Alkyd resin paint 2000017813-67 2017/8/14

Safety Data Sheet

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1. Product Identifier
Substance or Mixture name ： Alkyd resin paint
EC No. ：
REACH No. ：
CAS No. ：
1.2. Relevant identified uses of the substance or mixture and uses advised against
Sector of uses [SU] ： Industrial uses
Use of the substance/mixture ： Paint
Uses advised against ： Do not use for private purposes (household).
1.3 Details of the Supplier of the Safety Data Sheet
Supplier ： iBou Inc.
Address ： Nakao, Nago city, Okinawa pref., Japan
P.O.Box ： 905-1153
Telephone ： 1234-5678
Telefax ： 1234-6789
E-Mail ： de@ibou.com
1.4 Emergency telephone number
Emergency telephone number ： 1234-9876
Remark ： Only available during office hours.

SECTION 2: Hazards identification

2.1. Classification of the substance or mixture： ：

Flammable liquids:Flam. Liq. 2
Acute toxicity oral:Classification not possible
Acute toxicity Dermal:Acute Tox. 4
Acute toxicity inhalation:Classification not possible
Skin corrosion/irritation:Skin Corr. 2
Serious eye damage/eye irritation:Eye Irrit. 1
Respiratory sensitization:Classification not possible
Skin sensitization:Classification not possible
Germ cell mutagenicity:Muta. 1B
Carcinogenicity:Carc. 1B
Reproductive toxicityv:Repr. 1A
Specific target organ toxicity - Single exposure:Not classified
Specific target organ toxicity -Repeated exposure:STOT RE 2
Aspiration hazard:Not classified
Hazardous to the aquatic environment-Acute hazard:Not classified
Chronic aquatic hazard:Not classified
Hazardous to the ozone layer:Classification not possible
Reproductive toxicity (Effects on or via lactation):Classification not possible

2.2. Label elements：

：

Hazard pictograms：

Signal word： Danger

Hazard statements：
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H225 ·Highly flammable liquid and vapour
H312 ·Harmful in contact with skin
H315 ·Causes skin irritation
H318 ·Causes serious eye damage
H340 ·May cause genetic defects
H350 ·May cause cancer
H360 ·May damage fertility or th unborn child
H373 ·May cause damage to organs through prolonged or repeated exposure

Precautionary statement：
【Prevention】
P201 ·Obtain special　instructions before use
P202 ·Do not handle until all safety precautions have been read and understood
P210 ·Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking.
P233 ·Keep container tightly closed.
P240 ·Ground/bond container and receiving equipment.
P241 ·Use explosion-proof electrical/ventilating/lighting equipment.
P242 ·Use only non-sparking tools.
P243 ·Take precautionary measures against static discharge.
P260 ·Do not breathe dust/fume/gas/mist/vapours/spray.
P264 ·Wash hands thoroughly after handling.
P280 ·Wear protective gloves/protective clothing/eye protection/face protection.

【Response】
P302+P352 ·IF ON SKIN: Wash with plenty of water/….
P303+P361+P353 ·IF ON SKIN(or hair): Take off immedately all contaminated clothing. Rinse skin with water/shoewer.
P305+P351+P33 ·IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
8 Continue rinsing.
·IF exposed or concerned: Get medical advice/attention.
P308+P313 ·Immediately call a POISON CENTER/doctor/….
P310 ·Call a POISON CENTER/doctor/…/ if you feel unwell.
P312 ·Get medical advice/attention if you feel unwell.
P314 ·Specific treatment (see SDS)
P321 ·If skin irritation occurs, Get medical advice/attention.
P332+P313 ·Take off contaminated clothing and wash it before reuse.
P362+P364 ·In case of fire: Use appropriate extinguishing media to extinguish.
P370+P378

【Disposal】
P501 ·Dispose of contents/container to an authorized garbage disposal place.

【Storage】
P403+P235 ·Store in a well-ventilated place. Keep cool.
P405 ·Store locked up.

Supplemental Hazard information (EU) :

EUH066 EUH201
39.80% of the mixture consists of components of unknown toxicity-oral 26.20% of the mixture consists of
components of unknown toxicity-dermal 39.80% of the mixture consists of components of unknown toxicity-
inhalation

SECTION 3: Composition / information on ingredients ： Mixtures

Substance REACH Reg. No. %（weight) Type of No No. Hazard class,category, H code
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Ethyl bromoacetate Not available 0～5% CAS 105-36-2
ethylbenzene 123-57 5～10% CAS 100-41-4 Asp. Tox. 1,Flam. Liq. 2,STOT Rep. 2,Acute Tox. 4 H304,H225,H373,H332

mineral spirit Not available 0～5% CAS 8052-41-3 Asp. Tox. 1,Carc. 1B,Muta. 1B,STOT Rep. 1 H304,H350,H340,H372

melamine Not available 35～40% CAS 108-78-1

alkyd resin Not available 10～15% CAS 63148-69-6
2-Butanone Not available 0～5% CAS 78-93-3 Flam. Liq. 2,Eye Irrit. 2A,STOT Single 3 H225,H336

xylene Not available 5～10% CAS 1330-20-7 Flam. Liq. 3,Skin Irrit. 2,Acute Tox. 4,Acute Tox. H226,H315,H312,H332

titanium dioxide Not available 5～10% CAS 13463-67-7

lead sulphate Not available 0～5% CAS 7446-14-2
2-methylpropan-1-ol Not available 0～5% CAS 78-83-1 Eye Dam. 1,Flam. Liq. 3,Skin Irrit. 2,STOT Single H318,H226,H315,H335

lead chromate Not available 10～15% CAS 7758-97-6 Aquatic Acute 1,Aquatic Chronic 1,Carc. 1B,Repr. 1 H400,H410,H350,H360Df,H373

Additional information : Full text of H-statements to be referred in SDS Section 16

SECTION 4: First aid measures

4.1. Description of first aid measures
General information :
If unconscious place in recovery position and seek medical advice.
Following inhalation：
：
In case of inhaling spray mist, consult a doctor immediately and show him packing or label.
Following skin contact
Wash immediately with : Water and soap Water and soap
In the case of contact with hot melt, treat skin with :
Water
Do not wash with : Cleaning agent, acidic
After eye contact：：
Rinse immediately carefully and thoroughly with eye-bath or water.
After ingestion :
Induce vomiting when the affected person is not unconscious.
If swallowed immediately drink :
Water
Self-protection of the first aider :
Not applicable
4.2. Most important symptoms and effects, both acute and delayed
Symptoms
The following symptoms may occur :
Nausea
Effects : Drowsiness
4.3. Indication of any immediate medical attention and special treatment needed
Notes for the doctor :
Treat symptomatically.
Special treatment :
No data available

SECTION 5: Firefighting measures

5.1. Extinguishing media
Suitable extinguishing media ：
ABC-powder Carbon dioxide (CO2) Sand Dry sand
Unsuitable extinguishing media：
Full water jet
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products :
Carbon dioxide (CO2)

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5.3. Advice for firefighters
Special protective equipment for firefighters:
Protective clothing. Rubber boots rubber gloves.
5.4. Additional information:
Move undamaged containers from immediate hazard area if it can be done safely.

SECTION 6: Accidental release measures

6.1. Personal precautions,protective equipment and emergency procedures
Personal precautions :
Use personal protection equipment.
Protective equipment :
Wear breathing apparatus if exposed to vapours/dusts/aerosols.
Emergency procedures :
Provide adequate ventilation.

6.2. Enviromental precautions :

Do not allow to enter into surface water or drains.

6.3. Methods and materials for containment and cleaning up

For containment
Suitable material for taking up:
Earth Sawdust
For cleaning up
Suitable material for diluting or neutralising :
White spirit
6.4. Reference to other sections :
Safe handling: see section 7 Disposal: see section 13 Personal protection equipment: see section 8

SECTION 7: Handling and storage

7.1. Precautions for safe handling
Protective measure
Advice on safe handling
Avoid : Generation/formation of mist
Handle under (gas) : Not applicable
Handle under (liquid) : Not applicable
Keep away from : Acid
Remark : Take precautionary measures against static discharges.
Measures to prevent aerosol and dust generation
During filling,metering and sampling should be used if possible :
Devices with local exhaust
Use the following local exhaust ventilation type :
Receptor hood for fumes/vapours
Environmental precaution :
Shafts and sewers must be protected from entry of the product.
Special requirements or handling rules :
Floors, walls and other surfaces in the hazard area must be cleaned regularly.
Advice on general occupational hygiene :
Wash hands before breaks and after work.

7.2. Conditions for safe storage, including any incompatibilities

Packaging materials
Suitable container/equipment material : Zinc
　Unsuitable container/equipment material : Glass

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Hints on joint storage
Combustible substances of acute toxicity, category 3 / hazardous substances that are toxic or
Storage class :
produce chronic effects (liquid)
Materials to avoid : Oxidising agent
Further information on storage conditions : Keep only in the original container in a cool, well-ventilated place.

SECTION 8: Exposure controls/personal protection

8.1. Control parameters

Occupational exposure limit values
Ingredient CAS NO. EC No Country Limit valu - 8 hours Limit value-Short term
ppm mg/m3 ppm mg/m3
lead chromate 7758-97-6 231-846-0 GB 0.05
xylene 1330-20-7 215-535-7 GB 50 220 100 441
ethylbenzene 100-41-4 202-849-4 GB 100 441 125 552
2-Butanone 78-93-3 201-159-0 GB 200 600 300 899
2-methylpropan-1-ol 78-83-1 201-148-0 GB 50 154 75 231
titanium dioxide 13463-67-7 236-675-5 GB 4

Biological limit values

Ingredient CAS NO. EC No Country Unit Limit valu Parameter
lead chromate 7758-97-6 231-846-0 GB µmol/mol creatinine
10 chromium (VI) compounds
xylene 1330-20-7 215-535-7 GB mmol/mol creatinine
650 methyl hippuric acid

8.2. Exposure controls

Appropriate engineering controls
Initial Remarks : See section 7. No additional measures necessary.
Substance/mixture related mesures to privent exposure during identified users :
Fresh air (open windows and doors) is necessary.
Technical mesures to provent exposure :
Reduce exposure to fume by keeping operating temperatures as low as possible taking into account occupational
exposure limits and safe handling temperatures (see Section 7). Where practicable handle within an enclosed
process. Alternatively local exhaust ventilation should be considered.

Personal protection equipment

Eye/face protection
Suitable eye protection : goggles
Remark: Not applicable
Skin protection
Hand protection
Suitable gloves type : Half-gloves
Suitable material : Butyl caoutchouc (butyl rubber)
Required properties : liquid-tight
The quality of the protective gloves resistant to chemicals must be chosen as a function of the
Remark :
specific working place concentration and quantity of hazardous substances.
Body protection
Suitable protective clothing : Boots Protective apron
Required properties : flame-resistant
Recommended material : heat-resistant synthetic fibres
Respiratory protection
Respiratory protection necessary at :
insufficient ventilation
According to experience this refers to the following tasks :
Filling and transfer
Suitable respiratory protection apparatus :
Combination filtering device (EN 14387)

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Remarks :
Usually no personal respirative protection necessary.
Environmental exposure controls
Technical measures to prevent exposure
Use the following filter types for cleaning waste gases :
Fabric filter
Use the following recovery and/or abatement technique for cleaning waste gases :
Adsorption
Use the follwoing chemical treatment methods for waste water :
Sludge treatment e.g. thermal sludge reduction

SECTION 9: Physical and chemical properties

Physical state liquid

Color opaque
Odour pungent
PH
Melting point/freezing point
Initial boiling point and boiling range 136.20℃～144.40℃
Flash point 19.5℃
Evaporation rate
Flammability
Upper/lower flammability or explosive
limits
Vapour pressure
Vapour density
Density
Solubility(ies) Insoluble
Partition coefficient: n-octanol/water
Auto-ignition temperature 200℃
Decomposition temperature
Viscosity 20.5000m㎡/s
Explosive properties
Oxidising properties

SECTION 10: Stability and reactivity

10.1. Reactivity :
Thermally unstable.
10.2. Chemical stability :
The mixture is chemically stable under recommended conditions of storage, use and temperature.
10.3. Possibility of hazardius reactions
In case of melting :
Ignition hazard
In case of vaporization :
Danger of bursting container.
In case of freezing :
No data available
10.4. Condition to avoid
In dry state :
Not applicable
In an isolated state :
No data available
In fine dispersion/spraying/misting :
Danger of bursting container.

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In case of warming :
Danger of bursting container.
In case of light influence :
Not applicable
In case of impact or pressure influence :
Danger of bursting container.
In case of air intake :
Not applicable
In case of exceeding the storage time :
No data available
In case of exceeding the storage temperature :
Danger of bursting container.
10.5. Incompatible materials
Materials to avoid
Oxidising agent
10.6. Hazardous decomposition products:
Thermal decomposition can lead to the escape of irritating gases and vapours.
10.7. Additional information
No data available

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Dermal
xylene(Acute Tox. 4) /ethylbenzene(Acute Tox. 4)
Skin corrosion/irritation
2-methylpropan-1-ol(Skin Corr. 2) /xylene(Skin Corr. 2)
Serious eye damage/eye irritation
2-Butanone(Eye Irrit. 2) /2-methylpropan-1-ol(Eye Irrit. 1)
Germ cell mutagenicity
mineral spirit(Muta. 1B)
Carcinogenicity
lead chromate(Carc. 1B) /mineral spirit(Carc. 1B)
Reproductive toxicityv
lead chromate(Repr. 1A)
Specific target organ toxicity - Single exposure
2-Butanone(STOT SE3(Respir.-Irrit.)) /2-methylpropan-1-ol(STOT SE3(Respir.-Irrit.))
Specific target organ toxicity -Repeated exposure
lead chromate(STOT RE 2) /mineral spirit(STOT RE 1) /ethylbenzene(STOT RE 2)
Aspiration hazard
mineral spirit(Asp. Tox. 1) /ethylbenzene(Asp. Tox. 1)

11.2. Symptoms related to the physical, chemical and toxicological characteristics

In case of ingestion :
No data available
In case of skin contact :
Has degreasing effect on the skin.
In case of inhalation :
Inhalation causes narcotic effects/intoxication.
11.3. Additional information :
Protective clothing. Rubber boots rubber gloves.

SECTION 12: Ecological information

Hazardous to the aquatic environment-Acute hazard：
：
lead chromate(Aquatic Acute 1)

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Hazardous to the aquatic environment-Chronic hazard：
：
lead chromate(Aquatic Chronic 1)
Hazardous to the ozone layer ：

Additional ecotoxicological information:

There are no data available on the mixture itself.

SECTION 13: Disposal considerations

13.1. Waste treatment methods

Product/packaging disposal
Properties of waste which render it hazardous :
Flammable
　Waste treatment option
Appropriate disposal/Product :
Dispose of waste according to applicable legislation.
Appropriate disposal/Package :
Contaminated packages must be completely emptied and can be re-used following proper cleaning.
　Remarks :
Consult the appropriate local waste disposal expert about waste disposal.

SECTION 14: Transport information

14.1 UN number
Land transport(ADR/RID) 1263
Inland waterway transport(ADN) 1263
Sea transportation(IMDG) 1263
Air transportationICAO-TI/IATA-DGR 1263
14.2. UN proper shipping name
Land transport(ADR/RID) Paint
Inland waterway transport(ADN) Paint
Sea transportation(IMDG) Paint
Air transportationICAO-TI/IATA-DGR Paint
14.3. Transport hazard class(es)
Land transport(ADR/RID) 3
Inland waterway transport(ADN) 3
Sea transportation(IMDG) 3
Air transportationICAO-TI/IATA-DGR 3
14.4. Packing group
Land transport(ADR/RID) 2
Inland waterway transport(ADN) 2
Sea transportation(IMDG) 2
Air transportationICAO-TI/IATA-DGR 2
14.5. Environmental hazards
Land transport(ADR/RID) ENVIRONMENTALLY HAZARDOUS
Inland waterway transport(ADN) ENVIRONMENTALLY HAZARDOUS
Sea transportation(IMDG) ENVIRONMENTALLY HAZARDOUS
Air transportationICAO-TI/IATA-DGR ENVIRONMENTALLY HAZARDOUS

Not applicable
14.6. Transport in bulk according to MARPOL73/78 and the IBC Code

SECTION 15: Regulatory information

15.1. Safety, health and environmental regulations/legislation specific for the substance or mixture
EU regulation

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Authrisations and/or restrictions on use
Lead chromate,CAS 7758-97-6;
Authorisations :
by REACH TITLE VII
ethylbenzene,;
Volatile esters of bromoacetic acids: Ethyl bromoacetate,;
xylene,;
Lead sulphates: (a) PbSO4,;
lead chromate,;
Restrictions on use :
2-methylpropan-1-ol,;
2-Butanone,;
mineral spirit,;
by REACH TITLE VIII

Restriction of occupation : Observe employment restrictions for women of child-bearing age.

Other regulations (EU)
Directive 2004/42/CE on the limitation of emissions of volatile organic compounds
VOC product category : Paints and varnishes
VOC subcategory of the product : Interior/exterior trim and cladding paints for wood, metal or plastic
VOC content(g/L), ready to use condition :
VOC content(g/L), delivery state :
VOC-value(in g/L) :
Method : ISO 11890-2
Remak : This chemical is a VOC according to 2004/42/EC.
Directive 2012/18/EU on the control of major-accident hazards involving dangerous substances [Seveso-III-Directive]
P5b orP5c FLAMMABLE LIQUIDS
Classification according to Annex I, Part I :

Entry in Annex I, Part 2

Number : Not available
Named dangerous substances : Not available
At temperatures above the boiling point, this product is assigned to the risk category
Remark :
P5a.
Lead chromate,CAS No 7758-97-6；
Candidate of SVHC

15.2. Chemical Safety Assessment :

Chemical safety assessments for substances in this mixture were not carried out.

SECTION 16: Other information

Relevant H-phrases in Section 3 and EUH-phrases in Section 2 (Number and full text) :
EUH066 Repeated exposure may cause skin dryness or cracking.
EUH201 Contains lead. Should not be used on surfaces liable to be chewed or sucked by children.

Data sources:
The above information describes exclusively the safety requirements of the product and is based on our present-day knowledge. The
information is intended to give you advice about the safe handling of the product named in this safety data sheet, for storage,
processing, transport and disposal. The information cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily valid for the new made-up material.

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