12th CRP Adv2 PDF

FIITJEE
PHYSICS, CHEMISTRY & MATHEMATICS
CPT-1 CODE:110666 PAPER - 2

SET - A
Time Allotted: 3 Hours Maximum Marks: 201
 Please read the instructions carefully. You are allotted 5 minutes specifically for
this purpose.
 You are not allowed to leave the Examination Hall before the end of the test.
INSTRUCTIONS
Caution: Question Paper CODE as given above MUST be correctly marked in the answer
OMR sheet before attempting the paper. Wrong CODE or no CODE will give wrong results.
BATCHES –1719
A. General Instructions
1. Attempt ALL the questions. Answers have to be marked on the OMR sheets.
2. This question paper contains Three Sections.
3. Section-I is Physics, Section-II is Chemistry and Section-III is Mathematics.
4. Each Section is further divided into Two Parts: Part-A & B.
5. Rough spaces are provided for rough work inside the question paper. No additional sheets will be
provided for rough work.
6. Blank Papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic
devices, in any form, are not allowed.
B. Filling of OMR Sheet

1. Ensure matching of OMR sheet with the Question paper before you start marking your answers on
OMR sheet.
2. On the OMR sheet, darken the appropriate bubble with Blue/Black Ball Point Pen for each
character of your Enrolment No. and write in ink your Name, Test Centre and other details at the
designated places.
3. OMR sheet contains alphabets, numerals & special characters for marking answers.
C. Marking Scheme For All Three Parts.

(i) Part-A (01 – 06) contains 6 Multiple Choice Questions which have Only One Correct answer. Each
question carries +3 marks for correct answer and –1 mark for wrong answer.
(ii) Part-A (07 – 09) contains 3 Assertion-Reasoning Questions (MCQs) which have Only One Correct
answer. Each question carries +3 marks for correct answer and – 1 mark for wrong answer.
(iii) Part-A (10 – 15) contains 2 Paragraphs. Based upon each paragraph, 3 Multiple Choice Questions
have to be answered. Each question has Only One Correct answer and carries +4 marks for the
correct answer and –1 mark for a wrong answer.
(iv) Part-B (01 – 02) contains 2 Matrix Match Type Questions which have statements given in 2
columns. Statements in the first column have to be matched with statements in the second column.
There may be One or More Than One Correct choices. Each question carries +8 marks for all
correct answer however for each correct row +2 marks will be awarded and –1 mark for each row
matched incorrectly.
Name of the Candidate :____________________________________________
Batch :____________________ Date of Examination :___________________
Enrolment Number :_______________________________________________

JEE ADV PAPER – 2 SET - A – PCM-2
Useful Data Chemistry:

Gas Constant = 8.314 J K1 mol1
R
= 0.0821 Lit atm K1 mol1
= 1.987  2 Cal K1 mol1
Avogadro's Number Na = 6.023  1023
Planck’s Constant h = 6.626  10–34 Js
= 6.25 x 10-27 erg.s
1 Faraday = 96500 Coulomb
1 calorie = 4.2 Joule
1 amu = 1.66 x 10-27 kg
1 eV = 1.6 x 10-19 J
Atomic No : H=1, D=1, Li=3, Na=11, K=19, Rb=37, Cs=55, F=9, Ca=20, He=2, O=8,
Au=79.
Atomic Masses: He=4, Mg=24, C=12, O=16, N=14, P=31, Br=80, Cu=63.5, Fe=56, Mn=55,
Pb=207,
Au=197, Ag=108, F=19, H=2, Cl=35.5, Sn=118.6
Useful Data Physics:
Acceleration due to gravity g = 10 m / s2
FIITJEE Ltd., Bhopal Centre. Plot No. 102, Zone-2, M.P. Nagar, Bhopal. Ph. : 07554253355, 4253455
website: www.fiitjee.com
S
SEEC
CTTIIO
ONN–– 1
1:: P
PHHY
YSSIIC
CSS
PART – A
(Single Correct Choice Type)
This section contains 6 multiple choice questions. Each question has four choices (A), (B), (C) and (D) out of
which ONLY ONE is correct.
1. In the given figure the time constant of the circuit for current is
(a) RC (b) 2RC (c) 3RC (d) RC/2
2. Convert the given v-x graph into E-x graph
(a) (b)
(c) (d)
3. A parallel plate capacitor C has initially charge Q on its one of the plates [i.e. no charge on one plate
and Q charge on second plate]. If space between capacitor charge plate is filled with slab of finite
electrical resistance. Find total energy lost in the slab.
Q2 Q2 3Q2 7Q2
(a) (b) (c) (d)
2C 8C 8C 8C
4. An ideal battery of EMF  is connected in series with an ammeter and a voltmeter of unknown internal
resistance. If a certain resistance is connected in parallel with voltmeter. The voltmeter and ammeter
readings becomes 1/n and n times of their respective initial readings. What is initial reading of voltmeter
?
 n n (n  1) 
(a) (b) (c) (d)
(n  1) (n  1) (n  1) n
5. A thin conducting shell of radius r carry total charge q. Two point charges q and 2q are at points A and
B. If shell is earthed how much charge will flow to earth ?
FIITJEE Ltd., Bhopal Centre. Plot No. 102, Zone-2, M.P. Nagar, Bhopal. Ph. : 0755-4253355, 4253455
(a) 2q (b) 4q (c) 2.5q (d) 3q
6. The circuit shown in figure extends to the right into  . Each branch resistance is r. Find resistance
between A and B.
( 5  1)r ( 5  1)r
(a) (b) (c) ( 5  1) r (d) ( 5  1)r
2 2
PART – A
Assertion – Reason Type
This section contains 3 questions numbered 7 to 9. Each question contains STATEMENT-1 (Assertion)
and STATEMENT – 2 (Reason). Each question has 4 choices (a), (b), (c) and (d) out of which ONLY
ONE is correct.
7. STATEMENT 1: When ever a capacitor (charged or uncharged) is connected across a battery.

Half of the work done by battery is decipitade into heat.
Because
STATEMENT 2: When ever current flow through resistance heat is generated in it.
(a) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(b) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for Statement-1
(c) Statement-1 is True, Statement-2 is False
(d) Statement-1 is False, Statement-2 is True.
8. STATEMENT 1: Work done by magnetic force is always zero.
Because
STATEMENT 2: In the given figure force acts on wire which is free to slide over rails. This force
changes Kinetic energy of rod.
9. STATEMENT 1: EMF of cell is due to battery force which is always conservative in nature.
Because
STATEMENT 2: EMF and potential difference across ideal [zero internal resistance] cell are
different things.
(Paragraph Type)
This section contains 2 paragraphs. Based upon the paragraphs 3 multiple choice questions have to be
answered. Each of these questions has 4 choices (A), (B), (C) and (D) out of which ONLY ONE is correct.
Paragraph for Question no. 10 to 12
Plate area is A (d1 > d2)

Charge on middle plate is Q
10. Electric field E1 between two upper plates is

Qd2 Qd1 Qd2 Qd1
(a) (b) (c) (d)
(d1  d2 )A0 (d1  d2 )0 A 4(d1  d2 )0 A 20 A(d1  d2 )
11. Net force on middle plate is

Q2 Q2 d1 Q2 (d1  d2 ) Q2 (d1  d2 )
(a) (b) (c) (d)
2 0 A 2 0 A d2 20 A (d1  d2 ) 20 A(d1  d2 )
12. Total electrostatic energy inside plate system

Q2 d1d2 Q2 d1d2 Q2 d1d2 Q2 d1d22
(a) (b) (c) (d)
0 A(d1  d2 ) 20 A(d1  d2 ) 40 A(d1  d2 ) 40 A(d1  d2 )2

A wire loop carrying current I is placed in the X-Y plane as shown in the figure (i) If a particle with
charge +Q and mass m is placed at the centre P and given a velocity along NP (figure).
13. Magnetic field at centre P is

 I 3 3   I 3 3   0I  3 3 
(a) 0   2 (b) 0   1 (c)  1 (d) 0
6a    4a    6a   
14. If an external uniform magnetic field B  Biˆ is applied, find the torque acting on the loop due to the
field.
 3  2ˆ  3  2ˆ  3  2ˆ
(a)   BI    a j (b)   BI    a j (c)   BI   a j (d) None of these
3 4  3 2  6 4 
15. Find the instantaneous acceleration of point mass m.

QV 0I  3 3  QV 0I  3 3  QV 0I  3 3 
(a)   2 (b)   1 (c)  1 (d) None of these
m 6a    m 4a    m 6a   
PART - B
Matrix-Match Type
This section contains 2 questions. Each question contains statements given in two columns which have
to be matched. Statements (a, b, c, d) in Column I have to be matched with statements (p, q, r, s) in
Column II. The answer to these questions have to be appropriately bubbled as illustrated in the
following example. If the correct matches are a-p, a-s, b-q, b-r, c-p, c-q and d-s, then the correctly
bubbled 4 × 4 matrix should be as follows :
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
Match the conditions/expressions in Column I with statements in Column II and indicate your answer
by darkening the appropriate bubbles in the 4 × 4 matrix given in OMR
1. The following statements have been made regarding the electric field E   xiˆ  yjˆ . Then match
Column-I with Column-II. (magnitude in SI units)
Column-I Column-II
(a) Electric field value at a distance ‘A’ from origin is (P) A
(b) If Potential at origin is zero. Potential at point (A, (Q) A2
A) is____
(c) If Particle of mass m = 1 kg and charge Q = 1 (R) A2/2
coulomb is moving on a circle x2 + y2 = A2. Then
its speed will be ____
(d) A –ve charge is just released at origin (Q = - 1 (S) A/ 2
coulomb) and reaches a distance ‘A’ from origin
with velocity. (m – 1 kg)
2. A conducting ring of mass m and radius r is placed on a smooth horizontal plane. The ring carries a
current i. A horizontal magnetic field B is switched on at t = 0 as shown :
Column-I Column-II
(a) Magnetic moment of the loop (P) 2ir B 2
mr 2
(b) Torque acting on the loop (Q) ir 2
(c) Initial angular acceleration of loop (R) ir 2B
(d) Angular velocity of loop at time t = 1 sec (S) None of these
S
SEEC
CTTIIO
ONN--2
2:: C
CHHE
EMMIIS
STTR
RYY
PART – A
1. In the reaction
NH2
(i) Br / HOH

2
[X]
(ii) NaNO2 / HCl
(iii)HF / BF3
(iv) 
[X] will be :
(a) p  Bromofluorobenzene (b) 2, 4, 6–Tribromofluorobenzene
(C) p–Bromoaniline (D) 1, 3, 5–Tribromobenzene
2. In the given reaction sequence:

CHCl / Alc.KOH H O /H
C6H5  CH2  NH2 
3
[X] 
2

[Y]

Y will be:
(A) C6H5  CN (B) C6H5NC
(C) C6H5  CH2  NH2 (D) C6H5  CH2OH
3. The given reaction

H3C CH3

C CH3 O/ CH3OH
CH2 
 H3C C CH 2OCH 3
H3C O
OH
is example of:
(A) SN1 reaction (B) SN2 reaction
(C) Unimolecular addition (D) Bimolecular addition
Space For Rough Work
4. In the given reaction,

OH
COOH
Br / CH COOH

2 3
[X]
[X] will be:
(A) OH (B) OH
Br Br
COOH
Br Br
(C) OH (D) OH
H3C COOH Br
Br Br
5. In the given reaction

O O
C H ONa
C CH 3 + CH3 C OC2H5 
2 5
C H OH
[X]
2 5
[X] will be:
OH O O
(A) C CH2 C CH3 (B) CH CH C CH3

H
O O
O
(C) H3C C CH2 C (D) ||
CH3  C CH2  COOH
6. In the given reaction sequence
 
(i) OH NH2NH2 / OH
(A)  (B)
(ii) C6H5CHO / 
O
Compound (B) is
(A) CH C 6H 5 (B)
CH C 6H5
(C) CH2 C6H5 (D)
CH2 C6H5
PART – A
ONE is correct.
7. STATEMENT 1: Salicylic acid is more acidic than p–hydroxy benzoic acid

Because
STATEMENT 2: Intramolecular hydrogen bonding takes place in salicylic acid
8. STATEMENT 1: Formaldehyde is more reactive than benzaldehyde for nucleophilic addition

reaction
Because
STATEMENT 2: Formaldehyde undergo self-aldol condensation
9. STATEMENT 1: Epoxide always gives SN2 reaction with Grignard reagent

Because
STATEMENT 2: The reaction is catalysed by acid as well as base
(Paragraph Type)
Compound (A) C4H8O2 on reduction with LiAlH4 gives only one compound (B) C2H6O. Compound (B)
gives iodoform test. Compound (A) gives the following sequence of reactions:
 
C2H5ONa H3 O (i) NaH/ THF (i)H3 O
(A)  (C)  (D) (E)  (F)
C2H5OH (ii) CH2CH  CH2 (ii) 
|
Br
10. Compound (A) is
O
||
(A) CH3  COOCH2  CH3 (B) CH3  CH2  C O  CH3
(C) CH3  CH2  CH2  COOH (D) CH3  CH  COOH
|
CH3
11. Compound (F) gives the following reaction:
O
||
Ozonolysis NaOH
(F)  G H  C H, G 
H

structure of (H)
(A) O (B) O
H 3C
(C) O (D) O
OH
OH
12. In the given reaction sequence product (P) is

HBr CH MgBr
(F) 
(M) 
3
(P)
OH Br O
| | ||
(A) CH3  C  CH2  CH2  C H  CH3 (B) CH3  C CH2  CH2  C H  CH3
| |
CH3 CH3
H3C
OH
| O CH3
H3C
(C) CH3  C  CH2  CH2  C H  CH3 (D)
| |
CH3 CH3

Fischer represented the structure of D-(+)-glucose with the cross formulation–
CHO
H OH
OH H
H OH
H OH
CH2–OH
Glucose exists in two cyclic forms which are called hemiacetal forms. They are formed by an intramolecular
reaction of one of the –OH group with aldehyde group. Two forms are known as anomers of each-other
hemiacetal carbon is called anomeric carbon and anomers differ in configuration of anomeric carbon and
named as -D-(+)-glucose and -D-(+)-glucose in aqueous solution and -anomers exist in equilibrium
Aqueous solution of D-glucose shows an optical rotation +52.2º.
13. Correct stereochemical designation of D-(+)-glucose is–
(A) (2R, 3R, 4S, 5R) (B) (2R, 3S, 4S, 5R)
(C) (2R, 3S, 4R, 5R) (D) (2R, 3S, 4R, 5S)
14.  and -anomers of glucose have following structures

CH2OH CH2OH
H O H H O OH
H H
&
OH H OH H
OH OH OH H
H OH H OH
Choose the correct statement–
(A) They are Diastereomers of each other
(B) They have different optical activity
(C) They have D-configuration
(D) all
15. -D-(+)-glucose having optical rotation +112º is dissolved in water slowly, this solution shows an optical
rotation about +52.2º. Choose the correct alternative for this change–
(A) In solution -and -D-(+)-glucose both are present
(B) -D-glucose is first converted in to open chain form then, further hemiacetal formation gives both ,
 anomers.
(C) Process is known as mutarotation.
(D) All
PART - B
Matrix-Match Type
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. Match List–I with List–II
LIST – I LIST – II
(A) CH2Cl2 (P) Thermal elimination
CH3
+ -
(B) H3C CH2 CH N O (Q) Hofmann elimination
CH3 CH3
H3C CH2 CH N(CH 3)3OH

(C) (R) E2 reaction
CH3
H3C CH2 CH F
 –elimination
(D) (S)
CH3
(T) Cope elimination
2. Match List–I with List–II
LIST – I LIST– II
OH OH
CHO
(A) (P) Electrophilic aromatic substitution
OH OH
COOH
(B) (Q) Kolbe reaction
OH OH
COCH 3
(C) (R) Reimer–Teimann carbonylation
HO OH HO OH
OH
(D) (S) Reimer–Teimann carboxylation
HO N N SO3H
Intramolecular hydrogen bonding

(T)
S
SEEC
CTTIIO
ONN--3
3:: M
MAAT
THHE
EMMA
ATTIIC
CSS
PART – A
1. If f : R  R, g : R  R be two functions, then F(x) = 2 min  f(x)  g(x), 0 equals 

(A) f(x)  g(x)  g(x)  f(x) (B) f(x)  g(x)  g(x)  f(x)
(C) f(x)  g(x)  g(x)  f(x) (D) f(x)  g(x)  g(x)  f(x)
2. If f(x)  x3  ax2  bx  c attains it’s local minima at certain negative real number, then –
(A) a2  3b  0, a  0, b  0 (B) a2  3b  0, a  0, b  0
(C) a2  3b  0, a  0, b  0 (D) a2  3b  0, a  0, b  0
3. If x is a real number in [0, 1], then the value of f(x)  lim

m n
 
lim 1  cos2m (n! x) is given by –
(A) 2 or 1 according as x is rational or irrational (B) 1 or 2 according as x is rational or irrational

(C) 1 for all x (D) 1 or 2 for all x
 etan x 1 x  x2 .d cot1 x is equal to –

1
4.
1 1
(A) etan x  c (B) etan x  c
1 1
(C)  x.etan x  c (D) x.etan x  c
b
 b  a   a  b 
5. 
If f(x)  x3 and f(x)dx  
 6  
f(a)  f(b)  k f
 2  
then k is equal to
a
(A) 0 (B) 2
(C) 3 (D) 4
6. The length of longest interval in which Rolle’s theorem can be applied for the function f(x)  x2  4 is –
(A) 4 (B) 4 2
(C) 2 (D) 16
PART – A
ONE is correct.
7. STATEMENT 1: The graph of y = x3 + ax2 + bx + c has no extremum if a2 > 3b.

Because
STATEMENT 2: y is either increasing or decreasing x R
(A) Statement-1 is True, Statement-2 is True ; Statement-2 is a correct explanation for Statement-1
(B) Statement-1 is True, Statement-2 is True ; Statement-2 is Not a correct explanation for Statement-1
(C) Statement-1 is True, Statement-2 is False
(D) Statement-1 is False, Statement-2 is True.
8. STATEMENT 1: f(x)  sin x  [x] is discontinuous at x = 0. where [.] is G.I.F.

Because
STATEMENT 2: If g(x) is continuous and h(x) is discontinuous at x =a then g(x) +h(x) will
necessarily be discontinuous at x = a
9. STATEMENT 1: If f(x) = cosx and g(x) = x2, then f(g(x)) is an even function.
Because
STATEMENT 2: If f(g(x) is an even function, then both f(x) and g(x) must be even function.
(Paragraph Type)

x
0
Let f : R  R be a differentiable function such that f(x)  x2  e t f(x  t)dt
10. f(x) increases for –
(A) x > –1 (B) x < –2
(C) x > –2 (D) None
11. y = f(x) is –
(A) injective but not surjective (B) Surjective but not injective
(C) Bijective (D) Neither injective nor surjective
1
12. The value of 0 f(x)dx is equal to –
1 1
(A) (B) 
4 12
5 12
(C) (D)
12 7

2
Consider the curve x  1  3t , y  t  3t3 . If a tangent at point (1–3t2, t–3t3) inclined at an angle  to
positive x–axis and another tangent at point P(–2, 2) cuts the curve again at Q.
13. The value of tan   sec  is equal to –

(A) 3t (B) t
(C) t– t2 (D) t2 – 2t
14. The point Q is –

 1 2 
(A) (1, –2) (B)  ,
 3 9 
 2 1
(C)  ,  (D) None
 3 3
15. The angle between the tangents at P and Q is –

 
(A) (B)
4 6
 
(C) (D)
3 2
PART - B
Matrix-Match Type
p q r s
(a) p q r s
(b) p q r s
(c) p q r s
(d) p q r s
1. Match the column –
Column I Column II
(A) x (p) ln 2
0 sin t dt
2
lim
x0 2sin x  sin2x
(B) e dx (q) 1/2
1 ln(x x .ex )
(C) n (r) 1/3
 k 
lim
n
n  sin  
 2n 
k 1
(D) n2 n2 n2 (s) 1
lim   ...... 
n (n2  1)3 / 2 (n2  22 )3 / 2 (n2  (n  1)2 )3 / 2 2
1 x 1
2 let f(x)  x and g(x) 
x x2
Match the composite function given in column I with their respective domains given in column II.
Column I Column II
(A) fog (p)  5 
R  2, 
 3 
(B) gof (q) R– {–1, 0}
(C) fof (r) R–{0}
(D) gog (s) R–{–2, –1}
ANSWERS (ADV) PAPER – 2 SET - A

SR. NO PHYSICS C.CODE CHEMISTRY C. CODE MATHS C.CODE
1. C P120216 B C124514/524 D M113418
2. A P120106 C C12507 D M120608
3. B P120114 B C124603 A M110615
4. B P12021 B C121401 C M120803
5. D P120111 C C122709 D M120802
6. C P120215 A C121709 A M120613
7. D P120420 B C122815 D M120608/04
8. B P120306 C C121401 A M113617
9. D P120516 B C121807 C M113420
10. A P120424 A C121504 B M113423
11. D P120424 A C121405 B M113410
12. D P120424 D C121405 C M120802
13. C P120302 C C122901 A M120601
14. A P120302 D C122902 B M120601
15. C P120302 D C114004 D M120601
1. P, Q, P, P P120407 S, PT, QR, QR C122902 R, P, Q, S M120801
2. Q, R, P, S P120307 PRT, PQST, PT, P C1221804/09/02 S, Q, R, P M113419
HINTS & SOLUTONS :
PHYSICS :
1.
By K.L.L
q i
   R  iR
c 2
q 3
   iR
c 2
3 dq
c  q  RC
2 dt
dq 2dt
 ec  q   3Rc
3
   RC for charge on ‘c’ 50 for current is 3 RC
2
dv kQ
2. By E  and v 
dx x
3.
By TEi  T f  Heat
5. Because of shielding effect induced charges on inner surface of shell does not change. On earthing
potential of shell becomes zero.
6.
R is equivalent resistance between A and B
Comprehension 1:
E1d1  E2 d2
qd1 (Q  q)d2

A0 A0
Solving we get q
q (Q  q)
Then E1  and  2 
A0 A0
E1q E2 (Q  q)
Fnet  
2 2
1
Energy stored is U  U1  U2  0 [E12 Ad1  E22 Ad2 ]
2
Comprehension 2 :
0 i
Field due to current wire is B  2sin 
4 d
Field due to circular arc is
 i   
B 0 
2 R  360º 
   B
CHEMISTRY :
 
NH2 .N  NCl F
NH2
Br Br Br Br Br
Br
NaNO2 / HCl HF / BF3
1. 2(i) Br / HOH

[X] 
 
(ii) NaNO2 / HCl
(iii)HF / BF3
(iv) 
Br Br Br
CH/ Cl / Alc.KOH H O /H

2. C6H5  CH2  NH2 
3
 C6H5  CH2  NC 
2

 C6H5  CH2  NH2  HCOOH

3. In Basic Medium SN2
OH OH
COOH Br Br
4. Br / CH COOH

2 3

Br
5. Claisen condensation
6.
CH Ph
CH Ph
O
A B
MATHS : (SOLUTION)
SINGLE CORRECT
1. Ans. (D)
Sol. Let f(x)  g(x)  0  F(x)  0
and F(x)  f(x)  g(x)  g(x)  f(x)
then f(x)  0
= f(x)  g(x)  g(x)  f(x)
=0
2. Ans. (D)
Sol. f '(x)  3x2  2ax  b  3(x  )(x  ) let   
f '(x)  0  x  (, )
f '(x)  0  x (, )  (, )
If  is local maxima & x   is local minima then bigger root of f '(x)  0 must be negative
 D  0, b  0, a  0
3. Ans. (A)
Sol. If 0  cos2 (n! x)  1 then x  Qc
 lim
m n
 
lim 1  (cos2 (n! x)m  1  0  1
2
If cos (n! x)  1 then x  Q
n!  x  p 
p
x Q
n!

 lim lim 1  cos2 n! x)m  2
m n

4. Ans. C
 1
etan x 
1
x X  tan1 x
Sol. 
 etan  1  
1  X2 
dx =  

e  dx  
1  x2
.x dx

1
=  x tan x c
5. Ans. (D)
b 4  a 4  b  a
b
Sol.  f(x)dx 
4

4

. (b  a)(a2  b2 ) 
a
=
(b  a) 3
4

a  b3  ab(a  b) 
 b  a   a  b   b  a  3 (a  b)3 
=    f(a)  f(b)  k       a  b3  k 
 6   2   6   8 
(b  a) (8  k)  3 3k 
a  b3  (a  b)ab
8 
= .
6 8k 
k 1 3k
  and 1
48 4 8k
k=4 k=4
 k=4
6. Ans. (A)
Sol.
f(x) is continuous and differentiable in [–2, 2] and (–2, 2) respectively and f '(c)  0 in (2, 2)
 Longest interval is [–2, 2]
ASSERTION– REASON TYPE
7. Ans. (D)
dy
Sol.  3x2  2ax  b  0
dx
D  0  a2  3b
8. Ans. (A)
Fundamental property
9. Ans. (C)
f(g(x) can be even also when one of them is even and other is odd.
PARAGRAPH
10. Ans. (B)
11. Ans. (B)
12. Ans. (C)
x
0 e
(x  t)
Sol. f(x)  x2  f(x  (x  t))dt
x
= x 2  e x 0 e f(t)dt
t
x
f '(x)  2x  e x .ex f(x)  e x 0 e f(t)dt
t
= 2x  x2  x(x  2)
x3
f(x)   x2  c
3
f(0)  0
x3
 f(x) =  x 2  many–one onto fun.
3
1
1 x 4 x3 5
0
f(x)dx  
12 3

12
0
PARAGRAPH
13. Ans. (A)

14. Ans. (B)
15. Ans. (D)
Sol. x  1  3t2, y  t  3t3
dy 1  9t 2
  tan   9t2  6t tan   1  0
dx 6t
(3t  tan )2  1  tan2 
3t  tan   sec 
P(2,2)  t  1
4
Tangent : y  2   x  2
3
t  3t3  2  
4
3

1  3t 2  2 
t  3t3  2  4t2  4
3t3  4t2  t  2  0
t  2 / 3,  1,  1
 1 2 
 Q  , 
 3 9
dy 3

dx t 3 / 2 4

 angle is
2
MATRIX TYPE
1. Ans. A(r), B(p), C(q), D(s)
sin x2
Sol. (A) lim
x0 2cos x  2cos2x
sin x 2 1
lim 
x 0 3x x 3
4 sin . sin
2 2
e dx

e
(B)  ln(ln x  11  ln2
1 x(ln x  1)
n
  k 
 ln  sin  n . 2  
1
(C) ln y  lim
n n
k 1
1   2 /2
= 0 ln sin  2 x dx   0 lnsint dt
2  
   ln2   ln2
 2 
1
 y
2
(n1)

1 1 1 1
(D) lim
n n
r 1  2 3/2
 0 (1  x2 )3 / 2 dx
r
1  2 
 n 
1 dx
= 0 (1  x2 ) 1  x2
Let x  tan 
dx  sec 2 d
/4 d. sec 2  /4
= 0 2
(sec ) 3/2
 0 cos  d
/4
= sin  0
1
=
2
2. Ans. A(s), B(q), C(r), D(p)
2x2  6x  5
Sol. fog 
(x  1)(x  2)
x2  x  1
gof 
(x  1)2
x 4  3x 2  1
fof  ,
x(x2  1)
2x  3
gog 
3x  5

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FIITJEE

PHYSICS, CHEMISTRY & MATHEMATICS

CPT-1 CODE:110666 PAPER - 2

B. Filling of OMR Sheet

C. Marking Scheme For All Three Parts.

Name of the Candidate :____________________________________________

Batch :____________________ Date of Examination :___________________

Enrolment Number :_______________________________________________

Useful Data Chemistry:

Acceleration due to gravity g = 10 m / s2

(a) RC (b) 2RC (c) 3RC (d) RC/2

2. Convert the given v-x graph into E-x graph

(a) 2q (b) 4q (c) 2.5q (d) 3q

7. STATEMENT 1: When ever a capacitor (charged or uncharged) is connected across a battery.

8. STATEMENT 1: Work done by magnetic force is always zero.

Paragraph for Question no. 10 to 12

Plate area is A (d1 > d2)

10. Electric field E1 between two upper plates is

11. Net force on middle plate is

12. Total electrostatic energy inside plate system

Paragraph for Question no. 13 to 15

13. Magnetic field at centre P is

15. Find the instantaneous acceleration of point mass m.

2. In the given reaction sequence:

3. The given reaction

Space For Rough Work

4. In the given reaction,

[X] will be:

5. In the given reaction

[X] will be:

(A) C CH2 C CH3 (B) CH CH C CH3

Space For Rough Work

6. In the given reaction sequence

(C) CH2 C6H5 (D)

7. STATEMENT 1: Salicylic acid is more acidic than p–hydroxy benzoic acid

8. STATEMENT 1: Formaldehyde is more reactive than benzaldehyde for nucleophilic addition

9. STATEMENT 1: Epoxide always gives SN2 reaction with Grignard reagent

Paragraph for Question no. 10 to 12

Space For Rough Work

12. In the given reaction sequence product (P) is

Paragraph for Question no. 13 to 15

14.  and -anomers of glucose have following structures

Space For Rough Work

1. Match List–I with List–II

(A) CH2Cl2 (P) Thermal elimination

H3C CH2 CH N(CH 3)3OH

(T) Cope elimination

Space For Rough Work

2. Match List–I with List–II

(D) (S) Reimer–Teimann carboxylation

Intramolecular hydrogen bonding

Space For Rough Work

1. If f : R  R, g : R  R be two functions, then F(x) = 2 min  f(x)  g(x), 0 equals 

3. If x is a real number in [0, 1], then the value of f(x)  lim

(A) 2 or 1 according as x is rational or irrational (B) 1 or 2 according as x is rational or irrational

 etan x 1 x  x2 .d cot1 x is equal to –

7. STATEMENT 1: The graph of y = x3 + ax2 + bx + c has no extremum if a2 > 3b.

8. STATEMENT 1: f(x)  sin x  [x] is discontinuous at x = 0. where [.] is G.I.F.

Paragraph for Question no. 10 to 12

Batch :__ Date of Examination :_