MATERIAL SAFETY DATA SHEET

1. SUBSTANCE AND SOURCE IDENTIFICATION

National Institute of Standards and Technology SRM Number: 2556
Standard Reference Materials Program MSDS Number: 2556
100 Bureau Drive, Stop 2300 SRM Name: Used Auto Catalyst (Pellets)
Gaithersburg, Maryland 20899-2300
Date of Issue: 09 May 2007

MSDS Coordinator: Mario Cellarosi Emergency Telephone ChemTrec:

Telephone: 301-975-6776 1-800-424-9300 (North America)
FAX: 301-926-4751 +1-703-527-3887 (International)
E-mail: SRMMSDS@nist.gov
Description: Standard Reference Material (SRM) 2556 is intended for use in evaluating
chemical and instrumental methods for the analysis of platinum group metals
and lead. It is a recycled pellet auto catalyst in the form of fine powder (less
than 74 μm). A unit of SRM 2556 consists of 70 g.
Substance: Used Auto Catalyst

2. COMPOSITION AND INFORMATION ON HAZARDOUS INGREDIENTS(a)

Component CAS Number EC Number Nominal Concentration

(EINECS) (mass fraction %)
Used Auto Catalyst (Pellets) not applicable not applicable 100
Major/Hazardous Constituents
Alumina (Al2O3) 1344-28-1 215-691-6 97
Lead Oxide (PbO) 1317-36-8 215-267-0 0.7
Danger/Hazard Symbol: T
EC Risk (R No.): 33, 52/53, 61
EC Safety (S No.): 45, 53, 60, 61
(a)
Individual MSDS information is provided for Hazardous components 1 % or greater; carcinogens 0.1 % or greater are listed in
compliance with OSHA 29 CFR 1910.1200.

3. HAZARDS IDENTIFICATION
NFPA Ratings (Scale 0–4): Health = 1 Fire = 0 Reactivity = 0

Major Health Hazards: Lead has been found to cause nerve damage, kidney damage, and birth defects.
Lead is also a suspect cancer hazard (in animals).
Potential Health Effects
Inhalation: Inhalation (acute exposure) may cause coughing, shortness of breath, and
respiratory tract irritation due to mechanical action. Absorption of large
amounts of lead may cause a metallic taste, thirst, a burning sensation in the
mouth and throat, salivation, abdominal pain with severe colic, vomiting,
diarrhea of black or bloody stools, constipation, fatigue, irritability, memory
loss, loss of concentration, delirium, visual failure, muscle pain and weakness,
convulsions, and paralysis. Death may result from cardiorespiratory arrest. The
fatal dose of absorbed lead is approximately 0.5 grams. Prolonged exposure to
low levels of lead my result in an accumulation in body tissues and cause effects
on the blood, nervous systems, heart, endocrine, immune systems, kidneys, and
reproduction. Early stages of lead poisoning include symptoms similar to those
described in absorption of large amounts of lead.

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 Skin Contact: Skin contact may cause irritation by abrasion. Prolonged contact or repeated
exposure may cause dermatitis.
Eye Contact: Eye contact (acute exposure) may cause irritation due to abrasion and corneal
necrosis.
Ingestion: Absorption of large amounts of lead from the intestinal tract may cause effects
as detailed in inhalation of lead. Prolonged or repeated exposure to low levels of
lead may result in an accumulation in body tissues and adverse effects on the
kidneys, heart, and blood and on the nervous, reproductive, endocrine, and
immune systems as detailed in inhalation of lead.
Listed as a Carcinogen/
Potential Carcinogen: Lead Oxide
Yes No
X In the National Toxicology Program (NTP) Report on Carcinogens.
X In the International Agency for Research on Cancer (IARC) Monographs.
X By the Occupational Safety and Health Administration (OSHA).

Aluminum Oxide
Yes No
X In the National Toxicology Program (NTP) Report on Carcinogens.
X In the International Agency for Research on Cancer (IARC) Monographs.
X By the Occupational Safety and Health Administration (OSHA).

4. FIRST AID MEASURES

Inhalation: If adverse effects occur, remove to uncontaminated area. If not breathing, give
artificial respiration by qualified personnel. Get immediate medical attention.
Skin Contact: Wash affected area with soap and water for at least 15 minutes. Get medical
attention, if needed.
Eye Contact: Immediately flush eyes, including under the eyelids, with copious amounts of
water for at least 15 minutes. Get immediate medical attention.
Ingestion: If a large amount is ingested, get medical attention.

5. FIRE FIGHTING MEASURES

Fire and Explosion Hazards: Negligible fire hazard.
Extinguishing Media: Use extinguishing agents appropriate for surrounding fire.
Fire Fighting: Avoid inhalation of material or combustion by-products. Wear full protective
clothing and NIOSH-approved self-contained breathing apparatus (SCBA).
Flash Point: Not available.
Method Used: Not available.
Autoignition Temp.: Not available.
Flammability Limits in Air
UPPER (Volume %): Not available.
LOWER (Volume %): Not available.

6. ACCIDENTAL RELEASE MEASURES

Occupational Release: Collect spilled material in an appropriate container for disposal. Avoid
generating dust. Lead is subject to California Safe Drinking Water and Toxic
Enforcement Act of 1986 (Proposition 65). Keep out of water supplies and
sewers.
Disposal: Refer to Section 13, “Disposal Considerations”.

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7. HANDLING AND STORAGE
Storage: Store and handle in accordance with all current regulations and standards. Keep
separated from incompatible substances.
Safe Handling Precautions: See Section 8, “Exposure Controls and Personal Protection”.

8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

Exposure Limits: Aluminum Oxide (Alumina)
OSHA (PEL): 5 mg/m3 TWA (respirable dust fraction)
OSHA (PEL): 15 mg/m3 TWA (total dust)
ACGIH: 10 mg/m3 TWA
UK WEL: 10 mg/m3 TWA (total inhalable dust)
UK WEL: 4 mg/m3 TWA (respirable dust)

Exposure Limits: Lead, Inorganic Fumes and Dust (as Pb)

OSHA (PEL): 5 μg/m3 TWA (8 h)
OSHA (PEL): 30 μg/m3 (action level 8 h)
ACGIH: 0.05 mg/m3 TWA
NIOSH: 0.050 mg/m3 recommended TWA (10 h) (metal and compounds)
EC OEL: 0.15 mg/m3 TWA
Ventilation: Use local exhaust ventilation system. Ensure compliance with applicable
exposure limits.
Respirator: The SRM is a particulate matter that requires inhalation protection by OSHA
because the material’s average particulate size, as manufactured, is less than the
inhalation average particulate size established by the ACGIH, Appendix D
(particulates with average particulate sizes less than 100 micrometers require
proper inhalation/respiratory protection). A respiratory protection program that
meets OSHA’s 29 CFR 1910.134 and ANSI Z88.2 requirements must be
followed if workplace conditions warrant a respirator. Refer to the “NIOSH
Guide to the Selection and Use of Particulate Respirators Certified under
42 CFR 84” for selection and use of respirators certified by NIOSH.
Eye Protection: Wear safety goggles. An eye wash station should be readily available near areas
of use.
Personal Protection: Wear appropriate protective clothing and chemically resistant gloves to prevent
skin exposure.

9. PHYSICAL AND CHEMICAL PROPERTIES

Component: Used Auto Catalyst
Appearance and Odor: White to gray. Powder. Odorless.

10. STABILITY AND REACTIVITY

Stability: X Stable Unstable
Stable at normal temperatures and pressure.
Reactivity: May ignite if exposed to friction or heating. Finely divided material may ignite
spontaneously.
Conditions to Avoid: Avoid generating dust.
Incompatible Materials: Oxidizing materials. Halogens. Halocarbons. Combustible materials. Metal
carbide. Metals. Metal oxides. Reducing agents. Acids.
Fire/Explosion Information: See Section 5, “Fire Fighting Measures”.
Hazardous Decomposition: Thermal decomposition produces miscellaneous decomposition products.
Hazardous Polymerization: Will Occur X Will Not Occur

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11. TOXICOLOGICAL INFORMATION
Route of Entry: X Inhalation X Skin X Ingestion
Toxicity Data: Aluminum Oxide (Alumina)
Rat, Intermittent Inhalation TCLO: > 200 mg/ m3 (5 h to 28 weeks)
Lead Oxide
Rat, Intraperitoneal LDLO: 450 mg/kg
Rat, Continuous Inhalation TCLO: 10 μg/ m3 (24 h to 22 weeks)
Health Effects
(Acute and Chronic): See Section 3: “Hazards Identification” for potential health effects.

12. ECOLOGICAL INFORMATION

Ecotoxicity Data: Lead is toxic to aquatic life.

13. DISPOSAL CONSIDERATIONS

Waste Disposal: Dispose in accordance with all applicable federal, state, and local regulations.
Lead is subject to disposal regulations, U.S. EPA 40 CFR 262 for concentrations
at or above the Regulatory Level, 5.0 mg/L.

14. TRANSPORTATION INFORMATION

U.S. DOT and IATA: Not regulated by DOT or IATA.

15. REGULATORY INFORMATION

U.S. Regulations: CERCLA Sections 102a/103 (40 CFR 302.4): Lead: 4.54 kg 10 Lbs RQ (solid
metal particles, 100 μm diameter.
SARA Title III Section 302 (40 CFR 355.30): Not regulated.
SARA Title III Section 304 (40 CFR 355.40): Not regulated.
SARA Title III Section 313 (40 CFR 372.65): Lead, Lead Compounds,
Aluminum, Metallic, Powder.
OSHA Process Safety (29 CFR 1910.119): Not regulated.
SARA Title III Sections 311/312 Hazardous Categories (40 CFR 370.21):
ACUTE: Yes.
CHRONIC: Yes.
FIRE: No.
REACTIVE: No.
SUDDEN RELEASE: No.
State Regulations: California Proposition 65: Lead and lead compounds are known to the state of
California to cause cancer (1992), developmental toxicity (1987), male
reproductive toxicity (1987), female reproductive toxicity (1987).
CANADIAN Regulations
WHMIS Classification: Not provided for this material.
EUROPEAN Regulations
EC Classification (assigned): Lead/Lead Compounds: Reproductive Toxin Category 1
Reproductive Toxin Category 3
Danger/Hazard Symbol: T Toxic
EC Risk Phrases: R33 Danger of cumulative effects.
R52/53 Harmful to aquatic organisms; may cause long-term
adverse effects in the aquatic environment.
R61 May cause harm to unborn child.

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 S45 In case of accident or if you feel unwell, seek medical
advice immediately (show label where possible).
S53 Avoid exposure.
S60 This material and its container must be disposed of as
hazardous waste.
S61 Avoid release to the environment.
National Inventory Status
U.S. Inventory (TSCA): Aluminum Oxide: Listed on inventory.
Lead Oxide: Listed on inventory.
TSCA 12(b)
Export Notification: Not listed.

16. OTHER INFORMATION

Sources: MDL Information Systems, Inc., MSDS Aluminum Oxide, 07 December 2006.
MDL Information Systems, Inc., MSDS Lead Oxide, 07 December 2006.

Disclaimer: Physical and chemical data contained in this MSDS are provided only for use as a guide in assessing
the hazardous nature of the material. The MSDS was prepared carefully, using current references; however, NIST
does not certify the data in the MSDS. The certified values for this material are given in the NIST Certificate of
Analysis.

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