mg/l

-3

-4

t (min)
ln(C-Ce) 1
0
0 10 20 30 40 50 60 70 80 90100
-1
-2
-3
-4
-5
-6

t (min)
 C=156 C=78 C=31 C=14 C=7,8 C=3,1
t (min) mg/L mg/L mg/L mg/l mg/l mg/l
0 -0.02738 0.196584 -0.00565 0.154419 0.03072 1.008931
5 0.012353 -0.01071 -0.31883 -0.34924 -0.41477 0.131393
10 -0.11611 -0.19233 -0.73009 -0.66284 -0.64981 -0.22544
15 -0.12587 -0.23841 -0.74558 -0.82934 -0.81141 -0.62164
20 -0.35359 -0.62401 -0.73229 -1.01707 -0.9923 -0.90095
25 -0.24472 -0.75003 -0.77041 -1.11127 -1.064 -1.19644
30 -0.12261 -0.73747 -0.84384 -1.19416 -1.23821 -1.42262
35 -0.41557 -0.77819 -0.93369 -1.37259 -1.36349 -1.69767
40 -0.27047 -0.6745 -1.25655 -1.46757 -1.47953 -1.97162
45 -0.24472 -0.82325 -1.41618 -1.69648 -1.74451 -1.93308
50 -0.24109 -0.63981 -1.5402 -1.87711 -1.81277 -2.18982
55 -0.32975 -0.88748 -1.66488 -2.02939 -1.95691 -2.14228
60 -0.28547 -1.01286 -1.77582 -2.14179 -2.29309 -2.80747
65 -0.36165 -0.94675 -2.01891 -2.40298 -2.52772 -2.43659
70 -0.35359 -1.00961 -2.38418 -2.56194 -2.82799 -2.95176
75 -2.12241 -1.06279 -2.66953 -2.98192 -3.48035 -3.91695
80 -0.56842 -1.09396 -2.88635 -3.10478 -3.12794 -4.43637
85 -0.41345 -1.3256 -2.90514 -3.62861 -3.11924 -2.43659
90 -0.76154 -1.87932 -3.16331 -3.86534 -4.05024 -2.7216
95 -0.57827 -2.29617 -3.58392 -4.44683 -4.70855 -2.60511

Ce 128.037 60.35873 17.27257 4.789347 2.335013 0.359866

Co 149.8589 72.59813 29.96766 13.13218 7.619371 0.980212
k 0.0083 0.0177 0.0340 0.0406 0.0417 0.0394
 2
ln[(C-Ce)/(Co-Ce)]
C=156 mg/L
1
Linear (C=156 mg/L)

C=78 mg/L
0
0 10 20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)

C=31 mg/L
-1
Linear (C=31 mg/L)

-2 C=14 mg/l

Linear (C=14 mg/l)

-3 C=7,8 mg/l

Linear (C=7,8 mg/l)

-4
C=3,1 mg/l

Linear (C=3,1 mg/l)

-5
t (min)
0.5

0
0 f(x)10
= - 0.0083413768x
20 30 40 50 60 70 80 90 100
R² = 0.6179235541
-0.5
C=156 mg/L
Linear (C=156 mg/L)
-1

-1.5

-2

-2.5
t (min)
0.5

C=78 mg/L
0
0 f(x)10
= - 0.0176701924x
20 30 40 50 60 70 80 90 100 Linear (C=78 mg/L)
R² = 0.945452189
-0.5

-1

-1.5

-2

-2.5
t (min)
 0
0 f(x) 10
= - 0.0340477348x
20 30 40 50 60 70 80 90 100
R² = 0.9901621895
-0.5 C=31 mg/L
Linear (C=31 mg/L)
-1

-1.5

-2

-2.5

-3

-3.5

-4
t (min)
1

0
0 f(x) = 10
- 0.0406177x
20 30 40 50 60 70 80 90 100
R² = 0.9903796338
C=14 mg/l
-1 Linear (C=14 mg/l)

-2

-3

-4

-5
t (min)
1
C=7,8 mg/l
0 Linear (C=7,8 mg/l)
0 f(x) =10
- 0.0417180162x
20 30 40 50 60 70 80 90 100
R² = 0.9863441189

-1

-2

-3

-4

-5
t (min)
2
C=3,1 mg/l
1 Linear (C=3,1 mg/l)

0
0 f(x) = 10
- 0.039445988x
20 30 40 50 60 70 80 90 100
R² = 0.9299770554
-1

-2

-3

-4

-5
t (min)
 25.0

20.0
T (oC)

T(oC) 1
15.0
T(oC) 2
T(oC) 3
T(oC) 4
T(oC) 5
10.0
T(oC) 6

5.0

0.0
0 10 20 30 40 50 60 70 80 90 100
t (min)
 9.00

8.00

7.00

6.00
pH
1
pH

5.00 pH
2
pH
4.00 3
pH
4
3.00

2.00

1.00

0.00
0 10 20 30 40 50 60 70 80 90 100
t (min)