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SUMITOMO PRODUCTS

FOR THE OIL AND GAS


INDUSTRIES
CONTENTS
1 INTRODUCTION
2 FACILITIES AND LOCATIONS
3 MANUFACTURING SITES
4 MANUFACTURING PROCESS OF STEEL TUBES AND PIPES
6 MATERIAL SELECTION GUIDELINES
6 THE NEW SM-SERIES AND THEIR APPLICATIONS TO CORROSIVE WELLS
8 AVAILABLE GRADES
10 PHYSICAL PROPERTIES – OCTG
12 SM-SERIES GRADE DESCRIPTION
12 1. CASING AND TUBING FOR GENERAL AND DEEP WELL SERVICE
13 2. CASING AND TUBING FOR SOUR OIL AND GAS SERVICE
15 3. HIGH COLLAPSE CASING FOR DEEP WELL SERVICE
16 4. CASING AND TUBING FOR ARCTIC SERVICE
17 NEW SM-SERIES
17 1. 13CR, SUPER 13CR AND DUPLEX STAINLESS STEEL
22 2. H2S + CO2 + Cl- CORROSION (Ni BASE ALLOYS)
24 3. GUIDELINES CONCERNING BRINES ACCEPTABILITY FOR 13CR, 13CRS, 13CRM
DUPLEX STAINLESS AND CRA STEEL
25 4. MECHANICAL AND THERMAL PROPERTIES
26 5. COST COMPARISON WITH 13 CHROME
27 FEATURES OF PREMIUM CONNECTIONS
29 MATERIAL AND CONNECTION DESIGN
30 MARKING, COLOR IDENTIFICATION AND INQUIRY AND/OR ORDER DETAIL
30 MARKING, COLOR IDENTIFICATION
32 INQUIRY AND/OR ORDER DETAIL
INTRODUCTION
For more than five decades, Sumitomo Metals has been serving the needs of the oil and gas indus-
tries. All the supply records for most of the severe drilling environments indicate that Sumitomo
Metals is the leader in tubular technologies. Field development where it was impossible to drill yes-
terday becomes a reality with Sumitomo’s tubular products today. Customer satisfaction and reliabili-
ty are the key words for our product development.

Our product line covers almost all applications from carbon steel to Ni based alloy steel with conven-
tional API connections or advanced sealing mechanisms such as VAM premium connections.
Sumitomo Metals has the widest material grades for OCTG products. And as a result of continuous
R&D effort, you can find more “fit for purpose” products in this brochure.

Principle of Sumitomo OCTG


Quality
Quality is the most fundamental element of our OCTG business. We understand that quality leads to
product reliability, which in turn leads to customer trust and that in the end, quality is the basis of our
reputation. We will continue to be dedicated to maintaining and improving our quality standard.

Technology
The more severe the drilling conditions, the greater our customers’ needs for cutting edge products.
We understand that customers rely on the quality of our products when they drill in harsh conditions,
and we are proud of our No. 1 technical position. We will continue to work through our R&D activities
to develop high-end products for the future.

Customer Satisfaction
Our goal is to be more than just a superior product supplier. We intend to also be a superior solu-
tions provider for our tubular products customers. We place importance not just on managing materi-
al sales, but also on “before” and “after service”. Customer satisfaction drives our constant and
growing commitment to the oil and gas industries.

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 1


FACILITIES AND LOCATIONS
Sumitomo Metals has almost all kinds of steel pipe manufacturing
facilities which produce a wide range of seamless and welded
steel pipe and tubes.
The main facilities are composed of our Amagasaki Steel Tube
Works, Wakayama Steel Works, and Kashima Steel Works.
These works are able to produce approximately three million met-
ric tons of steel pipe and tubes annually.
The company also possesses facilities in affiliated companies in
Kashima and Koga.
Sumitomo's facilities and locations are tabulated on next page
together with their available size ranges (O.D.).
Kashima Steel Works
● Location of Sumitomo Metals' Steel Mills

Corporate Research & Corporate Research &


 Development Laboratories (Amagasaki)  Development Laboratories (Hasaki)

Amagasaki Steel Tube Works

Tokyo Head Office

Osaka Head Office

Wakayama Steel Works (Wakayama)

Wakayama Steel Works (Kainan)

Sumitomo Tube Making Equipment and Available Sizes (OCTG)

Tube Mills Location of Outside Diameter in Inches


Works
1 2 3 4 5 6 7 8 9 10 15 20 25 30 35 40 45 50 60 70 80 90 100 110 120

Mandrel (2 sets) Kainan 2 3/8 7


Seamless (Hot Finished)

Mandrel Wakayama 5 1/2 16 3/4

Ugine-Sejournet Amagasaki 2 3/8 9 5/8

Erhardt
Amagasaki 8 28
 -Push bench

Chain Drawbench
Cold Finished

Amagasaki
Tube Reducing 2 3/8 7
Machine Kainan

Hydraulic
Amagasaki 2 3/8 20
Drawbench

2 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


Manufacturing Sites
Amagasaki Steel Tube Works

The Steel Tube Works was established in 1919 as the first


integrated mill in Japan for the production of high quality
seamless steel tubes and pipe. Since then, the Works has
specialized in high quality steel tubes and pipes. The com-
pany is committed to ongoing research to improve manufac-
turing methods and to upgrade quality.

Wakayama Steel Works

Wakayama Steel Works is the integrated supply center for


seamless pipes. The steel billets are produced by a blast
furnace, converter, continuous-casting machine. Then, three
seamless pipe mills roll the billets into seamless pipes.
Above all, the medium-size seamless mill is the most Wakayama Plant
advanced in the world that is directly connected to a round
CCM, combined with a cone-type piercer with high cross
angle, a mandrel mill and an in-line heat treatment furnace.

Kainan Plant

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 3


MANUFACTURING PROCESS OF
STEEL TUBES AND PIPES
CARBON & ALLOYED STEEL MAKING PROCESS

Continuous
Casting
Machine

Round Billet
Blast Furnace
Desulphurization Dephosphorization Decarburization
RH-PB

Bloom

STANLESS STEEL & Ni BASE ALLOYS


MAKING PROCESS Ingot

Bloom
Dephosphorization AOD (Argon Oxygen Decarburization)

O2

Vacuum

VOD Ladle
Continuous
Casting
Electric Machine
Arc Furnace VOD (Vacuum Oxygen Decarburization)

Blooming Mill Bar Mill Billet

4 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


Medium size TUBE AND PIPE MAKING PROCESS
Seamless
Plant

Cone-type Piercer Mandrel Mill Sizing Mill

Mannesmann
Process

Small size Hot Finished Seamless


Seamless Steel Pipe
Plant OD: 1.0~16.75 inch

Cone-type Piercer Mandrel Mill Stretch Reducing Mill

Extrusion Process

Extrusion
Process

Hot Finished Seamless


Vertical Expanding Press Horizontal Extrusion Press Steel Tube and Pipe
1,200t 4,000t OD: 1.4~10.8 inch

Hollow Forging Process

Forging
Process

Hot Finished Seamless


Vertical Piercing Press Horizontal Push Bench Steel Pipe
3,000t 1,500t / 600t OD: 6.5~37.5 inch

Cold Pilger Mill

Cold Finished Seamless


Steel Tube and Pipe
Cold Drawing Bench OD: 0.24~20 inch

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 5


Material Selection Guidelines
THE NEW SM-SERIES AND THEIR APPLICATIONS TO CORROSIVE WELLS

Concept of Material Selection according to Gas (CO2 and H2S) Partial Pressure
(MPa)

(bar)

SM25CRW-125 SM2535-110, 125 SM2550-110, 125


(≦250℃) SM2242-110, 125 (≦350°
F(177℃))
SM2035-110, 125
SM25CR-110, 125 (≦300°
F(149℃))
(≦250℃)
102 103
104
SM22CR-110, 125
(≦200℃)

10 102
103
SM13CRM SM13CRS
-95, 110 -95, 110
(≦180℃) (≦180℃)
Partial Pressure of CO2

1 10 SM13CRI

Partial Pressure of CO2 (psi)


-80, 110 102
(≦150℃)

SM13CR
 -80, 85
-1 1
10 (≦150℃) (Note)
SM2050(≦400° F(204℃)), SMC276(≦450° F(232℃)) 10
are available for well containing free S

10-2 10-1 API SM-125S SM-110S SM-80S


J55 (≦150℃) (≦150℃) 1
SM-90S
N80Q
P110 SM-95S
(Q125-1) SM-C100
10-3 10-2 SM-C110
10-1
API
L80-1
C90
10-4 10-3
T95-1
10-2
(Note)
For grades with 110ksi or higher, please contact a Sumitomo representative for
guidance regarding sour service environment applications.
10-5 10-4
10-4 10-3 10-2 10-1 1 10 102 103 (bar)

10-5 10-4 10-3 10-2 10-1 1 10 102 (MPa)

(psi)
10-2 10-1 1 10 102 103 104

Partial Pressure of H2S

(Note) ※C - content is less than 30,000ppm for SM 13CR

6 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


OCTG materials are basically selected according to PCO2, PH2S and
temperature of the environment.
Ni alloy
≦232℃(450F)  12%Mo
(C276, 16%Mo)

Ni alloy
≦204℃(400F) 9%Mo
(SM2050, 11%Mo)
>0.01
Temperature

Ni alloy
≦177℃(350F) 6%Mo
(SM2550)

>0.02 Ni alloy
H2S (MPa) ≦149℃(300F) 3%Mo
(SM2535)

≦0.01 Duplex SS
CO2 (MPa) Temperature ≦250℃ (22CR*, 25CR,
25CRW)

≦0.003 Super 13Cr


Temperature ≦180℃ 2%Mo
(SM13CRS)

Modified 13Cr
≦180℃ 0.6%Mo
(SM13CRM)
≦0.0003
Temperature

13Cr steel
≦150℃ 0%Mo
(API 13CR, SM13CR)

C steel &
≦150℃ Low Alloy steel
[with Inhibitor]
≦0.02
Temperature

C steel &
>150℃
Low Alloy steel

※Note: Critical temperature of 22CR=200℃

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 7


AVAILABLE GRADES
Min. Yield API SPEC 5CT SM SERIES (SUMITOMO STANDARD)
Strength SEAMLESS SEAMLESS
(psi)
GROUP 1 GROUP 2 GROUP 3 GROUP 4 GENERAL & HIGH SOUR SERVICE
DEEP WELL COLLAPSE
SERVICE STRENGTH GENERAL COLLAPSE
40,000 H40
55,000 J55
K55

65,000 M65
70,000
75,000
80,000 N80Q L80-1 SM-80T SM-80S SM-80TS
L80-13CR

85,000
90,000 C90-1 SM-90S SM-90TS
95,000 C95 SM-95T SM-95S SM-95TS
T95-1 SM-95TT

100,000 SM-C100
105,000

110,000 P110 SM-110T SM-110S SM-C110T


SM-110TT SM-C110

125,000 Q125-1 SM-130G SM-125TT SM-125S

140,000 SM-140G

150,000

8 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


NEW SM SERIES (SUMITOMO STANDARD)
SEAMLESS
ARCTIC WET CO2 WET CO2 & WET CO2, SOUR &
SERVICE SERVICE SOUR CI SERVICE
SERVICE

SM-80L SM13CR-80
SM-80LL SM13CRI-80

SM13CR-85

SM-95L SM13CR-95
SM-95LL SM13CRM-95
SM13CRS-95

SM-110L SM13CRI-110 SM22CR-110 SM2535-110 SM2550-110


SM-110LL SM13CRM-110 SM25CR-110 SM2242-110 SM2050-110
SM13CRS-110 SM2035-110 SMC276-110

SM22CR-125 SM2535-125 SM2550-125


SM25CR-125 SM2242-125 SM2050-125
SM25CRW-125 SM2035-125 SMC276-125

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 9


PHYSICAL PROPERTIES - OCTG
SPECIFICATION APPLICATION GRADE MECHANICAL PROPERTIES
YIELD STRENGTH TENSILE STRENGTH ELONGATION (%)
(psi) (psi)
API 5CT GROUP 1 H40 40,000∼ 80,000 ≧ 60,000 API FORMULA
J55 55,000∼ 80,000 ≧ 75,000 API FORMULA
K55 55,000∼ 80,000 ≧ 95,000 API FORMULA
N80Q 80,000∼110,000 ≧ 100,000 API FORMULA
GROUP 2 M65 65,000∼ 85,000 ≧ 85,000 API FORMULA
L80-1 80,000∼ 95,000 ≧ 95,000 API FORMULA
L80-13CR 80,000∼ 95,000 ≧ 95,000 API FORMULA
C90-1 90,000∼105,000 ≧ 100,000 API FORMULA
C95 95,000∼110,000 ≧ 105,000 API FORMULA
T95-1 95,000∼110,000 ≧ 105,000 API FORMULA
GROUP 3 P110 110,000∼140,000 ≧ 125,000 API FORMULA
GROUP 4 Q125-1 125,000∼150,000 ≧ 135,000 API FORMULA
SM SERIES G 95,000∼125,000 ≧ 110,000 API FORMULA
GENERAL & DEEP SM-130G 130,000∼160,000 ≧ 135,000 API FORMULA
WELL SERVICE SM-140G 140,000∼170,000 ≧ 150,000 API FORMULA
150,000∼180,000 ≧ 160,000 API FORMULA
T, TT SM-80T 80,000∼110,000 ≧ 100,000 API FORMULA
HIGH COLLAPSE SM-95T 95,000∼125,000 ≧ 110,000 API FORMULA
STRENGTH SM-95TT 95,000∼125,000 ≧ 110,000 API FORMULA
SM-110T 110,000∼140,000 ≧ 125,000 API FORMULA
SM-110TT 110,000∼140,000 ≧ 125,000 API FORMULA
SM-125TT 125,000∼155,000 ≧ 135,000 API FORMULA
TS SM-80TS 80,000∼ 95,000 ≧ 100,000 API FORMULA
HIGH COLLAPSE & SM-90TS 90,000∼105,000 ≧ 103,000 API FORMULA
SOUR WELL SERVICE SM-95TS 95,000∼110,000 ≧ 105,000 API FORMULA
SM-C110T 110,000∼125,000 ≧ 115,000 API FORMULA
S SM-80S 80,000∼ 95,000 ≧ 95,000 API FORMULA
SOUR WELL SM-90S 90,000∼105,000 ≧ 103,000 API FORMULA
SERVICE SM-95S 95,000∼110,000 ≧ 105,000 API FORMULA
SM-110S 110,000∼125,000 ≧ 115,000 API FORMULA
SM-125S 125,000∼140,000 ≧ 130,000 API FORMULA
SM-C100 100,000∼115,000 ≧ 105,000 API FORMULA
SM-C110 110,000∼125,000 ≧ 115,000 API FORMULA
L, LL SM-80L 80,000∼110,000 ≧ 100,000 API FORMULA
LOW TEMPERATURE SM-80LL 80,000∼110,000 ≧ 100,000 API FORMULA
SERVICE SM-95L 95,000∼125,000 ≧ 105,000 API FORMULA
SM-95LL 95,000∼125,000 ≧ 105,000 API FORMULA
SM-110L 110,000∼140,000 ≧ 125,000 API FORMULA
SM-110LL 110,000∼140,000 ≧ 125,000 API FORMULA
NEW SM SERIES CO2 CORROSIVE SM13CR-80 80,000∼ 95,000 ≧ 95,000 API FORMULA
WELL SERVICE SM13CR-85 85,000∼100,000 ≧ 100,000 API FORMULA
SM13CR-95 95,000∼110,000 ≧ 105,000 API FORMULA
SM13CRI-80 80,000∼ 95,000 ≧ 95,000 API FORMULA
SM13CRI-110 110,000∼125,000 ≧ 110,000 API FORMULA
SM13CRM-95 95,000∼110,000 ≧ 105,000 API FORMULA
SM13CRM-110 110,000∼125,000 ≧ 110,000 API FORMULA
SM13CRS-95 95,000∼110,000 ≧ 105,000 API FORMULA
SM13CRS-110 110,000∼125,000 ≧ 110,000 API FORMULA
CO2-LOW H2S SM22CR-110 110,000∼140,000 ≧ 125,000 12
CORROSIVE SM22CR-125 125,000∼145,000 ≧ 130,000 11
WELL SERVICE
SM25CR-110 110,000∼140,000 ≧ 125,000 12
SM25CR-125 125,000∼145,000 ≧ 130,000 11
SM25CRW-125 125,000∼145,000 ≧ 130,000 11
CO2-H2S-CI- SM2535-110 110,000 ∼ 140,000 ≧ 115,000 12
CORROSIVE SM2535-125 125,000 ∼ 145,000 ≧ 130,000 10
WELL SERVICE
SM2242-110 110,000 ∼ 140,000 ≧ 115,000 13
SM2242-125 125,000 ∼ 145,000 ≧ 130,000 9
SM2035-110 110,000 ∼ 140,000 ≧ 115,000 11
SM2035-125 125,000 ∼ 145,000 ≧ 130,000 9
SM2550-110 110,000 ∼ 140,000 ≧ 120,000 15
SM2550-125 125,000 ∼ 145,000 ≧ 130,000 13
140,000 ∼ 160,000 ≧ 145,000 11
SM2050-110 110,000 ∼ 140,000 ≧ 120,000 16
SM2050-125 125,000 ∼ 145,000 ≧ 130,000 14
140,000 ∼ 160,000 ≧ 145,000 12
SMC276-110 110,000 ∼ 140,000 ≧ 115,000 20
SMC276-125 125,000 ∼ 145,000 ≧ 130,000 14
140,000 ∼ 160,000 ≧ 145,000 10

10 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


SPECIFIC REMARKS
HARDNESS GRAVITY
HRC RANGE △HRC
1.000
(13CR :
0.989 MAY BE USED)

HRC ≦ 22 M65 : CHARPY IMPACT TEST


HRC ≦ 23
HRC ≦ 23
HRC ≦ 25.4 ≦3∼6

HRC ≦ 25.4 ≦3∼6

≦3∼5 <CHARPY IMPACT TEST>


1.000 <CHARPY IMPACT TEST>

<COLLAPSE TEST>
SEE PEFORMANCE TABLE

<CORROSION TEST>
REFER THE TABLE ON PAGE 12

HRC 15 / 22
HRC ≦ 25.4
HRC ≦ 25.4
HRC 23 / 30 ≦3∼6
HRC ≦ 36
HRC ≦ 27 ≦3∼6
HRC ≦ 30
<CHARPY IMPACT TEST>
・SM-L SERIES : 10 × 10 × 2V at−50 F (−46℃)
 MIN AVE : 20FT-LB, MIN SINGLE : 15FT-LB
・SM-LL SERIES : 10 × 10 × 2V at−67 F (−55℃)
 MIN AVE : 23.1FT-LB, MIN SINGLE : 15.4FT-LB

HRC ≦ 23 1.000
HRC ≦ 24
HRC ≦ 27
HRC ≦ 25
HRC ≦ 32
HRC ≦ 28
HRC ≦ 32
HRC ≦ 28
HRC ≦ 32
HRC ≦ 36
HRC ≦ 37
HRC ≦ 36
HRC ≦ 37
HRC ≦ 37
HRC ≦ 32 1.028
HRC ≦ 34
HRC ≦ 32 1.037
HRC ≦ 35
HRC ≦ 32 1.032
HRC ≦ 33
HRC ≦ 33 1.060
HRC ≦ 36
HRC ≦ 39
HRC ≦ 34 1.093
HRC ≦ 36
HRC ≦ 38
HRC ≦ 38 1.129
HRC ≦ 38
HRC ≦ 40

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 11


SM-SERIES GRADE DESCRIPTION
1. CASING AND TUBING FOR GENERAL AND DEEP WELL SERVICE
SM-G meant for general and deep well service are remarkable for their high yield and tensile strengths while maintaining
good ductility and fracture toughness.
SM-130G and SM-140G offer additional tensile and yield strengths for deep well services.

Grade Yield Strength Tensile Strength Elongation Impact Properties min Ave Value
min psi (MPa) max psi (MPa) min psi (MPa) min % At 14゜F (-10˚C) ft-lb (J)
SM-130G 130,000 ( 862) 160,000 (1069)  135,000 ( 965)
SM-140G 140,000 ( 965) 170,000 (1172)  150,000 (1034) API Formula 15 (20) (Specimen: 10 by 10 mm)

CHARACTERISTICS
1. Tensile Strength
The resistance to collapse and the longitudinal high strength
requirements of well casing is becoming increasingly impor-
tant with the drilling of deeper and deeper wells. SM130G
and SM-140G offer the high strength properties.

2. Mechanical Properties
Mechanical Properties of SM-G series are shown in above
Table. SM130G and SM140G offer the required high Yield Strength (ksi)
strength properties. 40 60 80 100 120 140 160 180

150 No SSC
SSC
Application of High Strength
Temperature (℃)

R.D. Kane et., al.


Grades for Deep Sour Gas & Oil Wells
100
The smallest amount of H2S contamination should always
be taken into consideration when looking at high strength
material applications. No SSC SSC
Fig shows the applicability of high strength steels for sour
50
service integrating the following variables; H2S concentra-
tion, applied stress level and temperature.
Sulfide stress corrosion cracking susceptibility increases
with material strength and grades such as SM140G should 300 600 900 1200
never be used if H2S is present. Yield Strength (MPa)

12 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


2. CASING AND TUBING FOR SOUR OIL AND GAS SERVICE
In order to prevent possible sulfide stress corrosion cracking in sour gas and oil wells containing H2S, it is necessary to use
specially manufactured tubing and casing. API 5CT Group 2 grade tubing and casing have been developed and used widely
for this purpose. However these may not be adequate in high concentration of H2S.
To address this, Sumitomo Metal, after years of research and development, has succeeded in developing improved materials
with higher strength and higher corrosion resistance for casing and tubing.
These are available in our SM-S series as shown below.
Sumitomo Metals does not recommend SM sour series 100ksi and higher grade for tubing applications.
Each of these grades is produced with rigid manufacturing controls covering chemical composition, heat treatment (quench-
ing and tempering), tensile property, hardness and microstructure.

Mechanical Characteristics Quality Control

Type Tensile HRC Min.


Grade Yield Strength SSC test * (1)
Strength Hardness tempering temp.
min psi (MPa) max psi (MPa) min psi (MPa) max. (oF) NACE TM0177 Method-A

L80-1 80,000 (552) 95,000 (655) 100,000 (689) 23.0 1050 ―

80%SMYS
API C90 90,000 (621) 105,000 (724) 100,000 (689) 25.4 1150
(1bar H2S, Solution-A)
80%SMYS
T95-1 95,000 (655) 110,000 (758) 105,000 (724) 25.4 1200
(1bar H2S, Solution-A)
90%SMYS
SM-80S 80,000 (552) 95,000 (655) 95,000 (655) 23.0 1150
(1bar H2S, Solution-A)
90%SMYS
SM-90S 90,000 (621) 105,000 (724) 100,000 (689) 25.4 1150
(1bar H2S, Solution-A)
Sour Service
90%SMYS
SM-95S 95,000 (655) 110,000 (758) 105,000 (724) 25.4 1150
(1bar H2S, Solution-A)
85%SMYS
SM-95TS *(2) 95,000 (655) 110,000 (758) 105,000 (724) 26.0 1150
(1bar H2S, Solution-A)
85%SMYS
SM-C100 100,000 (689) 115,000 (793) 105,000 (724) 27.0 1100
(1bar H2S, Solution-A)
High Strength 85%SMYS
SM-C110 110,000 (758) 125,000 (862) 115,000 (793) 30.0 1100
Sour Service (1bar H2S, Solution-A)
85%SMYS
SM-C110T *(2) 110,000 (758) 125,000 (862) 115,000 (793) 30.0 1100
(1bar H2S, Solution-A)
85%SMYS
SM-110S 110,000 (758) 125,000 (862) 115,000 (793) 30.0 1100
High Strength (0.1bar H2S, Solution-B)
Mild Sour Service 85%SMYS
SM-125S 125,000 (862) 140,000 (965) 130,000(896) 36.0 1050
(0.03bar H2S, Solution-B)

*(1) SSC test of method-B & method-D is available on request


*(2) Collapse and sour

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 13


CHARACTERISTICS
1. Materials
The chemical compositions have been carefully determined
to provide resistance to sulfide stress corrosion cracking as
well as to insure complete through wall hardening.

2. Heat Treatment
Quenching and tempering are conducted under rigid tem-
perature control to assure homogeneous physical properties
and microstructures.
New Higher Strength Sour Resistant Grades SM-110S, SM-
C100, SM-C110, SM-C110T, SM-125S have been devel-
oped.

3. Micro Structure
These grades exhibit fully tempered martensite which is
considered to be the most desirable for resistance to sulfide
stress corrosion cracking.

4. Tensile Properties and Hardness


Yield strength is limited within a narrow range and hardness
is controlled to within the predetermined maximum limit. Sustain load type
Sulfide stress corrosion cracking
test apparatus
5. Sulfide Stress Cracking (SSC) Performance
SM sour resistant grades are designed for 85% or 90%
SMYS in NACE condition.
Excellent SSC resistance has been achieved through rigor-
ous, chemical composition, heat treatment, microstructure,
tensile properties, hardness and so on.

14 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


3. HIGH COLLAPSE CASING FOR DEEP WELL SERVICE
Sumitomo High Collapse Casing SM-T grade is a seamless product designed for deep wells where high collapse pressures
are anticipated. In order to meet deep well service requirements, SM-T casing has improved collapse properties well in
excess of API ratings. These properties are achieved by strict mill control incorporating a unique production technique inclu-
sive of quenching and tempering. SM-T casing shows a very high resistance to tension load, internal pressure, and collapse.
SM-95TS is also highly resistant to sulfide stress corrosion cracking and can be used for deep and sour gas and oil service.

Grade Yield Strength Tensile Strength Elongation Collapse


min psi (MPa) min % Resistance
min psi (MPa) max psi (MPa)
SM- 80T 80,000 (552) 110,000 ( 758) 100,000 (689) API Formula
SM- 95T 95,000 (655) 125,000 ( 862) 110,000 (758) API Formula
Refer website
SM- 95TT 95,000 (655) 125,000 ( 862) 110,000 (758) API Formula
(sumitomo-tubulars.com)
SM-110T 110,000 (758) 140,000 ( 965) 125,000 (862) API Formula
or ask SMI representative
SM-110TT 110,000 (758) 140,000 ( 965) 125,000 (862) API Formula
SM-125TT 125,000 (862) 155,000 (1069) 135,000 (931) API Formula

As wells are drilled deeper, the external pressures applied to well casings become greater. Thus, a well casing must have
adequate collapse strength to withstand these horizontal pressures without deformation. For reasons of economy such cas-
ings should also be as light-weight as possible while still retaining ample collapse resistance properties.
With this in mind Sumitomo Metals has developed its SM-T High Collapse Casing. This casing was developed from experi-
ments in which Sumitomo studied the critical collapse pressure of a well casing under external pressure in relation to its lon-
gitudinal tensile strength and the geometry of its cross section.

Specified Minimum Collapse Pressure


20,000 CHARACTERISTICS
Example of
Actual Data 1. Unique Production Technique
: SM-95T
: SM-110T
The material for SM-T casing is carefully selected to
: SM-125TT insure structural homogeneity. Strict control of heat treat-
SM

ment and dimensional tolerances is adhered to throughout


-1
25

15,000
the manufacturing process.
TT M-1
S
Collapse pressure (psi)

10

2. Rigid Dimensional Control


T
SM

Dimensional tolerances, such as roundness, straightness,


-9
5T

10,000
O.D. and wall thickness are strictly controlled.

3. Specified Collapse Value


AP
IP
A collapse test is carried out on each production run of
AP -1
IC
-9
10 SM-T casing with the same frequency as the tensile test
5
5,000 using the most modern testing equipment.

12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27
D/t

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 15


4. CASING AND TUBING FOR ARCTIC SERVICE
Sumitomo SM-L grades are designed for high impact tough- CHARACTERISTICS
ness at subzero temperatures, as this is experienced in arc-
1. Material
tic regions.
Special steel is used in order to obtain sufficient resistance
These properties are achieved through tight material chem-
to low temperature impact.
istry control and specific heat treatment.
The following Tables show tensile and impact toughness
2. Heat Treatment
properties.
Both casing and coupling are quenched and tempered with
special care.
Tensile Properties
Grade Yield Strength Tensile Elongation 3. Impact Properties
Strength min. %
min. psi max. psi min. psi Refer below table.
(MPa) (MPa) in 2 inches
(MPa)
SM-80L 80,000 110,000 100,000
SM-80LL (552) (758) (689)
SM-95L 95,000 125,000 105,000 API
SM-95LL (655) (862) (742) Formula
SM-110L 110,000 140,000 125,000
SM-110LL (758) (965) (862)

Impact Toughness Properties (Charpy impact value)

Grade Size of Min. Average Min. Value of


Specimen Value of Each One Specimen
mm Set of Three Only of a Set
Specimens ft-lb (J)
ft-lb (J)

SM-80L 10 by 10 20 (27) 15 (20)


SM-95L 10 by 7.5 15 (20) 11 (15)
SM-110L 10 by 5 10 (14) 8 (11)
10 by 2.5 5 ( 7) 4 ( 5)
Test temperature : −50 F (−46℃)

Grade Size of Min. Average Min. Value of


Specimen Value of Each One Specimen
mm Set of Three Only of a Set
Specimens ft-lb (J)
ft-lb (J)

SM-80LL 10 by 10 23.1 (31) 15.4 (21)


SM-95LL 10 by 7.5 18.5 (25) 12.3 (17)
SM-110LL 10 by 5 12.7 (17) 8.5 (12)

Test temperature : −67 F (−55℃)

16 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


NEW SM-SERIES
1. 13CR, Super 13CR and Duplex Stainless Steel

1.1 Chemical composition


Grade Chemical Composition (wt%)
C Si Mn Cu Ni Cr Mo W N
≦0.5 12.0
SM13CR ≦ 0.22 ≦ 1.00 ≦ 1.00 ∼14.0
1.5 10.5 0.2
SM13CRI ≦ 0.03 ≦ 0.50 ≦ 1.50 ∼3.0 ∼12.5 ∼0.4
4.0 11.0 0.2
SM13CRM ≦ 0.03 ≦ 0.50 ≦ 1.00 ∼6.0 ∼14.0 ∼1.2
5.0 11.5 1.5
SM13CRS ≦ 0.03 ≦ 0.50 ≦ 0.50 ∼6.5 ∼13.5 ∼3.0
4.5 21.0 2.5 0.08
SM22CR ≦ 0.03 ≦ 1.00 ≦ 2.00 ∼6.5 ∼23.0 ∼3.5 ∼0.20
0.2 5.5 24.0 2.5 0.10 0.10
SM25CR ≦ 0.03 ≦ 0.75 ≦ 1.00 ∼0.8 ∼7.5 ∼26.0 ∼3.5 ∼0.50 ∼0.30
0.2 6.0 24.0 2.5 2.01 0.24
SM25CRW ≦ 0.03 ≦ 0.80 ≦ 1.00 ∼0.8 ∼8.0 ∼26.0 ∼3.5 ∼2.50 ∼0.32

1.2 CO2 Corrosion Resistance


(1) High Cr steels such as 13Cr stainless steels are resis- (2) Effect of Cr content and temperature on CO2 corrosion
tant to CO2 corrosion and have used widely, and suc- are shown in Fig. 13CR & 13CRI critical temperature is
cessfully in wells containing CO2 and CL-. 150°C ; For 13 CRM & 13CRS is 180°C. Duplex stain-
less steels (25Cr) have excellent corrosion resistance up
to a temperature of 250°C.

Temperature ( F)
0 100 200 300 400 500 600
70
15
C-steel 2500
500 60 2Cr
5Cr
Corrosion rate (mm/y)

Corrosion rate (mpy)

10 9Cr-1Mo
50 2000
13Cr
Corrosion rate (mpy)
Corrosion rate (mm/y)

22Cr/25Cr

40
1500
5

30

1000
0 0
20
0.01 0.05 0.1 0.5 1 5 10
Cr content (wt.%)
500
10
Effect of Cr content of commercial tubular goods on corrosion rate by loop tester
(Synthetic sea water, CO2 partial pressure 0.1 MPa (60℃), test temperature 60℃,
test duration 150h, flow velocity 2.5 m/s, specific volume : 800 cc/cm2) 0
0
0 100 200 300

Temperature (℃)

Effect of temperature on corrosion rate by autoclave


(Synthetic sea water, CO2 partial pressure ; 3.0 MPa (R.T.), test duration 72h,
flow velocity 2.5 m/s, specific volume : 42 cc/cm2)

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 17


0.05 0.5 5 20 0.05 0.5 5 20
100℃ 150℃ (A) 13Cr
5
5 3.0 MPa
CO2 100
9Cr-1Mo 0.1 MPa
13Cr (420) 50
SM22Cr-Duplex 1
SM25Cr-Duples

Corrosion rate (mpy)


Corrosion rate (mm/y)
0.5
Corrosion rate (mm/y)

10
1
5
0.1
0.5 (B) 25Cr

10
0.2 5
0.1

0.1
50 100 150 200 250 (℃)

100 200 300 400 500 ( F)


102 103 104 105 102 103 104 105
Cl- (ppm) Effect of CO2 partial pressure and temperature on corrosion rate of Cr steel
(5% NaCl, CO2 3.0 and 0.1 MPa at 25℃, test duration 96hr, flow velocity 2.5 m/s)
Effect of Cl- low concentration on the corrosion rate of Cr steels at 150℃ in the
autoclave. (3.0MPa CO2 at 25℃, test duration 96hr, flow velocity 2.5 m/s)

101
Solid mark : Cracked
Half Solid : Pitting
GC : General Corrosion GC
100 GC

13Cr
Corrosion rate (mm/y)

-1
10

SM13CRS
10-2

22Cr
10-3

10-4
0 50 100 150 200
Temperature (℃)
Effect of temperature on corrosion resistance of SM13CRS
(5%NaCl + 3.0MPa (450psi) CO2 + 0.001MPa (0.15psi) H2S)

18 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


1
Test environments:
A
3.0 MPa CO2, 80゚C, 336hr 1% NaCI
(6000ppm CI-)
Corrosion rate (mm/y)

Solid: General corrosion


Half Solid: Pitting

B
0.1 C 5% NaCI
(30000ppm CI-)

B
C
A
25% NaCI
L80-13Cr (150000ppm CI-)
0.01
0 10 20 30
NaCl [wt%]

Effect of NaCl concentration on corrosion behavior of 13Cr steel in CO2 environment


(3.0MPa (450psi) CO2 at 80℃, 336h)

Solid : General corrosion


Half Solid : Pitting
Open : Passive
L80-13Cr
SM13CRS
Corrosion rate (mm/y)

SM13CRM A 200μm
Conventional 13CR

CO2 = 3.0MPa
25wt%NaCl
SM13CRM 200μm
0 100 200
Testing temperature (゚C)
175℃

Effect of temperature on corrosion rate of conventional 13CR, SM13CRS and SM13CRM in CO2 environment
(3.0MPa (450psi) CO2, 150,000ppm Cl-)

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 19


1.3 Sulfide Stress Corrosion Cracking (SSCC) Resistance
(1) 13CR has a high SSCC susceptibility as shown in below taining up to 0.03bar H2S.
fig; 13CR usage is not advisable for usage in environ- (3) Duplex stainless steels (SM22CR, SM25CR, SM25CRW)
ments containing a small amount of H2S (≦ 0.003bar). are recommendable over marternsitic stainless steel
(2) 13CRS has good SSCC resistance in environments con- (SM13CRS) in a small amount of H2S.

13Cr (Y. S. 602MPa) 13Cr (Y. S. 768MPa) Calculated H2S at 80℃ (MPa)
Temperature ( F)

10-4 10-3
Temperature (℃)

10-2 10-1
150 300
: Type 316L : SM25CR
100 200 : SM22CR : SM25CRW SM25CR
Solid mark : Crack SM25CRW
50 100 SM22CR 25Cr
25Cr (Y. S. 553MPa) 25Cr (Y. S. 822MPa) Type 316L 22Cr
Cl- concentration(ppm) 105
Temperature ( F)
Temperature (℃)

150 300

100 200 104

50 100

10-4 10-3 10-2 10-4 10-3 10-2 103


PH2S (MPa)
Effect of H2S partial pressure and temperature on the SSCC susceptibility.
102
5% NaCl, 3.0MPa CO2 + H2S at 25℃ (77°
F), test duration 336h, flow velocity
2.5m/s, 1σy with notch

13Cr Cr:12-16% Ni:5-7% 10-4 10-3 10-2 10-1


H2S (MPa)
120℃
SCC susceptibility of duplex stainless steel in Cl--H2S environment.
0.1 : No SCC, : SCC
(SSRT method ; 80℃, strain rate 4.2 x 10-6/s)(annealed)
0.01

0.001 1.2

SM25CRW
60℃ SM25CRW
Corrosion rate (mm/y)

SM25CR
1
0.1
SM25CR
0.01

0.8
0.001
L/L0

25℃
0.6

0.1

0.01 0.4

0.001
( : SSC, : No SSC, : Pitting)
0.2
13Cr 1Mo 2Mo 3Mo 0.5 1 2 5 10
SM13CrS Cl- (104ppm)

Effect of Mo content on corrosion rate and SSCC. <SM13CRS> SCC susceptibility of duplex steel in Cl--H2S environment.
: No SCC, : SCC
(
5% NaCl + 3.0MPa (450psi) CO2 + 0.001MPa (0.15psi) H2S
4-point bent beam with notch, 1σy, 336h ( (SSRT method ; 80℃ ,Calculated H2S 0.015MPa, strain rate 4.2 x 10-6/s)

20 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


1.4 Erosion Properties

(1) 13CR, Super 13CR and Duplex stainless steels have


superior erosion properties.

Effect of Flow velocity (Field test results)


Average test conditions in the DFT (Dynamic Field Tester) experiments 1 (Test duration: 3672h) and 2 (Test duration: 4493h)

Experiment Internal diameter Gas flow rate Pressure Temperature Gas velocity Flow pattern
(mm) (m3/h) (m/s)
(psi) (MPa) (F) (K)

52 9000 1960 13.8 190 361 17.6 Transition Annular mist

27 9000 1917 13.5 190 361 66.6 Annular mist


1
20 9000 1775 12.5 188 360 131.4 Annular mist

15 9000 1661 11.7 188 360 250.5 Annular mist

52 7860 1755 12.1 181 355 10.6 Transition

27 7860 1726 11.9 175 352 39.7 Annular mist


2
20 7860 1598 11.1 175 352 78.2 Annular mist

15 7860 1406 9.9 171 350 157.1 Annular mist

13Cr (Exp. 1)
13Cr (Exp. 2)
SM13CRS (Exp. 2)
DP1 (Exp. 2)
0.2 SM22Cr (Exp. 1)
0.1 SM22Cr (Exp. 2)

0.05
Corrosion rate (mm/y)

0.01
0.005

0.001
0.0005

0.0001

0 50 100 150 200 250 300


Gas velocity VsG (m/s)
Effect of flow velocity on corrosion rate of 13Cr, SM13CRS, DP1, and
SM22Cr steels in the DFT experiments 1 and 2.

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 21


2. H2S+CO2+Cl- CORROSION (Ni BASE ALLOYS)
High Alloy Materials become necessary where severe well (3) The effect of fundamental elements on corrosion behav-
conditions with high concentrations of H2S, CO2 and CI- iors are shown in the following Figures.
brines are encountered. These can be recapped as follows.
(1) High Ni corrosion resistant alloys for OCTG feature a ・Application limit temperature is strongly depending on
single austenitic phase. Strength is developed through Mo content in the Ni Base Alloys.
cold working. ・In combined H2S, CO2, Cl- media, the basic minimal
Addition of essential alloying elements such as Cr, Ni, chemistry of Cr≧18%, Ni≧28%, Mo≧3% is required.
Mo determines the corrosion resistance properties. ・Hydrogen embrittlement susceptibility increases with
(2) Resistance to general (weight loss) corrosion and local- material chemistries exceeding 60% Ni.
ized (pitting and crevice) corrosion is achieved by the (4) Elemental S is very aggressive to SCC. SM2050 and
formation of a stable passivation film on the material sur- SMC276 is applicable depending on environmental tem-
face. perature.

Grade Chemical Composition (mass %)


C Si Mn Cu Ni Cr Mo Ti W Fe
29.5 24.0 2.50
SM2535 ≦ 0.03 ≦ 0.50 ≦ 1.00 ≦ 1.5 ∼36.5 ∼27.0 ∼4.00 Bal

1.50 38.0 19.5 2.50 ≦ 1.20


SM2242 ≦ 0.05 ≦ 0.50 ≦ 1.00 ∼3.00 ∼46.0 ∼24.0 ∼4.00 Bal

33.0 20.5 4.00 0.20


SM2035 ≦ 0.03 ≦ 0.75 ≦ 1.00 ≦ 0.07 ∼38.0 ∼23.5 ∼5.00 ∼0.80 Bal

47.0 23.0 6.00


SM2550 ≦ 0.03 ≦ 1.00 ≦ 1.00 ≦ 1.20 ∼54.0 ∼26.0 ∼9.00 ≦0.69 ≦ 3.0 Bal

49.0 19.0 10.1


SM2050 ≦ 0.03 ≦ 0.50 ≦ 1.00 ≦ 2.00 ∼53.0 ∼23.0 ∼12.0 ≦ 1.50 Bal

14.5 15.0 3.0 4.0


SMC276 ≦ 0.01 ≦ 0.08 ≦ 1.00 Co ≦ 2.5 Bal ∼16.5 ∼17.0 V≦0.35 ∼7.0
∼4.5

250℃(482 F) 300℃(572 F) 350℃(662 F)


0 0 0

3 3 3

6 6 6
0 0 0
10 10 Corrosion- 10
Corrosion-resistant resistant
3 3 region 3
Corrosion-resistant region
region
Mo (%)

6 6
Mo (%)

15 15 15
Mo (%)

6
30 30 30
C
C

SC
C
SC

25 25 25
SC
SC

10 10 10
TG
TG

IG
TG
)

20 20 20
%

%
(

(
Cr

Cr

Cr

15 15 15 15 15 15
60 40 20 0 60 40 20 0 60 40 20 0
Ni (%) Ni (%) Ni (%)
Corrosion resistant region of Fe-Cr-Ni-Mo alloy (20% NaCl+0.5% CH3COOH, 1.0 MPa H2S-1.0MPa CO2-pH 2)

22 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


Without CH3COOH (pH:High)
300
No SCC SCC in 3 months
in 10 months 20Cr
SCC in 10 months 15
Temperature (℃)

250 pH0.5
12
No SCC
in 10 months HE
SM2050

Mo (%)
200 9
pH2.0
6
150
0 3 5 9 12 15 18
Mo (%) 3

0
30 40 50 60 70
Ni (%)
With 0.5%CH3COOH (pH:Low)
300
No SCC SCC in 3 months Corrosion resistant region−pH−alloying element
in 10 months SCC in 10 months (1)Corrosion resistance pH 2 ; No SCC and C.R. ≦0.05 mm/y,
Temperature (℃)

(2)Environment, SCC : 20% NaCl +0.5% CH3COOH−1.0 MPa H2S


250 −1.0 MPa CO2 −250℃, HE : NACE TM01-77 solution, Iron
No SCC
in 10 months coupling/400℃×1,000h aging)

200

150
0 3 5 9 12 15 18
Mo (%)
Effect of Mo and temperature on SCC resistance
(C ring test, 20% NaCI, 1MPa H2S +1 MPa CO2, 100% YS)

SCC SCC
SMC276
450 232 450 232
Temperature (゚C)

Temperature (゚C)
Temperature (゚F)

Temperature (゚F)

400 204 400 204


Localized
SM2050 corrosion
350 177 350 177
SM2550
300 No SCC 149 300 149
SM2242
SM2535
3 6 9 12 15 3 6 9 12 15 18
Mo+ 1/2W (wt%) Mo (mass %)

1
Relationship between testing temperature and Mo+−W content of Ni Base Alloys The relationship between testing temperature and Mo content of Ni-base alloys
2
in H2S-CL- environment in the SSRT tests. in an elemental S-containing sour environment.
(SSRT test condition ; 25% NaCl-0.5% CH3COOH, 0.7MPa H2S, E=4.0×10-6S-1) (25% NaCl+1g / S, 1.0MPaH2S+1.0MPaCO2, 4PB with notch Applied Stress;
100% SMYS(110ksi), 336h)

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 23


3. Guidelines concerning Brines acceptability for 13CR, 13CRS, 13CRM,
Duplex stainless and CRA steel
The below guidelines are based on laboratory testing engers, etc. Cosequently the brine “package” suitability and
excluding O2 contamination or usage of common brine addi- long term stability needs to be carefully ascertained prior to
tives such as corrosion inhibitors, biocide, oxygen scav- usage.

C-steel 13CR 13CRS, 13CRM 22Cr (Duplex s.s.)


PH※1
Corrosion※2 Corrosion※3 SCC※5 Pitting※4 SCC※5

NaCl △ △ ○ ○ △ ○

CaCl2 ○ △ △ × × ×

MgCl2 × ○ △ × × ○

ZnCl2 × × × × ○ ○

NaBr ○ ○ ○ ○ △ −

CaBr2 ○ △ △ ○ △ ○

MgBr2 △ △ △ − △ −

ZnBr2 × × × − ○ ○

(1g/m2/h=1.1mm/year)
※1) In 60℃, 0.1MPaCO2
  ○ : pH≧4
  △ : 3<pH<4
  × : pH≦3

※2.3) Autoclave test 150℃, 0.4MPaCO2


※2) Brine applications identified with × are NO GO areas
2
  ○ : C.R.≦1g/m /h Brines identified with ○ are acceptable for Completion &
  △ : 1<C.R.≦10 packer fluid applications
  × : C.R.>10
Brines identifided with △ may be acceptable for short term
※3)
  ○ : C.R.≦0.1
completion fluid applications.
  △ : 0.1<C.R.≦1.0 Addition of corrosion inhibitor, biocide, and oxygen scaveger
  × : C.R.>1.0 is recommended but these additives long term stability will
be carefully ascertained prior to usage.
※4) Pitting potential
  ○ : Vp≧0.3V Whenever possible an oil base solids free packer fluid will
  △ : 0<Vp<0.3 be preferred.
  × : Vp≦0

※5)
  ○ : Crack Free
  × : Crack

24 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


4. Mechanical and Thermal Properties

Mechanical properties
Specific Gravity
(kg/m3) Young' Modulus (GPa) Poisson's Ratio

No Grade 25℃ 25℃ 100℃ 200℃ 250℃ 25℃ 100℃ 200℃ 250℃

1 SM-95S 7.80 213 209 203 200 0.30 0.29 0.29 0.28
2 SM-C110 7.75 212 209 203 200 0.30 0.30 0.29 0.29
3 SM-125S 7.80 212 209 203 200 0.30 0.30 0.29 0.29
4 SM13CR-80 7.71 221 217 211 208 0.30 0.29 0.29 0.29
5 SM13CRS-95 7.73 203 200 194 190 0.30 0.30 0.30 0.29
6 SM13CRS-110 7.72 202 198 193 189 0.30 0.29 0.30 0.29
7 SM13CRM-110 7.68 204 202 196 192 0.29 0.30 0.30 0.29
8 SM22CR-110 7.85 198 194 184 189 0.25 0.24 0.23 0.24
9 SM25CR-110 7.85 191 184 177 193 0.26 0.25 0.24 0.27
10 SM25CRW-125 7.85 200 198 191 188 0.27 0.27 0.27 0.27
11 SM2535-110 8.07 205 194 189 187 0.31 0.29 0.30 0.30
12 SM2242-110 8.14 210 197 184 187 0.31 0.29 0.28 0.29
13 SM2035-110 8.10 203 194 181 177 0.32 0.30 0.31 0.30
14 SM2550-110 8.29 211 195 186 185 0.31 0.29 0.29 0.28
15 SM2050-110 8.58 216 201 192 196 0.33 0.31 0.31 0.31
16 SMC276-110 8.87 220 207 197 196 0.33 0.31 0.31 0.31

Thermal properties
Thermal Expansion Thermal Diffusivity Heat Capacity Thermal Conductivity Specific Heat
Coefficient (/deg-C) (m2/s) 106 (J/(m3・K)) (W/(m・K)) (J/(kg・K))
No Grade 25- 25- 25-
25℃ 100℃ 200℃ 250℃ 25℃ 100℃ 200℃ 250℃ 25℃ 100℃ 200℃ 250℃ 25℃ 100℃ 200℃ 250℃
100℃ 200℃ 250℃

1 SM-95S 12.4 12.8 13.0 12.30 11.90 10.60 9.96 3.61 3.83 4.15 4.34 44.4 45.6 44.0 43.3 463 492 535 562
2 SM-C110 12.3 12.6 12.8 11.90 11.50 10.30 9.74 3.49 3.72 3.97 4.17 41.5 42.8 40.9 40.6 450 481 516 543
3 SM-125S 12.3 12.8 13.0 12.60 12.00 10.80 10.20 3.50 3.66 3.89 4.08 44.1 43.9 42.0 41.6 449 470 502 528
4 SM13CR-80 10.9 10.9 11.0 7.74 7.70 7.02 6.75 3.48 3.64 3.93 4.11 27.0 28.0 27.6 27.7 452 473 512 537
5 SM13CRS-95 10.9 11.0 11.1 4.67 4.85 4.97 5.00 3.39 3.67 3.98 4.12 15.8 17.8 19.8 20.6 438 476 517 537
6 SM13CRS-110 10.7 10.8 10.9 4.67 4.87 4.99 5.00 3.37 3.46 3.72 3.87 15.7 16.8 18.5 19.3 436 449 484 504
7 SM13CRM-110 10.7 10.8 11.0 4.78 4.99 5.06 5.07 3.38 3.62 3.96 4.13 16.2 18.0 20.0 20.9 440 472 518 542
8 SM22CR-110 12.5 12.8 13.3 3.59 4.16 4.39 4.38 3.77 4.12 4.52 4.73 13.7 16.2 18.1 19.3 468 496 526 562
9 SM25CR-110 12.5 12.7 13.0 3.59 4.14 4.45 4.65 3.86 4.61 4.98 5.36 13.1 16.0 18.3 20.5 465 492 524 562
10 SM25CRW-125 13.0 13.2 13.5 3.33 3.64 3.93 3.99 3.93 4.25 4.55 5.08 13.0 15.3 17.7 19.9 498 536 574 636
11 SM2535-110 14.5 14.9 14.9 2.96 3.26 3.71 4.04 3.75 3.99 4.23 4.39 10.8 12.4 14.7 16.6 453 471 491 509
12 SM2242-110 14.6 14.7 14.9 2.83 3.15 3.71 4.16 3.68 3.96 4.31 4.52 10.4 12.0 14.7 17.1 452 467 487 505
13 SM2035-110 14.8 14.8 14.8 2.91 3.16 3.54 3.96 3.82 3.93 4.17 4.39 10.7 12.0 14.0 16.3 454 469 488 509
14 SM2550-110 14.0 14.1 14.2 2.81 3.07 3.50 4.19 3.75 4.18 4.23 4.52 10.3 11.7 13.9 16.3 442 460 480 469
15 SM2050-110 13.2 13.5 13.6 2.79 3.03 3.58 3.90 3.74 4.00 4.21 4.41 10.1 11.5 13.9 15.6 421 442 452 466
16 SMC276-110 12.2 12.4 12.5 2.69 2.90 3.46 3.74 3.67 4.09 4.14 4.27 9.5 10.6 13.2 14.9 399 413 430 449

Note : 1cal/cm・s・C=360kcal/m・h・℃=419W・m-1・C-1

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 25


5. Cost Comparison with 13 Chrome
Example

$ 7,000,000

6,000,000

5,000,000

4,000,000

3,000,000

2,000,000

1,000,000 Batch
CTS
13 Chrome
0
1 2 3 4 6 8 10 12 14 Years

Batch: $7,016,485.00
(Chemical Inhibition Batch Treating)
CTS: $2,779,800.00
(Continuous Treating System)
13 Chrome: $289,000.00
(The economics are dated and the reader is cautioned to compare current prices.)

Source of reference:
Debbie A. Baudoin, David K. Barbin and Jim Skogsberg,
"Experiences with 13Cr for mitigating CO2 corrosion in the oilfield
Case histories: The Gulf of Mexico and inland gas wells",
Corrosion 95,paper No.639 (1995)

26 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


FEATURES OF PREMIUM CONNECTIONS
■Newly patented sealing system with 14° ■Newly patented sealing system with 20°or
tapered metal to metal seal including VAM 14°tapered metal-to-metal seal provides
stabilizer TM provides gall free gas tightness gall-free gas-tightness which maintains their
which is as strong as pipe body, even under integrity, even under the most severe condi-
the most severe condition such as High tion as true tubing application in casing sizes
pressure and High temperature well as true (23/8"∼14").
tubing application in casing sizes (9 5/8"-13 ■Hooked thread design increases resistance
3/8"). to jumping-out and decrease hoop stress on
■VAM stabilizer TM composes double taper coupling under higher bending and
guides for good make up condition, reverse tension/compression, making this connec-
angle torque shoulder and extended lip tion suitable for application in long deviated
which can sustain most severe collapse and or horizontal well.
compression load and results in superior ■Reverse angle torque shoulder results in
sealing performance and structural resis- superior sealing performance and structural
tance under severe combined load condi- resistance under severe combined load con-
tion. dition.
■Innovative thread form with cylindrical crest ■Streamlined internal profile with tight toler-
and root for stable stabbing, no-cross ance minimize gas flow turbulance.
threading and self alignment can be ■High compression version (VAM TOP HC) is
obtained. Hooked thread design increase available.
resistance to jumping out and decrease ■High torque version (VAM TOP HT) provides
hoop stress on coupling under higher bend- reinforced torque capacity for liner applica-
ing and tension/ compression, making this tion where high torque is anticipated.
connection suitable for application in long ■Special coupling with 80% and 90% tensile
deviated or horizontal well. efficiency are available.
■A fully cleared internal profile with tight toler-
ance minimizes gas flow turbulence, no
interference with well bore operations and
no invitation to wear.
■Special coupling with 80% and 90% tensile
efficiency are available.

■A make-up arrestor positions the coupling ■Ideally suited to controlled-yield material


accurately on the mill end. ■T&C design for controlled-yield material with
■Pin to pin torque shoulder for positive torque no cold working or upsetting that could alter
stop on the field end allows overtorque and metallurgy.
compression resistance. ■Self energizing metal-to-metal seal with 50%
■Modified hook thread profile, with -9° taper provides pressure integrity to API mini-
reverse angle on the load flank and +20°on mum-yield.
the stabbing flank which provides superior ■Tensile efficiency equals 100%
load carrying performances. ■Hook threads with 3°reverse angle and
■Increased thread taper, combined with a proper thread length prevent jump-out under
wider thread profile which allows deep stab- tension or bending, and reduce tensile hoop
bing with no cross-threading. stresses.
■Increased thread pitch to reduce make-up ■Smooth bore for turbulence-free flow. The
time. VAM HW ST is the ideal connection for
■Jump-out free. extra-heavy casing application.
■Special thread design to offer superior
thread sealing performances.
■Vanishing threads, fully covered.
■100% tensile efficiency for all sizes with
standard API Buttress OD.
■Pins shoulder, thereby providing a smooth
bore ID to minimize turbulence and energy
losses.
■Pins shoulder, thereby providing high com-
pression resistance and immunity to jump-in.

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 27


■Optimized clearance with 70% to 80% ten- ■The extreme high torque strength permits
sion efficiencies of the pipe body yield. pipe rotation in deviated wells without struc-
■Combination of internal and external seals tural failure.
provides pressure ratings equal or greater ■The connection OD and ID are 100% flush
than pipe body ratings. to the pipe body provides maximum clear-
■Excellent compression ratings of 70% of ance.
joint strength by 90 degree middle torque ■Combination of internal and external seals
shoulder and thread form. provides pressure ratings equal or greater
■User friendly, deep stab, withstand severe than pipe body ratings.
excess of thread compound.
■The negative 10 degree hooked thread locks
the connection and prevent jump-out under
high tension.

■15°hooked thread for optimal load transmis- ■Based on the same concept of VAMTOP
sion and resistance to "jump out." sealing system, thread profile and torque
■Independent metal-to-metal multi-seal shoulder shape, VAMTOP HC maintain high
arrangement for excellent gas-tight perfor- performance meeting to ISO13679 Class 4
mance with burst and collapse pressure rat- application
ings equivalent to the pipe body. ■The torque shoulder dimension of VAM-
■External torque shoulder for easy running. TOPHC is significantly larger than VAMTOP
and with a mixture of reduced torque, this
enables the connection to withstand extreme
compression. VAMTOPHC is 100% com-
pression connection rating with 100% VME
ellipse.
■Special clearance/special bevel of VAMTOP
HC is consulted case by case.
■Size availability is from 4-1/2" to 7-3/4".
■4-1/2" VAMTOPHC is not compatible with 4-
1/2" VAMTOP connection.

28 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


MATERIAL AND CONNECTION DESIGN
CUSTOMER SUMITOMO METALS
SEARCH DATABASE
Well Information Material Selection ● Application Records

● Failure Records
● Well Condition ● Expert System
● Well Operation ECONOMICAL EVALUATION
● Running Condition ● Analysis Profitability

of Selected Material

String Design

STRESS ANALYSIS
● Under Anticipated

 Load Conditions

Connection Design Material Design & Evaluation


CAD SYSTEM MATERIAL EVALUATION
FEM ANALYSIS ● Evaluation under Simulated

PHYSICAL TESTS Well Condition


● Make & Break Tests ・Production
● Leak Resistance Evaluation Test ・Acidizing
● Thermal Cycle Tests ・Completion, Packer Fluids
● Measurment of the Stress ● Material Combination

● Failure Tests with DHE


● Fatigue Tests NEW MATERIAL DESIGN

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 29


MARKING, COLOR IDENTIFICATION AND
INQUIRY AND/OR ORDER DETAIL
MARKING, COLOR IDENTIFICATION
API 5CT N-80Q
DATE OF MANUFACTURE
MANUFACTURER'S API LICENSE NO LENGTH TYPE OF THREAD SHIPPING MARK
Mark

5CT*** *
. P DATE OF MFR 9-5/8 53.5 NQ S P*** D 41.5 BC SUMITOMO METALS MADE IN JAPAN NO1

API MONOGRAM SIZE LBS/FT GRADE PROCESS OF MANUFACTURE PIECE NO


COLOR COATING FOR GRADE
IDENTIFICATION

SM SERIES
DATE OF MANUFACTURE
MANUFACTURE'S Mark SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK

SUMITOMO METALS. DATE OF MFR 9-5/8 53.5 SM-95T   S   P*** D 41.5 VAM TOP MADE IN JAPAN NO1

COLOR
BAND PROCESS OF MANUFACTURE PIECE NO
COLOR COATING FOR GRADE
IDENTIFICATION

NEW SM SERIES
DATE OF MANUFACTURE
MANUFACTURE'S Mark SIZE LBS/FT GRADE LENGTH TYPE OF THREAD SHIPPING MARK
COLOR BAND

SUMITOMO METALS DATE OF MFR 4-1/2 12.6 SM13CRS-95 S   P*** D 31.5 VAM TOP MADE IN JAPAN NO1

PROCESS OF MANUFACTURE PIECE NO


COLOR COATING FOR GRADE
IDENTIFICATION NO DIE STAMP

30 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


API and SMI Proprietary Steel Grades Colour Code Chart
Application High High Collapse Low Martensitic Duplex Austenitic
API Collapse Sour Service and Sour Service Temperature Deep Well
Strength Stainless Steel Stainless Steel Stainless Steel
55 ksi J55 Tubing

J55 Casing

K55

80 ksi N80 Q SM-80T SM-80S SM-80TS SM-80L SM13CR-80

L80-1 SM-80LL SM13CRI-80

L80 13Cr

85 ksi SM13CR-85

90 ksi C90-1 SM-90S SM-90TS

95 ksi C95 SM-95T SM-95S SM-95TS SM-95L SM13CR-95

T95-1 SM-95TT SM-95LL SM13CRM-95

SM13CRS-95

SM13CRS-95(ISO 13680)

100 ksi SM-C100

110 ksi P110 SM-110T SM-110S SM-C110T SM-110L SM13CRI-110 SM22CR-110(ISO 13680) SM2535-110(ISO 13680)

SM-110TT SM-C110 SM-110LL SM13CRM-110 SM25CR-110(ISO 13680) SM2242-110(ISO 13680)

SM13CRS-110 SM2035-110(ISO 13680)

SM13CRS-110(ISO 13680) SM2550-110(ISO 13680)

SM2050-110(ISO 13680)

SMC276-110(ISO 13680)

125 ksi Q125-1 SM-125TT SM-125S SM22CR-125(ISO 13680) SM2535-125(ISO 13680)

SM25CR-125(ISO 13680) SM2242-125(ISO 13680)

SM25CRW-125(ISO 13680) SM2035-125(ISO 13680)

SM2550-125(ISO 13680)

SM2050-125(ISO 13680)

SMC276-125(ISO 13680)

130 ksi SM-130G

140 ksi SM-140G

150 ksi

Note : These materials may be supplied without color coding to avoid chloride contamination.

SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES 31


INQUIRY AND/OR ORDER DETAIL
You are requested to specify your conditions for the follow-
ing items on your order sheet.

Applicable specification, grade and type:


(Ex.) SUMITOMO SM-95S
SUMITOMO SM-95T
SUMITOMO SM2535-110
Type of pipe : Casing or tubing
Type of ends : Threaded or plain end
Round (Short, Long), Buttress (casing) or
Premium joint; VAM TOP, VAM TOP HC,
VAM TOP HT or DINO VAM (casing or tub-
ing)
Size (outside diameter)
Weight per foot or wall thickness
Range length (Range-1, 2, 3)

Quantity
Delivery date and shipping instructions Mill inspection by
purchaser.
If you have any special requirements, please specify the
details accordingly.

Hydrostatic test pressure


Non-destructive inspection
Type of joint (other than regular coupling)
Special clearance coupling (same or higher grade)
Special bevelled coupling
Special designed joints
(VAM TOP, VAM TOP HC, VAM TOP HT, VAMFJL,
VAM HWST, DINO VAM)
Coupling make-up (other than regular power tight):
Torque turn device or hand tight
Special drift or alternative drift (API 5CT)
(EXAMPLE)

ABC CO 1234-90

Specification : SUMITOMO SM2535-110


Type of pipe : Tubing
Type of end : VAM TOP
Size. weight : 3-1/2" * 9.2# Range 2
Quantity : 12000ft
Delivery : xxx.xxx.xxx on site shipping mark as
per attached sheet
Mill inspection : Mill final inspection (No third party
inspection)

32 SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES


SUMITOMO METAL INDUSTRIES, LTD.
HEAD OFFICE
Tokyo: 1-8-11, Harumi, Chuo-ku, Tokyo 104-6111, Japan
Fax: +81-3-4416-6288,6789
(Oil Country Tubular Goods Export Section)
Phone: +81-3-4416-6280
(Line Pipe Export Section)
Phone: +81-3-4416-6285
(Speciality Tubular Products Export Section)
Phone: +81-3-4416-6311

OVERSEAS OFFICES
Singapore: 5 Shenton Way #25-07, UIC Building, 068808 Singapore
Phone: +65-6220-9193
Fax: +65-6224-0386
London: Horatio House 77-85 Fulham Palace Road
London W6 8JB UK
Phone: +44-20-8748-4480
Fax: +44-20-8748-8350
Dubai: Level 10, JAFZA View 18, Jebel Ali Free Zone,
PO Box 262517, Dubai, UAE
Phone: +971-4-886-5900
Fax: +971-4-886-5901

OVERSEAS AFFILIATE
Sumitomo Metal USA Inc.
Chicago: 25 Northwest Point Blvd., Suite 675
Elk Grove, IL 60007, U.S.A.
Phone: +1-847-290-2600
Fax: +1-847-290-2666
Houston: 820 Gessner, Suite 1670
Houston, TX 77024, U.S.A.
Phone: +1-713-654-7111
Fax: +1-713-654-1261

URL h ttp://www.sumitomo-tubulars.com/
http://www.sumitomometals.co.jp/e
No.18522/Jul.2010/SUMITOMO PRODUCTS FOR THE OIL AND GAS INDUSTRIES/Printed in Japan by Sumikin Cosmo Plans Inc. TR/2

◦LEGAL NOTICE
This catalogue is not intended a design manual. Its purpose is for gen-
eral information only.
While this catalogue has been prepared with the greatest care,
Sumitomo makes no warranty or representation, expressed or implied,
of any kind with respect to the information contained herein and shall in
no event assume liability or responsibility for any loss, damage or injury
whatsoever resulting from the use of the information. In all cases the
customer is therefore requested to use the information at its own risk
and responsibility.

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