Nme 8.6

Nama : Aalya Sholikhatul Choerunnisa
NPM : 3335170054
Tugas : NME Himmelblau example dan problem 8.6
SOAL
1. Pada proses absorbsi CO2 dibutuhkan air sebanyak 7,5 kali dari aliran Feed. Jika
ditargetkkan 78% gas CO2 dapat diserap pada proses ini beserta setengah dari uap
air yang ada pada aliran feed. Diketahui komposisi aliran masuk sebanyak CO2
60%, CO 10%, NO2 10%, SO2 5% dan sisanya uap air. Berapakah komposisi
aliran keluar pada kolom absorbsi ini.
Dik :
Komposisi = CO2 60%
CO 10%
NO2 10%
SO2 5%
H2O 15%
Air pada absorber : 7,5 kali dari total aliran Feed.
CO2 yang diserap : 78 % CO2 dari Feed.
H2O yang diserap : 50 % Uap air.
Dit :
Aliran keluar absorber?
JAWAB : H2O
CO2
CO CO2
CO
Feed
Absorber NO2
NO2
SO2
SO2
CO2
H2O H2O
H2O
Basis Perhitungan = 100 kg aliran keluar
100 kg feed absorber :
CO2 = 65% x 100 kg = 65 kg
CO = 10 % x 100 kg = 10 kg
NO2 = 10 % x 100 kg = 10 kg
SO2 = 5 % x 100 kg = 5 kg
H2O = 10 % x 100 kg = 10 kg
-Jadi H2O untuk menangkap CO2 pada absorber
= 7,5 x gas keluar
= 7,5 x feed absorber
= 7,5 x 100 kg
= 750 kg
-CO2 yang diserap 78% dalam feed
= 78 % x 65 kg
= 50,7 kg
-CO2 yang tidak diserap

= (6,5 – 50,7) kg
= 14,3 kg
- H2O yang diserap 50 % dalam Feed
= 50 % x 10 kg
= 5 kg
- H2O yang tidak diserap
= (10-5) kg
= 5 kg
FLOW CHART :
CO2 = 65% x 100 kg = 65 kg
CO = 10 % x 100 kg = 10 kg
NO2 = 10 % x 100 kg = 10 kg B H2O = 750 kg
SO2 = 5 % x 100 kg = 5 kg
H2O = 10 % x 100 kg = 10 kg CO2 = 14, 3

C kg
Total : 100 kg A Absorber + Stripper
CO = 10 kg
NO2 = 10 kg
SO2 = 5 kg
H2O = 5 kg
Total : 44,3
D
H2O = 750 Kgkg
H2Os = 5 Kg
CO2 = 50,7 Kg
Total = 855,7 Kg
Cek :
Aliran masuk = Aliran keluar
A+B =C+D
(100 + 750 ) kg = ( 805,7 + 44,5 ) kg
850 kg = 850 kg
EXAMPLE 8.6 Crystallization
A tank holds 10,000 kg of a saturated solution of Na,CO, at 30°C. You want to
crystallize from this solution 3000 kg of Na, CO, H2 without any accompanying
water. To what temperature must the solution be cooled?
Solution:
This problem is a Little more complicated to analyze than the previous problems
because it not only requires a decision as to what the compounds are in the problem,
but also it implies without specifically stating so that the final solution is saturated ar
the final emperarure. No reaction occurs. Although the problem could be set up as a
steady-state problem with lows in and out of the system (the tank), it is equally
justified to treat the process as an unsteady-state process. The major difficulty posed
in this problem is to get all the necessary information about the compositions of the
solutions and solid precipitate. If you can calculate the final concentration of the
Na2CO, in the tank, you can look up the corresponding temperature in a handbook
containing solubility data. The components mentioned in the problem statement are
Na2CO. H2O, and Na CO 10H20. Although these components can exist as separate
compounds, only two chemical species actually exist in the tank: Na2CO, and H20.
Let's select these species as the components for which to make material balances,
because it takes fewer steps to make the required calculations.
Step 1,2, and 3
Figure E8,6 is a diagram of process
Next, you need to get the compositions of the streams oinsofar as pssible for each
solution and the solid crystals of Na2SO4.10H2O .
Step 2,3,and 4.
You definitely need solubility data for Na2CO3 as a function of the temprature :
Because the initial solution is saturated at 30 C, you can calculate the compotition of
the initial solution :
38,8 g Na2CO3
= 0,280 mass fraction Na2CO3
38,8 g Na2CO3+100 g H2O
Next you should calculate the composition of the crystals.
Step 5
Select a basis. The following is convenient: others can be used, such as 3000 gram of
Na2CO3 . H2O
Basis : 10.000 kg of saturated solution at 30 C.
Steps 2 and 3 (Repeated)
From the known data we have calculated the compositions the compounds and
solutions, and put them on Figure E8.6b. The problem now appears to be quite similar
to the previous examples, particularly Example 8.4

Because we are treating this problem as an unsteady-state problem, the mass balance
reduce to (the flow in = 0)
Accumulation = in – out
Step 6 dan 7
The analysis of the degrees of freedom yields a value of zero ( l stands for the initial,
F the final state, and C the crystals).
Step 8 and 9
After substitusing the specifications and basis into the material balances, (only two
are independent) you get ( in kg)

The solution for the composition and amount of the final solutions is
Check using the total balance
7000 + 3000 = 10.000
To find the temperature of the final solution, calculate the composition final solution
in terms of grams of Na2CO3 /100 grams of H2O so that you can use the tabulated
solubility data listed in Steps 2-4 above.
1,687 kg Na2CO3 3,18 g Na2CO3

=
5,313 kg H2O 100 g H2O
Thus the temperature to which the solution must be cooled lies between 20 C and 30
C by linear interpolation.
38,8−31,8
30 C – ( 10,0 C) = 26 C
38,8−21,5
PROBLEM 8.6
A liquid adhesive consists of a polymer dissolved in a solvent. The amount of poly-
mer in the solution is important to the application. An adhesive dealer receives an
order for 3000 pounds of an adhesive solution containing 13 % polymer by weight on
hand is 500 pounds of 10 % solution and very large quantities of 20 % solution and
pure solvent. Calculate the weight of each that must be blended together to fill this
order . Use all of the 10 % solution .
Solution :
Basis : 3000 lb of final Product
Unknowns : A and S, Balance, Total and Polymer.
Total Weight = A + S + 500 = 3000
A + S = 2500
Polymer = 0,2A + 50 = 390
A = 5(340) = 1700
S = 2500 – 1700 = 800
Translate :
Suatu perekat cair terdiri dari polimer yang dilarutkan dalam suatu pelarut. Jumlah
poli dalam solusi penting untuk aplikasi. Sebuah agen perekat menerima pesanan
untuk 3000 pon larutan perekat yang mengandung 13% polimer berat di tangan adalah
500 pon larutan 10% dan jumlah yang sangat besar dari larutan 20% dan pelarut
murni. Hitung berat masing-masing yang harus dicampur bersama untuk mengisi
pesanan ini. Gunakan semua solusi 10%.
Solusi :
Basis Perhitungan : 3000 lb dari berat total

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Nama : Aalya Sholikhatul Choerunnisa

Tugas : NME Himmelblau example dan problem 8.6

aliran keluar pada kolom absorbsi ini.

Komposisi = CO2 60%

Air pada absorber : 7,5 kali dari total aliran Feed.

CO2 yang diserap : 78 % CO2 dari Feed.

H2O yang diserap : 50 % Uap air.

Basis Perhitungan = 100 kg aliran keluar

100 kg feed absorber :

CO2 = 65% x 100 kg = 65 kg

-Jadi H2O untuk menangkap CO2 pada absorber

= 7,5 x gas keluar

= 7,5 x feed absorber

-CO2 yang diserap 78% dalam feed

-CO2 yang tidak diserap

- H2O yang diserap 50 % dalam Feed

- H2O yang tidak diserap

CO2 = 65% x 100 kg = 65 kg

NO2 = 10 % x 100 kg = 10 kg B H2O = 750 kg

H2O = 10 % x 100 kg = 10 kg CO2 = 14, 3

Aliran masuk = Aliran keluar

(100 + 750 ) kg = ( 805,7 + 44,5 ) kg

EXAMPLE 8.6 Crystallization

A tank holds 10,000 kg of a saturated solution of Na,CO, at 30°C. You want to

water. To what temperature must the solution be cooled?

because it takes fewer steps to make the required calculations.

Step 1,2, and 3

Figure E8,6 is a diagram of process

solution and the solid crystals of Na2SO4.10H2O .

the initial solution :

Next you should calculate the composition of the crystals.

Basis : 10.000 kg of saturated solution at 30 C.

Steps 2 and 3 (Repeated)

to the previous examples, particularly Example 8.4

reduce to (the flow in = 0)

F the final state, and C the crystals).

are independent) you get ( in kg)

Check using the total balance

7000 + 3000 = 10.000

solubility data listed in Steps 2-4 above.

1,687 kg Na2CO3 3,18 g Na2CO3

A liquid adhesive consists of a polymer dissolved in a solvent. The amount of poly-

mer in the solution is important to the application. An adhesive dealer receives an

order for 3000 pounds of an adhesive solution containing 13 % polymer by weight on

order . Use all of the 10 % solution .

Basis : 3000 lb of final Product

Unknowns : A and S, Balance, Total and Polymer.

Total Weight = A + S + 500 = 3000

Polymer = 0,2A + 50 = 390

S = 2500 – 1700 = 800

pesanan ini. Gunakan semua solusi 10%.

Basis Perhitungan : 3000 lb dari berat total

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