Condensation in Horizontal Tubes, Part 2: New Heat Transfer Model Based On Ow Regimes
Condensation in Horizontal Tubes, Part 2: New Heat Transfer Model Based On Ow Regimes
Condensation in Horizontal Tubes, Part 2: New Heat Transfer Model Based On Ow Regimes
www.elsevier.com/locate/ijhmt
a
Laboratory of Heat and Mass Transfer, Faculty of Engineering Science, Swiss Federal Institute of Technology,
Lausanne, CH-1015 Lausanne, Switzerland
b
Dipartimento di Fisca Tecnica, University of Padova, Padova, I-35131, Italy
Received 24 June 2002; received in revised form 4 March 2003
Abstract
A new general flow pattern/flow structure based heat transfer model for condensation inside horizontal, plain tubes
is proposed based on simplified flow structures of the flow regimes, and also includes the effect of liquid–vapor in-
terfacial roughness on heat transfer. The model predicts local condensation heat transfer coefficients for the following
flow regimes: annular, intermittent, stratified-wavy, fully stratified and mist flow. The new model has been compared to
test data for 15 fluids (R-11, R-12, R-22, R-32, R-113, R-125, R-134a, R-236ea, a R-32/R-125 near-azeotrope, R-404A,
R-410A, propane, n-butane, iso-butane and propylene) obtained in nine independent research laboratories. The new
model has been tested over the following range of conditions: mass velocities from 24 to 1022 kg/(m2 s), vapor qualities
from 0.03 to 0.97, reduced pressures from 0.02 to 0.80 and tube internal diameters from 3.1 to 21.4 mm. Overall, the
model predicts 85% of the heat transfer coefficients in the non-hydrocarbon database (1850 points) to within 20% with
nearly uniform accuracy for each flow regime and predicts 75% of the entire database to within 20% when including
the hydrocarbons (2771 points), the latter all from a single laboratory whose data had some unusual experimental
trends over part of their test range.
Ó 2003 Elsevier Science Ltd. All rights reserved.
Nomenclature
2. Literature review of condensation models used for the calculation of heat transfer coefficients: an
interfacial shear model or a two-phase multiplier cor-
In the early models, the flow patterns were classified relation. The latter is the most common approach
under only two categories, as either stratified (or strati- consisting in calculating the Nusselt number during
fying, or wavy) flow or as annular flow. In the first case, condensation by multiplying the Nusselt number for
the gravity dominated flow has been modelled consid- turbulent single-phase flow by a suitable two-phase
ering a thick condensate layer flowing along the bottom multiplier. The two-phase multiplier is usually given as a
of the tube, while a thin liquid film forms on the wall in function of some of the following parameters: vapor
the upper portion of the tube. Heat transfer through quality, viscosity and density ratios between the liquid
the thin film is treated by a classical Nusselt type ana- and vapor phases, reduced pressure, liquid Froude
lysis, while heat transfer through the thick condensate number, Martinelli Xtt parameter, etc. For the single-
layer can either be neglected as in Jaster and Kosky phase Nusselt number upon which these multipliers
[4], or treated as a convective process. In the shear act, the equation by Dittus and Boelter [5] is often the
dominated annular flow, two different approaches were basis.
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3367
Worth mentioning, although very old, are the equa- mental data, that is generally within 20%. This applies
tions by Akers et al. [6] and Akers and Rosson [7], still in particular, with somewhat different approximations,
recommended as a design tool in the ASHRAE Hand- to the methods by Shah, Cavallini-Zecchin, Dobson-
book [8]. Three straightforward equations are given, Chato, Tang, Traviss et al. and Haraguchi et al. Never-
each of them applicable within definite ranges of suitable theless, this did not hold true when the same methods
dimensionless parameters; they cover both annular and were applied to condensation of some of the new gen-
stratified flow conditions. The one for annular flow is of eration HFC refrigerants, those that are commonly used
the two-phase multiplier type. Cavallini and Zecchin [9] at higher pressure (also higher reduced pressure) than
proposed a simple dimensionless semi-empirical equa- the traditional refrigerants. In this case the available
tion to be applied when annular flow is present during predicting methods, developed in the past in connection
condensation. The same authors showed later [10] that with availability of experimental data only concerning
their equation represented, within narrow limits, the traditional refrigerants, either cannot be applied because
results of a flow-dynamic analysis of the condensation of the cited limits in their application ranges, or unac-
phenomenon. Similar analyses, based on the assumption ceptably overpredict the experimental data, typically by
that the Von Karman velocity profile for pipe flow holds 20–40%. To overcome this situation, Cavallini et al. [20]
true in the condensate annulus, had previously been presented a new heat transfer flow pattern-based
used by Kosky and Staub [11] and Traviss et al. [12], to method, that was able to give satisfactory predictions
develop their own calculation procedures, valid of also with the new generation high-pressure refrigerants
course only with an annular flow pattern. The method while their flow pattern map was discussed in Part I of
by Kosky and Staub is for instance recommended by this two-part paper. In the annular flow regime, the
Butterworth [13] in the Heat Transfer Design Handbook. method employs an interfacial shear model similar to
Analyses based on a similar type of approach are also that developed by Kosky and Staub [11], with a modified
suggested for design purposes in Germany in their VDI Friedel [21] correlation for the calculation of the fric-
W€ armeatlas, i.e. VDI Heat Atlas [14] translated in tional pressure drop and related wall shear stress. For
English, and still in the most recent version in German, their comparison, Cavallini et al. [20] used an extensive
VDI W€armeatlas [15]. A two-phase multiplier correla- experimental data bank formed from quite a few data
tion extensively used in North America is the one by sets taken in independent research laboratories. Details
Shah [16], which should coherently be applied only in of this data bank are reported in Table 1, where they
the presence of an annular flow pattern, even if the au- represent the first nine listings. While their new model
thor did not establish this limitation, presenting his ex- was an improvement upon past methods, it also in-
pression as a ‘‘generalised’’ one. cluded a large number of empirical constants and also
Tang [17], based on his condensation measurements, predicts an unlikely jump in the heat transfer coefficient
also developed a new heat transfer two-phase multiplier across one flow transition boundary. Hence, the objec-
correlation valid in the annular flow regime, when mass tive here is to present a new condensation heat transfer
velocities are larger than 300 kg/(m2 s) and the reduced model that avoids these pitfalls and also will predict
pressure is between 0.2 and 0.53. The computational hydrocarbon data.
method suggested by Haraguchi et al. [18] is extensively
used in Japan. It consists of two dimensionless equa-
tions, one each for both annular and stratified flow 3. Heat transfer database
conditions, combined together in an asymptotic way.
Appropriate applicability ranges are specified. Dobson The database of condensation heat transfer coeffi-
and Chato [19] presented a set of equations able to cients available for the current study is described in
predict the heat transfer coefficient both in the stratified Table 1. These studies are contributions from nine in-
flow regime and in the annular one; the annular flow dependent research laboratories and cover 15 fluids and
correlation was derived using the two-phase multiplier a wide range of test conditions. Only studies from the
approach. In some circumstances quite discontinuous 1990s to the present have been considered as they are
results are calculated when passing from one flow regime more accurate than the older databases, i.e. newer
to the other, contrary to experimental evidence. studies use Coriolis mass flow meters for both the
Recently, Cavallini et al. [20] compared most of the coolant and the refrigerant, more accurate data acqui-
above prediction methods to heat transfer coefficients of sition systems and so on. The newest study, that of
halogenated refrigerants condensing inside horizontal Liebenberg [29], only includes his R-22 data available at
plain tubes, for experimental data obtained by inde- this time.
pendent research workers. The outcome of this com- This list of test fluids includes single component
parison showed that a few of the above methods, when refrigerants (R-11, R-12, R-22, R-32, R-113, R-125,
employed with condensation of the old generation re- R-134a, R-236ea), binary azeotropic or very near azeo-
frigerants, were able to predict satisfactorily the experi- tropic refrigerant mixtures (60% R-32/40% R-125,
3368 J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387
Table 1
Condensation heat transfer data bank (pure fluids and quasi-azeotropic mixtures)
Author(s) Data points Refrigerants d (mm) Tsat (°C) Tsat Tw (°C) G (kg/(m2 s))
Cavallini et al. [22,23] 425 R-22, R-134a, R-410A, 8.0 27–60 2.4–15.4 63–773
R-125, R-32, R-236ea
Dobson–Chato [19] 644 R-22, R-134a, R-410A, 3.1–7.0 33.5–46.4 1.1–8.8 24–812
R-32/R-125 (60/40% by mass)
Zhang [24] 77 R-22, R-134a, R-404A 3.3–6.2 23.1–65.2 1.0–5.6 245–1022
Tang [17] 218 of 231 R-22, R-134a, R-410A 8.8 35.2–40.8 – 258–817
Chitti–Anand [25] 41 of 48 R-410A 8.0 24–36 – 161–491
Kim et al. [26] 225 R-22 8.0 48–49 2.7–9.6 229–343
Kim et al. [26] 921 Propane, n-Butane, iso-Butane, 8.0 46.6–50.2 1.2–9.8 44–204
Propylene
Wijaya–Spatz [27] 14 R-410A 7.8 46–52 – 481
Fujii [28] 158 R-11, R-12, R-113 16.0–21.4 28.4–50.1 2.2–32.7 33–577
Liebenberg [29] 48 of 50 R-22 8.11 38.4–43.2 – 304–832
Data marked with refers to data which could not be used because they fell in a flow regime requiring experimental measurement of
(Tsat Tw ) which were not reported.
R-404A, R-410A) and pure hydrocarbons (propane, n- e.g. a error of 0.02 at x ¼ 0:03 means that the real
butane, iso-butane and propylene). The database covers vapor quality could be from 0.01 or 0.05, which may
a very broad range of conditions: mass velocities from result in a halving or doubling the value of e, respec-
24 to 1022 kg/(m2 s), vapor qualities from 0.03 to 0.97, tively. At very high x, e and the annular liquid film
reduced pressures from 0.02 to 0.80 and tube inter- thickness d are very sensitive to small changes in the
nal diameters from 3.1 to 21.4 mm. The database in- liquid fraction (1 x); e.g. a change of just 0.01 in e
cludes heat transfer coefficients for the following flow may result in a doubling or halving of the condensate
regimes: stratified, stratified-wavy, annular, intermittent film thickness. Hence, it is particularly difficult to ac-
and mist. curately measure condensation data at vapor qualities
Regarding the experimental condensation heat less than 0.05 and above 0.95.
transfer coefficients themselves, they are ‘‘quasi-local’’ Desuperheating and subcooling. There is a less than
data obtained in short test sections that give a mean heat obvious effect of desuperheating on the test data at high
transfer coefficient for a small (or sometimes even large) vapor qualities, caused by the condensate formed in a
change in vapor quality, Dx, from inlet to outlet. The Dx desuperheater before the test section, i.e. condensate
should optimally be on the order of 0.05 or less but in formed while cooling the vapor to its saturation tem-
some tests was as large as 0.20–0.40. It would be better perature. This condensate enters the condenser test
in the future to utilize an enthalpy profile approach to section and hence the film begins with some initial value
get true local heat transfer coefficients, such as described of din > 0 rather than starting from d ¼ 0 at x ¼ 1 and
in Z€urcher et al. [30] for measuring local flow boiling e ¼ 1. This effect tends to increase the film thickness,
heat transfer coefficients. With respect to condensation which in turn decreases the heat transfer coefficient
heat transfer data, the most difficult test conditions to measured. This ‘‘desuperheating’’ condensate only in-
make accurate measurements are as follows: fluences data where its preexisting fraction of the total
Near flow regime transition zones. If a transition from condensate is significant, i.e. at high x for say
one flow pattern to another takes place within the 1:0 P x P 0:9. This may be the reason that some high
‘‘quasi-local’’ test section, the mean heat transfer coef- vapor quality heat transfer coefficients tend to plateau at
ficient for the section is an unknown average of the two high vapor qualities. Secondly, some local condensation
regimes. Also, consider that the transition from one re- test data may include subcooling since the Dx in the test
gime to the next typically occurs over a mass velocity sections during quasi-local experiments are often from
range of about 50 kg/(m2 s), which is analogous to the 0.05 to 0.3 and thus data for x < 0:05 may be averaged
transition regime in single-phase flow (where heat over a single-phase liquid zone too.
transfer coefficients are more difficult to measure). Stable operating conditions. All experimental test
Very high and low vapor qualities. As x ) 1 and as loops have a limited range in which steady-state test
x ) 0, small errors in energy balances of 2% are conditions can be maintained. At low mass velocities,
magnified. Typical errors in energy balances are on the typically a threshold is reached where fluctuations in
order of 1% to 3%, which represent identical errors pressure and flow rate become significant. In particular,
in x. Referring to Fig. 4 in Part I, at low x the void pressure fluctuations significantly influence Tsat , which is
fraction e decreases very rapidly with small changes in x; used to reduce the data, and hence the measured heat
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3369
an adiabatic stratified-wavy flow in a horizontal tubular Our objective here is to develop a new flow pattern/
sight glass of 13.6 mm internal diameter for ethanol and flow structure based condensation heat transfer model
air obtained using a laser sheet, a video camera and analogous to that which was proposed by Kattan et al.
image analysis by Wojtan et al. [31]. The height of the [1–3] for evaporation inside horizontal tubes. The con-
liquid on the left is a little higher than on the right be- densation model therefore uses the same flow pattern
cause of the asynchronous height of the waves on the map as for evaporation but with the new modifications
walls. Hence, the equivalent geometry assumed here in introduced in Part I. Their flow pattern map for near
Fig. 2 for stratified-wavy flow is reasonably representa- adiabatic and evaporating flows has proved to be very
tive of the real situation. accurate and reliable in comparisons to over 1000 flow
In stratified-wavy flow, the interfacial waves are pattern observations for eight different refrigerants to
small in amplitude and do not reach the top of the tube. date. In addition, the same simplified two-phase flow
Hence the top perimeter of the tube is not wetted by the structures assumed for the flow patterns in the evapo-
stratified liquid but only by the condensate that forms ration model are also assumed for the condensation
on this part of the exposed tube perimeter. Here, once model. It is also a goal here to develop a new heat
again, for simplicity the stratified liquid is assumed to transfer model with as few empirical constants as pos-
form an annular truncated ring as shown in the middle sible. Prediction methods that include a large number of
diagram at the bottom of Fig. 2. Thus, the angle h varies empirical parameters, some of the methods mentioned in
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3371
flow of a falling film on the internal perimeter of the pattern transition boundaries without any jump in the
tube, where af is the mean coefficient for this perimeter. value of atp .
Rather than integrating from the top of the tube to the
stratified liquid layer at h=2 to obtain af , which would be 4.4. Implementation
more theoretically satisfying, it was found sufficient to
simply use the mean value for condensation around the The condensation heat transfer model is implemented
perimeter from top to bottom with its analytical value of as follows:
0.728, and thus avoid a numerical integration to facili-
tate practical use of this method in designing condensers. 1. determine the local vapor void fraction using the
Hence, af is LMe method (Part 1);
2. determine the local flow pattern using the flow pat-
1=4 tern map (Part 1);
q ðq qV ÞghLV k3L
af ¼ 0:728 L L ð17Þ 3. identify the type of flow pattern (annular, intermit-
lL dðTsat Tw Þ
tent, mist, stratified-wavy or stratified in Part 1);
4. if the flow is annular or intermittent or mist, then
Since heat exchanger design codes are typically im-
h ¼ 0 and ac is determined with Eq. (7) and hence
plemented assuming a heat flux in each incremental zone
atp ¼ ac in Eq. (2) where d is obtained with Eq. (10)
along the exchanger, it is more convenient to convert
and fi is determined with Eq. (15);
this expression to heat flux using NewtonÕs law of
5. if the flow is stratified-wavy, then hstrat and h are calcu-
cooling, such that the heat flux version of NusseltÕs
lated using Eq. (3) or (19) and Eq. (6), then ac and af
equation where the local heat flux is q, is given by the
are calculated using Eqs. (7) and (17) or (18), and
expression
finally atp is determined using Eq. (2) where again d
is obtained with Eq. (10) and fi is determined with
1=3
q ðq qV ÞghLV k3L Eq. (15);
af ¼ 0:655 L L ð18Þ
lL dq 6. if the flow is fully stratified, then hstrat is calculated us-
ing Eq. (3) or (19) and hstrat is set equal to h, then ac and
af are calculated using Eqs. (7) and (17) or (18), and fi-
where the leading constant 0.655 comes from 0.7284=3 . nally atp is determined using Eq. (2) where d is ob-
The difference in the accuracy of the predictions whether tained with Eq. (10) and fi is determined with Eq. (16).
using the first or second of these expressions for af is
negligible.
To completely avoid any iterative calculations, the
recent explicit expression of Biberg [36] can be used to 5. Comparison to refrigerant database
very accurately (error 0.00005 rad for 2p P hstrat P 0)
evaluate the implicit expression above for hstrat , that is Fig. 5 shows a typical example of condensation heat
Eq. (3) here and Eq. (10) in Part 1: transfer data plotted as a function of vapor quality at
( 1=3 )
pð1 eÞ þ 3p ½1 2ð1 eÞ þ ð1 eÞ1=3 e1=3
hstrat ¼ 2p 2 2 ð19Þ
1
200 ð1 eÞe½1 2ð1 eÞ
½1 þ 4ðð1 eÞ2 þ e2 Þ
This expression gives hstrat directly from the void fraction various mass velocities. The data are those of Cavallini
and has no effect on the location of the transition curves et al. [22,23] for R-134a in an 8.0 mm tube. The heat
compared to the prior method. transfer coefficients fall monotonically from large values
The above heat transfer prediction method cannot be at high vapor quality (where the annular film thickness is
evaluated at e ¼ 1:0 because of division by zero. Fur- thinnest) to small values at low vapor qualities. The ef-
thermore, experimental condensation heat transfer test fect of mass velocity is more significant at large vapor
data will have an error in vapor quality of at least 0.01 qualities than at low vapor qualities. Hence the slope of
and hence it does not make sense that test data can be the data curves increases with increasing mass velocity.
evaluated for x > 0:99. Thus, the above condensation All of these data fall within the annular or intermittent
prediction method is applicable when 0:99 P x; when flow regimes, except at the lowest vapor qualities and
x > 0:99, then x should be reset to 0.99. Also, the lower mass velocities where they reach the stratified-wavy re-
limit of applicability is for vapor qualities x P 0:01. Our gime.
range of test data is for 0:97 > x > 0:03. This method The new model was primarily developed using the
provides for a smooth variation in atp across all the flow heat transfer database of Cavallini et al. [22,23] and then
3374 J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387
the other independent studies were used to determine its useful as a method for the optimisation of heat ex-
general applicability. First of all, to demonstrate the changers, it is important that the method respect the
importance of the interfacial effects in the data, Fig. 6 characteristic trends in the data, i.e. the effect of indi-
depicts a comparison of the new heat transfer model vidual variables on the prediction of the local heat
without use of the interfacial roughness factor (i.e. transfer coefficient. Hence, the same data are shown in
fi ¼ 1:0) and optimised to all 425 data points of Cav- a more detailed graphical presentation below in the
allini et al. [22,23] for six refrigerants, ranging from low following graphs in which the % error f% error ¼
pressure fluids (R-236ea) to high pressure fluids (R-125, 100% ðapred ameas Þ=ameas g is plotted versus the im-
R-410A and R-32). For this case, the optimum values of portant parameters in the model: vapor quality x, void
c and n are 0.0016 and 0.8585. In comparison, Fig. 7 fraction e, liquid film thickness d, liquid Reynolds
shows the same data including fi where the optimal number ReL , reduced pressure pred , mass velocity G, tube
values are those cited in the previous section. As can be diameter d, flow regime, and interfacial roughness factor
visually noted, the inclusion of the interfacial roughness fi . Hence, positive values represent over prediction and
factor significantly improves accuracy. negative values represent under prediction.
Fig. 8 depicts a comparison of the new heat transfer Fig. 9 depicts the data plotted versus vapor quality
model to all data, except the hydrocarbon data of Kim where the % error is quite evenly distributed over the
et al. [26]. There are eleven fluids represented with a total range of vapor qualities. This means that the model is
of 1850 data points. Based on all the data points in Fig. correctly capturing the slope of atp vs. x as G changes.
8 from these numerous different test facilities, about The scatter is larger at very high and very low vapor
85.0% are predicted within 20%. A comparison to the qualities where measurements typically have larger er-
hydrocarbon data is shown in a later section. rors or may include desuperheating or subcooling effects
as mentioned earlier.
Fig. 10 presents the data plotted versus void fraction.
6. Parametric study on accuracy As void fraction increases rapidly with vapor quality,
refer for example to Fig. 4 (Part 1), most of the data is in
Figs. 7 and 8 provide only a statistical view of the the high void fraction range. Even so, the % errors are
accuracy of the new model. However, in order to be reasonably well distributed over the range. Data at high
3376 J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387
void fractions tend to be the most difficult to predict Fig. 13 depicts the important comparison of the new
because a very small change of 0.005 in void fraction has model to test data versus reduced pressure. The lowest
a notable effect on the film thickness when the void pressure represented in the database is 78 kPa while the
fraction is larger than 0.95. Referring to Fig. 5, the in- highest is 3184 kPa. The new model works just as well at
crease in the slope of atp versus x with increasing G is the low reduced pressures as at high ones, that is from 0.02
effect of G on the void fraction via Eqs. (2) and (6) in to 0.8, while previous prediction methods are not reli-
Part 1. Other previous condensation models that used able over such a wide range.
the Zivi [37] void fraction equation, which is indepen- Fig. 14 shows the % errors plotted versus mass ve-
dent of G, therefore introduced numerous empirical locity. The range in mass velocities here is very large, 24–
correction factors to account for this trend, while the 1022 kg/(m2 s), and the new model predicts the entire
present model does not require these. range with good accuracy. The band of errors is some-
Fig. 11 shows the data plotted versus the liquid what larger at low mass velocities since these flows are in
film thickness. The values of d in the database range the stratified-wavy and fully stratified regimes, or in
from as low as 0.008 mm (only 8 lm!) up to as high as annular or intermittent flow near the transition, where
8 mm (a ratio of 1000–1). The strong deviations for the prediction of the heat transfer coefficient is sensitive
R-22 at low values are the high vapor quality data of to the calculation of the dry angle and the Gwavy flow
Kim (see comments later on his data). The experimen- pattern transition, respectively.
tal data at very high vapor qualities, which result in Fig. 15 illustrates the prediction errors as a function
the very small film thicknesses, will be affected by any of tube internal diameter. The range of internal diame-
pre-existing condensate formed during desuperheating ters represented is very broad, i.e. from 3.1 to 21.4 mm,
the vapor as mentioned earlier, which will cause the which covers nearly all the sizes of the heat transfer
model to over predict the measured heat transfer coef- tubes used in industrial practice. The predictions for
ficients. most of the tube sizes are pretty well centered around 0%
Fig. 12 depicts a comparison versus the liquid Rey- error. At the smallest diameter, the capillary effects in
nolds number, which is a key parameter in calculating the flow pattern map on flow pattern transitions and
ac . The experimental range in ReL is from 300 to 85,000. heat transfer may start to play a role, since this size may
The deviations in the data are well centered around the be in the mesoscale between macrochannels and micro-
0% error line when plotted versus this parameter. channels.
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3377
Fig. 16 shows the breakdown of how the new model very old data that are available in the mist flow regime
works by individual flow regime (S ¼ fully stratified for R-12 (21 points) at 757 and 1532 kg/(m2 s) and R-22
flow, SW ¼ stratified-wavy flow, I ¼ intermittent flow, (2 points) at 1002 kg/(m2 s) from Travis et al. [12],
A ¼ annular flow and MF ¼ mist flow). First of all, it is classifying their data using the mist flow transition
seen that the method works about equally well for all the equation of the flow pattern map in Part 1. These mist
flow regimes, as indicated by how the data scatter flow heat transfer coefficients are predicted reasonably
around the 0% error line. The stratified regime is the well, under predicting their values by about 15–20%.
only one a little off center and those data are some of the However, while it is interesting to see that the annular
most difficult to predict and measure (e.g. it is difficult to flow heat transfer model seems to work surprisingly well,
maintain steady-state conditions and get good energy not enough data are available to develop a separate mist
balances at these very low mass velocities and also the flow heat transfer model at present.
variation in the falling film heat transfer coefficient Fig. 17 shows the range of interfacial roughness
around the perimeter of the tube may not be captured factor fi in the database and the % error plotted versus
correctly unless 8–10 thermocouples are used). Also, it is this parameter. The test data have also been plotted
seen that applying the annular flow heat transfer struc- versus the wall temperature difference, (Tsat Tw ), but
ture to intermittent flow works just as well as for annular these are not shown here. The plot shows that the %
flow itself. error tends to increase as the temperature difference
Regarding mist flow, which was not originally one of becomes smaller, similar to the propagation of error in
the flow regimes planned to be modelled here, applying the experiments.
the annular flow heat transfer structure (h ¼ 0) gives a
surprisingly good prediction for these few data (nine
points) that are above the mist flow transition boundary 7. Comparison to hydrocarbons
(Gmist ). Apparently, what this means physically is that
reformation of the condensate film is very rapid on the Addressing now condensation of hydrocarbons, such
wall where liquid has been stripped off into the mist. Not data are only available from a single source, Kim et al.
many data are often measured at this high of mass ve- [26]. In addition to their tests on R-22, they tested
locity, so we have also compared the new model to some propane, n-butane, iso-butane and propylene in an
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3381
8.0 mm tube. Their experimental technique is similar to we simply eliminate all the Kim data for mass velocities
others and they quote good experimental accuracy. Fig. less than 100 kg/(m2 s), where his data deviate from
18 shows their data plotted versus vapor quality, where all others (refer to Fig. 20 with respect to predictions),
the predictions are much poorer for some of the hydro- then the model retains its high accuracy also for hydro-
carbons than for R-22, and Fig. 19 plots their data sets carbons.
for their lowest mass velocity for each of their five fluids.
It is seen that their test data exhibit an unusual levelling
off or even a minimum at high vapor qualities, which is 8. Statistical comparison
not seen in any of the other data sets in the database for
refrigerants, e.g. compare these trends to Fig. 5 at high Table 2 provides a statistical summary of the com-
vapor qualities. Hence, there seems to be an experi- parison of the new heat transfer model to the experi-
mental problem with the Kim data in the high vapor mental database. The data are classified by flow regime
quality range. Also, Fig. 20 shows all their data plotted to show their distribution. The errors reported in Cav-
versus mass velocity. It is seen that their data also ex- allini et al. [20] for the comparison of their method to
hibit a strong deviation only at low mass velocities, for parts of the current database are also shown in brackets
those below about 100–120 kg/(m2 s). Hence, again there for comparison purposes. They did not compare their
appears to be an unidentified experimental problem (for method to the hydrocarbon data nor to the Fujii data.
example, energy balances or flow instabilities as men- Statistically, the two methods give nearly the same ac-
tioned earlier) with data in this lower flow range, com- curacy while the new model here is also shown to work
pared to the earlier comparison in Fig. 14, which showed well for the data of Fujii and Liebenberg for refrigerants
good agreement with numerous independent data sets at and for the hydrocarbon data of Kim. The values in the
low G. Thus, overall, the new heat transfer model seems table for the hydrocarbons are not really representative
to work well for hydrocarbons in the range that the Kim since all the data were included, even those with the
data follow the expected trends of the other data sets, unusual trends pointed out earlier.
for which the large majority are predicted within 20%. In summary, the new heat transfer model involves
Compared to all the refrigerant data plus all KimÕs only six basic equations (Eqs. (2), (6), (7), (15) or (16),
hydrocarbon data (2771 points), the new model predicts (17) or (18) and the void fraction from Part 1) plus
75% of the data to within 20%. On the other hand, if auxiliary equations to define dimensionless numbers and
3384
Statistical information by flow regime and source
Author Fluid Present model (Cavallini et al. model)
Number of points Mean error Arithmetic error Standard deviation
S SW I A MF S SW I A MF S SW I A MF S SW I A MF
Cavallini R22 1 21 33 51 7 13 7 7 8 )13 )6 )6 0 9 7 7
)8 ()5)
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387
106 (106) 8 (5) 8 (3)
R134a 1 19 23 31 32 11 7 8 32 1 1 8 0 13 8 5
74 (74) 9 (4) 4 (4) 10 (5)
R410A 11 20 22 9 9 13 2 1 12 10 10 7
53 (53) 11 (6) 6 (5) 10 (5)
R125 25 25 19 4 12 5 11 4 )9 1 4 4 10 6 11 2
73 (73) 9 (5) )2 (0) 10 (6)
R236ea 14 7 45 6 18 11 4 18 10 7 5 7
66 (66) 11 (5) 10 (2) 8 (7)
R32 10 19 24 8 9 12 )1 3 10 9 10 8
53 (53) 10 (5) 5 (4) 10 (4)
Dobson R22 11 62 81 92 11 17 19 12 11 )15 )19 )11 4 13 6 6
& Chato 246 (246) 15 (12) )14 ()8) 10 (12)
R134a 10 76 44 66 8 10 13 12 8 )7 )11 )11 4 10 12 8
196 (196) 11 (11) )8 ()8) 11 (9)
R410A 9 21 40 36 23 14 14 10 23 4 )14 )10 8 17 9 12
106 (106) 14 (12) )6 ()9) 16 (12)
R32/R125(60/40%) 17 46 33 14 21 13 6 )21 )13 15 6 9
96 (96) 17 (12) )13 ()6) 13 (13)
Tang R22 42 48 12 5 )12 )5 7 3
90 (73) 8 (12) )8 ()12) 6 (7)
R134a 34 42 15 4 12 3 13 4
76 (66) 9 (8) 7 (0) 10 (11)
R410A 39 11 2 7 2 3 4 1 )3 9 2 1
52 (34) 5 (14) 3 (1) 8 (16)
Zhang R22 10 13 10 7 )7 )2 10 8
23 (23) 8 (9) )4 (5) 10 (11)
R134a 18 20 8 11 1 11 11 10
38 (38) 10 (11) 7 (10) 11 (8)
R404A 9 7 14 6 )14 )6 7 7
16 (16) 11 (6) )11 ()3) 8 (7)
Chitti R410A 20 21 8 10 )4 9 11 9
&Anand 41 (12) 9 (14) 3 (7) 12 (26)
Wijaya R410A 10 4 17 17 )17 )17 2 2
14 (7) 17 (27) )17 ()27) 2 (1)
Fujii R11 3 40 3 20 3 45 14 9 11 20 45 )4 4 )5 )20 25 17 12 12 6
69 14 )2 19
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3385
12
12
13
6
11
5
11
9
13
18
16
32
17
16
from its tubular flow value of 0.4 to its film flow value of
0.5, similar to Labuntsov [33]. Thus, the use of the flow
7
4
10
12
32
20
16
pattern map to categorize the flow regimes, the simpli-
fied flow structures to describe the flow regimes, and a
9
23
)4
12
19
45
22
equations.
5 (12)
31
23
41
9
)8
)5
3
)5
)2
10
65
12
0
0
65
39
)9
)6
)14
19
45
22
5
8
41
6
18
23
3
10
12
65
14
13
65
39
13
6
125
248
15
62
65
24
flow regime, goes then into the annular flow regime and
225 (225)
144
147
135
39
48
65
9
50
152
24
4
26
35
95
76
144
going into their slug flow regime. Also of note, the heat
transfer coefficient would exhibit a small peak in the SW
zone at 200 kg/(m2 s) if the same simulations were re-
peated for Fig. 21 at a low heat flux, such as 10 kW/m2 ,
iso-Butane
n-Butane
Propane
Propene
R22
R22
Liebenberg
mixtures or for condensation in the presence of non- obtained in nine different laboratories. The new model
condensable gases by use of the Bell and Ghaly [38] has so far been tested for the following range of condi-
method. This method essentially consists of assuming tions: mass velocities from 24 to 1022 kg/(m2 s), vapor
two thermal resistances in series: the first resistance is for qualities from 0.03 to 0.97, reduced pressures from 0.02
convective heat transfer in the vapor-phase from the to 0.80 and tube internal diameters from 3.1 to 21.4 mm.
bulk vapor temperature to the temperature at the vapor– Overall, the method predicts 85% of the refrigerant heat
liquid interface and the second resistance is across the transfer coefficients in the database (1850 points) to
condensate film itself, given by 1=atp . Comparison to within 20% and predicts 75% of the refrigerant plus
such test data is beyond the present scope and will be hydrocarbon heat transfer coefficients in the database
treated in a future study. (2771 points) to within 20%.
A new general flow pattern based heat transfer model A. Cavallini participated in this project as an ER-
for condensation inside horizontal, plain tubes has been COFTAC Scientific Visitor to the Laboratory of Heat
proposed here based on the same simplified flow struc- and Mass Transfer in Lausanne and we are grateful to
tures of the flow regimes used in the flow boiling model him for providing the majority of the database used in
of Kattan et al. [3]. The condensation heat transfer this project.
model includes the effect of interfacial roughness of the
liquid–vapor on heat transfer. The model resorts to very
few empirical constants and exponents compared to References
other previous methods. The model accurately predicts
local condensation heat transfer coefficients for the fol- [1] N. Kattan, J.R. Thome, D. Favrat, Flow boiling in
lowing flow regimes: annular, intermittent, stratified- horizontal tubes: part 1––development of a diabatic two-
wavy, fully stratified and mist flow. It accurately predicts phase flow pattern map, J. Heat Transfer 120 (1998) 140–
a very broad experimental database for fifteen fluids 147.
J.R. Thome et al. / International Journal of Heat and Mass Transfer 46 (2003) 3365–3387 3387
[2] N. Kattan, J.R. Thome, D. Favrat, Flow boiling in [21] L. Friedel, Improved friction pressure drop correlations for
horizontal tubes: part 2––new heat transfer data for five horizontal and vertical two-phase pipe flow, European
refrigerants, J. Heat Transfer 120 (1998) 148–155. Two-phase Flow Group Meeting, Ispra, Italy, 1979, Paper
[3] N. Kattan, J.R. Thome, D. Favrat, Flow boiling in E2.
horizontal tubes: part 3––development of a new heat [22] A. Cavallini, D. Del Col, G.A. Longo, L. Rossetto,
transfer model based on flow pattern, J. Heat Transfer 120 Condensation heat transfer with refrigerants, in: Proceed-
(1998) 156–165. ings of the Two-Phase Flow Modelling and Experimenta-
[4] H. Jaster, P.J. Kosky, Condensation heat transfer in a tion Conference, ETS, Pisa, vol. 1, 1999, pp. 71–88.
mixed flow regime, Int. J. Heat Mass Transfer 19 (1976) [23] A. Cavallini, D. Del Col, G.A. Longo, L. Rossetto,
95–99. Experimental investigation on condensation heat transfer
[5] F.W. Dittus, M.L.K. Boelter, Heat transfer in automobile and pressure drop of new HFC refrigerants (R134a, R125,
radiators of the tubular type, University of California R32, R410A, R236ea) in a horizontal tube, Int. J. Refrig.
Publications on Engineering, Berkeley, CA 2(13), 1930, 24 (2001) 73–87.
p. 443. [24] M. Zhang, A new equivalent Reynolds number model for
[6] W.W. Akers, H.A. Deans, O.K. Crosser, Condensing heat vapour shear-controlled condensation inside smooth and
transfer within horizontal tubes, Chem. Eng. Progr. Symp. micro-fin tubes, Ph.D. Thesis, Pennsylvania State Univer-
Series 55 (1959) 171–176. sity, University Park, PA, 1998.
[7] W.W. Akers, H.F. Rosson, Condensation inside a hori- [25] M.S. Chitti, N.K. Anand, Condensation heat transfer
zontal tube, Chem. Eng. Progr. Symp. Series 56 (1960) inside smooth horizontal tubes for R-22 and R-32/125
145–149. mixture, Int. J. HVAC&R Res. 2 (1996) 79–101.
[8] ASHRAE Handbook––Fundamentals, ASHRAE, At- [26] M.S. Kim, Y.S., Chang, S.T. Ro, Performance and heat
lanta, GA, 2001, 4–10. transfer of Hydrocarbon refrigerants and their mixtures in
[9] A. Cavallini, R. Zecchin, High velocity condensation of a heat pump system, in: Proceedings of IIR-IIF Meeting of
organic refrigerants inside tubes, in: Proceedings 13th Commissions B1, B2, E1 and E2 Applications for Natural
International Congress of Refrigeration, vol. 2, 1971, Refrigerants, Aarhus, Denmark, 1996, pp. 477–486.
pp. 193–200. [27] H. Wijaya, M.W. Spatz, Two-phase flow heat transfer and
[10] A. Cavallini, R. Zecchin, A dimensionless correlation for pressure drop characteristics of R-22 and R-32/125, ASH-
heat transfer in forced convection condensation, in: Pro- RAE Trans. 101 (1) (1995) 1020–1027.
ceedings Sixth International Heat Transfer Conference, [28] T. Fujii, personal communication to A. Cavallini, 1993.
vol. 3, 1974, pp. 309–313. [29] L. Liebenberg, Condensation performance in smooth and
[11] P.J. Kosky, F.W. Staub, Local condensing heat transfer enhanced tubes, Ph.D. thesis, Department of Mechanical
coefficients in the annular flow regime, AIChE J. 17 (1971) Engineering, Rand Afrikaans University, 2002.
1037–1043. [30] O. Z€ urcher, J.R. Thome, D. Favrat, Evaporation of
[12] D.F. Traviss, M.W. Rohsenow, A.B. Baron, Forced ammonia in a smooth horizontal tube: heat transfer
convection inside tubes: a heat transfer equation for measurements and predictions, J. Heat Transfer 121
condenser design, ASHRAE Trans. 79 (1972) 157–165. (1999) 89–101.
[13] D. Butterworth, Film condensation of pure vapor, in: Heat [31] L. Wojtan, T. Ursenbacher, J.R. Thome, Technique for
Transfer Design Handbook, Begell House, New York, measurement of void fraction in horizontal tubes, in:
1993. Compact Heat Exchangers and Enhancement Technology
[14] Condensation within horizontal tubesVDI Heat Atlas, D.5, for the Process Industries––2001, Begell House, New York,
VDI-Verlag GmbH, D€ usseldorf, 1993, pp. 13–16. 2001, pp. 353–360.
[15] Kondensation an waagerechten Rohren, VDI-W€armeatlas [32] Z. Rouhani, E. Axelsson, Calculation of void volume
8. Auflage 1997, D4, VDI-Verlag GmbH, D€ usseldorf, fraction in the subcooled and quality boiling regions, Int.
1997, 7–9. J. Heat Mass Transfer 13 (1970) 383–393.
[16] M.M. Shah, A general correlation for heat transfer during [33] D.A. Labuntsov, Heat transfer in film condensation of
film condensation inside pipes, Int. J. Heat Mass Transfer steam on a vertical surface and horizontal tubes, Tep-
22 (1979) 547–556. loenergetika 4 (7) (1957) 72–80.
[17] L. Tang, Empirical study of new refrigerant flow conden- [34] S.S. Kutateladze, Fundamentals of Heat Transfer, Aca-
sation inside horizontal smooth and micro-fin tubes. Ph.D. demic Press, New York, 1963.
Thesis, University of Maryland at College Park, 1997. [35] W. Nusselt, Die oberflachenkondensation des wasser-
[18] H. Haraguchi, S. Koyama, T. Fujii, Condensation of dampfes, Z. Ver. Dt. Ing. 60 (1916) 541–546, 569–575.
refrigerants HCFC22, HFC134a and HCFC123 in a [36] D. Biberg, An explicit approximation for the wetted angle
horizontal smooth tube (2nd report, proposal of empirical in two-phase stratified pipe flow, Canadian J. Chemical
expressions for local heat transfer coefficient), Trans. Engineering 77 (1999) 1221–1224.
JSME 60 (574) (1994) 245–252. [37] S.M. Zivi, Estimation of steady state void fraction by
[19] M.K. Dobson, J.C. Chato, Condensation in smooth means of minimum entropy production, J. Heat Transfer
horizontal tubes, J. Heat Transfer 120 (1998) 193–213. 86 (1964) 247–252.
[20] A. Cavallini, G. Censi, D. Del Col, L. Doretti, G.A. [38] K.J. Bell, M.A. Ghaly, An approximate generalized design
Longo, L. Rossetto, In-tube condensation of halogenated method for multicomponent/partial condenser, AIChE
refrigerants, ASHRAE Trans. 108 (1) (2002), Paper 4507. Symp. Ser. 69 (1973) 72–79.