Construir un diagrama T vs xi e yi de una mezcla ideal

yiP = xiPisat
A B C P/kPa
para 1-clorobutano 13.9600 2826.26 224.10 90.00
clorobenceno 13.9926 3295.12 217.55 90.00
Ley de Raaoult y Dalton
y1P = x1P1sat
y2P = x2P2sat
así
x1 = y1P/P1sat
x2 = y2P/P2sat
De esta forma
p = x1P1sat + x2P2sat (y1+y2)P = x1P1sat + x2P2sat

f(t) = x1*P1sat + (1-x1)*P2sat - presión total = 0

x1 t P1sat P2sat f(t) p total

0.1 60 55.25 8.33 -76.9736 13.0263515
0.1 80 106.29 18.51 -62.7103 27.2897074
0.1 100 188.61 37.18 -37.6728 52.327156
0.1 120 313.10 68.77 3.2003 93.2003077
0.1 119 305.69 66.80 0.6903 90.6902884
0.1 118 298.42 64.88 -1.7659 88.2341011
0.1 118.7 303.50 66.22 -0.0522 89.9478171
0.1 118.8 304.23 66.41 0.1948 90.1947706
0.1 118.75 303.86 66.32 0.0712 90.0712268
0.1 118.72 303.64 66.26 -0.0028 89.9971649
0.1 118.7211 303.65 66.26 -0.0001 89.9998796

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.2 60 55.25 8.33 -72.2820
0.2 80 106.29 18.51 -53.9327
0.2 100 188.61 37.18 -22.5306
0.2 110 244.86 51.04 -0.1928
0.2 110.1 245.48 51.20 0.0569
0.2 110.05 245.17 51.12 -0.0680
0.2 110.08 245.35 51.17 0.0069
0.2 110.07 245.29 51.15 -0.0181
0.2 110.075 245.32 51.16 -0.0056
0.2 110.077 245.34 51.17 -0.0006
0.2 110.077 245.34 51.17 -0.0006

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

 0.3 60 55.25 8.33 -67.5904
0.3 80 106.29 18.51 -45.1552
0.3 100 188.61 37.18 -7.3884
0.3 102 198.97 39.68 -2.5332
0.3 103 204.31 40.98 -0.0225
0.3 104 209.76 42.31 2.5449
0.3 103.1 204.85 41.11 0.2317
0.3 103.01 204.37 40.99 0.0029
0.3 103.005 204.34 40.98 -0.0098
0.3 103.009 204.36 40.99 0.0004
0.3 103.0088 204.36 40.99 -0.0001

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.4 60 55.25 8.33 -62.8988
0.4 80 106.29 18.51 -36.3776
0.4 100 188.61 37.18 7.7539
0.4 95 164.52 31.50 -5.2939
0.4 97 173.85 33.68 -0.2513
0.4 98 178.67 34.82 2.3573
0.4 97.05 174.09 33.74 -0.1223
0.4 97.08 174.23 33.77 -0.0448
0.4 97.09 174.28 33.78 -0.0189
0.4 97.1 174.33 33.79 0.0069
0.4 97.097 174.31 33.79 -0.0008

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.5 60 55.25 8.33 -58.2072
0.5 80 106.29 18.51 -27.6001
0.5 97 173.85 33.68 13.7656
0.5 93 155.58 29.43 2.5053
0.5 92 151.26 28.44 -0.1534
0.5 92.5 153.41 28.93 1.1683
0.5 92.25 152.33 28.68 0.5056
0.5 92.125 151.79 28.56 0.1756
0.5 92.06 151.51 28.50 0.0044
0.5 92.056 151.49 28.49 -0.0061
0.5 92.058 151.50 28.49 -0.0008

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.6 60 55.25 8.33 -53.5156
0.6 80 106.29 18.51 -18.8225
0.6 90 142.88 26.54 6.3452
0.6 87 131.01 23.88 -1.8431
0.6 87.5 132.93 24.31 -0.5180
0.6 87.75 133.90 24.52 0.1505
0.6 87.65 133.51 24.43 -0.1174
0.6 87.68 133.63 24.46 -0.0371
0.6 87.7 133.71 24.48 0.0165
 0.6 87.695 133.69 24.47 0.0031
0.6 87.6938 133.68 24.47 -0.0001

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.7 60 55.25 8.33 -48.8240
0.7 80 106.29 18.51 -10.0450
0.7 85 123.53 22.23 3.1402
0.7 83 116.39 20.68 -2.3249
0.7 84 119.92 21.44 0.3751
0.7 83.75 119.03 21.25 -0.3059
0.7 83.87 119.45 21.34 0.0205
0.7 83.86 119.42 21.33 -0.0068
0.7 83.865 119.44 21.34 0.0069
0.7 83.862 119.43 21.33 -0.0013
0.7 83.8621 119.43 21.33 -0.0010

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.8 60 55.25 8.33 -44.1324
0.8 80 106.29 18.51 -1.2674
0.8 81 109.58 19.21 1.5025
0.8 80.5 107.92 18.86 0.1091
0.8 80.4 107.59 18.79 -0.1675
0.8 80.46 107.79 18.83 -0.0016
0.8 80.465 107.81 18.83 0.0122
0.8 80.462 107.80 18.83 0.0039
0.8 80.461 107.79 18.83 0.0012
0.8 80.46 107.79 18.83 -0.0016
0.8 80.4609 107.79 18.83 0.0009

x1 t P1sat P2sat f(t) y1 = x1P1sat/P

0.9 60 55.25 8.33 -39.4408
0.9 78 99.95 17.18 1.6681
0.9 77 96.89 16.54 -1.1475
0.9 77.5 98.41 16.85 0.2517
0.9 77.4 98.10 16.79 -0.0296
0.9 77.41 98.13 16.80 -0.0015
0.9 77.415 98.15 16.80 0.0126
0.9 77.41 98.13 16.80 -0.0015
0.9 77.411 98.14 16.80 0.0013
0.9 77.41 98.13 16.80 -0.0015
0.9 77.41 98.13 16.80 -0.0015

P total (kPa) t x 1-clorobutano y 1-clorobutano

90.00 129.57 0 0
90.00 118.72 0.1000 0.3374
90.00 110.08 0.2000 0.5452
90.00 103.01 0.3000 0.6812
90.00 97.10 0.4000 0.7747
90.00 92.06 0.5000 0.8417
90.00 87.69 0.6000 0.8912
90.00 83.86 0.7000 0.9289
90.00 80.46 0.8000 0.9582
90.00 77.41 0.9000 0.9813
90.00 74.65 1.0000 1.0000
 Problema resuelto Dr Juan Carlos Vázquez Lira Feb 2017

exp(c5-d5/(100+e5))
t sat = exp(A-B/(t+C))
P

74.65 °C clorobutano P1 sat

129.57 °C clorobenceno P2 sat

y1+y2)P = x1P1sat + x2P2sat

0.33738865 y1 = x1P1sat/P

y1 = x1P1sat/P

0.54518943

y1 = x1P1sat/P
 0.68119637

y1 = x1P1sat/P

0.77472389

y1 = x1P1sat/P

0.84168629

y1 = x1P1sat/P
 0.89123098

y1 = x1P1sat/P

Mezcla de clobenceno y 1-clorobutano

Diagrama T vs xi e yi p=cte
140.00

120.00
0.92887349T

(°C)
y1 = x1P1sat/P 100.00

80.00

60.00

40.00

20.00
0.95816115

y1 = x1P1sat/P 0.00
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1

x 1-clorobutano

x clorobutano y clorobutano

0.98132069
8 0.9 1