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    NC Water Analysis PDF

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    Yeisson Mora
    This document describes the configurations, consumables, and performance of the FlashSmart Analyzer for analyzing saline and acid samples. It can be configured with single or double reactors and uses a manual injector or autosampler for sample introduction. Comparisons show that double reactors and autosampling provide lower detection limits for nitrogen and carbon content compared to single reactors and manual injection. Blank evaluations and sample runs demonstrate the analyzer's ability to accurately measure nitrogen and carbon levels down to parts-per-million.

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    NC Water Analysis PDF

    Uploaded by

    Yeisson Mora
    63 views10 pages
    This document describes the configurations, consumables, and performance of the FlashSmart Analyzer for analyzing saline and acid samples. It can be configured with single or double reactors and uses a manual injector or autosampler for sample introduction. Comparisons show that double reactors and autosampling provide lower detection limits for nitrogen and carbon content compared to single reactors and manual injection. Blank evaluations and sample runs demonstrate the analyzer's ability to accurately measure nitrogen and carbon levels down to parts-per-million.

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    This document describes the configurations, consumables, and performance of the FlashSmart Analyzer for analyzing saline and acid samples. It can be configured with single or double reactors and uses a manual injector or autosampler for sample introduction. Comparisons show that double reactors and autosampling provide lower detection limits for nitrogen and carbon content compared to single reactors and manual injection. Blank evaluations and sample runs demonstrate the analyzer's ability to accurately measure nitrogen and carbon levels down to parts-per-million.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    63 views10 pages

    NC Water Analysis PDF

    Uploaded by

    Yeisson Mora
    This document describes the configurations, consumables, and performance of the FlashSmart Analyzer for analyzing saline and acid samples. It can be configured with single or double reactors and uses a manual injector or autosampler for sample introduction. Comparisons show that double reactors and autosampling provide lower detection limits for nitrogen and carbon content compared to single reactors and manual injection. Blank evaluations and sample runs demonstrate the analyzer's ability to accurately measure nitrogen and carbon levels down to parts-per-million.

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    You are on page 1of 10

    FlashSmart Analyzer for

    saline and acid samples analysis

    Dr. Liliana Krotz, OEA Application Manager,


    Thermo Fisher Scientific, Milan, Italy
    Configurations

    Single reactor Double reactors

    Manual Injector AI / AS 1310 Liquid Autosampler

    2
    Consumables
    • For Single reactor
    Reactor: Ceramic tube (18 mm diameter, p/n 468 020 10)
    Catalyst: Copper Oxide (p/n 338 217 10)
    High Quality Copper (p/n 338 353 12)

    • For double reactors


    Combustion Reactor: Ceramic tube (18 mm diameter, p/n 468 020 10)
    Catalyst: Oxidation catalyst (mix CuO + Pt on allumina, p/n 338 400 00)
    Reduction reactor: quartz tube (18 mm diameter, p/n 468 200 70)
    High Quality Copper (p/n 338 353 12)

    • For both configurations


    Nickel sheet (p/n 252 051 10, set of 2, 0.15x130x130 mm)
    Big filter (p/n 281 130 64)
    Anhydrone (p/n 338 219 00)
    Quartz Turnings (p/n 338 223 00)
    Quartz Wool (p/n 338 222 00)
    IRMS Separation Column (SS, 3 m, 6x5 mm, p/n 260 07931) installed into the oven at 50°C

    3
    Comparison between manual and automatic injection (100 ul)
    using a single reactor

    4
    Data comparison between single reactor and double reactors
    using the AS 1310 Autosampler (volume injected 100ul)

    Lower
    N and C
    content

    5
    Blank evaluation
    Blank analysis was performed with 100 ul of bidistillated water. The area of
    Nitrogen and Carbon was evaluated using the single and double reactors.
    Method Single reactor Double reactors
    Element N C N C
    Blank Area (mVolt/sec) 1300 1100 1800 2000
    Area of 10 ppm N (mVolt/sec) 2500
    Area of 4.2 ppm C (mVolt/sec) 4200 3800
    Area of 12 ppm N (mVolt/sec) 4000
    Area of 7 ppm C (mVolt/sec) 6000

    Overlay of chromatograms
    Red chromatogram: Blank – bidistillated water; Black chromatogram solution with the lower content of N and C

    Single reactor Double reactors

    6
    Manual injection - 200 ul / Double reactors
    Carbon determination

    Sample Solution 5 Solution 3.2


    ppm C ppm C
    3.9 3.1
    4.7 3.3
    4.0 3.0
    4.8 3.0 Overlay of chromatograms
    4.9 3.2 Red chromatogram: Blank Area about 2500 mVolt/sec
    4.9 3.0 Black chromatogram solution 3.2 ppm C Area about 6000 mVolt/sec
    4.0 3.0
    4.9 3.1
    5.0 3.2
    4.9 2.9
    Average 4.6 3.1
    RSD % 9.668 3.991

    7
    Manual injection - 250 ul / Double reactors
    Carbon determination

    Sample Solution Solution Solution


    3.2 ppm C 2.1 ppm C 1.4 ppm C
    3.3 2.2 1.4
    3.1 2.3 1.4
    3.3 2.0 1.4
    3.1 2.1 1.5
    3.0 2.0 1.4
    2.9 2.2 1.4
    Overlay of chromatograms
    3.2 2.1 1.4 Red chromatogram: Blank Area about 2000 mVolt/sec
    2.8 2.1 1.3 Black chromatogram solution 1.4 ppm C Area about 4300 mVolt/sec
    3.0 2.0 1.4
    3.1 2.2 1.5
    Average 3.1 2.1 1.4
    RSD % 5.258 4.872 4.026

    8
    Filling of the Nickel sheet – Lifetime ceramic tube
    • Single Reactor method.
    • The Nickel sheet is inserted only in the combustion zone.
    • Volume injected 100 ul by AS 1310 Liquid Autosampler.

    Sample Saline Lake water


    Determination TC (ppm) TOC (ppm)
    32 4.0
    33 4.1
    32 4.1
    32 4.1
    34 3.8
    32 3.9
    32 4.0
    34 4.0
    32 3.8
    33 3.8
    Average 33 4.0
    RSD% 2.59 3.19

    9
    Summarize of the lower Carbon results

    Sampling Manual Injection AS1310 Liquid Autosampler

    Reactor Single tube Double tubes Single tube Double tubes

    Volume Injected C (ppm) C (ppm) C (ppm) C (ppm)

    100 ul 4 7 4 7

    200 ul 3 3 - -

    250 ul 1.5* 1.5* - -

    * The lowest limit reaches by FlashSmart Analyzer stand-alone

    10

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