IT 2019 JEE Main 2019 Mock Test (Code-100328.

1)-PCM 23

Hints and Solutions

PHYSICS (PART-1)
2
4m 2
1. I 2m when (m = )
3

2. Reading = 1 M + ( LC V) = 1 2 + 0.01 26 = 2.26 mm

a v v
3. acos
v
a v
asin a
v

4. after cutting the lens new focal length f = 2f

1 1 1
feq f
feq f f

5
5. i
5 R
B = BH tan
0Ni
BH tan
2r
2rBH 5
i tan
0N 5 R
Solving R = 1.8

6. produce minima. If the slit separation is d, then,

xd 1 xd 1
n1 , n2
D 1 2 D 2 2
xd 1 1
or , n1 n2 7
D 1 2
Substituting the values, D = 1m, 1 2
we get d = 0.2 mm.

t
V
8. i 1 e
R
di
P.D. across inductor = L
dt
t
V
V e
R

2a a
y
9. r
2 2
r2 1 a2 a2 a
Total area = a a
2 2 4 2
A x
a2 a2 a
Magnetic moment of the loop is I .
4 2

1 2 hc hc
10. m
2 0
1 hc hc
m(2 )2
2 ' 0
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 24

putting 0 600nm , 480nm,

we get, ' 300nm

11. W nR T
U nCV T
U 3
W 2

12. Since VL = VC,

so it is resonance.
V
and i
R
13. A node is a point where there is no vibration.
nd
For standing waves, 2 wave must travel in ve x direction and at x = 0, y must be zero always.

15.
A
A A.B
B
B A.B A.B

A Y

A.B
B
16. mobj meye 100
v
meye 10
u
1 1 1
v u f
25
=f cm
9

17. N2 sin = Mg sin

N1
N1 = Mg cos + N2 cos

90 -
N2

Mg sin Mg cos

18.
x

track

y
At = g sin
dy
|tan | = =x
dx

20. TE = PEmin + KEmax

dV
x3 x 0 x 0,x 1
dx
d2 V
3x 2 1 at x = 1 Vmin
dx 2
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 25

Vmin = 1
J
4
3
Vmax
2
21.

30 v0

u R/2

e = velocity of separation / velocity of approach

22. VAy 0 since = 2 rad/sec

VAx 3 m/s rigid body constrain
2 t
23. y A sin
T
T y y2
t2 t1 sin 1 1 sin 1
= 0.17
2 A A

3
24. PA PB = a
2
3a
h= h a
2g

A B

1 dq 1 dq
25. E 2
cos , V , where r = 2R cos + +
4 0 r 4 0 r dq +
+
+ r
O A
+
B E A , VA
+
+
+
+
++

26. Induced e.m.f. = B v = 0.125 V 0.5T

+
10 V 0.25 m
10 e
10 0.125 V
current I = 0.5 N
2 R 2
V
10 0.125
Force BI = 0.5 0.25 0.5N (given) Q
2
Solving v = 16 m/s.

dA1 r2 d r2
27. A
dt 2 dt 2
L = Mr 2
L = 2MA
28. B

28.
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 26

10 m/s
t=3
30 m/s
30
ux = 10 3
t=2

60

t=0

Gm(M m)
29. F 0
r2
dF G
(M 2m) 0
dm r 2
M = 2m
m = (M/2)

30. For maximum

1N 3N 9N 10N 23N

9N
10N

3N 1N
A triangle is possible with sides 4 unit, 9 unit and 10 unit. Hence minimum
resultant is zero.

CHEMISTRY (PART-II)
1. A
The vapour will contain higher percentage of benzene
A : Benzene B : Toluene
pT p'A pB' ; pT p0A x A pB0 xB
1 1
75 22 37.5 11 48.5
2 2
Mole fraction of benzene in vapour,
pA 37.5
yA 0.78
pT 48.5
Similarly, mole fraction of toluene in vapour, yB = 0.22
The vapour will contain higher percentage of benzene.
2. B

O O

OH O
MnO2 selectively oxidises allylic or benzylic hydroxyl group to (C = O) group, whereas Jones reagent

3. D
+4
B
z = ? ; E = 326.4
1 1
13.6 z2 2 eV
n1 n22
1 1
326.4 13.6 z2
(1)2 (5)2
z=5
4. D
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 27

2
FeCl3 Reducing agent Fe
Yellow Green

5. B
Weak bases are good leaving group.
Acidic order : H2O ROH CH CH NH3
Basic order : OH RO CH C NH2
Weaker the base, better is the leaving group. Leaving group order: OH RO CH C NH2
6. D
H /KMnO4 /
PhCH2OH
O
||
(A) Lindl converts group to (PhCHO)
(B) Lithium aluminium t-butoxide also converts (PhCOCl) group to (PhCHO))
(C) DIBAL-H converts PhC N to PhCHO
+
(D) H /KMnO4/ acid
7. A
C 195 0.05 3 1
k 9.75 10 Scm
1000 1000
1 A
Also, G k
R
3 1 1.5 cm2
9.75 10 Scm
0.50 cm
3 1
29.25 10 ohm
V
Also, V IR I 5 29.25 10 3

R
0.146 0.15 A
8. B
No. of molecules per gram of N2 in monolayer
6 1023
1.30 3.48 10 19
22400
Cross-sectional area of a molecule
1.6 1019 m2
Area covered by molecules per gram
3.48 1019 1.6 10 19 5.568 m2
2 1
Surface area = 5.568 cm g .
9. B
4S3 4 10 12 S 10 4 M
Now let molarity of CaCl2 = x [Cl ] = 2x
If 2 then
S
S' 2.5 10 13
4 108
K sp 4 10 12 2.5 10 13 (2x)2
x=2M
10. D
11. D
Xenon is trapped in the cavities formed when water is fronzen under high pressure of gas and the
nature of bonding between xenon and water molecule is dipole-induced dipole interaction.
12. A
The order is [MnCl4 ]2 [CoCl4 ]2 [Fe(CN)6 ]4
+2 5 0 2
Mn : 3d 4s [MnO4] :
Hence, maximum magnetic moment
+2 7 0 2
Co : 3s 4s [CoCl4] :
+2 6 0 4
Fe : 3d 4s [Fe(CN)6] :
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 28

Pairing takes place because CN is a strong field ligand.

13. C
O
||
3
14. D
different with 1, 0 and 2 lone pair of electrons respectively
15. B
(I) is most stabilise as it is neutral, (II) structure is more stabilise the (III) and (IV) because of complete
octet. (IV) is destabilise electronegative oxygen contain positive charge.
16. D
Ea
log k log A
2.3RT
lim log k log A
T

17. C
+
trans-[Co(en)2Cl2] is optically inactive.
18. A
Gypsum CaSO4 2H2O
1
P.O.P CaSO4 H2O
2
19. D
Enthalpy of adsorption ( Hadsorption) is low and positive
20. A
Aromatic nucleophilic substitution reactions are favoured by strong EWG, I effect of F is highest
(more EN of F).
F OH

OH

NO 2 NO 2

21. C
(A) NH3 > PH3 > AsH3 > SbH3
(As E.N. value of C.A. bond angle )
(B) OF2 < OH2 < OCl2
+ + + +
(C) H3Te < H3Se < H3S < H3O
(D) BF3 = BCl3 = BBr3 = BI3
22. D
Given, a 2r = 60.3 and for bcc. 4r = 3a
3
a a 60.3 a 450 pm
2
2 48
Density( ) 23
1.75 g / cc
6.023 10 (4.5)3 10 24

23. C
2KCN AgNO3 Ag(CN)2 KCN3 K
0.1 0.03 0 0 0
(0.1 0.06) 0 0.03 0.03 0.03
[Ag(CN)2 ] = 0.03 M
Now use Ag(CN)2 Ag 2CN
0.03 0 0.04
(0.03 a) a 0.04 + a
Since, Kc is too small and dissociation of Ag(CN)2 is very less and thus,
[Ag ] [CN ]2 a (0.04)2
Kc
[Ag(CN)2 ] 0.03
18
a = 7.5 10
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 29

24. D

25. A

26. B

HO NHCOCH 3

27. D
On moving top to bottom, size of central atom increases. Bond length of X H bond increases and
bond dissociation energy decreases. Hence reducing nature increases.
28. A
Synthetic polymers containing repeated R2SiO units
29. D
It is an example of bimolecular reduction (formation of pinacol).
O O OH OH

Et C C Et HCl
Et C C Et
By free radical
Ph Ph mechanism Ph Ph

30. B
2ZnS 3O2 2ZnO 2SO2
1270 K
ZnO C Zn CO

MATHEMATICS (PART-III)
1
1. Equation of plane will be x y 3 + (z 5) = 0 and =
3

2. Let 1 t2 = z2
2t dt = 2z dz
1
1
I ln 1 z2 dz
20
1
1 z4 z6
= z2 ..... dz
20 2 3
1 1 1
= 1 ..... 1
2 3 4
2
= ln
e

4a 2b c f 2 1
3.
3a b f 2 f 1 f 1
1
f 2

y
4. |z 2 2i| 1 (2,2)
Denotes the region inside a circle with centre (2, 2) and radius is (0,2)
1
1 x
|3iz + 6| = |3i(z 2i) | O 1 2 3

= |3i| |z 2i|
= 3|z 2i|

5. Locus is a circle with diameter (5, 6) and (2, 3).

2 2
k 7 h 2 k h 5
6.
2 2
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 30

7. Put x2 + 5x + 5 = t

40 39 39 39 39 39 39 39 39 39 39
8. C0 C0 C1 C1 C2 C2 C3 ..... C18 C19 C19 C20
39
= C20

9. y + 2 = m(x + 2)
y = mx + 2m 2
(2m 2)2 = 9m2 + 1
4m2 + 4 8m = 9m2 + 1
5m2 + 8m 3 = 0

1 1
r r
10. Tr 2 2
1 1
r2 r r2 r
2 2
11. Let OP = x A d B d C d D
x h
cot = h h h
h
x d
cot =
h
x 2d
cot =
h
x 3d O x P Q R S
cot =
h
Now, cot2 cot2
2
x2 x 3d
=
h2 h2
x2x2 6xd 9d2
=
h2
3d(2x 3d)
=
h2
2 2 x2 2xd d2 x2 4xd 4d2 2xd 3d2
cot cot = 2
=
h h2
2 2 3d(2x 3d)
3(cot cot ) =
h2
cot2 cot2 = 3(cot2 cot2 )
Hence (A) is the correct answer

2
12. Equation of circle can be assumed as zz 2 3i z 2 3i z 7 z i 0
= 7 as circle S = 0 passes through origin
zz 2 3i z 2 3i z 7 7 zz iz iz 1 0
8zz 2 4i z 2 4i z 0

13. Put y3 = t
dt x 1t
xex
dx x
ex
Multiply by and solve
x
ex y3 e2x
c put (1, 1)
x 2
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 31

ex y3 e2x 1 2
e e f x
x 2 2
f(1) = e

14. Let lim f n L then L = cos L

n

L is less than , greater than and independent of t

4 6

15. Let mid-point of chord be (x1 y1), then its equation becomes 3xx1 4yy1 = 3x12 4y12
Which is same as 8yy1 6xx1 = 8y12 6x12
Hence, AC BD is always zero

1
16. Let x1, x2 n be n items. Then, x xi
2
Let y1 = x1 + 1, y2 = x2 + 2, y3 = x3 n = xn + n
1 1 n
Then the mean of the new series is yi xi i
n ni1
1 n 1 1n n 1 n 1
= xi 1 2 3 ..... n = x x
ni1 n n 2 2

17. (A), (B), (C) contains T in the last column of their truth tables. So, they all are tautology
except (D)

18. C2 C2 + C1

1 1
19. cos1
2 2
sin cos sin cos1 cos cos1 sin cos
4 4 3 3
3 1
3 2 < 3(sin(cos 1) + cos(cos 1)) < 3
2
20. sin 4 = 4 sin cos (2 cos2 1)
Let cos = x, [0, ]
sin 4cos 1 x 4 1 x2 x 2x2 1

sin 1 sin 4cos 1 x sin 1

4 1 x 2 2x3 x

1 3 1
cos
2 2 12 8
1
Hence, 4 cos x
2
1 1
4cos x sin 4 1 x2 2x3 x

a
cos a x
21. I ln dx
0
sina cos x
a
cos x
I ln dx
0
sina cos a x
a
1
2I ln dx 2alnsina
0 sin2 a
IT 2019 JEE Main 2019 Mock Test (Code-100328.1)-PCM 32

22. Vector perpendicular to a and lie on the plane of a and b is a b a = 3 2i 2j k

x 1
23. lim tan x lim cos x x
x 0 x 0
loge tan x
1

lim e x
e0 1
x 0
1
lim cos x x 1 as 0 < cos x < 1
x 0

24. Let A t12, 2t1 , B t 22, 2t 2 t1 t2 A

2
Slope AB =
t1 t2 B
t12 t 22
Centre of circle , t1 t2
2
Radius is (t1 + t2) = r
2
Slope of AB =
r

x sin x 2x x 2 1 cos x
25. We have f x 2
x sin x
x x 2sin x x cos x
= 2
x sin x
x x x x x
x 2x cos2 4 sin cos 2x 2 cos2tan
2 2 2 2 2
= = 1 0
x sin x
2
x sin x
2 x
2
x
tan
x
2 x 2
2x sin cos 1
2 2 x
and similarly on solving g' x 2 0
2
1 cos x

2a 3b 4 a b a b
26. Projection = = 4a b 8 2
a b

27. Required cases = 15, total cases = 36

5
Required probability =
12
28. For x [0, ], f(x) will be dis-continuous at infinite points
f(x) is non-differentiable at infinite points
3
29. A x 9 x 2 dx
0

30. (12 2) + (6 3) + 2 + 1 + 1