BILGEWATER FLOCCULANT

Revision: 20 May 2015

SAFETY DATA SHEET

This Safety Data Sheet is provided in compliance with the EC Directive 1907/2006-453/2010

SECTION 1 Identification of the substance/mixture and of the

company/undertaking

1.1 Product identifier

- Product Name: BILGEWATER FLOCCULANT
- Product Part Number: 690669 (25 liter)
1.2 Relevant identified uses of the substance or mixture and uses advised against
- Use of the substance/mixture: Water treatment
1.3 Details of the supplier of the safety data sheet
- Name of Supplier: Wilhelmsen Ships Service AS
- Address of Supplier: Willem Barentszstraat 50, 3165AB Rotterdam, The Netherlands
- Telephone: +31 4877 777 Fax: +31 4877 888
-
- Head office: Wilhelmsen Ships Service AS
- Strandveien 20, N1324 Lysaker
- Norway, Tel: (47) 6349 440 35
-
- Other suppliers SEE SECTION 16!!!
- For quotations contact your local Customer Services
-
- Responsible Person: Product HSE Manager,
- Email: Email: WSS.GLOBAL.SDSINFO@wilhelmsen.com
- Telephone: Tel.: +31 10 4877775
- Responsible Person: Product HSE Manager,
1.4 Emergency telephone number
- ****ONLY TO BE USED IN CASE OF AN INCIDENT****
-
- International 24hrs Emergency NCEC:+ 44 1865 407333
- American Chemistry Council 24hrs +1 703 527 3887
- American 24hrs Emergency CHEMTREC (800) 424 9300
- Greece: Poisoning emergency center, +30 210 7793777
- Norway: Poison information centre, +47 22591300
- Sweden: Poison information centre, +46 08 33 12 31
- China NRCC 24hrs emergency telephone number: +86-0532-8388 9090
- Wilhelmsen Ships Service, Melbourne, AUSTRALIA Emergency 24hrs: +61 3 9630 0998

- The Netherlands: National Poisons Information Centre + 31 30 274 88 88

SECTION 2 Hazards identification

2.1 Classification of the substance or mixture

- Counsil Directive 1999/45/EEC Classification, packing and labelling of dangerous
preparations.

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SECTION 2 Hazards identification (....)
- Refer to current The Dangerous Substances Directive (67/548/EEC)
- Symbols: Xi
- Risk of serious damage to eyes (R41)
-
- Regulations 1272/2008/EEC. Classification, labeling and packing of dangerous
substances and preparations
- Signal Word: Danger
- Symbols: GHS05
- Eye Dam. 1
- Met. Corr. 1
- Causes serious eye damage (H318).
- May be corrosive to metals (H290).
2.2 Label elements

- Signal Word: Danger

-
- Contains:
- Polyaluminiumchloride hydroxide silicate
- Polydiallyldimethyl amoniumchloride
-
- Hazard phrases
Causes serious eye damage (H318).
May be corrosive to metals (H290).
- Precautionary Phrases
Wash thoroughly after handling (P264).
Wear protective gloves/protective clothing/eye protection/face protection (P280).
Avoid breathing dust/fume/gas/mist/vapours/spray (P261).
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
if present and easy to do. Continue rinsing (P305+P351+P338).
Immediately call a POISON CENTER or doctor/physician (P310).
2.3 Other hazards
- Not applicable
- Not a PBT according to REACH Annex XIII
- Appearance: Liquid, viscous, amber
- Odour: Characteristic odour

SECTION 3 Composition/information on ingredients

3.1 Mixtures

- Polydiallyldimethyl
ammoniumchloride
Concentration: 1-5%
CAS Number: 26062-79-3

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SECTION 3 Composition/information on ingredients (....)

EC Number: Not applicable

R/H Phrases: R52/53 - H412
Symbols: Not applicable
Categories: Aquatic Chronic 3
- Polyaluminiumchloride
hydroxy silicate
Concentration: 30-60%
CAS Number: 1327-41-9
EC Number: 215-477-2
R/H Phrases: R41 - H318, H290
Symbols: Xi, GHS05
Categories: Eye Dam. 1, Met. Corr. 1
REACH REG. NO: 01-21195315 63-43

SECTION 4 First aid measures

4.1 Description of first aid measures

- IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing (P305+P351+P338).
- Get immediate medical advice/attention (P315).
-
- IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin
with water/shower (P303+P361+P353).
-
- IF INHALED: If breathing is difficult, remove victim to fresh air and keep at rest in a position
comfortable for breathing (P304+P341).
-
- IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell
(P301+P312).
- Give plenty of water to drink
- Never give anything by mouth to an unconscious person
4.2 Most important symptoms and effects, both acute and delayed
- Can cause damage to the eyes
- Prolonged skin contact will result in defatting of the skin, leading to irritation, and in some
cases, dermatitis
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract
- The ingestion of significant quantities may cause gastro-intestinal disturbances
- The ingestion of significant quantities may cause dizziness
- The ingestion of significant quantities may cause diarrhoea
4.3 Indication of any immediate medical attention and special treatment needed
- Treat symptomatically

SECTION 5 Fire-fighting measures

5.1 Extinguishing media

- Not flammable. In case of fire use extinguishing media appropriate to surrounding
conditions

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SECTION 5 Fire-fighting measures (....)
- Keep container(s) exposed to fire cool, by spraying with water
5.2 Special hazards arising from the substance or mixture
- In case of fire: (P370)
- Hydrogen chloride may be formed
5.3 Advice for firefighters
- In the event of an adjacent fire, cool containers with water spray
- Wear Positive-Pressure Breathing Apparatus

SECTION 6 Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures

- Wear protective clothing as per section 8
6.2 Environmental Precautions
- Do not flush spilt material into any public water system
- Do not allow to enter public sewers and watercourses
6.3 Methods and material for containment and cleaning up
- Absorb spillage in inert material and shovel up
- Absorb spillage in inert material and shovel up
- Ventilate the area and wash spill site after material pick-up is complete
6.4 Reference to other sections
- See Section 13

SECTION 7 Handling and storage

7.1 Precautions for safe handling

- Eyewash bottles should be available
- See Section 8
7.2 Conditions for safe storage, including any incompatibilities
- Store between 0 and 20 °C
7.3 Specific end use(s)
- Contact supplier for further information

SECTION 8 Exposure controls/personal protection

8.1 Control parameters

- No exposure limits have been set for this substance
8.2 Exposure controls
- No special ventilation is required unless the product is used in a spray form
8.3 Occupational exposure controls

- Wear suitable protective clothing, including eye/face protection and gloves (plastic or rubber
are recommended)
- No respiratory protection is required unless subject to contact with substance mist

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SECTION 9 Physical and chemical properties

9.1 Information on basic physical and chemical properties

- Odour: Odourless
- Appearance: Liquid, colourless to yellow, soluble in water
- pH 1-2 at 100 % concentration
- Boiling point 100-120 °C to 760 °C
- Vapour pressure - not known
- Vapour density - not applicable
- Freezing point - 25 °C to 760 °C
- Completely soluble in water
- Specific gravity (water=1) 1.30
- Log Pow <<3
9.2 Other information
- No information available

SECTION 10 Stability and reactivity

10.1 Reactivity
- This article is considered stable under normal conditions
10.2 Chemical stability
- Considered stable under normal conditions
10.3 Possibility of hazardous reactions
- Not applicable
10.4 Conditions to avoid
- Avoid overheating
10.5 Incompatible materials
- Incompatible with acids and alkalis
- Avoid contact with metals
10.6 Hazardous Decomposition Products
- Decomposition products may include nitrogen and carbon oxides

SECTION 11 Toxicological information

11.1 Information on toxicological effects

- LD50 (oral,rat) Acute: (Aluminiumchloride)>2000 mg/kg
11.2 Contact with eyes
- Causes redness and irritation
11.3 Contact with skin
- In cases of severe exposure, redness and irritation may develop
11.4 Ingestion
- The ingestion of significant quantities may cause gastro-intestinal disturbances
11.5 Inhalation
- Inhalation is unlikely to occur
- Vapours or aerosols may cause irritation of eyes, nose and respiratory tract

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SECTION 12 Ecological information

12.1 Toxicity
- LC50 (fish) >1000 mg/l (96 hr)
- EC50 (daphnia) 98 mg/l (48 hr)
- This product does not contain ingredients which are classified in the EU as dangerous for the
environment.
12.2 Persistence and degradability
- Its main ingredients will either dissolve rapidly and dissociate in water or are
readily/inherently biodegradable.
12.3 Bioaccumulation Potential
- Bioaccumulation of the components in this product is insignificant.
12.4 Mobility in soil
- Completely soluble in water
12.5 Results of PBT and vPvB assessment
12.6 Other Adverse Effects
- No environmental problems are expected when the product is used / handled
correctly.
- Presents little or no hazard to the aquatic environment

SECTION 13 Disposal considerations

13.1 Waste treatment methods

- Do not discharge into drains or the environment, dispose to an authorised waste
collection point
- Disposal should be in accordance with local, state or national legislation
13.2 Classification
- EU Waste class: 06.03.11 / 06.03.13

SECTION 14 Transport information

14.1 UN
- UN No.: UN3264
- Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(polyaluminiumchloridehydroxysilicate solution)
- Hazard Class: 8
- Packing Group: III
14.2 Environmental hazards
- Not Classified
14.3 Special precautions for user
- No special precautions are required for this product
14.4 Transport in bulk according to Annex II of MARPOL 73/78 and the IBC code

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SECTION 14 Transport information (....)
- Not applicable
14.5 Road/Rail (ADR/RID)
- ADR UN No.: UN3264
- Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(polyaluminiumchloridehydroxysilicate solution)
- ADR Hazard Class: 8
- ADR Packing Group: III
14.6 Sea (IMDG)
- IMDG UN No.: UN3264
- Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(polyaluminiumchloridehydroxysilicate solution)
- IMDG Hazard Class: 8
- IMDG Pack Group.: III
- IMDG EmS: F-A, S-B
14.7 Air (ICAO/IATA)
- ICAO UN No.: UN3264
- Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(polyaluminiumchloridehydroxysilicate solution)
- ICAO Hazard Class: 8
- ICAO Packing Group: III
14.8 DOT / CFR (US Department of Transportation)
- Identification Number: UN3264
- DOT Proper Shipping Name: Corrosive liquid, acidic, inorganic, n.o.s.
(polyaluminiumchloridehydroxysilicate solution)
- DOT Labels: 8
- Product RQ (lbs): Not applicable

SECTION 15 Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

- This Safety Data Sheet is provided in compliance with The Dangerous Substances
Directive (67/548/EEC)
- This Safety Data Sheet has been prepared in accordance with article 31 and annex II in
REACH and Directive 453/2010/EU.
15.2 Chemical Safety Assessment
- None

SECTION 16 Other information

Text not given with phrase codes where they are used elsewhere in this safety data sheet:- H290:
May be corrosive to metals. H318: Causes serious eye damage. H412: Harmful to aquatic life with
long lasting effects. R41: Risk of serious damage to eyes. R52/53: Harmful to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
The information provided about the product on this Safety Data Sheet has been compiled from
knowledge of the individual constituents

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SECTION 16 Other information (....)

The data given here only applies when product used for proper application(s). The product is not sold as
suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use
for other application(s) without seeking advice from manufacturer
The data given here is based on current knowledge and experience. This Safety Data Sheet
describes the product in terms of safety requirements and does not signify any warranty with regard
to the product's properties
The most up-to-date version of this MSDS can be found on www.wilhelmsen.com/shipsservice

OTHER CONTACT INFORMATION MAJOR CHEMICAL OFFICES

Wilhelmsen Ships Service Level 17, 636 St Kilda Road Melbourne Vic 3004 AUSTRALIA
Tel: +61 3 9630 0900 Emergency 24hrs: +61 3 9630 0998
Wilhelmsen Ships Service INC 210 Edgewater Street US-10305 Staten Island New York United States
Telephone daytime: (+1) 718 815 1310 Fax: (+1) 718 233 3268
Wilhelmsen Ships Service INC 2200 W. Pacific Coast Highway US-90810 Long Beach California, United
States Tel (+1) 562 624 8888 Fax (+1) 562 624 1011
Wilhelmsen Ships Service INC 701 Ashland Ave. Ashland Center Two, Bay 12 US- 19032 Folcroft
Pennsylvania United States Tel (+1) 610 586 7801 Fax (+1) 215 701 0646
Wilhelmsen Ships Service INC. 9400 New Century Drive US-77507 Pasadena Texas United States
Telephone daytime: (+1) 281 867 2000 Fax: (+1) 281 867 2800
Wilhelmsen Ships Service Ltd. Unit 3A NewtonsCourt Crossways DA2 6QL Dartford, Kent United
Kingdom Tel (+44) 1322 282 412 Fax (+44) 1322 284 774
Wilhelmsen Ships Service Ltda Rua Bispo Lacerda nos.61/67 Del Catilho BR 21051120 Rio de Janeiro
Brazil Tel (+55) 21 25 82 8000 Fax (+55) 21 25 82 8001
Wilhelmsen Ships Service (S) Pte Ltd 186 Pandan Loop Singapore 128376 Tel (+65) 6395 4545
Wilhelmsen Ships Service Co., Ltd 12-31 Torihama-cho Kanazawa-ku Yokohama-shi JP-236 0002,
Japan Tel (+81) 45 775 0012 Fax (+81) 45 775 0070
Wilhelmsen Ships Service Hellas SA 100, D. Moutsopoulou & Serifou str GR-185 41 Piraeus Greece
Tel (+ 30) 210 4239100 Fax (+ 30) 210 4212480
Wilhelmsen Ships Service AS U.A.E . Fl 24 Executive Heights, Tecom C Sheikh Zayed Road (East)
Dubai United Arab Emirates Tel (+971) 4 382 3888
Wilhelmsen Ships Service AS, Willem Barentszstraat 50 3165 AB Rotterdam-Albrandswaard,
the Netherlands. Tel (+31) 10 4877 777

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