Sodium Hypochlorite MSDS

Safety data sheet
according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
Sodium hypochlorite solution 12 % Cl, technical
article number: 9062 date of compilation: 14.07.2016

Version: 4.0 en Revision: 10.06.2020
Replaces version of: 25.07.2019
Version: (3)
SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Identification of the substance Sodium hypochlorite solution
Article number 9062
Registration number (REACH) 01-2119488154-34-xxxx
Index No 017-011-00-1
EC number 231-668-3
CAS number 7681-52-9
1.2 Relevant identified uses of the substance or mixture and uses advised against
Identified uses: laboratory chemical
laboratory and analytical use
1.3 Details of the supplier of the safety data sheet
Carl Roth GmbH + Co KG
Schoemperlenstr. 3-5
D-76185 Karlsruhe
Germany
Telephone: +49 (0) 721 - 56 06 0

Telefax: +49 (0) 721 - 56 06 149
e-mail: sicherheit@carlroth.de
Website: www.carlroth.de
Competent person responsible for the safety data : Department Health, Safety and Environment
sheet:
e-mail (competent person): sicherheit@carlroth.de
1.4 Emergency telephone number
Emergency information service Poison Centre Munich: +49/(0)89 19240
SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008 (CLP)
Classification acc. to GHS
Section Hazard class Hazard class and cat- Hazard

egory state-
ment
2.16 substance or mixture corrosive to metals (Met. Corr. 1) H290
3.2 skin corrosion/irritation (Skin Corr. 1B) H314
3.3 serious eye damage/eye irritation (Eye Dam. 1) H318
4.1A hazardous to the aquatic environment - acute hazard (Aquatic Acute 1) H400
4.1C hazardous to the aquatic environment - chronic hazard (Aquatic Chronic 2) H411
Malta (en) Page 1 / 17

Safety data sheet
article number: 9062

Supplemental hazard information
Code Supplemental hazard information
EUH031 contact with acids liberates toxic gas
2.2 Label elements

Labelling according to Regulation (EC) No 1272/2008 (CLP)
Signal word Danger
Pictograms
GHS05, GHS09
Hazard statements
H290 May be corrosive to metals
H314 Causes severe skin burns and eye damage
H410 Very toxic to aquatic life with long lasting effects
Precautionary statements
Precautionary statements - prevention
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
Precautionary statements - response
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin
with water [or shower].
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
Supplemental hazard information
EUH031 Contact with acids liberates toxic gas.
Hazardous ingredients for labelling: Sodium hypochlorite, solution … % Cl active, Sodi-
um hydroxide
Labelling of packages where the contents do not exceed 125 ml
Signal word: Danger
Symbol(s)
H314 Causes severe skin burns and eye damage.

P280 Wear protective gloves/protective clothing/eye protection/face protection.
P301+P330+P331 IF SWALLOWED: rinse mouth. Do NOT induce vomiting.
P303+P361+P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water or shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to
do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
EUH031 Contact with acids liberates toxic gas.

Safety data sheet

contains: Sodium hypochlorite, solution … % Cl active, Sodium hydroxide
2.3 Other hazards

There is no additional information.
SECTION 3: Composition/information on ingredients

3.2 Mixtures
Description of the mixture
Composition/information on ingredients.
Name of sub- Identifier wt Classification Pictograms Specific Conc. M-Factors
stance % acc. to 1272/ Limits
2008/EC
Sodium hypo- CAS No 5 –  Skin Corr. 1B / H314 M-factor (acute) =

chlorite, solution 7681-52-9 15 Eye Dam. 1 / H318 10.0
… % Cl active Aquatic Acute 1 /
EC No H400
231-668-3 Aquatic Chronic 1 /
H410
Index No EUH031
017-011-00-1
REACH Reg.
No
01-
2119488154-
34-xxxx
Sodium hydrox- CAS No 1 –  Met. Corr. 1 / H290 Skin Corr. 1A;
ide 1310-73-2 < 2 Skin Corr. 1A / H314 H314: C ≥ 5 %
Eye Dam. 1 / H318 Skin Corr. 1B;
EC No H314: 2 % ≤ C < 5
215-185-5 %
Skin Irrit. 2;
Index No H315: 0,5 % ≤ C <
011-002-00-6 2%
Eye Dam. 1;
REACH Reg. H318: C ≥ 2 %
No Eye Irrit. 2; H319:
01- 0,5 % ≤ C < 2 %
2119457892-
27-xxxx
Remarks
For full text of Hazard- and EU Hazard-statements: see SECTION 16.
SECTION 4: First aid measures

4.1 Description of first aid measures
General notes
Take off immediately all contaminated clothing. Self-protection of the first aider.
Following inhalation
Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice.

Safety data sheet

Following skin contact
After contact with skin, wash immediately with plenty of water. Immediate medical treatment re-
quired because corrosive injuries that are not treated are hard to cure.
Following eye contact
In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold-
ing eyelids apart and consult an ophthalmologist. Protect uninjured eye.
Following ingestion
Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed
danger of perforation of the esophagus and the stomach (strong corrosive effects).
4.2 Most important symptoms and effects, both acute and delayed
Corrosion, Cough, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Dyspnoea
4.3 Indication of any immediate medical attention and special treatment needed
none
SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing media

Co-ordinate fire-fighting measures to the fire surroundings
water spray, foam, dry extinguishing powder, carbon dioxide (CO₂)
Unsuitable extinguishing media
water jet
5.2 Special hazards arising from the substance or mixture
Non-combustible.
Hazardous combustion products
In case of fire may be liberated: hydrogen chloride (HCl), chlorine (CI₂), May produce toxic fumes of
carbon monoxide if burning.
5.3 Advice for firefighters
Do not allow firefighting water to enter drains or water courses. Fight fire with normal precautions
from a reasonable distance. Wear self-contained breathing apparatus. Wear full chemical protective
clothing.
SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
For non-emergency personnel

Provision of sufficient ventilation. Use personal protective equipment as required. Avoid contact with
skin, eyes and clothes. Do not breathe vapour/spray.

Safety data sheet

6.2 Environmental precautions
Keep away from drains, surface and ground water. Retain contaminated washing water and dispose
of it.
6.3 Methods and material for containment and cleaning up
Advice on how to contain a spill
Covering of drains.
Advice on how to clean up a spill
Absorb with liquid-binding material (e.g. sand, diatomaceous earth, acid- or universal binding agents).
Other information relating to spills and releases
Place in appropriate containers for disposal. Ventilate affected area.
6.4 Reference to other sections
Hazardous combustion products: see section 5. Personal protective equipment: see section 8. Incom-
patible materials: see section 10. Disposal considerations: see section 13.
SECTION 7: Handling and storage

7.1 Precautions for safe handling
Handle and open container with care. Provide adequate ventilation.
Advice on general occupational hygiene
Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs.
7.2 Conditions for safe storage, including any incompatibilities
Protect from sunlight. Keep only in the original container. Due to gaseous decomposition products,
overpressure can occur in tightly sealed containers.
Incompatible substances or mixtures
Observe hints for combined storage.
Consideration of other advice
• Ventilation requirements
Use local and general ventilation.
• Specific designs for storage rooms or vessels
Recommended storage temperature: 15 – 25 °C.
7.3 Specific end use(s)
No information available.
SECTION 8: Exposure controls/personal protection

8.1 Control parameters
National limit values
Occupational exposure limit values (Workplace Exposure Limits)
Data are not available. Data are not available.

Safety data sheet

Relevant DNELs/DMELs/PNECs and other threshold levels
• relevant DNELs of components of the mixture
Name of sub- CAS No End- Threshold Protection Used in Exposure time
stance point level goal, route of
exposure
Sodium hypochlor- 7681-52- DNEL 1,55 mg/m³ human, inhalatory worker (in- chronic - systemic ef-
ite, solution … % Cl 9 dustry) fects
active
Sodium hypochlor- 7681-52- DNEL 3,1 mg/m³ human, inhalatory worker (in- acute - systemic ef-
ite, solution … % Cl 9 dustry) fects
active
Sodium hypochlor- 7681-52- DNEL 1,55 mg/m³ human, inhalatory worker (in- chronic - local effects
ite, solution … % Cl 9 dustry)
active
Sodium hypochlor- 7681-52- DNEL 3,1 mg/m³ human, inhalatory worker (in- acute - local effects
ite, solution … % Cl 9 dustry)
active
Sodium hydroxide 1310-73- DNEL 1 mg/m³ human, inhalatory worker (in- chronic - systemic ef-
2 dustry) fects
Sodium hydroxide 1310-73- DNEL 1 mg/m³ human, inhalatory worker (in- chronic - local effects
2 dustry)
• relevant PNECs of components of the mixture

Name of substance CAS No Endpoint Threshold level Environmental Exposure time
compartment
Sodium hypochlorite, 7681-52-9 PNEC 0,21 µg/l freshwater short-term (single in-
solution … % Cl active stance)
Sodium hypochlorite, 7681-52-9 PNEC 0,042 µg/l marine water short-term (single in-
solution … % Cl active stance)
Sodium hypochlorite, 7681-52-9 PNEC 4,69 mg/l sewage treatment short-term (single in-
solution … % Cl active plant (STP) stance)
8.2 Exposure controls

Individual protection measures (personal protective equipment)
Eye/face protection
Use safety goggle with side protection. Wear face protection.

Skin protection

Safety data sheet

• hand protection
Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374.
Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check
the resistance to chemicals of the protective gloves mentioned above together with the supplier of
these gloves. The times are approximate values from measurements at 22 ° C and permanent con-
tact. Increased temperatures due to heated substances, body heat etc. and a reduction of the effect-
ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in
doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective
breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred
to substance mixtures, they may only be considered as a guide.
• type of material
Butyl caoutchouc (butyl rubber)
• material thickness
0,5 mm.
• breakthrough times of the glove material
>480 minutes (permeation: level 6)
• other protection measures
Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is
recommended.
Respiratory protection
Respiratory protection necessary at: Aerosol or mist formation. Type: B-P2 (combined filters for acidic
gases and particles, colour code: Grey/White).
Respiratory protection necessary at: Aerosol or mist formation.
Environmental exposure controls
Keep away from drains, surface and ground water.
SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
Appearance
Physical state liquid (fluid)
Colour light yellow - light green
Odour like: chlorine
Odour threshold No data available
Other physical and chemical parameters
pH (value) 12 – 13 (20 °C)
Melting point/freezing point -25 °C
Initial boiling point and boiling range 98 °C
Flash point not determined
Evaporation rate no data available
Flammability (solid, gas) not relevant (fluid)
Explosive limits
• lower explosion limit (LEL) this information is not available

Safety data sheet

• upper explosion limit (UEL) this information is not available
Explosion limits of dust clouds not relevant
Vapour pressure 23 hPa
Density 1,22 – 1,26 g/cm³ at 20 °C
Vapour density This information is not available.

Bulk density Not applicable
Relative density Information on this property is not available.
Solubility(ies)
Water solubility miscible in any proportion
Partition coefficient
n-octanol/water (log KOW) -3,42 (20 °C)
Auto-ignition temperature Information on this property is not available.
Decomposition temperature >111 °C
Viscosity
• kinematic viscosity 2,222 mm²/s at 20 °C
• dynamic viscosity 2,8 mPa s at 20 °C

Explosive properties Shall not be classified as explosive
Oxidising properties none
9.2 Other information
There is no additional information.
SECTION 10: Stability and reactivity

10.1 Reactivity
Substance or mixture corrosive to metals.
10.2 Chemical stability
Reactivity if exposed to light. Slow decomposition of the material.
10.3 Possibility of hazardous reactions
Violent reaction with: Amines, Ammonia (NH3), Ammonia (NH3), Organic substances, Oxidisers, Re-
ducing agents, Formic acid, Acetic anhydride, Methanol, Cyanide, Dangerous/dangerous reactions
with: Acids,
=>
Release of an acute toxic gas: Chlorine
10.4 Conditions to avoid
Keep away from heat. Decompostion takes place from temperatures above: >111 °C.
10.5 Incompatible materials
different metals
10.6 Hazardous decomposition products
Hazardous combustion products: see section 5.

Safety data sheet
SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity
Shall not be classified as acutely toxic.
• Acute toxicity of components of the mixture
Name of substance CAS No Exposure route ATE
Sodium hypochlorite, solution … % Cl active 7681-52-9 oral 1.100 mg/kg
Skin corrosion/irritation
Causes severe burns.
Serious eye damage/eye irritation
Causes serious eye damage.
Respiratory or skin sensitisation
Shall not be classified as a respiratory or skin sensitiser.
Summary of evaluation of the CMR properties
Shall not be classified as germ cell mutagenic, carcinogenic nor as a reproductive toxicant
• Specific target organ toxicity - single exposure
Shall not be classified as a specific target organ toxicant (single exposure).
• Specific target organ toxicity - repeated exposure
Shall not be classified as a specific target organ toxicant (repeated exposure).
Aspiration hazard
Shall not be classified as presenting an aspiration hazard.
Symptoms related to the physical, chemical and toxicological characteristics

• If swallowed
If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects)
• If in eyes
causes burns, Causes serious eye damage, risk of blindness
• If inhaled
cough, Dyspnoea
• If on skin
causes severe burns, causes poorly healing wounds
Other information
None

Safety data sheet
SECTION 12: Ecological information

12.1 Toxicity
Toxic to aquatic life with long lasting effects.
Aquatic toxicity (acute)
Very toxic to aquatic organisms.
Aquatic toxicity (acute) of components of the mixture
Name of substance CAS No Endpoint Value Species Exposure
time
Sodium hypochlorite, 7681-52-9 EC50 35 µg/l aquatic inverteb- 48 h

solution … % Cl active rates
Sodium hypochlorite, 7681-52-9 ErC50 0,036 mg/l algae 72 h

solution … % Cl active
Sodium hydroxide 1310-73-2 EC50 40,4 mg/l water flea (Daph- 48 h

nia)
Aquatic toxicity (chronic)

May cause long-term adverse effects in the aquatic environment.
12.2 Process of degradability
The methods for determining the biological degradability are not applicable to inorganic substances.
12.3 Bioaccumulative potential
Does not significantly accumulate in organisms.
n-octanol/water (log KOW) -3,42 (20 °C)
Bioaccumulative potential of components of the mixture
Name of sub- CAS No BCF Log KOW BOD5/COD
stance
Sodium hypochlorite, 7681-52-9 -3,42 (pH value: 12,5,

solution … % Cl active 20 °C)
12.4 Mobility in soil

Data are not available.
12.5 Results of PBT and vPvB assessment
12.6 Other adverse effects
SECTION 13: Disposal considerations

13.1 Waste treatment methods
This material and its container must be disposed of as hazardous waste. Dispose of contents/contain-
er in accordance with local/regional/national/international regulations.

Safety data sheet

Sewage disposal-relevant information
Do not empty into drains. Avoid release to the environment. Refer to special instructions/safety data
sheets.
Waste treatment of containers/packagings
It is a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used.
13.2 Relevant provisions relating to waste
The allocation of waste identity numbers/waste descriptions must be carried out according to the
EEC, specific to the industry and process.
13.3 Remarks
Waste shall be separated into the categories that can be handled separately by the local or national
waste management facilities. Please consider the relevant national or regional provisions.
SECTION 14: Transport information

14.1 UN number 1791
14.2 UN proper shipping name HYPOCHLORITE SOLUTION
Hazardous ingredients Sodium hypochlorite, solution … % Cl active, Sodi-
um hydroxide
14.3 Transport hazard class(es)
Class 8 (corrosive substances)

14.4 Packing group II (substance presenting medium danger)
14.5 Environmental hazards hazardous to the aquatic environment (Sodium
hypochlorite, solution … % Cl active)
14.6 Special precautions for user
Provisions for dangerous goods (ADR) should be complied within the premises.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code
The cargo is not intended to be carried in bulk.
14.8 Information for each of the UN Model Regulations
• Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN)
UN number 1791
Proper shipping name HYPOCHLORITE SOLUTION
Particulars in the transport document UN1791, HYPOCHLORITE SOLUTION, 8, II, (E), en-
vironmentally hazardous
Class 8
Classification code C9
Packing group II
Danger label(s) 8 + "fish and tree"

Safety data sheet

Environmental hazards yes (hazardous to the aquatic environment)
Special provisions (SP) 521
Excepted quantities (EQ) E2
Limited quantities (LQ) 1L
Transport category (TC) 2
Tunnel restriction code (TRC) E
Hazard identification No 80
• International Maritime Dangerous Goods Code (IMDG)
UN number 1791
Proper shipping name HYPOCHLORITE SOLUTION
Particulars in the shipper's declaration UN1791, HYPOCHLORITE SOLUTION, (contains:
Sodium hypochlorite, solution … % Cl active, Sodi-
um hydroxide), 8, II, MARINE POLLUTANT
Class 8
Marine pollutant yes (P) (hazardous to the aquatic environment)
Packing group II
Danger label(s) 8 + "fish and tree"
Special provisions (SP) 274, 900

Limited quantities (LQ) 1L
EmS F-A, S-B
Stowage category B
Segregation group 8 - Hypochlorites
• International Civil Aviation Organization (ICAO-IATA/DGR)
UN number 1791
Proper shipping name Hypochlorite solution
Particulars in the shipper's declaration UN1791, Hypochlorite solution, 8, II
Class 8
Environmental hazards yes (hazardous to the aquatic environment)
Packing group II
Danger label(s) 8
Special provisions (SP) A3

Safety data sheet

Limited quantities (LQ) 0,5 L
SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Relevant provisions of the European Union (EU)
• Regulation 649/2012/EU concerning the export and import of hazardous chemicals (PIC)
None of the ingredients are listed.
• Regulation 1005/2009/EC on substances that deplete the ozone layer (ODS)
• Regulation 850/2004/EC on persistent organic pollutants (POP)
• Restrictions according to REACH, Annex XVII
Name of substance CAS No Wt% Type of registration Conditions No
of restric-
tion
Sodium hypochlorite solution 100 1907/2006/EC annex R3 3

XVII
Legend
R3 1. Shall not be used in:
- ornamental articles intended to produce light or colour effects by means of different phases, for example in or-
namental lamps and ashtrays,
- tricks and jokes,
- games for one or more participants, or any article intended to be used as such, even with ornamental aspects,
2. Articles not complying with paragraph 1 shall not be placed on the market.
3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or per-
fume, or both, if they:
- can be used as fuel in decorative oil lamps for supply to the general public, and,
- present an aspiration hazard and are labelled with R65 or H304,
4. Decorative oil lamps for supply to the general public shall not be placed on the market unless they conform to
the European Standard on Decorative oil lamps (EN 14059) adopted by the European Committee for Standardisa-
tion (CEN).
5. Without prejudice to the implementation of other Community provisions relating to the classification, pack-
aging and labelling of dangerous substances and mixtures, suppliers shall ensure, before the placing on the mar-
ket, that the following requirements are met:
(a) lamp oils, labelled with R65 or H304, intended for supply to the general public are visibly, legibly and indelibly
marked as follows: ‘Keep lamps filled with this liquid out of the reach of children’; and, by 1 December 2010, ‘Just a
sip of lamp oil - or even sucking the wick of lamps - may lead to life-threatening lung damage’;
(b) grill lighter fluids, labelled with R65 or H304, intended for supply to the general public are legibly and indelibly
marked by 1 December 2010 as follows: ‘Just a sip of grill lighter may lead to life threatening lung damage’;
(c) lamp oils and grill lighters, labelled with R65 or H304, intended for supply to the general public are packaged in
black opaque containers not exceeding 1 litre by 1 December 2010.
6. No later than 1 June 2014, the Commission shall request the European Chemicals Agency to prepare a dossier,
in accordance with Article 69 of the present Regulation with a view to ban, if appropriate, grill lighter fluids and
fuel for decorative lamps, labelled R65 or H304, intended for supply to the general public.
7. Natural or legal persons placing on the market for the first time lamp oils and grill lighter fluids, labelled with
R65 or H304, shall by 1 December 2011, and annually thereafter, provide data on alternatives to lamp oils and grill
lighter fluids labelled R65 or H304 to the competent authority in the Member State concerned. Member States
shall make those data available to the Commission.
Name acc. to inventory CAS No Wt% Listed in Remarks
Substances and preparations, or the 12,5 A)

breakdown products of such, which
have been proved to possess carci-
nogenic or mutagenic properties or
properties which may affect steroid-
ogenic, thyroid, reproduction or oth-
er endocrine-related functions in or
via the aquatic environment

Safety data sheet
Name acc. to inventory CAS No Wt% Listed in Remarks
Biocides and plant protection 12,5 A)

products
Legend
A) Indicative list of the main pollutants
• Restrictions according to REACH, Title VIII

None.
• List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list
none of the ingredients are listed
• Seveso Directive
2012/18/EU (Seveso III)
No Dangerous substance/hazard categories Qualifying quantity (tonnes) for the ap- Notes
plication of lower and upper-tier re-
quirements
E1 environmental hazards (hazardous to the aquatic en- 100 200 56)

vironment, cat. 1)
Notation
56) Hazardous to the Aquatic Environment in category Acute 1 or Chronic 1
• Directive 75/324/EEC relating to aerosol dispensers

Filling batch
Deco-Paint Directive (2004/42/EC)
VOC content 0%
-0 g/l
Directive on industrial emissions (VOCs, 2010/75/EU)
VOC content 0%
VOC content -0 g/l

Water content was discounted
Directive 2011/65/EU on the restriction of the use of certain hazardous substances in electrical
and electronic equipment (RoHS) - Annex II
Regulation 166/2006/EC concerning the establishment of a European Pollutant Release and
Transfer Register (PRTR)
Directive 2000/60/EC establishing a framework for Community action in the field of water policy
(WFD)
Name acc. to inventory CAS No Listed in Remarks
Substances and preparations, or the breakdown products A)

of such, which have been proved to possess carcinogenic
or mutagenic properties or properties which may affect
steroidogenic, thyroid, reproduction or other endocrine-re-
lated functions in or via the aquatic environment
Biocides and plant protection products A)
Legend
A) Indicative list of the main pollutants

Safety data sheet

Regulation 98/2013/EU on the marketing and use of explosives precursors
Regulation 111/2005/EC laying down rules for the monitoring of trade between the Community
and third countries in drug precursors
National inventories
Country National inventories Status
AU AICS all ingredients are listed
CA DSL all ingredients are listed
CN IECSC all ingredients are listed
EU ECSI all ingredients are listed
EU REACH Reg. all ingredients are listed
JP CSCL-ENCS all ingredients are listed
KR KECI all ingredients are listed
MX INSQ all ingredients are listed
NZ NZIoC all ingredients are listed
PH PICCS all ingredients are listed
TR CICR not all ingredients are listed
TW TCSI all ingredients are listed
US TSCA all ingredients are listed
Legend
AICS Australian Inventory of Chemical Substances
CICR Chemical Inventory and Control Regulation
CSCL-ENCS List of Existing and New Chemical Substances (CSCL-ENCS)
DSL Domestic Substances List (DSL)
ECSI EC Substance Inventory (EINECS, ELINCS, NLP)
IECSC Inventory of Existing Chemical Substances Produced or Imported in China
INSQ National Inventory of Chemical Substances
KECI Korea Existing Chemicals Inventory
NZIoC New Zealand Inventory of Chemicals
PICCS Philippine Inventory of Chemicals and Chemical Substances
REACH Reg. REACH registered substances
TCSI Taiwan Chemical Substance Inventory
TSCA Toxic Substance Control Act
15.2 Chemical Safety Assessment

Chemical safety assessments for substances in this mixture were not carried out.
SECTION 16: Other information

Abbreviations and acronyms
Abbr. Descriptions of used abbreviations
ADN Accord européen relatif au transport international des marchandises dangereuses par voies de navigation
intérieures (European Agreement concerning the International Carriage of Dangerous Goods by Inland Wa-
terways)
ADR Accord européen relatif au transport international des marchandises dangereuses par route (European
Agreement concerning the International Carriage of Dangerous Goods by Road)
Aquatic Acute hazardous to the aquatic environment - acute hazard

Safety data sheet
Aquatic hazardous to the aquatic environment - chronic hazard

Chronic
ATE Acute Toxicity Estimate
BCF bioconcentration factor
BOD Biochemical Oxygen Demand
CAS Chemical Abstracts Service (service that maintains the most comprehensive list of chemical substances)
CLP Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures
CMR Carcinogenic, Mutagenic or toxic for Reproduction
COD chemical oxygen demand
DGR Dangerous Goods Regulations (see IATA/DGR)
DMEL Derived Minimal Effect Level
DNEL Derived No-Effect Level
EC50 Effective Concentration 50 %. The EC50 corresponds to the concentration of a tested substance causing 50
% changes in response (e.g. on growth) during a specified time interval
EC No The EC Inventory (EINECS, ELINCS and the NLP-list) is the source for the seven-digit EC number, an identifi-
er of substances commercially available within the EU (European Union)
EINECS European Inventory of Existing Commercial Chemical Substances
ELINCS European List of Notified Chemical Substances
EmS Emergency Schedule
ErC50 ≡ EC50: in this method, that concentration of test substance which results in a 50 % reduction in either
growth (EbC50) or growth rate (ErC50) relative to the control
Eye Dam. seriously damaging to the eye
Eye Irrit. irritant to the eye
GHS "Globally Harmonized System of Classification and Labelling of Chemicals" developed by the United Nations
IATA International Air Transport Association
IATA/DGR Dangerous Goods Regulations (DGR) for the air transport (IATA)
ICAO International Civil Aviation Organization
IMDG International Maritime Dangerous Goods Code
index No the Index number is the identification code given to the substance in Part 3 of Annex VI to Regulation (EC)
No 1272/2008
log KOW n-octanol/water
MARPOL International Convention for the Prevention of Pollution from Ships (abbr. of "Marine Pollutant")
Met. Corr. substance or mixture corrosive to metals
M-factor means a multiplying factor. It is applied to the concentration of a substance classified as hazardous to the
aquatic environment acute category 1 or chronic category 1, and is used to derive by the summation meth-
od the classification of a mixture in which the substance is present
NLP No-Longer Polymer
PBT Persistent, Bioaccumulative and Toxic
PNEC Predicted No-Effect Concentration
REACH Registration, Evaluation, Authorisation and Restriction of Chemicals

Safety data sheet
RID Règlement concernant le transport International ferroviaire des marchandises Dangereuses (Regulations
concerning the International carriage of Dangerous goods by Rail)
Skin Corr. corrosive to skin
Skin Irrit. irritant to skin
SVHC Substance of Very High Concern
VOC Volatile Organic Compounds
vPvB very Persistent and very Bioaccumulative
Key literature references and sources for data

- Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU
- Regulation (EC) No. 1272/2008 (CLP, EU GHS)
- Dangerous Goods Regulations (DGR) for the air transport (IATA)
- International Maritime Dangerous Goods Code (IMDG)
List of relevant phrases (code and full text as stated in chapter 2 and 3)
Code Text
H290 may be corrosive to metals
H314 causes severe skin burns and eye damage
H318 causes serious eye damage
H400 very toxic to aquatic life
H410 very toxic to aquatic life with long lasting effects
H411 toxic to aquatic life with long lasting effects
Disclaimer
The above information describes exclusively the safety requirements of the product and is based on
our present-day knowledge. The information is intended to give you advice about the safe handling of
the product named in this safety data sheet, for storage, processing, transport and disposal. The in-
formation cannot be transferred to other products. In the case of mixing the product with other
products or in the case of processing, the information on this safety data sheet is not necessarily val-
id for the new made-up material.

Sodium Hypochlorite MSDS

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Safety data sheet

according to Regulation (EC) No. 1907/2006 (REACH), amended by 2015/830/EU

Sodium hypochlorite solution 12 % Cl, technical

article number: 9062 date of compilation: 14.07.2016

SECTION 1: Identification of the substance/mixture and of the company/

Telephone: +49 (0) 721 - 56 06 0

SECTION 2: Hazards identification

Classification acc. to GHS

Section Hazard class Hazard class and cat- Hazard

2.16 substance or mixture corrosive to metals (Met. Corr. 1) H290

3.2 skin corrosion/irritation (Skin Corr. 1B) H314

3.3 serious eye damage/eye irritation (Eye Dam. 1) H318

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

EUH031 contact with acids liberates toxic gas

2.2 Label elements

Signal word Danger

H314 Causes severe skin burns and eye damage.

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Sodium hypochlorite solution 12 % Cl, technical

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2.3 Other hazards

SECTION 3: Composition/information on ingredients

Sodium hypo- CAS No 5 – Skin Corr. 1B / H314 M-factor (acute) =

SECTION 4: First aid measures

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

SECTION 5: Firefighting measures

Suitable extinguishing media

SECTION 6: Accidental release measures

For non-emergency personnel

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

SECTION 7: Handling and storage

SECTION 8: Exposure controls/personal protection

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

• relevant PNECs of components of the mixture

8.2 Exposure controls

Use safety goggle with side protection. Wear face protection.

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

SECTION 9: Physical and chemical properties

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

Vapour density This information is not available.

• dynamic viscosity 2,8 mPa s at 20 °C

SECTION 10: Stability and reactivity

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Sodium hypochlorite solution 12 % Cl, technical

article number: 9062

SECTION 11: Toxicological information

Sodium hypochlorite, solution … % Cl active 7681-52-9 oral 1.100 mg/kg

Symptoms related to the physical, chemical and toxicological characteristics

Sodium hypo- CAS No 5 –  Skin Corr. 1B / H314 M-factor (acute) =