Ally Designation: D 1654 - 08 Standard Test Method for Corrosive Environments" Evaluation of Painted or Coated Specimens Subjected to ‘This sans is ste ue he Fie designation 15S: the amber imme fling the designation intone the yee ot ginal adption one css of evison, the yer oft ein, A number in pavasses ines he year of nt eppoval A ‘peril epilon() eaten an etal chrige sac helt revision ce rapponal This sda has been approved or nse by agencies of he Departmen of Def 1. Scope LI This test method covers the treatment of previously. painted or coated specimens for accelerated and atmospheric ‘exposure tests and their subsequent evaluation in respect to corrosion, blistering associated with corrosion, loss of adhesion at a scribe mark, or other film failure 1.2 The values stated in SI units are to be regarded as the standard. The values given in parentheses are for information nly. 13 This standard does not purport to adress all of the safely concerns, if any, associated with its use. It is the responsibility of whoever uses this standard 10 consult and ‘establish appropriate safety and health practices and deter- ‘mine the applicability of regulatory limitations prior to use. 2. Referenced Documents 2.1 ASTM Standards? B 117 Practice for Operating Salt Spray (Fog) Apparatus D 610 Practice for Evaluating Degree of Rusting on Painted Steel Surfaces D714 Test Method for Evaluating Degree of Blistering of Paints D822 Practice for Filtered Open-Flame Carbon-Are Expo- sures of Paint and Related Coatings D870 Practice for Testing Water Resistance of Coatings Using Water Immersion D 1014 Practice for Conducting Exterior Exposure Tests of Paints and Coatings on Metal Substrates D 1735 Practice for Testing Water Resistance of Coatings Using Water Fog Apparatus thi est met is ener the jurniton of ASTM Comite DDI on Faint and Rel Coating, Mote. and Applicatons and isthe diet esponsibiy oF Sttoommitee DOI 25 on Evaluation af Wexthrng ets ‘Curatedioa epaved Nox. 1 2008, Pulled December 2008, Originally Tor referenced ASTM stfins, vin the ASTM shi wawastmone, of ‘onsact ASTM Cixomar Semc at sericea ng Por Annual Hook of ASTM Standard oluneifoaion, fer wo the sandals Docent Suny page o0 1D 2247 Practice for Testing Water Resistance of Coatings in 100 % Relative Humidity D 2803 Guide for Testing Filiform Corrosion Resistance of ‘Organic Coatings on Metal DAl41 Practice for Conducting Black Box and Solar Con- centrating Exposures of Coatings 1D 4385 Practice for Testing Water Resistance of Coatings Using Controlled Condensation 1D 4587 Practice for Fluorescent UV-Condensation Expo- sures of Paint and Related Coatings 1D 5894 Practice for Cyclic Salt Fog/UY Exposure of Painted Metal, (Alternating Exposures in a Fog/Dry Cabi net and a UV/Condensation Cabinet) 1.6695 Practice for Xenon-Are Exposures of Paint and Related Coatings D 7087 Test Method for An Imaging Technique to Measure Rust Creepage at Scribe on Coated Test Panels Subjected 10 Corrosive Environments E3 Guide for Preparation of Metallographie Specimens G85 Practice for Modified Salt Spray (Fog) Testing G87 Practice for Conducting Moist SO, Tests 2.2 ANSI Standard: * 1B94,50 Single-Point Cutting Tools, Basic Nomenclature ‘and Definitions for 3. Terminology 3.1. pains removal material, n—a device or substance used (0 remove loose coating around a scribe, 3.2 rust creepage or undercusting, n—corrosion of a sub- sirate that occurs around a damaged area of a coated material 3.3 scribe, n—a linear, intentionally prepared damaged area (on a coated material that extends down to the substrate. 3.4 seribing tool, n—a tool used (© prepare a seribe on a coated material 3.5 cone of corrosion, n—area of comrosion of a substrate * valabl oom Amoi Nana Sandu Insite (ANS, 28 W. 4rd St ‘enyiht ASTM rina 100 Br Her ve, PO Bo 708, Wet Cork, 1LO8-2958, Unie Se4) 0 1654 - 08 4. Significance and Use 4.1 This method provides @ means of evaluating and com- paring basic corrosion performance of the substrate, pretreat ‘ment, or coating system, or combination thereof, after exposure {o corrosive environments 5. Apparatus 5.1 Scribing Tools: S.L.1 Lathe Tool Type—High speed tool steel or tungsten ‘carbide thread cutting lathe tool bit with a cutting tip having a 60° included angle, ANSI B94.50, Style E has been found to ‘meet these requirements, (See Fig. 1.) The tool bit is typically. ‘mounted in a holder such as a wooden file handle to facilitate the seribing operation 5.1.2 Peneil Type—Pencil shaped device, with a high speed tool steel or tungsten carbide scribing tip. Typically the sripping surface is knurled. The tip may be replaceable or permanent 5.1.3 Motorized Circular Blade—A motor fitted with a 1 to 2 mm wide circular cutting device. 5.1.4 Other Types—Other types of scribing instruments which use a knife type blade such as a scalpel, razor blade, box ‘cutter knife, or other sharp pointed tool are acceptable if agreed ‘upon between the producer and the user 5.2 Siraightedge—Any straightedge of sullicient length and rigidity to guide the scribing tool in a straight line ‘3.3 Paint Removal Materials—The following materials can be used to remove the coating around the scribe. 53.1 Spatula 53.2 Knife or similar instrament—the sharpness of blade shall be agreed upon between purchaser and seller $3.3 Paint Stripper or strong solvent. 534 Materials for removal by air 53.4.1 Air Source—A source of compressed air capable of at least 4.72 Lis (10 ft'/oin) at 552 kPa (80 psi). 5.3.4.2 Air Gun—An air dusting gun and nozzle combina tion. The following configuration has been found to be suc- cessful Ai Consumo, Pressure, MPa Nozzle Dameter, Phin cei) ‘os nn) oases) ss0160) 304012) 5.3.5 Power Washer capable of delivering 3500 psi 34 Soale—Any rule with I-mm divisions 6, Preliminary Treatment of Test Specimens 6.1 Scribed Specimens: 6.1.1 Where specified or agreed upon, prepare each speci ‘men for testing by scribing it in such a manner that the scribe ccan be exposed lengthwise when positioned in the test cabinet. This position will allow solution droplets to run Tengthwise along the scribe. i. FIG. 1 Scribe Too! 6.1.2 Seribe the specimen by holding the tool at approxi mately a 70 t0 90° angle to the surface with the upper end of tool holder inclined toward the operator. Position the tool so that only the tip is in contact with the surface. (See Fig, 2.) Pull the seribing tool 1o obtain a uniform V-cut through the coating that is being tested, The endpoints ofthe seribe shall be atleast, 1.25 em (0.5 in.) from the edge of the panel. Inspect the tool frequently, using low power magnification, for dulling, chip- ping or wear and replace of repair as needed, The scribe should be of sullicient Iength to cover the significant test area, but should not contact the edge of the specimen. The scribe must penetrate all organie coating layers on the metal, leaving a uniformly bright line. The extent of scribe penetration through, ‘metal coatings, such as galvanize, should be agreed upon between the producer and user. The coil coating industry typically requires scribes to penetrate all organic coating layers bbut not penetrate the metal coating layers. The automotive industry typically requires scribes to penetrate all organic and ‘metal coating layers. The pencil type may be less effective than the lathe tool type when scribing coating systems consisting of ‘multiple layers of organic coatings or coating systems includ ing metal layers. When seribing coating systems consisting of ‘multiple layers of organic coatings or coating systems includ. ing metal layers the depth and quality of scribe technique should be evaluated using the cross section, castable plastic ‘mount, polishing technique described in Practice E 3. Quality of the seribe technique may also be observed with the aid of low-power magnification, Note, mark, and describe defects, coding, and flaws that may affect resulis. If a motorized circular blade is used, position the test specimen tallow for a straight, linear cut at the desired length, The blade shall be positioned (© a depth such that it is. able to cut into the substrate, This type of blade will result in a rectangular cut rather than a V-cut 6.1.3 One cut may not be sufficient to cut multi-layer protective coatings down to the metal, The use of more than ‘one cut must be agreed to between all concerned parties prior to seriing, and the number of cuts must be recorded in the test documentation. When multiple cuts are needed. each cut must, FIG. 2 Seribing Tool in Action4) 0 1654 - 08 TABLE 1 Rating of Failure at Scribe (Procedure A) epresertave Mean Greepaga From Serbe be done in the same direction, Ifa motorized blade is being, used, it may be necessary to clean out residual materials of the scribe with a pencil-type scriber. 6.14 Scribe lines other than those ofa single, straight nature ‘may be used if agreed upon between the producer and the user, 6.1.5 Wipe off the panel with a dry rag, or blow with air to remove any metal flakes from the scribing process. 6.1.6 The width of the scribe (1) shall be recorded. 6.2 Cur Edges—Cut edges of panels may be exposed dui testing, or protected by wax, tape, oF other means as agreed upon between the producer and the user. If left unprotected, method of shearing panel edges should be agreed upon between the producer and user, noting whether edges are ‘oriented in the “burr up” or “burr down” configuration. 6.3 Deformation—Deformation of test panels prior to ex- ‘posure, if desired, should be agreed upon between the producer and user. Exposure of Test Specimens 7.1 Expose test specimens in accordance with one or more ‘of the following test methods or practices: B 117, D822, D870, D 1014, D 1735, D 2247, D 2803, DAML, D4585, D4587, D 5894, D 6695, G85, G 87, or any other applicable test method, as agreed upon between the producer and the user. ‘The length of test and evaluation intervals should be agreed ‘upon prior to exposure of specimens, 8, Procedure A—Evaluation of Rust Creepage for Seribed Specimens 8.1 Rinse each specimen after completion of the exposure period, using a gentle stream of water at a temperature up to 45°C (110°F). Remove coating along scribe with one of the following methods such that all corrosion of the substrate (that is, rust ereepage or undercutting) can be observed using one of the following methods, 8.1.1 Method I (Scraping)—Scrape the specimen vigor ‘ously with ane! instrument deseribed in 5.3.1 8.1.2 Method 2 (Knife)—Pick off the loose or lifted coating, with a knife described in 5.3.2 1.3 Method 3 (Paint Siripper)—Soak the panels in paint Stripper or suitable solvent as described in 5.3.3 until the ‘coating around the scribe is removed, or can be removed with a spatula. 8.1.4 Method 4 (Air Blow-Of—Holding the nozzle, as described in 5.3.4, at approximately a 45° angle, blow along the entire scribe line, disturbing the surface adjacent «0 the scribe adjacent to the scribe mechanically by the air nozzle to ‘ensure an opening for the air blast 8.1.5 Method 5 (Power Washer)—Using a power washer described in 5.3.5, remove the coating around the seribe 8.1.6 Other methods ean be used (0 remove loose material around the scribe if agreed upon between purchaser and seller, Nore 1—The above methods may not be appropriate inal as, sch 28 for imterim ratings in continuing tests. Nore 2For all methods, compete the removal of lose coating with 15 in of specimen removal fom the exposure cabinet. f removal cannot te comple! within the prescribed ime, immerse the specimens i water st room temperature or store in aplastic hag to avoid any drying effect. ang Naber Over O10 05 Over 0.310 10 Over 2010 30 Over 301080 Over 5.01079 Gver F019 109. (ver 100 to 120 Over 13019 180 Gver t80 19 more 8.2 Rating—Only areas of the substrate that are discolored due to corrosion should be considered, Record the maximum, and minimum ereepage from the seribe, and note whether of not the maximum is an isolated spot. The mean can be dotermined by making at least 6 measurements of the width of the zone of corrosion uniformly distributed along the scribe, ignoring 3 mm (0.125 in.) of each end of the scribe. Determine the arithmetic mean, and use the following equation to deter ‘mine rust ereepage (e): @ where: Ww. = mean overall width of the corrosion zone and Ww) = width of the original seribe, As an altemative, use Test Method D 7087. Record creep values in millimetres, inches, or rating numbers as prescribed in Table 1, as agreed upon between producer and user. Loss of paint that does not extend down to the substrate and result in corrosion can be rated using the same procedure, but should not be considered as scribe crecpage, undercutting, or carro: sion. If this is the ease, not the coat(s) removed, 9. Procedure B—Evaluation of Unseribed Arcas 9.1 Use photographie blister standards given in Practice D714 to describe the results of the exposure test with respect to blisters, and Practice D 610 to describe the results of the exposure with respect to rusting 10, Procedure C—Eyaluation of Unprotected Edges 10.1 IF paint creepage from cut edges is tested, rate the corrosion or loss of paint extending from a cut edge in the same manner deseribed for scribes in Procedure A. 11. Procedure D—Evaluation of Formed Areas LIL If tested samples contain bends, dimples, or other formed areas of interest rte the extent of failure at these areas separately in the same manner described in Procedure B, or as agreed upon between the proxlucer and user. 12. Report 12.1 The report shall include the following information, unless otherwise agreed upon between the producer and user12.1.1 All pertinent information regarding the conduct of ceach corrosion test, as prescribed in the specifications for each, test, 12.1.2. Methods of scribing, shearing, or forming, or com- bination thereof, oF test specimens. 12.1.3. Method of removal of loose coating. 12.14 Rust creepage. 12,15 If applicable, the extent ofthe removal of loose paint around scribe that did not extend down to the substrate, noting, which coat(s) were removed. 4) 0 1654 - 08 13, Precision and Bias 13.1 Preciston—Since this is a method of evaluation based ‘on measurements alter vatious tess, the statement of precision applicable (© each specific method of exposure (© corrosive environments applies. 14, Keywords 14.1 blistering; corosion; creepage; edge/scribe: paints! related coatingmaterials; rust; undercutting ASTI intrationl takes no poston respecting tho vay of ny patent rons asserted connection with any tam mentioned in tis sandr Users of Os starr areexressy aised that deena of Be vabaty of ary such pte ahi ad Pe Fok Sfinhingemer of such ras are ental theron responsi. ‘This standars is utc to rovon at any tne bythe responsible ecniclcommitee and must bo reviewed var the years ae ‘wnat ene reapprovena wth Yur Cerise ated ei sono ts stand. fe onal anaes [Sod shuld ns adressen ASM introns Hanae. 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