Safety Data Sheet

Endbac Sanitizing Tablets

Revision: 2017-12-29 Version: 06.1

SECTION 1: Identification of the substance/mixture and of the company/undertaking

1.1 Product identifier
Trade name: Endbac Sanitizing Tablets

1.2 Recommended use and restrictions on use

For professional and industrial use only.

1.3 Details of the supplier of the safety data sheet

Diversey Egypt Ltd

Contact details
Square 1258d, 1st Plot,
El Akhbar St., Sheraton Bldgs.,
Heliopolis, Cairo

SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
EUH031
Serious eye irritation, Category 2
Acute aquatic toxicity, Category 1
Chronic aquatic toxicity, Category 1

2.2 Label elements

Signal word: Warning.

Hazard statements:
EUH031 - Contact with acids liberates toxic gas.
H319 - Causes serious eye irritation.
H410 - Very toxic to aquatic life with long lasting effects.

2.3 Other hazards

No other hazards known.

SECTION 3: Composition/information on ingredients

3.1 Substances / Mixtures

Ingredient(s) CAS number EC number Classification Weight percent

troclosene sodium 2893-78-9 220-767-7 Ox. Sol. 2 (H272) 30-50
EUH031
Acute Tox. 4 (H302)
STOT SE 3 (H335)
Eye Irrit. 2 (H319)
Aquatic Acute 1 (H400)
Aquatic Chronic 1
(H410)
adipic acid 124-04-9 204-673-3 Eye Irrit. 2 (H319) 20-30

* Polymer.
Workplace exposure limit(s), if available, are listed in subsection 8.1.
For the full text of the H and EUH phrases mentioned in this Section, see Section 16.

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SECTION 4: First aid measures

4.1 Description of first aid measures
Inhalation: Get medical attention or advice if you feel unwell.
Skin contact: Wash skin with plenty of lukewarm, gently flowing water. If skin irritation occurs: Get medical advice
or attention.
Eye contact: Hold eyelids apart and flush eyes with plenty of lukewarm water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If irritation occurs and persists, get
medical attention.
Ingestion: Rinse mouth. Immediately drink 1 glass of water. Never give anything by mouth to an unconscious
person. Keep at rest. Immediately call a POISON CENTRE, doctor or physician.
Self-protection of first aider: Consider personal protective equipment as indicated in subsection 8.2.

4.2 Most important symptoms and effects, both acute and delayed
Inhalation: May cause bronchospasm in chlorine sensitive individuals.
Skin contact: No known effects or symptoms in normal use.
Eye contact: Causes severe irritation.
Ingestion: No known effects or symptoms in normal use.

4.3 Indication of any immediate medical attention and special treatment needed
No information available on clinical testing and medical monitoring. Specific toxicological information on substances, if available, can be found
in section 11.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Carbon dioxide. Dry powder. Water spray jet. Fight larger fires with water spray jet or alcohol-resistant foam.

5.2 Special hazards arising from the substance or mixture

No special hazards known.

5.3 Advice for firefighters

As in any fire, wear self contained breathing apparatus and suitable protective clothing including gloves and eye/face protection.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
No special measures required.

6.2 Environmental precautions

Do not allow to enter drainage system, surface or ground water. Do not allow to enter the ground/soil. Inform responsible authorities in case
undiluted product reaches drainage system, surface or ground water or the ground/soil.

6.3 Methods and material for containment and cleaning up

Collect mechanically.

6.4 Reference to other sections

For personal protective equipment see subsection 8.2. For disposal considerations see section 13.

SECTION 7: Handling and storage

7.1 Precautions for safe handling
Measures to prevent fire and explosions:
No special precautions required.

Measures required to protect the environment:

For environmental exposure controls see subsection 8.2.

Advices on general occupational hygiene:

Handle in accordance with good industrial hygiene and safety practice. Keep away from food, drink and animal feeding stuffs. Do not mix with
other products unless adviced by Diversey. Wash hands before breaks and at the end of workday. Wash face, hands and any exposed skin
thoroughly after handling. Take off immediately all contaminated clothing. Use personal protective equipment as required. Use only with
adequate ventilation. See chapter 8.2, Exposure controls / Personal protection.

7.2 Conditions for safe storage, including any incompatibilities

Store in accordance with local and national regulations. Store in a closed container. Keep only in original container.
For conditions to avoid see subsection 10.4. For incompatible materials see subsection 10.5.

7.3 Specific end use(s)

No specific advice for end use available.

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SECTION 8: Exposure controls/personal protection

8.1 Control parameters
Workplace exposure limits

Air limit values, if available:

Ingredient(s) Long term value(s) Short term value(s) Ceiling value(s)
adipic acid 5 mg/m3

Biological limit values, if available:

8.2 Exposure controls

The following information applies for the uses indicated in subsection 1.2 of the Safety Data Sheet.
If available, please refer to the product information sheet for application and handling instructions.
Normal use conditions are assumed for this section.

Recommended safety measures for handling the undiluted product:

Covering activities such as filling and transfer of product to application equipment, flasks or buckets

Appropriate engineering controls: No special requirements under normal use conditions.

Appropriate organisational controls: Avoid direct contact and/or splashes where possible. Train personnel.

Personal protective equipment

Eye / face protection: No special requirements under normal use conditions.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: Should not reach sewage water or drainage ditch undiluted.

Recommended safety measures for handling the diluted product:

Recommended maximum concentration (%): 0.5

Appropriate engineering controls: No special requirements under normal use conditions.

Appropriate organisational controls: No special requirements under normal use conditions.

Personal protective equipment

Eye / face protection: No special requirements under normal use conditions.
Hand protection: Rinse and dry hands after use. For prolonged contact protection for the skin may be necessary.
Body protection: No special requirements under normal use conditions.
Respiratory protection: No special requirements under normal use conditions.

Environmental exposure controls: No special requirements under normal use conditions.

SECTION 10: Stability and reactivity

10.1 Reactivity
No reactivity hazards known under normal storage and use conditions.

10.2 Chemical stability

Stable under normal storage and use conditions.

10.3 Possibility of hazardous reactions

No hazardous reactions known under normal storage and use conditions.

10.4 Conditions to avoid

None known under normal storage and use conditions.

10.5 Incompatible materials

Reacts with acids releasing toxic chlorine gas. Keep away from acids.

10.6 Hazardous decomposition products

Chlorine.

SECTION 11: Toxicological information

11.1 Information on toxicological effects

Mixture data:.

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Relevant calculated ATE(s):

ATE - Oral (mg/kg): >2000

Substance data, where relevant and available, are listed below:.

Acute toxicity
Acute oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
troclosene sodium LD 50 1436 Mouse Method not given
adipic acid No data
available

Acute dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/kg) time (h)
troclosene sodium No data
available
adipic acid No data
available

Acute inhalative toxicity

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
troclosene sodium No data
available
adipic acid No data
available

Irritation and corrosivity

Skin irritation and corrosivity
Ingredient(s) Result Species Method Exposure time
troclosene sodium No data available
adipic acid No data available

Eye irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
troclosene sodium No data available
adipic acid No data available

Respiratory tract irritation and corrosivity

Ingredient(s) Result Species Method Exposure time
troclosene sodium No data available
adipic acid No data available

Sensitisation
Sensitisation by skin contact
Ingredient(s) Result Species Method Exposure time (h)
troclosene sodium No data available
adipic acid No data available

Sensitisation by inhalation
Ingredient(s) Result Species Method Exposure time
troclosene sodium No data available
adipic acid No data available

CMR effects (carcinogenicity, mutagenicity and toxicity for reproduction)

Mutagenicity
Ingredient(s) Result (in-vitro) Method Result (in-vivo) Method
(in-vitro) (in-vivo)
troclosene sodium No data available No data available
adipic acid No data available No data available

Carcinogenicity
Ingredient(s) Effect
troclosene sodium No data available
adipic acid No data available

Toxicity for reproduction

Ingredient(s) Endpoint Specific effect Value Species Method Exposure Remarks and other effects
(mg/kg bw/d) time reported
troclosene sodium No data
available

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adipic acid No data

available

Repeated dose toxicity

Sub-acute or sub-chronic oral toxicity
Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
troclosene sodium No data
available
adipic acid No data
available

Sub-chronic dermal toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
troclosene sodium No data
available
adipic acid No data
available

Sub-chronic inhalation toxicity

Ingredient(s) Endpoint Value Species Method Exposure Specific effects and organs
(mg/kg bw/d) time (days) affected
troclosene sodium No data
available
adipic acid No data
available

Chronic toxicity
Ingredient(s) Exposure Endpoint Value Species Method Exposure Specific effects and Remark
route (mg/kg bw/d) time organs affected
troclosene sodium No data
available
adipic acid No data
available

STOT-single exposure
Ingredient(s) Affected organ(s)
troclosene sodium No data available
adipic acid No data available

STOT-repeated exposure
Ingredient(s) Affected organ(s)
troclosene sodium No data available
adipic acid No data available

Aspiration hazard
Substances with an aspiration hazard (H304), if any, are listed in section 3. If relevant, see section 9 for dynamic viscosity and relative density
of the product.

Potential adverse health effects and symptoms

Effects and symptoms related to the product, if any, are listed in subsection 4.2.

SECTION 12: Ecological information

12.1 Toxicity

No data is available on the mixture.

Substance data, where relevant and available, are listed below:

Aquatic short-term toxicity

Aquatic short-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
troclosene sodium No data
available
adipic acid No data
available

Aquatic short-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
troclosene sodium No data
available
adipic acid No data
available

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Aquatic short-term toxicity - algae

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (h)
troclosene sodium No data
available
adipic acid No data
available

Aquatic short-term toxicity - marine species

Ingredient(s) Endpoint Value Species Method Exposure
(mg/l) time (days)
troclosene sodium No data
available
adipic acid No data
available

Impact on sewage plants - toxicity to bacteria

Ingredient(s) Endpoint Value Inoculum Method Exposure
(mg/l) time
troclosene sodium No data
available
adipic acid No data
available

Aquatic long-term toxicity

Aquatic long-term toxicity - fish
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
troclosene sodium No data
available
adipic acid No data
available

Aquatic long-term toxicity - crustacea

Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/l) time
troclosene sodium No data
available
adipic acid No data
available

Aquatic toxicity to other aquatic benthic organisms, including sediment-dwelling organisms, if available:
Ingredient(s) Endpoint Value Species Method Exposure Effects observed
(mg/kg dw time (days)
sediment)
troclosene sodium No data
available
adipic acid No data
available

Terrestrial toxicity
Terrestrial toxicity - soil invertebrates, including earthworms, if available:

Terrestrial toxicity - plants, if available:

Terrestrial toxicity - birds, if available:

Terrestrial toxicity - beneficial insects, if available:

Terrestrial toxicity - soil bacteria, if available:

12.2 Persistence and degradability

Abiotic degradation
Abiotic degradation - photodegradation in air, if available:

Abiotic degradation - hydrolysis, if available:

Abiotic degradation - other processes, if available:

Biodegradation
Ready biodegradability - aerobic conditions
Ingredient(s) Inoculum Analytical DT 50 Method Evaluation
method
troclosene sodium OECD 301D Not readily biodegradable.
adipic acid No data available

Ready biodegradability - anaerobic and marine conditions, if available:

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Degradation in relevant environmental compartments, if available:

12.3 Bioaccumulative potential

Partition coefficient n-octanol/water (log Kow)
Ingredient(s) Value Method Evaluation Remark
troclosene sodium No data available
adipic acid No data available

Bioconcentration factor (BCF)

Ingredient(s) Value Species Method Evaluation Remark
troclosene sodium No data available
adipic acid No data available

12.4 Mobility in soil

Adsorption/Desorption to soil or sediment
Ingredient(s) Adsorption Desorption Method Soil/sediment Evaluation
coefficient coefficient type
Log Koc Log Koc(des)
troclosene sodium No data available
adipic acid No data available

12.5 Results of PBT and vPvB assessment

Substances that fulfill the criteria for PBT/vPvB, if any, are listed in section 3.

12.5 Other adverse effects

No other adverse effects known.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Waste from residues / unused The concentrated contents or contaminated packaging should be disposed of by a certified handler
products: or according to the site permit. Release of waste to sewers is discouraged. The cleaned packaging
material is suitable for energy recovery or recycling in line with local legislation.

Empty packaging
Recommendation: Dispose of observing national or local regulations.

SECTION 14: Transport information

Land transport, Sea transport (IMDG), Air transport (ICAO-TI / IATA-DGR)

14.1 UN number: 3077
14.2 UN proper shipping name:
Environmentally hazardous substance, solid, n.o.s. ( ) sodium dichloroisocyanurate anhydrous
14.3 Transport hazard class(es):
Class: 9
Label(s): 9
14.4 Packing group: III
14.5 Environmental hazards:
Environmentally hazardous: Yes
Marine pollutant: Yes
14.6 Special precautions for user: None known.
14.7 Transport in bulk according to Annex II of MARPOL and the IBC Code: The product is not transported in bulk tankers.
Other relevant information:
IMO/IMDG
EmS: F-A, S-F
Transport regulations include special provisions for dangerous goods packed in small quantities classified under UN3077 or UN3082.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture

SECTION 16: Other information

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The information in this document is based on our best present knowledge. However, it does not constitute a guarantee for any specific product
features and does not establish a legally binding contract

SDS code: MS1200021 Version: 06.1 Revision: 2017-12-29

Reason for revision:
This data sheet contains changes from the previous version in section(s):, 2, 3, 16
Full text of the H and EUH phrases mentioned in section 3:
•H272-Mayintens i
fyf
ire;oxi
diser.
•H302-Harmful i
fswallowed.
•H319-Causess eri
ousey eirr
itat
ion.
•H335-Mayc aus erespir
ator
yi r
ri
tat
ion.
•H400-Veryt
ox ictoaquaticli
fe.
•H410-Veryt
ox ictoaquaticli
fewithlonglast
i
ngeff
ect
s.
•EUH031-Cont actwit
hac idsli
beratestoxi
cgas.

Abbreviations and Acronyms

•DNEL-Deri
vedNoEf fectLimit
•PNEC-Predict
edNoEf f
ectConcent
ration
•ATE-Acut
eTox ici
tyEs ti
mate
•LC50-Let
halConc entrati
on,50% /Medi anLethalConcent
rat
ion
•LD50-Let
halDos e,50% /Medi anLethal dose
•STOT-RE-Spec i
fi
ctargetorgantoxi
city( r
epeatedexposur
e)
•STOT-SE-Specif
ictargetorgantoxi
cit
y( singl
eex posur
e)
•ECNo.-EuropeanCommuni t
yNumber

End of Safety Data Sheet

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