Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

This SDS adheres to the standards and regulatory requirements of Canada and may not meet the regulatory requirements in
other countries.

SECTION 1. PRODUCT AND COMPANY IDENTIFICATION

Product name : DuPont™ Verimark™ Insect Control

SDS Number : 130000132666

Product Use : Insecticide

Manufacturer : E.I. du Pont Canada Company

P.O. Box 2200, Streetsville
Mississauga, ON
L5M 2H3
Canada

Product Information : 1-800-387-2122

Medical Emergency : 1-800-441-3637 (24 hours)

SECTION 2. HAZARDS IDENTIFICATION

Emergency Overview

This product has no known adverse effect on human health.

This product is toxic to: Aquatic invertebrates This product is highly toxic to: Bees

Potential Health Effects

Carcinogenicity
None of the components present in this material at concentrations equal to or greater than 0.1% are listed by IARC,
NTP, or OSHA, as a carcinogen.

SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS

Component CAS-No. Concentration

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

Cyantraniliprole 736994-63-1 18.66 %

Other Ingredients 81.34 %

SECTION 4. FIRST AID MEASURES

Skin contact : The material is not likely to be hazardous by skin contact, but cleaning the
skin after use is advisable. Consult a physician if necessary.

Eye contact : The material is not likely to be hazardous by eye contact, but flushing the eye
if contact occurs is advisable. Consult a physician if necessary.

Inhalation : No specific intervention is indicated as the compound is not likely to be

hazardous. Consult a physician if necessary.

Ingestion : No specific intervention is indicated as the compound is not likely to be

hazardous. Consult a physician if necessary.

General advice : Have the product container or label with you when calling a poison control
center or doctor, or going for treatment.
For medical emergencies involving this product, call toll free 1-800-441-3637.
See Label for Additional Precautions and Directions for Use.

SECTION 5. FIREFIGHTING MEASURES

Flammable Properties
Flash point : No flash up to boiling point.

Fire and Explosion Hazard : The product is not flammable.

Suitable extinguishing media : Water spray, Foam, Dry chemical, Carbon dioxide (CO2)

Unsuitable extinguishing : High volume water jet, (contamination risk)

media

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

Firefighting Instructions : In the event of fire, wear self-contained breathing apparatus. Use personal
protective equipment.
(on small fires) If area is heavily exposed to fire and if conditions permit, let
fire burn itself out since water may increase the area contaminated. Cool
containers/tanks with water spray.

SECTION 6. ACCIDENTAL RELEASE MEASURES

NOTE: Review FIRE FIGHTING MEASURES and HANDLING (PERSONNEL) sections before proceeding with clean-up.
Use appropriate PERSONAL PROTECTIVE EQUIPMENT during clean-up.

Safeguards (Personnel) : Evacuate personnel, thoroughly ventilate area, use self-contained breathing
apparatus. Use personal protective equipment.

Spill Cleanup : Soak up with sawdust, sand, oil dry or other absorbent material. Dispose of in
an approved container. If liquid has been spilt in large quantities clean up
promptly by scoop or vacuum.

Accidental Release Measures : Prevent material from entering sewers, waterways, or low areas.

SECTION 7. HANDLING AND STORAGE

Handling (Personnel) : Wash hands thoroughly with soap and water after handling and before eating,
drinking, chewing gum, using tobacco, or using the toilet. Remove
clothing/PPE immediately if material gets inside. Wash thoroughly and put on
clean clothing.

Handling (Physical Aspects) : The product is not flammable.

Storage : Store product in original container only in a location inaccessible to children

and pets. Do not contaminate water, other pesticides, fertilizer, food or feed in
storage. Not for use or storage in or around the home. Keep out of the reach
of children.

Storage temperature : > 0 °C (> 32 °F)

SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Engineering controls : Ensure adequate ventilation, especially in confined areas.
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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

Personal protective equipment

Skin and body protection : Applicators and other handlers must wear:
Long sleeved shirt and long pants
Shoes plus socks
Applicators and other handlers of the diluted material must wear: shirt, pants,
socks and shoes.
Personal protective equipment required for early entry:
Coveralls
Shoes plus socks
Chemical resistant gloves made of any waterproof material

Protective measures : Follow manufacturer's instructions for cleaning/maintaining PPE. If no such

instructions for washables exist, use detergent and hot water. Keep and
wash PPE separately from other laundry.

Exposure Guidelines
Exposure Limit Values

Cyantraniliprole
AEL * (DuPont) 3 mg/m3 8 hr. TWA

AEL * (DuPont) 2 mg/m3 12 hr. TWA

* AEL is DuPont's Acceptable Exposure Limit. Where governmentally imposed occupational exposure limits which are
lower than the AEL are in effect, such limits shall take precedence.

SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES

Form : liquid, suspension
Color : white
Odor : odourless
pH : 6-8
Melting point/range : Not applicable
Boiling point/boiling range : 98 °C (208 °F)
Oxidizing Substance : The product is not oxidizing.
Bulk density : 1.0 - 1.2 g/cm3
Water solubility : soluble

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

SECTION 10. STABILITY AND REACTIVITY

Stability : Stable at normal temperatures and storage conditions.

Conditions to avoid : Protect from frost.

SECTION 11. TOXICOLOGICAL INFORMATION

DuPont™ Verimark™ Insect Control
Inhalation 4 h LC50 : > 3.7 mg/l , Rat

Dermal LD50 : > 5,000 mg/kg , Rat

Oral LD50 : > 5,000 mg/kg , Mouse

Skin irritation : No skin irritation, Rabbit

Eye irritation : No eye irritation, Rabbit

Sensitisation : Animal test did not cause sensitization by skin contact., multiple
species

Cyantraniliprole
Repeated dose toxicity :
The following effects occurred at levels of exposure that significantly
exceed those expected under labeled usage conditions.

Oral
Rat
28 - 90 d
Thyroid effects, Organ weight changes, No effect to neurotoxicity.

Dermal
Rat
28 d
No toxicologically significant effects were found.

Oral
Mouse
90 d
No toxicologically significant effects were found.

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

Oral
Dog
90 d
altered blood chemistry, Liver effects, Vascular arteritis

Oral
multiple species
28 d
Immune System, No toxicologically significant effects were found.

Oral
Rat
14 d
No toxicologically significant effects were found.

Oral
Dog
365 d
Liver effects, Gallbladder effects, altered blood chemistry, Vascular
arteritis

Inhalation
Rat
28 d
No toxicologically significant effects were found.

Carcinogenicity : Not classifiable as a human carcinogen.

Animal testing did not show any carcinogenic effects.

Mutagenicity : Tests on bacterial or mammalian cell cultures did not show mutagenic
effects.
Evidence suggests this substance does not cause genetic damage in
animals.

Reproductive toxicity : No toxicity to reproduction

Animal testing showed no reproductive toxicity.

Teratogenicity : Animal testing showed effects on embryo-fetal development at levels

equal to or above those causing maternal toxicity.

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

SECTION 12. ECOLOGICAL INFORMATION

Aquatic Toxicity
DuPont™ Verimark™ Insect Control
48 h EC50 : Daphnia magna (Water flea) 0.0724 mg/l

Cyantraniliprole
96 h LC50 : Oncorhynchus mykiss (rainbow trout) > 12.6 mg/l

96 h LC50 : Lepomis macrochirus (Bluegill sunfish) > 13 mg/l

72 h ErC50 : Pseudokirchneriella subcapitata (green algae) > 13 mg/l

7 d ErC50 : Lemna gibba (duckweed) > 12.1 mg/l

Additional ecological information : Environmental Hazards: Do not apply directly to water. Drift and runoff
may be hazardous to aquatic organisms in water adjacent to treated
areas. Toxic to bees. Do not apply this product if bees are visiting the
treatment area. See product label for additional application
instructions relating to environmental precautions.

SECTION 13. DISPOSAL CONSIDERATIONS

Waste Disposal : Do not contaminate water, food or feed by disposal. Wastes resulting from the
use of this product must be disposed of on site or at an approved waste
disposal facility.

Container disposal: : Container Refilling and Disposal:

Refer to the product label for instructions.
Do not transport if this container is damaged or leaking.
In the event of a major spill, fire or other emergency, call 1-800-441-3637 day
or night.

SECTION 14. TRANSPORT INFORMATION

IATA_C UN number : 3082

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

Proper shipping name : Environmentally hazardous substance, liquid, n.o.s.

(Cyantraniliprole)
Class : 9
Packing group : III
Labelling No. : 9MI
IMDG UN number : 3082
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
LIQUID, N.O.S. (Cyantraniliprole)
Class : 9
Packing group : III
Labelling No. : 9

Marine pollutant : yes (Cyantraniliprole)

Not regulated as a hazardous material by DOT.

Not regulated as a hazardous material by TDG.

SECTION 15. REGULATORY INFORMATION

PCP Registration # : 30892

Remarks : Regulated under the Pest Control Products Act - WHMIS exempt.

SECTION 16. OTHER INFORMATION

MSDS preparation date : 03/30/2016

™
Trademark of E.I. du Pont de Nemours and Company.

Contact person : E.I. DuPont Canada Company, Mississauga, Ontario, L5M 2H3

The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the
date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,

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Material Safety Data Sheet

DuPont™ Verimark™ Insect Control

Version 2.0

Revision Date 03/30/2016 Ref. 130000132666

transportation, disposal and release and is not to be considered a warranty or quality specification. The information
relates only to the specific material designated and may not be valid for such material used in combination with any
other materials or in any process, unless specified in the text.

Significant change from previous version is denoted with a double bar.

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