Scribd Logo
Upload

Welcome to Scribd!

  • 483 views

    Titration Problems

    Uploaded by

    Angela Kocevska
    This document contains 5 titration problems involving acids and bases. Problem 1 calculates the pH at the equivalence point for the titration of HCN with NaOH. Problem 2 calculates the pH for the titration of HCl with NH3. Problem 3 calculates the volume of KOH needed to titrate a given volume of H2SO4. Problem 4 calculates the pH of the solution formed after mixing solutions of HClO4 and LiOH. Problem 5 calculates the concentration, mass in 1 L, and mass percent of acetic acid in vinegar from a neutralization reaction with NaOH.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd

    Titration Problems

    Uploaded by

    Angela Kocevska
    483 views8 pages
    This document contains 5 titration problems involving acids and bases. Problem 1 calculates the pH at the equivalence point for the titration of HCN with NaOH. Problem 2 calculates the pH for the titration of HCl with NH3. Problem 3 calculates the volume of KOH needed to titrate a given volume of H2SO4. Problem 4 calculates the pH of the solution formed after mixing solutions of HClO4 and LiOH. Problem 5 calculates the concentration, mass in 1 L, and mass percent of acetic acid in vinegar from a neutralization reaction with NaOH.

    Original Description:

    f

    Original Title

    titrat

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF, TXT or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    This document contains 5 titration problems involving acids and bases. Problem 1 calculates the pH at the equivalence point for the titration of HCN with NaOH. Problem 2 calculates the pH for the titration of HCl with NH3. Problem 3 calculates the volume of KOH needed to titrate a given volume of H2SO4. Problem 4 calculates the pH of the solution formed after mixing solutions of HClO4 and LiOH. Problem 5 calculates the concentration, mass in 1 L, and mass percent of acetic acid in vinegar from a neutralization reaction with NaOH.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    483 views8 pages

    Titration Problems

    Uploaded by

    Angela Kocevska
    This document contains 5 titration problems involving acids and bases. Problem 1 calculates the pH at the equivalence point for the titration of HCN with NaOH. Problem 2 calculates the pH for the titration of HCl with NH3. Problem 3 calculates the volume of KOH needed to titrate a given volume of H2SO4. Problem 4 calculates the pH of the solution formed after mixing solutions of HClO4 and LiOH. Problem 5 calculates the concentration, mass in 1 L, and mass percent of acetic acid in vinegar from a neutralization reaction with NaOH.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    You are on page 1of 8

    Titration Problems

    1) A 0.15 M solution of NaOH is used to titrate 200. mL of 0.15 M HCN. What


    is the pH at the equivalence point? (Ka = 4.9 x 10-10)

    2) A 0.25 M solution of HCl is used to titrate 0.25 M NH3. What is the pH at the
    equivalence point? (Kb = 1.8 x 10-5)

    3) What volume of 0.175 M solution of KOH is needed to titrate 30.0 mL of


    0.200 M H2SO4?

    4) 35.0 mL of a 0.040 M aqueous solution of perchloric acid reacts with 40.0 mL


    of a 0.090 M aqueous solution of lithium hydroxide. What is the pH of the
    solution?

    5) A 25.0 cm3 sample of vinegar, HC2H3O2, is neutralized by using 37.38 cm3 of


    a 0.500 M NaOH solution. Calculate:

    (a) the concentration of the vinegar.

    (b) the mass of vinegar in 1.00 dm3.

    (c) the mass percent of the vinegar assuming a density of 1.00 g/cm3.
    Solutions

    1) [HCN] = 0.15 M [NaOH] = 0.15 M

    Va = 200. mL Ka = 4.9 x 10-10

    [HCN] = na/Va

    na = [HCN] x Va

    na = 0.15 mol HCN/1 L x 200. mL x 1 L/103 mL = 0.030 mol HCN

    [NaOH] = nb/Vb

    Vb = nb/[NaOH] = 0.030 mol NaOH/0.15 M = 0.20 L x 103 mL/1 L

    = 2.0 x 102 mL NaOH

    NaOH(aq) Æ Na+(aq) + OH-(aq)

    HCN(aq) + OH-(aq) Æ CN-(aq) + H2O(l)

    mol before rxn: 0.030 0.030 0

    mol after rxn: 0 0 0.030

    [CN-] = n/V = 0.030 mol CN-/(400. mL x 1 L/103 mL) = 0.075 M

    CN-(aq) + H2O(l) ↔ HCN (aq) + OH-(aq)

    [ ]i 0.075 0 0

    [ ]c -x +x +x

    [ ]e 0.075 - x x x
    Ka x Kb = Kw = 1.00 x 10-14

    Kb = Kw/Ka = (1.00 x 10-14)/(4.9 x 10-10) = 2.0 x 10-5

    Kb = [HCN] x [OH-]/[CN-]

    2.0 x 10-5 = x · x/(0.075 - x) ≈ x2/0.075

    [OH-] = 1.2 x 10-3 M

    % ion = [HCN]/[CN-] x 100%

    % ion = (1.2 x 10-3 M)/(0.075 M) x 100% = 1.6%

    Because the % ion < 5%, 0.075 - x ≈ 0.075 is a valid assumption.

    Kw = [H+] x [OH-]

    [H+] = Kw/[OH-] = (1.00 x 10-14)/(1.2 x 10-3) = 8.3 x 10-12

    pH = -log[H+] = -log(8.3 x 10-12) = 11.08


    2) [HCl] = 0.25 M Kb = 1.8 x 10-5

    [NH3] = 0.25 M

    Assume Va = Vb = 100. mL.

    [HCl] = na/Va

    na = [HCl] x Va

    na = 0.25 mol HCl/1 L x 100. mL x 1 L/103 mL = 0.025 mol HCl

    [NH3] = nb/Vb

    nb = [NH3] x Vb = 0.025 mol NH3

    HCl(aq) Æ H+(aq) + Cl-(aq)

    H+(aq) + NH3(aq) Æ NH4+(aq)

    mol before rxn: 0.025 0.025 0

    mol after rxn: 0 0 0.025

    [NH4+] = n/V = 0.025 mol NH4+/(200. mL x 1 L/103 mL) = 0.12 M

    Ka x Kb = Kw = 1.00 x 10-14

    Ka = Kw/Kb = (1.00 x 10-14)/(1.8 x 10-5) = 5.6 x 10-10

    NH4+ (aq) ↔ H+(aq) + NH3(aq)

    [ ]i 0.12 0 0

    [ ]c -x +x +x

    [ ]e 0.12 - x x x
    Ka = [H+] x [NH3]/[NH4+]

    5.6 x 10-10 = x · x/(0.12 - x) ≈ x2/0.12

    [H+] = 8.2 x 10-6 M

    % ion = [H+]/[NH4+] x 100%

    % ion = (8.2 x 10-6 M)/(0.12 M) x 100% = 6.8 x 10-3%

    Because the % ion < 5%, 0.12 - x ≈ 0.12 is a valid assumption.

    pH = -log[H+] = -log(8.2 x 10-6) = 5.09


    3) [KOH] = 0.175 M [H2SO4] = 0.200 M

    Vb = ? Va = 30.0 mL

    2KOH(aq) + H2SO4(aq) Æ K2SO4(aq) + 2H2O(l)

    H+(aq) + OH-(aq) Æ H2O(l)

    [H2SO4] = na/Va

    na = nb

    [H2SO4] x Va = [KOH] x Vb

    0.200 mol H2SO4/L x 30.0 mL x 1 L/103 mL x 2 mol H+/1 mol H2SO4 =

    0.175 mol KOH/L x Vb x 1 mol OH-/1 mol KOH

    Vb = 0.0686 L x 103 mL/L = 68.6 mL KOH


    4) [HClO4] = 0.040 M [LiOH] = 0.090 M

    Va = 35.0 mL Vb = 40.0 mL

    [HClO4] = na/Va

    na = [HClO4] x Va

    na = 0.040 mol HClO4/1 L x 35.0 mL x 1 L/103 mL x 1 mol H+/1 mol HClO4

    na = 0.0014 mol H+

    [LiOH] = nb/Vb

    nb = 0.090 mol LiOH/1 L x 40.0 mL x 1 L/103 mL x 1 mol OH-/1 mol LiOH

    nb = 0.0036 mol OH-

    HClO4(aq) Æ H+(aq) + ClO4-(aq)

    LiOH(aq) Æ Li+(aq) + OH-(aq)

    H+(aq) + OH-(aq) Æ H2O(l)

    mol before rxn: 0.0014 0.0036

    mol after rxn: 0 0.0022

    [OH-] = n/V = 0.0022 mol OH-/(75.0 mL x 1 L/103 mL) = 0.029 M

    pH = -log[OH-] = -log(0.029) = 1.54

    pH + pOH = 14.00

    pH = 14.00 – pOH = 14.00 – 1.54 = 12.46


    5) [HC2H3O2] = ? [NaOH] = 0.500 M

    Va = 25.0 cm3 Vb = 37.38 cm3

    HC2H3O2(aq) + NaOH(aq) Æ NaC2H3O2(aq) + H2O(l)

    H+(aq) + OH-(aq) Æ H2O(l)

    (a) [HC2H3O2] = na/Va [NaOH] = nb/Vb

    na = nb

    [HC2H3O2] x Va = [NaOH] x Vb

    [HC2H3O2] = [NaOH] x Vb/Va

    [HC2H3O2] = 0.500 M x 37.38 cm3/25.0 cm3 = 0.748 M

    (b) [HC2H3O2] = na/Va

    na = [HC2H3O2] x Va

    na = 0.748 mol HC2H3O2/L x 1.00 dm3 x 1 L/1 dm3 = 0.748 mol HC2H3O2

    ma = 0.748 mol HC2H3O2 x 60.06 g HC2H3O2/1 mol HC2H3O2

    ma = 44.9 g HC2H3O2

    (c) D = M/V

    M = D x V = 1.00 g/cm3 x 1.00 L x 103cm3/1 L = 1.00 x 103 g

    m% = ma/msoln x 100% = 44.9 g/(1.00 x 103 g) x 100% = 4.49%

    You might also like

    pFad - Phonifier reborn

    Pfad - The Proxy pFad of © 2024 Garber Painting. All rights reserved.

    Note: This service is not intended for secure transactions such as banking, social media, email, or purchasing. Use at your own risk. We assume no liability whatsoever for broken pages.


    Alternative Proxies:

    Alternative Proxy

    pFad Proxy

    pFad v3 Proxy

    pFad v4 Proxy