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    Apch16 ps1 06

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    1. The document provides equilibrium expressions and calculations for a series of chemical reactions. 2. Key points covered include writing equilibrium expressions in terms of concentrations (Kc) and partial pressures (Kp), calculating Kc values, and exploring how changing reaction coefficients affects equilibrium expressions and values. 3. Examples show how reversing or modifying reaction coefficients changes the equilibrium expressions and calculated Kc values.

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    Apch16 ps1 06

    Uploaded by

    aoiwefowei
    93 views2 pages
    1. The document provides equilibrium expressions and calculations for a series of chemical reactions. 2. Key points covered include writing equilibrium expressions in terms of concentrations (Kc) and partial pressures (Kp), calculating Kc values, and exploring how changing reaction coefficients affects equilibrium expressions and values. 3. Examples show how reversing or modifying reaction coefficients changes the equilibrium expressions and calculated Kc values.

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    1. The document provides equilibrium expressions and calculations for a series of chemical reactions. 2. Key points covered include writing equilibrium expressions in terms of concentrations (Kc) and partial pressures (Kp), calculating Kc values, and exploring how changing reaction coefficients affects equilibrium expressions and values. 3. Examples show how reversing or modifying reaction coefficients changes the equilibrium expressions and calculated Kc values.

    Copyright:

    © All Rights Reserved
    Download as DOC, PDF, TXT or read online from Scribd
    Download as doc, pdf, or txt
    93 views2 pages

    Apch16 ps1 06

    Uploaded by

    aoiwefowei
    1. The document provides equilibrium expressions and calculations for a series of chemical reactions. 2. Key points covered include writing equilibrium expressions in terms of concentrations (Kc) and partial pressures (Kp), calculating Kc values, and exploring how changing reaction coefficients affects equilibrium expressions and values. 3. Examples show how reversing or modifying reaction coefficients changes the equilibrium expressions and calculated Kc values.

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    South Pasadena  AP Chemistry Name _______________________________

    Period ___ Date ___/___/___

    16  Chemical Equilibria
    PROBLEM SET #1
    For the following three reactions, 4. Knowing that pure water has a density of 1g/1mL
    a) write the Keq expression in terms of calculate the mass of 1.00 Liter of water.
    concentration, Kc.
    b) given the equilibrium concentrations, state
    whether each equilibrium is product-favored, Calculate the number of moles in 1.00 L of H2O.
    reactant-favored, or fairly even ([products] 
    [reactants]).
    c) calculate the value of Kc. What is the concentration (M) of water in water?

    1. N2g) + 3 H2(g)  2 NH3(g)


    At this temperature, can you get more moles of
    At equilibrium: [N2] = 1.50 M water into this Liter of water?
    [H2] = 2.00 M
    [NH3]= 0.01 M The [H2O] ________ (is / is not) constant.

    Important Note:
    Since the concentrations of solids and liquids are
    constant, they are incorporated into the
    equilibrium constant, Keq. That means, just leave
    them out of the Kc or Kp expression. Only
    2. HF(aq)  H+(aq) + F(aq) include (g) and (aq)!
    At equilibrium: [HF] = 0.55 M
    [H+] = 0.001 M
    [F]= 0.001 M 5. Write equilibrium expressions for each of the
    following reactions:
    a) CaCO3(s) CaO(s) + CO2(g)

    b) Ni(s) + 4CO(g) Ni(CO)4(g)


    3+  2+
    3. Fe (aq) + SCN (aq)  FeSCN (aq)
    At equilibrium: [Fe3+] = 0.55 M
    [SCN] = 0.001 M
    [FeSCN2+]= 0.001 M c) 5CO(g) + I2O5(s) I2(g) + 5CO2(g)

    d) Ca(HCO3)2(aq)
    CaCO3(s) + H2O(l) + CO2(g)
    Summarize:
    Fill in the blanks with product-favored, reactant-
    favored, and approximately equal
    Kc state of equilibrium
    Kc >> 1 e) AgCl(s) Ag+(aq) + Cl(aq)
    Kc << 1
    Kc  1
    6. Write the equilibrium expression in terms of (b) If we reverse the equation, it is:
    partial pressures (Kp) for each of the following 2 SO3(g)  2 SO2(g) + O2(g)
    reactions. Write the Kc expression for this equation and
    Rate the reactions in order of their increasing calculate the new value of Kc:
    tendency to proceed toward completion:
    ___ ___ ___ ___

    (a) 4NH3(g) + 3O2(g) 2N2(g) + 6H2O(g)


    Kp = 1 x 10228 atm
    How does the expression and the value of Kc in
    7(b) compare with those in 7(a)?

    (b) N2(g) + O2(g) 2NO(g)


    Kp = 5 x 10-31 (c) If we now multiply all of the coefficients by ½:
    SO3(g)  SO2(g) + ½ O2(g)
    Write the Kc expression for this equation and
    calculate the new value of Kc:

    (c) 2HF(g) H2(g) + F2(g)


    Kp = 1 x 10-13

    How do they compare with 7(b)?

    (d) 2NOCl(g) 2NO(g) + Cl2(g)


    -4
    Kp = 4.7 x 10 atm
    (d) What would happen to the Kc expression and its
    value if we doubled the coefficients?

    A Question That You Should Be Able To Answer:


    Why don’t the Kp’s in (b) and (c) have units?
    Summarize:
    Equation Kc expression & Value
    doubled
    reversed
    halved
    7. (a) Write the Kc expression for
    8. Consider an equilibrium that occurs in two steps:
    2 SO2(g) + O2(g)  2 SO3(g)
    H2S(aq)  H+(aq) + HS(aq)
    HS(aq)  H+(aq) + S2(aq)

    Calculate the value of Kc: (a) Write the overall reaction.


    At equilibrium: [SO2] = 1.50 M (b) How do the Kc’s for the two steps (Kc1 & Kc2)
    [O2] = 1.25 M relate to the Kc of the overall reaction (Kc)?
    [SO3]= 3.50 M

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