Homework 1

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CHE212- Process Engineering and Analysis 2016

Homework #1

Question 1. “Guessing” game:

In guessing game, your task is to guess a predetermined integer number between 0 and 999, by asking
questions. You are allowed to ask “Yes/No” questions about the number. Some examples:

• Is it 1?
• Is it 900?
• Is it greater than 100?
• Is it smaller than 900?
• Is it an even number?
• Etc.,

Lay out a strategy to determine the number with 10 questions.

Question 2.

1. Calculate the adiabatic flame temperature of burning CH4 (g) at 1 atm when burned with 50%
excess air, and the reactants enter at 25oC.
2. What would happen to the flame temperature qualitatively, if excess air is reduced to 20%?
(No calculation).

Standard heat of formation:

o
CH4: ∆Hˆ r = - 49.963 kJ / mol

o
CO2: ∆Hˆ r = - 393.25 kJ / mol

o
H2O (g): ∆Hˆ r = - 241.835 kJ / mol

Heat capacities (J/mol), T in oC:


-2 -5 2 -9 3
CO2 (g) : 36.11 + 4.233×10 T - 2.887×10 T + 7.464×10 T
H2O (g) : 33.46 + 0.688×10-2 T + 0.7604×10-5T2 + 3.593×10-9 T3
O2 (g) : 29.1 + 1.158×10-2 T - 0.6076×10-5T2 + 1.311×10-9 T3
N2 (g) : 29 + 0.2199×10-2 T + 0.5723×10-5T2 - 2.787×10-9 T3

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