Chapter 4 Electric Fields in Matter: 4.1 Polarization: 4.1.1 Dielectrics Dielectrics
Chapter 4 Electric Fields in Matter: 4.1 Polarization: 4.1.1 Dielectrics Dielectrics
Most everyday objects belong to one of two large classes: Dielectrics : Microscopic displacements are not as
conductors and insulators (or dielectrics) dramatics as the wholesale rearrangement of charge in
conductor, but their cumulative effects account for the
characteristic behavior of dielectric materials.
Conductors : Substances contains an “unlimited” supply
of charges that are free to move about through the
material.
There are actually two principal mechanisms by which
electric fields can distort the charge distribution of a
Dielectrics : all charges are attached to specific atoms or dielectric atom or molecule: stretching and rotating.
molecules. All they can do is move a bit within the atom or
molecule.
1 2
3 4
Sol.
Example 4.1 A primitive model for an atom consists of a point
nuclear (+q) surrounded by a uniformly charged spherical The electric field inside a uniform charged sphere of radius a
cloud (-q) of radius a. Calculate the atomic polarizability of 1 43 πρ r 3 1
Ee (r ) = rˆ = ρ rrˆ
such an atom. 4π r 2
ε0 3ε 0
Sol. The actual displacements involved are extremely small. 1 q
∴ Ee (a ) = rrˆ , where q = 43 πρ a 3
It is reason to assume that the electron cloud retains 4πε 0 a 3
its spherical shape. The electric field produces by two uniform charged spheres
The equilibrium occurs when the nucleus is displaced a separated by d
distance d from the center of the sphere.
1 q
The external field pushing the nucleus to the right exactly E(r )=Eq + (r+ ) + Eq − (r− ) = (r+ − r− )
4πε 0 a 3
balances the internal field pulling it to the left. How?
1 q 1 1 1 qd
1 qd = ((r − d) − (r + d))= −
Ee = p = qd = (4πε 0 a 3 ) E = α E 4πε 0 a 3
2 2 4πε 0 a 3
4πε 0 a 3
1
α = 4πε 0 a 3 = 3ε 0 v the atomic polarizability5 =− p ∴ α = 4πε 0 a 3
4πε 0 a 3 6
See Problem 2.18
When the field is at some angle to the axis, you must resolve
it into parallel and perpendicular components, and multiply
each by the pertinent polarizability:
The set of nine constants αij constitute the polarizability
tensor for the molecular.
p = α⊥E ⊥ + α∥E∥
It is always possible to choose “principal” axies such that
In this case the induced dipple moment may not even be in the off-diagonal terms vanish, learning just three nonzero
the same direction as E. polarizabilities.
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4.1.3. Alignment of Polar Molecules Torque for a Permanent Dipole in Uniform Field
The neutral atom has no dipole moment to start with--- In a uniform field, the force on the positive end, F =qE,
p was induced by the applied field E. However, some exactly cancels the force on the negative end. However,
molecules have built-in, permanent dipole moment. there will be a torque:
N = (r+ x F+) + (r- x F-)
= [(d/2) x (qE) + (-d/2) x (-qE)]
= qd x E
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1 P 1 1
= ∫
v
4πε 0 S r
⋅ da′ +
4πε 0 r∫v
(-∇′ ⋅ P ) dτ ′
Ex. 4.2 Find the electric field produced
by a uniformly polarized sphere of
σ b = P ⋅ n̂ ρ b = - ∇′ ⋅ P radius R.
4πε 0 ∫-1 R R
= ( ) P1 (cos θ ′) Pcosθ ′2π R 2 d cos θ ′
It will be easier if we let r lie on the z axis, so that the angle
between them changes from ϑ to θ ′ P orthogonality
= r only n =1 survive
1 1 ∞ R n 3ε 0
= ∑ ( ) Pn ( cos θ ′) r≥R 1 PR 3
r r n =0 r cosθ (r > R )
3ε 0 r 2
1 ∞ r Allow r a θ-dependence. V (r , 0, 0) =
= ∑ ( ) n Pn (cos θ ′) r≤R P rcosθ (r < R)
R n =0 R 19
3ε 0
20
Electric field of a Uniformly Polarized Sphere 4.2.2 Physical Interpretation of Bound Charges
3
P R What is the physical meaning of the bound charge?
V(r) = cos θ (outside)
3ε0 r 2 Consider a long string of dipoles.
4
( πP ⋅ R 3 )
1 3
V (r ) = cosθ
4πε0 r2
The net charge at the ends is called the bound charge. The
1 p ⋅ rˆ 4
= 2
where p = πR 3 P bound charge is no different from any other kind.
4πε0 r 3
Consider a “tube” of dielectric with a given polarization P.
q q
p p σb = =P σb = = P cos θ = P ⋅ nˆ
V(r) = r cos θ = z (inside) Why are the field A Aend
3ε0 3ε0
lines not continuous?
P
E = -∇V = - zˆ uniformly
3ε0
21 22
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1 p 1 43 πR 3 P 1
Ein = − = − =− P
4πε0 R 3 4πε0 R 3 3ε0
1 rˆ ⋅ P(r′)
V (r ) =
4πε0 ∫
R →0 r2
dτ ′
= ρ f − ∇ ⋅ P = ε 0∇ ⋅ E
What is the contribution of the bound surface charge?
where E is now the total field, not just that portion generated
by polarization . ε 0∇ ⋅ E + ∇ ⋅ P = ρ f The bound surface charge σb can be considered as ρb
varies rapidly but smoothly within the “skin”.
∇ ⋅ (ε 0 E + P) = ρ f
Let D = ε 0 E + P the electric displacement So Gauss’s law can be applied elsewhere .
Gauss’s law reads ∇⋅D = ρ f
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E 0 + ∆ E ′P → P0 + ∆ P0′
Stokes’ Theorem for the Polarization Shielding Effect & Susceptibility Tensor
In general, linear dielectrics
cannot escape the defect that
∇×P ≠ 0 The polarization of the medium partially
“shields” the charge, by surrounding it
with bound charge of the opposite sign.
However, if the space is entirely filled with a homogenous
linear dielectric, then this objection is void. For some material, it is generally easier to polarize in some
∇⋅D = ρf 1 1
directions than in others .
E= D= E vac
∇×D = 0 ε εr P = ε 0 χ eE linear dielectric
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Prob. 4.18 The space between the planes of a parallel-plate
capacitor is filled with two slabs of linear dielectric material. Each 4.4.2 Boundary Value Problems with Linear Dielectrics
slab has thickness a, so the total distance between the plates is 2a.
Slab 1 has a dielectric constant of 2, and slab 2 has a dielectric Relation between bound charge and free charge
constant of 1.5 the free charge density on the top plate is σ and on D χ
ρb = −∇ ⋅ P = −∇ ⋅ ε 0 χ e = − e ρ f ← in a homogenous
the bottom plate -σ.
ε 1+ χe
(a) Find the electric displacement D in each slab. linear dielectric
(b) Find the electric field E in each slab. shielding effect
(c) Find the polarization P in each slab.
(d) Find the potential difference between the plates. The boundary conditions that makes reference only to the
(e) Find the location and amount of all bound charge. free charge .
(f) Now that you know all the charge (free and bound), recalculate
the field in each slab, and confirm your answer to (d).
⊥
Dabovt ⊥
− Dbelow = σ f ⇒ ε above Eabove
⊥
− ε below Ebelow
⊥
=σ f
∞
Homogeneous Linear Dielectric Sphere V (r , θ ) = ∑ ( AA r A + BA r −( A +1) ) PA (cosθ )
A =0
Example 4.7 A sphere of homogeneous linear dielectric
∞
material is placed in a uniform electric field E. Find the
resulant electric field.
Vin ( r , θ ) = ∑
A =0
AA r A PA (cosθ ) r≤R
∞
Sol: Look at Ex. 3.8 an uncharged conducting sphere. In Vout (r ,θ ) = − E0 r cos θ + ∑ BA r −( A +1) PA (cosθ ) r ≥ R
A =0
that case the field of the induced charge completely
canceled E within the sphere; However, in a dielectric the B.C. (iii)
cancellation is only partial.
B.C. (i) : AA R A PA = − E0 R cos θ + BA R − ( A +1) PA
The boundary conditions A R = − E0 R + B1 R − 2 A = 1
⇒ 1
AA R = BA R
A − ( A +1)
A ≠1
no free charge B.C. (ii) : ε r AAA R PA = − E0 cos θ − (A + 1) BA R −( A + 2) PA
A −1
at the surface
ε r A1 = − E0 − 2 B1 R −3 A =1
⇒
ε r AAA R = −(A + 1) BA R A ≠1
A −1 −( A + 2)
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Partial Image Charge
A1 R = − E0 R + B1 R −2 A = 1 ε r A1 = − E0 − 2 B1 R −3 A =1
Example 4.8 Suppose the entire region below the plane z=0 is
A ≠1 ε r AAA R = −(A + 1) BA R A ≠1
− ( A +1) A −1 −( A + 2 )
AA R = BA R
A
filled with uniform linear dielectric material of susceptibility χ e .
Calculate the force on a point charge q situated at distant d
ε −1 3 above the origin.
3E0
A1 = − ; B1 = r R A =1 Sol: The surface bound charge on the xy plane is of opposite
⇒ εr + 2 εr + 2
AA = BA = 0 sign to q , so the force will be attractive.
A ≠1 1 q qb
z>0 V= +
4πε 0 x2 + y2 + ( z − d ) 2 2 2 2
x + y +(z +d)
3E0 1 ( q + qb )
Vin (r , θ ) = − r cos θ z<o V= 2 ← why ?
4πε 0 x + y 2 + ( z − d )
2
εr + 2
ε − 1 3 −2 ∂V ∂V 1 χe qd
Vout (r , θ ) = − E0 r cos θ + ( r ) R E0 r cos θ B.C. −ε0 − =− = σb
εr + 2 ∂z z=0+ ∂z z=0− 2π χe + 2 ( x2 + y2 + d2 ) 2
3
3E0 ∞ 1 χe qd 1 ∞ χe qd χ
Ein = −∇Vin = − zˆ ← uniform qb = 2π ∫ − rdr = − ∫ dr2 = − e q
εr + 2 r =0 2π χe + 2 r2 + d 2 2
( )
3
2 χe + 2 r2 + d 2 2
0
( )
3
χe + 246
45
49
dx 2 C 2 dx 2 dx 2d 50
ε 0 χ eω
F =− V 2 < 0 indicates that the force is in the negative
2d Homework #8
x direction; the dielectric is pulled into the capacitor.
1 dC
Fixed voltage F = + V 2 pushed out. why? Problems: 21, 27, 28, 33, 36.
2 dx
dW dQ 1 dC dC 1 2 dC
F =− +V =− V2 +V 2 = V
dx dx 2 dx dx 2 dx
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