High-Performance Fumasep Ion Exchange Membranes For Electro Membrane Processes

Ion Exchange Membranes
High-performance fumasep® ion exchange membranes for Electro Membrane Processes

High-performance fumasep® ion exchange membranes for Electro Membrane Processes
FuMA-Tech – the company for functional membranes and plant technology – is one of the leading manufacturers of ion exchange
membranes for different electrochemical operations.
Our modern coating plant produces porous, non-porous and functional membranes with excellent resistance to acids, bases,
solvents and oxidation. With our new membrane coating line in a clean room, our further improved polymer production and a
´state of the art´ air purification which will meet all future requirements, we do another important step in the new markets of water
treatment technology, the innovative change of energy whilst using fuel cells as well as the energy storage with batteries.
fumasep® membranes are produced according to FuMA-Tech`s proprietary solution casting technology. They are supplied in stan-
dard sheet sizes for example of 200 x 300 mm, 520 x 520 mm, 520 x 1050 mm and other sizes on request. The maximum width
of 1650 mm could be produced on rolls with thicknesses ranging from 10 µm up to 500 µm.
Standard Grade Membranes 3-Compartment-Cell ED-Bipolar

The fumasep® FAS and fumasep® FKS are standard homogene-
ous anion and cation exchange membranes for electrodialysis
H2 SO4 NaOH
and reversed electrodialysis. They are cost saving membrane Cation exchange membrane Anion exchange membrane
types with reinforcement as well as non reinforced films. Those
membrane types are optimised in view of thickness, conduc-
tivity, permselectivity and area resistance, depending on the
application. The recommended applications are for example
desalisation processes, concentration of salts, acids and bases, H+ OH
nitrogen removal from drinking water. Cathode Anode
Membranes for Electrodialysis with Bipolar Membranes Na+ SO4

Our products fumasep FAB, FKB and FBM are designed and
®
optimized for electrodialysis with bipolar membranes. Na2 SO4 Bipolar Membrane Na2 SO4
The EDBM is the combination of conventional electrodialysis
for salt separation with electrochemical water splitting for the Figure 1: Electrodialysis with bipolar membranes in a 3-compartment cell
conversion of a salt into its corresponding acid and base.
fumasep® FAB is an anion exchange membrane which is deve-

loped for very low proton crossover to receive a high concent-
ration of acid. fumasep® FKB is a cation exchange membrane
optimised for high cation transport in combination with high
OH- retention. fumasep® FBM is a bipolar membrane, which
induce the splitting of water into protons and hydroxide ions.
The bipolar membrane fumasep® FBM combines high selec-

tivity and efficiency as well as high chemical stability within
a broad pH range, excellent mechanical stability and low
electrical resistance. It is ideally suited for the production of
acid and base from the corresponding salts, as well as for
innovative concepts such as biological fuel cells.
Figure 2: Current/voltage plot of fumasep® FBM bipolar membrane
The patented multilayer membrane consists of a selective anion

and cation exchange film. The dissosiation of the water into
protons and hydroxy ions takes place in the special interface
layer. The water is transferred into this layer by osmotic effects.
Special Grade Membranes Depending on the process design, up to 95 % of the free acid
The fumasep FAD anion exchange membrane is a membrane
®
and up to 80 % of the base can be recovered in this way
type with excellent properties regarding proton and anion and returned to the production process, thus saving chemicals
transport as well as high efficiencey in view of the metal ions needed for the finishing baths or wastewater treatment.
rejection. This characteristic is predestinated for the operation
in diffusions dialysis processes for the recovery of free acids fumasep® FAP is a chlorine resistant anion-exchange membra-
from spent treatment bath solutions for example in surface ne which also allows the transport of protons. This membrane
finishing and textile processes. is used for applications that require highly permselective mem-
branes with excellent oxidative stability, low area resistance
and high mechanical stability.
Water – IN Reject Materials – OUT
AAM
fumasep® FAA is an alkaline stable anion-exchange
membrane for electrodialysis applications.
fumasep® FKL is a cation-exchange membrane for concent-

Acid-ions ration of bases by electrodialysis.
Hydrogen-ions
Metal-ions fumasep® FKE is a thin cation-exchange membrane and
proton conductor for electrolysis with high selectivity.
Reclaimed Acid – OUT Spent Acid – IN Fluorinated Membranes for Electrolysis

The fumasep® F-10180 PTFE is a cation exchange membrane
AAM = Anion exchange membrane
based on perfluorinated sulfonic acid/PTFE copolymers with
excellent chemical stability and superior ionic conductance
Figure 3: Diffusion dialysis in a 2-compartment cell intended for use in electrolysis. The membrane is reinforced
with woven PTFE for highest mechanical and chemical stabili-
For base recovery by diffusion dialysis, the fumasep® FKD ty. Further application is the production of sodium hypochlorite
cation exchange membrane is used likewise. and hypochlorous acid for water disinfection.
Physical and chemical properties
Type Reinforcement Thickness IEC Selectivity Specific Stability

area resistance
µm meq/g % Ωcm² pH
Standard Grade Membranes
FAS anion none 10-50 1.6-1.8 94-97 0.4-0.8 1-14
FKS cation none 10-50 1.3-1.4 98-99 0.9-1.9 1-14
FKS cation polyester 75-130 0.8-1.2 98-99 2.0-4.5 1-9
FAS anion polyester 75-130 1.0-1.4 92-97 2.0-3.0 1-9
Membranes for Electrodialysis with Bipolar Membranes
FAB anion PEEK 100-130 1.0-1.1 94-97 4-7 1-14
FKB cation PEEK 100-130 1.2-1.3 98-99 4-6 1-14
FBM bipolar PEEK 180-200 – – – 1-14
Special Grade Membranes
FAD anion polyester 75-90 1.5-1.7 >85 0.4-0.8 1-9
FKD cation PEEK 75-90 1.2-1.4 >94 1.0-1.2 1-14
FAP anion PEEK/PTFE 130-160 1.1-1.3 >91 1.1-1.3 1-11
FAA-3 anion PEEK 100-130 1.4-1.6 94-96 1.9-2.5 1-14
FKL cation PEEK 100-130 1.0-1.2 98-99 6-10 1-14
FAA-3 anion none 10-50 1.9-2.1 92-95 0.2-0.7 1-14
FKE cation none 10-50 1.4-1.5 98-99 0.3-0.9 1-14
Fluorinated Membranes for Electrolysis
F-10180 cation PTFE 150-180 1.0 >99 <0.5 1-14
Ultrex™ Membranes
AMI-7001 anion polypropylene 500 1.3 >96 25-30 1-10
CMI-7000 cation polypropylene 450 1.6 >97 25-30 1-10

FUMATECH – functional membranes for fuel cells, batteries and electrolysis
The company
Focussing on water as the basis of all forms of life, and energy as the basis for a higher quality of life, FUMATECH
“Functional Membranes and Plant Technology“ combines the important tasks of providing energy and water.
The company is engaged in the field of fuel cell technology and membrane separation technology, particularly
for the treatment of aqueous solutions.
FUMATECH draws its particular strengths as a leading The high performance membranes are the heart of a proton
producer of ion-exchange membranes from its membership exchange membrane (PEM) fuel cell stack.
in the BWT Best Water Technology Group.
FUMATECH produces and develops
FUMATECH is committed to develop new products that will polyelectrolytes (fumion® ionomers),
accelerate progress in polymer electrolyte fuel cells. proton conductive membranes (fumapem® membranes) and
separation membranes (fumasep® membranes)
The company is both competent und competitive as a leading based on proprietary technology and designed for
supplier of polymers and membranes for manufacturing of high precision mass manufacturing.
membrane electrode assemblies.
fumion® ionomer resin as granular polymer, in solution form or in dispersion

fumion® FF granular perfluorosulfonyl fluoride resin for extrusion
fumapem® F perfluorosulfonic acid membranes for PEMFC
fumapem® AM polybenzimidazole membranes for high temperature PEMFC
fumapem® ST hydrocarbon membranes for DMFC and PEMFC
fumapem® P,E hydrocarbon membranes for DMFC
fumapem® FAA anion-exchange membrane for alkaline FC
fumasep® FAP anion-exchange membrane for redox flow batteries
fumasep® FBM bipolar membrane
fumasep® HF hollow fibre cartridge for gas humidification
fumasep® ion-exchange membranes for humidifier, electrodialysis and electrolysis
fumea® catalyst coated membranes for water electrolysis
Druck: 140311DK
BWT – The Company
The Best Water Technology Group is Europe’s leading water tech- customers to enjoy the highest levels of safety, hygiene and health
nology company with 2,800 employees and a vast network of in their daily use of water – the precious elixir of life. Among these
partner companies, service staff, installers, planners, architects are: SEPTRON®, the world’s first Electrodeionisation module (EDI)
and hygiene experts. Our R&D teams apply state-of-the-art meth- with spiral winding, the MDA (manganese oxide activation) method
ods and use the latest processes and materials to create products for effective removal of manganese, AQA total bipolar technology
that are both economical and green. One of the key objectives is for chemical-free limescale protection, SANISAL – the world’s first
to reduce the resource and energy consumption levels of our regeneration salt for softening systems that also disinfects at the
products, resulting in a reduction in CO2 emissions. same time, and the revolutionary new Mg2+ technology for better
tasting filtered water, coffee and tea. BWT, with its
Practically everywhere where water is involved, unique, high-performance membranes for fuel
BWT’s pioneering products have proved their cells and batteries, is setting the 21st century
worth millions of times over; where domes- standard for the supply of clean energy.
tic water enters a building (‘point of
entry’) and at its tapping point BWT – For You and Planet Blue signi-
(‘point of use’), for the treatment fies our mission to take ecological,
of seawater, drinking water, min- economic and social responsibility,
eral water, ultrapure water for and to provide our customers with
pharmaceuticals, water for the best products, systems, technolo-
swimming pools, heating and gies and services in all areas of
process water, boiler water, water treatment, while making a
cooling water and water for air- valuable contribution to the preser-
conditioning systems. Our numer- vation of our blue planet’s global
ous innovations enable our resources.
For further information:
FuMA-Tech Gesellschaft für BWT Aktiengesellschaft

funktionelle Membranen und Walter-Simmer-Straße 4
Anlagentechnologie mbH A-5310 Mondsee
Carl-Benz-Straße 4 Tel.: +43/6232/5011-0
D-74321 Bietigheim-Bissingen Fax: +43/6232/4058
Tel.: +49/7142/3737-900 E-Mail: office@bwt-group.com
Fax: +49/7142/3737-999 www.bwt-group.com
E-Mail: office@fumatech.de
www.fumatech.de

High-Performance Fumasep Ion Exchange Membranes For Electro Membrane Processes

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What types of membranes are discussed?

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What is electrodialysis with bipolar membranes?

What is electrodialysis with bipolar membranes?

Ion Exchange Membranes

High-performance fumasep® ion exchange membranes for Electro Membrane Processes

Standard Grade Membranes 3-Compartment-Cell ED-Bipolar

Membranes for Electrodialysis with Bipolar Membranes Na+ SO4

fumasep® FAB is an anion exchange membrane which is deve-

The bipolar membrane fumasep® FBM combines high selec-

The patented multilayer membrane consists of a selective anion

fumasep® FKL is a cation-exchange membrane for concent-

Reclaimed Acid – OUT Spent Acid – IN Fluorinated Membranes for Electrolysis

Type Reinforcement Thickness IEC Selectivity Specific Stability

Standard Grade Membranes

FAS anion none 10-50 1.6-1.8 94-97 0.4-0.8 1-14

FKS cation none 10-50 1.3-1.4 98-99 0.9-1.9 1-14

FKS cation polyester 75-130 0.8-1.2 98-99 2.0-4.5 1-9

FAS anion polyester 75-130 1.0-1.4 92-97 2.0-3.0 1-9

Membranes for Electrodialysis with Bipolar Membranes

FAB anion PEEK 100-130 1.0-1.1 94-97 4-7 1-14

FKB cation PEEK 100-130 1.2-1.3 98-99 4-6 1-14

FBM bipolar PEEK 180-200 – – – 1-14

Special Grade Membranes

FAD anion polyester 75-90 1.5-1.7 >85 0.4-0.8 1-9

FKD cation PEEK 75-90 1.2-1.4 >94 1.0-1.2 1-14

FAP anion PEEK/PTFE 130-160 1.1-1.3 >91 1.1-1.3 1-11

FAA-3 anion PEEK 100-130 1.4-1.6 94-96 1.9-2.5 1-14

FKL cation PEEK 100-130 1.0-1.2 98-99 6-10 1-14

FAA-3 anion none 10-50 1.9-2.1 92-95 0.2-0.7 1-14

FKE cation none 10-50 1.4-1.5 98-99 0.3-0.9 1-14

Fluorinated Membranes for Electrolysis

F-10180 cation PTFE 150-180 1.0 >99 <0.5 1-14

AMI-7001 anion polypropylene 500 1.3 >96 25-30 1-10

CMI-7000 cation polypropylene 450 1.6 >97 25-30 1-10

fumion® ionomer resin as granular polymer, in solution form or in dispersion

For further information:

FuMA-Tech Gesellschaft für BWT Aktiengesellschaft

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