Carnot Cycle

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The efficiency of the cycle of a thermal machine depends largely on how it is

executed each of the processes that constitute the cycle. Net work and, for
Therefore, cycle efficiency can be maximized through processes that they require
the minimum amount of work and deliver as much as possible, that is, through
reversible processes.

Reversible isothermal expansion (process 1-2, constant TH). Initially (state 1),
the gas temperature is TH and the cylinder head is in close contact with a TH
temperature source. It allows the gas expand slowly and perform work on the
surroundings. When the gas expands its temperature tends to decrease, but as
soon as the temperature decreases by an infinitesimal amount dT, a certain
amount of heat is transferred from the reservoir to the gas, so that the
temperature from this it rises to TH.

Expansión adiabática reversible (proceso 2-3, la temperatura disminuye de TH a


TL). En el estado 2, el depósito que estuvo en contacto con la cabeza del cilindro
se elimina y se reemplaza por aislamiento para que el sistema se vuelva
adiabático.

Reversible isothermal compression (process 3-4, constant TL). At state 3, the


insulation of the head of the cylinder is removed and placed on it in contact with
a drain at TL temperature. After an external force pushes the cylinder inward, so
work is done on the gas.

Reversible adiabatic compression (process 4-1, temperature rises from TL to


TH). State 4 is such that when the low temperature reservoir is removed, the
insulation is placed again on the head of the cylinder and compresses the gas
reversibly, then the gas returns to its state initial (state 1).

Reverse Carnot cycle

The cycle of the Carnot thermal machine just described is completely reversible,
therefore all the processes it covers can be reversed, in which case becomes the
Carnot refrigeration cycle. This time, the cycle is exactly the same except that the
directions of the interactions of heat and work are reversed: the heat in the
amount QL is absorbed from a deposit at low temperature, the heat in the quantity
QH is rejected towards a deposit at high temperature, and a quantity of work is
required Wneto, entry to complete all this.

The second law of thermodynamics restricts the operation of devices cyclicals as


expressed by the Kelvin-Planck and Clausius statements. A thermal machine can
not operate exchanging heat with a single deposit, and a refrigerator can not work
without a net energy input from an external source.

A temperature scale that is independent of the properties of the


substances used to measure temperature is called thermodynamic scale
of temperature, which offers great advantages in calculations
thermodynamics, and its derivation is given below by means of some
reversible thermal machines

The quantities of heat rejected by machines B and C must be the same


because machines A and B can be combined in another reversible that
operates between the same deposits in which machine C does, therefore the
combined machine will have the same efficiency of the machine C. As the heat
input to machine C is the same as the heat input to the combined A and B, both
systems must reject the same amount of heat.
The hypothetical thermal machine that operates in the reversible Carnot cycle It
is called the Carnot thermal machine. The thermal efficiency of any Thermal
machine, reversible or irreversible, is determined by the equation

This relationship is called Carnot efficiency because the thermal machine


Carnot is the best known reversible machine. This is the efficiency maximum
that a thermal machine that operates between the two deposits can have
Thermal energy sites at temperatures TL and TH

A refrigerator or a heat pump, which operates in the reverse cycle of Carnot, It


is called Carnot cooler or Carnot heat pump. The coefficient of performance of
any refrigerator or heat pump, reversible or irreversible, is expressed by the
equations

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