Chemistry PDF
Chemistry PDF
1. CHEMISTRY INTRODUCTION List of some common compounds with their common name
Pure chemical substances are composed of only one kind of matter Alumina Al2O3
and connot be split physically into more than one kind of Aquafortis Conc. HNO3
substance. Eg. Iron, water, etc. Baking soda NaHCO3
Mixture or impure chemical substance is obtained by mixing two or Blue vitriole CuSO4.5H2O
more (elements or compounds) in any ratio so that components do Borax Na2B4O7.10H2O
not lose their characters. Eg. Air, mud, clay, milk, steel, etc. Calamine ZnCO3
Physical change is temporary change in which there is slight Calomel Hg2Cl2
change in physical characters like color, aggregation state, Caustic soda / lye NaOH
electrical and magnetic conditions without bringing any change in Caustic potash KOH
the composition of molecule. Chile salt peter NaNO3
Chemical change is a permanent change in which a new chemical Cinnabar HgS
substance is formed totally with different properties and Corrosive sublimate HgCl2
compositon. Dolomite CaCO3.MgCO3
Atom is the smallest unit of an element that takes part in chemical Epsom MgSO4.7H2O
reaction and composed of three sub atomic particles: proton, Fool's gold CuFeS2
electron and neutron. Fluorspar CaF2
Atom is electrically neutral. Glauber's sat Na2SO4.IoH2O
Molecules are smallest particle of element or compound, which Glucose , fructose C6H12O6
doesnot generally participle in chemical reaction but it has free Green vitriole FeSO4.7H2O
existence. Hom silver AgCl
Term molecule was given by Avogadro. Hypo compound Na2S2O3.5H2O
Hydrolith CaH2
The name and formula of some common compounds Haematite Fe2O3
General name Chemical name Molecular formula Litharge PbO
Caustic soda Sodium hydroxide NaOH Lead vitriole PbSO4
Caustic potosh Potassium hydroxide KOH Lunar caustic AgNO3
Common salt Sodium chloride NaCl Magnetite Fe3O4
Vinegar Acetic acid CH3COOH Magnesia MgO
Lithrage Lead oxide PbO Mik of magnesia Mg(OH)2
Quick lime Calcium oxide CaO Muriatic acid Conc.HCl
Slaked lime Calcium hydroride Ca(OH)2 Nessler's reagent K2HgI4/OH-
Washing soda Sodium carbonate Na2CO3 Oil of vitriole Conc.H2SO4
Baking soda Sodium bicarbonate NaHCO3 Pearlash or potash K2CO3
Sand Silicon dioxide SiO2 Philosopher's wool (Zincite) ZnO
Marble Calcium carbonate CaCO3 Phosphine PH3
Pesticides
These substances destroy the harmful agents like insects, herbs (weeds)
fungi and rodents of crop. These are respectively called insecticides,
herbicides, fungicides and rodenticides.
Insecticides
Chlorine containing:
DDT (Dichloro-diphenyl trichloroethane)
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BHC (Benzene hexa Chloride) Anesthetics:
Chlordane, Heptachlor, Aldrin, Dialdrin They are used for producing general or local insensibility to pain &
other sensation.
Phosphorus containing: Example: Ether, Chloroform, Nitrous Oxide etc.
Phosdrin, Malathion, Parathion, Folone, Demeton
Glass
Herbicides Glass is called super cooled liquid because its molecules are in slow
2, 4 – dichlorophenoxyAcetic acid (2, 4-D) motion from higher to lower surface when placed vertically. Glass is
5 – trichlorophenoxyAcetic acid (2, 4, 5 -T) mixture of silicates but a wide variety of chemicals can be added to
give different characteristics.
Fungicides
Copper Sulphate, Copper nephthonate, 2, 4, 6 – trichloro phenol, 1. Water glass:
CuSO4 + lime water (Bordeaux mixture) Water glass is formed by melting of Silica & Sodium Carbonate and is
soluble in water.
Rodenticides:
Sodium monochloroacetate, Sodium fluoroacetate, Zinc posphide etc. Ordinary or soda glass consists of silica (50%), Sodium Carbonate
(15%), Calcium Carbonate (10%), Scrap glass (25%).
Chemicals in medicine
Drugs is a substance with an abnormal effect on certain body functions. 2. Pyrex (Borosilicate glass):
It is heat resistant glass made by adding Boron Oxide to soda glass.
Chemotherapeutic agents are used for treatment and cure of specific
disease, while pharmacodynamic agents are not specific remedies for 3. Lead crystal or optical glass or flint:
particular disease. For optical purpose, this type of glass is prepared by mixing some
quantity of Lead Oxide and Potassium Carbonate with mixture used for
Antiseptics: ordinary glass.
They prevent sepsis of wound.
Example: Savlon, Chloro-m-xylenol, Salol, Boric acid, Potassium 4. Crooke’s glass:
Permanganate, Iodine etc. It is glass containing Cerium Oxide (CeO2). It can absorb UV light, so
it is used for making goggles.
Disinfectant:
They are applied to disinfect contaminated objects, utensil, clothes etc. 5. Jana glass:
It is a mixture of Zn and Ba borosilicate and is resistant to heat, shock
Example: Chlorine, Phenol (1%), H2O2, SO2 etc. etc.
Polystyrene are polymer of styrene. It is hard but transparent glass like The molten and solid masses are mixed up and form small balls called
plastic. cement clinker. Clinker is mixed with Gypsum and grind to powder
form called portland cement. Gypsum is chemically CaSO4.2H2O and
Thermosetting plastic: is added to cement to regulate the setting of cement.
These plastic which once set at a temperature does not soften again.
Example: Bakelite The average composition of Portland cement is as follows:
Silica = 22%, Fe2O3 = 2.5%, MgO = 2.5%, CaO = 62%, SO3 = 1.5%,
Bakelite is polymer of Formaldehyde and Carbolic acid. Alumina (Al2O3) = 7.5%
Soap Less amount of lime lowers the strength of cement and the cement sets
Soap is Sodium salt of higher fatty acid with cleansing property. A very soon. If more lime is there, the cement cracks.
soap molecule has a large non-ionic hydrocarbon group and small ionic
group. Multiple Choice Questions:
246. Which of the following glass is used to make gems?
Example of soap are: Sodium Stearate (C17H35COONa), Sodium Oleate a) Hard glass b) Flint glass
(C17H33COONa), Sodium, Palmitate (C15H31COONa). c) Quartz glass d) Pyrex glass
247. Brown coloured glass is prepared by heating simple glass with:
When oil or fat is heated with Sodium Hydroxide, oil or fat molecule a) FeO b) NiO
breaks down to form sodium salt of long chain fatty acid which is soap. c) Cr2O3 d) MnO
The process of breaking oil or fat by alkali to form soap is called 248. Bakelite plastic is example of:
saponification. a) Thermoplastic b) Thermosetting
c) a and b d) None
Esterification: 249. The chemical formula of Pyrex glass is:
When Acetic acid is treated with ethylalcohol in presence of conc a) Aluminum silicate b) Aluminum boron silicate
H2SO4, we get ester and water. c) Boron silicate d) None
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250. % of silica in ordinary glass: 264. Best fertilizer is:
a) 15% b) 25% a) (NH4)3 PO4 b) Ca3 (PO4)2
c) 50% d) None c) NH2CONH2 d) None
251. PVC is example of: 265. Tincture of Iodine is used as:
a) Natural polymer b) Synthetic polymer a) Analgesic b) Antiseptic
c) a and b d) None c) Both (a) and (b) d) None
252. Which of the following glass is soluble in water? 266. Monomer of Bakelite Plastic is:
a) Ordinary b) Hard glass a) Carbolic Acid + Acetaldehyde
c) Borosilicate glass d) Water glass b) Carbolic Acid + Formaldehyde
253. Molecular formula of soap is: c) Carbolic Acid + ethanol
a) C17H35COONa b) SiO2 d) None
c) AlCl3 d) C17H35COOLi 267. Zeolites are used as:
254. P.V.C is the example of: a) Gem b) Ion-exchanger
a) Thermoplastics b) Thermosetting plastics c) Pigment d) Lubricant
c) Both a and b d) Non of the above 268. Aspirin is a drug used as:
255. Other name of hard glass is: a) antipyretic b) analgesic
a) Pyrex glass b) Ordinary glass c) antiseptic d) both a and b
c) Potash lime glass d) Soft glass 269. BHC is an example of:
256. Which one is the natural polymer? a) Fertilizer b) Antiseptic
a) Bakellite b) Rubber c) Insecticides d) None
c) PVC d) None 270. Thickening of glass at the bottom after sometime is known as:
257. Monomer of bakelite plastic is: a) Annealing b) Super cooling
a) Phenol+Acetic Acid b) Phenol+Oxalic Acid c) Hardening d) None
c) Phenol +Formalin d) None 271. Substance which bring body temperature down is called:
258. General formula of Soap is: a) Antipyretics b) Analgesics
a) RCOO Na b) RCOO Mg c) Antibiotics d) None
c) RONa d) None 272. Molecular formula of urea fertilizer is:
259. Which one is the Natural Polymer? a) (NH4)2.SO4 b) NH4NO3
a) Rubber b) Starch c) (NH4)3.PO4 d) CO(NH2)2
c) Protein d) All of them 273. Which of the following is not a use for chlorine?
260. Rubber is obtained from: a) sterilizing water b) making domestic bleaches
a) Cell Sap b) Latex c) making table salt d) manufacturing plastics
c) Ethylene d) None 274. An NPK fertilizer is made by mixing together one mole of each
261. Rough glass is: of three compounds. Which mixture contains equal number of
a) transparent b) translucent atoms of nitrogen, phosphorus and potassium?
c) opaque d) all Mixture Components
262. Pyrex glass is: 1 2 3
a) Sodium Silicate b) Sodium silicate +Ni +Cu a) K2SO4 Ca3(PO4)2 KNO3
c) Borosilicate d) None b) NH4NO3 Na2HPO4 KNO3
263. PVC is ----- Plastic. c) (NH4)2CO3 K2H PO4 Na NO3
a) Thermosetting b) Thermoplastic d) (NH4)2 SO4 Ca3(PO4)2 K2SO4
c) Both a and b d) None
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275. Which ions must be present in the fertilizer? (NH2)2CO
NH4CNO
a) NH4+ and NO3- b) NH4+ and Fe2+
c) Fe2+ and SO42- d) Fe3+ and NO3- Ammonium Cyanate Urea.
276. DDT is an example of:
a) Fertilizer b) Plastic Thus, it failed vital force theory.
c) Fibre d) Insecticide
277. Which of the following oxide imparts the green colour in the
glass? Reasons for separate study of organic and inorganic compounds
a) PbO b) Cr2O3 S.N. Organic Inorganic
c) Fe2O3 d) ZnO compounds compounds
278. Which natural resource is being depleted by the manufacture of 1. Number of The number of The number of
organic organic compounds inorganic compounds
plastics?
compounds are more than 3 are only 1 lakh.
a) air b) fossil fuels millions.
c) metal ores d) water 2. Composition They are composed They are composed of
279. In the given example, which one is detergent? of very few different elements.
a) Sodium stereate b) Alkylbenzene sulphonate elements like C, H, Eg. FeSO4.
c) DDT d) Urea O, N, S, halogen (NH4)2SO4.6H2O
280. Which of the following compound is separated by the vacuum and phosphorus. Eg. (Mohr's salt)
distillation method form the mixture? CH3COOH.
a) Ethanol b) Aniline 3. Nature of They are generally They are generally
c) Glycerol d) Diethyl ether bonds covalent. Eg ionic in nature. Eg.
(Methane) +
Na + Cl (Sodium
Chloride)
5. ORGANIC CHEMISTRY 4. Solubility They are generally They are soluble in
Organic chemistry is the chemistry of carbon compounds excluding soluble in non-polar polar solvent and
Oxides, Carbonates, bicarbonates and Hydrogen Cyanides. The solvent (eg. CCl4, insoluble in non-polar
CS2, C6H6 etc) but solvent.
immediate question is why there is anything so distinctive about
insoluble in polar
Carbon that out of all the elements, it receives the special attention. The solvent (eg. Water).
answer lies in its extra-ordinary combining power. 5. Unique or They show unique They do not show
homogeneous character due to unique character.
character catenation (self
Vital force theory:
linkage of carbon
Vital force theory states that the organic compounds can only be atoms)
produced in plants and animals by some vital force supplied by living 6. Combustibility They are generally They are generally
cells. combustible in non-combustible.
nature. Eg.
Methane, Butane
In the year 1828, Wohler prepared organic compound Urea by heating 7. Melting and They have generally They have generally
Ammonium Cyanate, an inorganic compound. boiling point low m.p. and b.p. high m.p. and b.p.
because they have because they have
covalent bond. ionic bonds.
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8. Reactivity Generally they show They show fast 6. Melting and boiling points:
slow reaction due to reaction due to In case of organic compounds the melting and boiling points are
presence of covalent presence of ionic generally low and sometimes decompose on strong heating. On the
bond. bond. other hand, inorganic compounds have high melting and boiling points
9. Isomerism They generally They generally do not and can withstand high temperature.
show isomerism. show isomerism.
Sources of Organic Compounds
Distinction of Organic Compounds: The main natural sources or organic compounds are living bodies, i.e.
1. Number: plants and animals. Numerous organic compounds are also prepared
artificially in the laboratory. The important sources of organic
The number of organic compounds available these days is more than compounds are as follows:
three million and is ever increasing. It is much more than the combined 1. From Animals: Compounds like urea, proteins, fats, vitamins,
no. of compounds available from other element. enzymes, amino acid, etc are obtained from animals.
2. Close relation: 2. From Plants: Compounds like sugar, glucose, starch, cellulose,
There exists a close relationship amongst carbon compounds whereas proteins, fats, oils, drugs, enzymes, etc are obtained from plants.
3. Petroleum and coal tar: These organic compounds are obtained
no such close relationship exists among inorganic compounds.
by decaying of animals and plants under high pressure,
temperature in the absence of air in the inner part (inner core) of
3. Catenation:
earth like petroleum, coal tar and natural gas. From these
The very unique property of carbon, which justifies its separate study is
compounds, we can get kerosene, diesel, petrol, paraffin, wax,
catenation i.e its ability to form long chains or large rings. It gives rise
benzene, phenol, pyridine, etc.
to a very large number of compounds. No other elements show
4. By artificial synthetic methods: More than 90% of organic
catenation to the extent shown by Carbon.
compounds are prepared by synthetic method like fermentation
(slow biological degradation of carbohydrate in the presence of
C C C yeast plant, low temp), destructive distillation (distillation in the
absence of air), polymerization, etc.
C C C C C C C C Example: Alcohol, Acetone, Polythene, Bakelite plastic, etc.
C C C Importance (Utilities) of Organic Chemistry
Straight chain Branched chain Rings
Organic chemistry plays important role in our daily life because the
existence of living life is not possible without organic compounds. The
4. Linkage:
remarkable importance of organic chemistry in our daily life are as
Organic compounds are generally covalent in bonding, while inorganic
follows:
compounds are mostly electrovalent in nature. Thus organic
1. Food: Food is the most essential constituents of life, which is
compounds do not ionize and do not show properties associated with
composed of mainly carbohydrates, fats, proteins, organic
electrovalent compounds.
compounds, etc.
2. Clothes: Clothing is 2nd necessary for the human beings to
5. Solubility:
survive. Natural and synthetic fibres, used to manufacture clothes
Organic compound are generally insoluble in water but soluble in
are silk, wool, cotton, polyester, rayon, teryelene, etc are organic
organic solvents like ether, alcohol, benzene etc. whereas inorganic
polymers.
compounds are insoluble in organic solvents.
3. Shelter: Straws, bamboos, woods, etc.
Alkyl group: There are two types of nomenclature systems. They are:
If one Hydrogen is less than alkane is known as alkyl group. Its general a) Trivial (traditional) or common system of nomenclature
formula is CnH2n + 1 (+yl). It is denoted by R. In the early stages of development of organic compound, there was no
For example: -CH3 (Methyl), - C2H5 (Ethyl) any systematic scientific method of naming of organic compounds. The
organic compounds were named by knowing the sources from which
Alcohol: they were obtained.
Its functional group is –OH. Its general formula is CnH2n + 1.OH
(ROH). For example: CH3OH. For example: Methane (CH4) was named as marsh gas because it was
produced in marshy (damp) places. Formic acid (HCOOH) was named
1. Monohydric alcohol: If alcohol contains one –OH group is known because it was first prepared by distillation of red ants (Latin:
as monohydric alcohol. For example: CH3OH (Methyl alcohol), formicus), similarly the name acetic acid (CH3COOH) was derived
C2H5OH (Ethyl alcohol) etc. from acetum (Latin: acetum means vinegar). Hence naming of organic
compounds without any systematic rules and structural values is called
2. Dihydric alcohol: If alcohol contains two –OH group is known as trivial or common system of nomenclature.
dihydric alcohol. For example: CH2OH CH2OH ethylene glycol
b) IUPAC System of nomenclature:
3. Trihydric alcohol: If alcohol contains three –OH group is known as In order to rationalize the system of nomenclature, an International
trihydric alcohol. Congress of Chemists (ICC) was held at Genera in 1892 and a
systematic method known as Geneva system was developed. The
Genera system was further revised from time to time for betterment of
naming system and it was extended to international union of chemistry
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(IUC) in 1930. The continuation of effort of various chemists for better a) an organic compound b) a covalent compound
understanding of nomenclature led to the development of an ideal c) an ionic compound d) an element.
worldwide system of nomenclature which is known as International 288. Which of the follwing elements does not show the allotropy?
Union of Pure and Applied Chemistry (IUPAC) system. a) C b) S8
c) P4 d) I2
289. Diamond is example of:
Multiple Choice Questions: a) Sedimentary b) Igneous
281. The reaction condition leading to best yielding of C2H5Cl is: c) Metamorphic d) None
uv light 290. Example of good conductor is:
a) C2H6(excess) + Cl2 a) Diamond b) Coal
dark room c) Graphite d) None
b) C2H6 + Cl2 291. What is CH4O?
temp a) Alkene b) Alkane
uv light c) Alcohol d) Carbohydrate
c) C2H6 + Cl2(excess) 292. General formula of cycloalkane is:
uv light a) CnH2n+2 b) CnH2n
d) C2H6 +Cl2 c) CnH2n+1 d) CnH2n-2
282. Different forms of same element, which have similar chemical 293. The general formula of diene is:
properties but different physical properties are known as: a) CnH2n+2 b) CnH2n
a) Isomerism b) Allotropy c) CnH2n-2 d) CnH2n+1
c) Polymorphism d) both b and c 294. Which of the following is not organic compound?
283. The isomer of ethanol is: a) CO2 b) CH4
a) Methanol b) Ethanol c) CCl4 d) CH3CHO
c) Dimethyl ether d) None 295. Formalin is used as:
284. The basis of C-14 dating method is that: a) Insecticides b) pesticide
a) Carbon-14 fraction is the same in all objects c) Antiseptic d) None
b) C-14 is highly unstable and is readily lost from object 296. B.H.C is used as:
c) the ratio of Carbon-14 to carbon-12 in our atmosphere has a) antiseptic b) disinfectant
always been constant. c) insecticide d) None
d) Living tissue will not absorb Carbon-14 but will absorb C-12 297. Protein is the example:
from source of carbon a) Natural polymer b) Artificial
285. Which statement about the graphite is not true? c) Man made d) none
a) it burns to form carbon dioxide. 298. Which of the following compound is not organic compound?
b) it is a carbon compound. a) CO2 b) CO
c) it is a macromolecule. c) CH4 d) Both a and b
d) it is used as lubricant. 300. What happens when sodium acetate is treated with sodium
286. In which substance is each carbon atom covalently bonded to hydroxide in presence of calciumoxide?
only three other atoms? a) Ethane gas is formed
a) carbon dioxide b) diamond b) Propane gas is formed
c) graphite d) methane c) Methane gas is formed
287. Diamond is the hardest substance in which each carbon atom is d) All of the above
bonded with four other carbon atoms. Diamond is:
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301. What is general formula of alkane? 315. Which of the following bond are found in alcohol?
a) CnH2n b) CnH2n –2 a) Electrovalent bond b) Covalent bond
c) CnH2n +1 d) CnH2n +2 c) Hydrogen bond d) b and c
302. Which of the following compound is used as anaesthesia? 316. What is the M.F. of dimethyl ether?
a) CCl4 b) CHCl3 a) C2H5OC2H5 b) CH3OC2H5
c) CH3Cl d) CH2Cl2 c) CH3OCH3 d) None of the above
303. Which of the following gas in biogas? 317. What is the boiling point of ether?
a) C2H6 b) CH4 a) 38oC b) 35oC
o
c) CO2 d) CO c) 37 C d) 36oC
304. What is the general formula of alkyl group? 318. Carbolic acid and formalin is reacted to each other, we get:
a) CnH2n+1 b) CnH2n+2 a) Polyethylene b) Polyvinyl chloride
c) CnH2n d) CnH2n-2 c) Bakelite plastic d) None of the above
305. What is the M.F. of acetylene? 319. Vital force theory was given by:
a) C2H4 b) C2H2 a) Dalton b) Lavoiser
c) C2H6 d) None of above c) Berzelius d) None
306. What is the M.F of ethanol? 320. Formation of soap and glycerol from fats in presence of alkali is
a) CH3OH b) C2H5OH due to:
c) C3H7OH d) C4H9OH a) Neutralisation b) Saponification
307. Which of the following compound is called glycol? c) Esterification d) None
a) CH2OHCH2OH b) CH2OHCHOHCH2OH 321. Structural formula of Glycerol is:
c) C2H5OH d) C4H9OH a) b)
308. What is the boiling point of alcohol? CH2OH CH2OH
a) 78.6oC b) 99oC
o
c) 80 C d) 81oC CHOH C(OH)
309. Which of the following compound is soluble in water?
a) Ethane b) Propane CH2OH CH3OH
c) Alcohol d) Ether
310. What is the functional group of ether? c) CH2OH d) None
a) -OH b) -O-
c) -NH2 d) -CO CH2OH
311. Which of the following compound is used in thermometer?
a) Ether b) Alcohol CH3OH
c) Potassium chloride d) Sodium hydroxide 322. For a particular organic compound, which of the following pairs
312. Which of the following compound is unsaturated compound? can represent the empirical and the molecular formula,
a) CH4 b) C2H6 receptively?
c) C3H8 d) C2H4 a) CH and CH4 b) CH and C6H6
313. Which of the following compound is iodoform? c) CH2 and C2H2 d) CH2 and C2H3
a) CHI3 b) CHBr3 323. IUPAC name of Acetylene gas is:
c) C3H8 d) C2H4 a) Ethane b) Ethene
314. What is the general formula of alkyne? c) Ethyne d) None
a) CnH2n-2 b) CnH2n+2
c) CnH2n d) CnH2n+1
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324. Functional group of aldehyde is: 335. The property of carbon to form long chain is called:
a) -CO- b) -CHO a) catenation b) complex character
c) -COOH d) None c) isomerism d) vital force theory
325. Molecular formula of ether is: 336. Which of the following processes does not result in the
a) C2H5-O-C2H5 b) CH3COCH3 formation of both carbon dioxide and water?
c) CH3CHO d) None a) addition of a dilute acid to a carbonate
326. First organic compound is synthesized by: b) burning ethanol
a) F. Wohler b) Lavosier c) burning methane
c) Rutherford d) None d) heating crystals of anhydrous sodium carbonate
327. Unsaturated hydrocarbons contain:
337. C4H6 is example of:
a) carbon-carbon single bond b) c-c double bond
a) Alkane b) Alkene
c) c-c triple bond d) both b and c
328. An organic compound has percentage by wt of C & H is 6:1 and
c) Alkyne d) Alkyl
that of C & O is 3:4. The compound is: 338. Wine i.e alcoholic beverage is:
a) HCHO b) CH3OH a) CH3OH b) C6H6
c) CH3CH2OH d) None c) C2H5OH d) C3H7OH
329. Formalin is used as: 339. When sodium acetate is heated with soda lime, we get:
a) Disinfectant reagent a) C2H6 b) C2H4
b) Preservation of biological specimens c) C2H2 d) CH4
c) Both a and b 340. Formation of ethyl acetate fro acetic acid and ethyl alcohol in
d) None presence:
330. Which of the following statement is not true for ethyne gas? a) Etherification b) Saponification
a) It is an unsaturated hydrocarben c) Esterification d) None
b) It is the monomer of benzene 341. Functional group of aldehyde is:
c) It satisfies the formula Cn H2n -2 O O
d) Benzene is natural polymer || ||
331. An organic compound has been found to possess the empirical a) – C – b) – C – H
formula CH2O and molecular weight 90. Give its molecular formula c) – COOH d) None
(C = 12, H = 1, O = 16) 342. When aq. ethanoic acid was added to ethanol, a sweet smelling
a) CH3COOH b) HCOOH liquid was produced. What type of reaction occurred?
c) C6H12O6 d) C3H6O3 a) esterification b) hydrolysis
332. An organic compound on analysis was found to contain 10.06% c) oxidation d) reduction
carbon, 0.84% hydrogen and 89.1% chlorine. Calculate its empirical 343. If the empirical formula of the given compound is CH2O and its
formula. molecular weight is 180 a.m.u., find the molecular formula of the
a) CHCl2 b) CH2Cl2 given compound.
c) CH2Cl3 d) CHCl3 a) CH3COOH b) C3H6O3
333. The liquefied petroleum gas mainly contains: c) C6H12O6 d) None
a) methane + ethane b) ethane + propane 344. Methane is used as a fuel. What property is essential for this use?
c) butane + isobutene d) methane + propane a) it is odourless b) it burns exothermically
334. Formation of Vanaspati Ghee from soyabean oil with hydrogen in c) it is a gas d) it has a low boiling point
presence of heated nickel catalyst is known as:
345. The soap with the formula C17H35COONa is:
a) Esterification b) Hydrogenation
a) acid b) an alcohol
c) Hardening of oil d) Both b and c
c) an ester d) a salt
a) F b) Ba
c) Ge d) Ni The common characteristics of acid, e.g. sour taste, ability to turn blue
524. Which of these when burnt in air give black coloured compound litmus red, ability to neutralize base etc are because of presence of
is malleable? Hydrogen ions in aqueous solution. The common properties of acids
a) Na b) Al are, in fact, the properties of Hydrogen ions.
c) Cu d) CH4
525. Total number of electrons in ferric ion are: Arrhenius Definition of Base
a) 26 b) 23 A base is a compound, which ionizes to give Hydroxide ion as they
c) 24 d) none only negative ion when dissolved in water.
526. Valency of phosphate is:
a) 1 b) 2 Thus, Sodium Hydroxide, Potassium Hydroxide, Calcium Hydroxide
c) 3 d) none are all bases, because each of them furnishes Hydroxide ion when
527. Example of Alkali metal is: dissolved in water.
a) Ca b) Ba NaOH Na+ + OH-
c) Na d) None KOH K+ + OH-
528. F, O, Cl, N what elements is missing hare? Ca(OH)2 Ca ++
+ 2OH -
a) Mg b) Na
c) NaCl d) C The common properties of base, i.e. bitter taste, ability to turn red
litmus blue, phenolphthalein to pink, ability to neutralize acid are due
to the Hydroxide ions. Arrhenius base is limited to water soluble bases
i.e. alkalis.
Lewis concept excludes ionization process, hence it fails to assign the Stomach gland release HCl and during ant-sting formic acid is released.
strength of acid or base. Base Use
NaOH Soap making
Salts Al(OH)3 Antacid for gastric patients
Salts are compounds made up of positive and negative ions, the
positive derived from base and negative derived form acid. Salt Use
NaCl Edible salt
Normal salt is formed by neutralization of acid and base completely. CuSO4 Fungicides
Example: NaCl, K2SO4. It is produced by replacement of all replacable MgSO4 For constipation patients
Hydrogen present in acid by metal on NH4+ group.
Buffer solutions:
Acidic salt is formed when polybasic acids like H2SO4, H3PO4 is Buffer solutions are equilibrium system that resists changes in acidity
neutralised partly by base. Example: NaHSO3, NaH2PO4 etc. and maintain constant pH when acids or bases are added to them.
Basic salt is formed when polyacidic base like Ba(OH)2, Bi(OH)3 is Amphoteric Oxides:
neutralized partly by acid. Example: Ba(OH)Cl, Bi(OH)2Cl, Ca(OH)Cl They have properly of both acid and base. It acts as an acid when
etc. strong base is present and also acts as base when strong acid is present.
Example:Al2O3, ZnO, SnO etc.
Acid salt is formed when a polybasic acid like H2SO4, H2SO3, H3PO4 is
neutralized partly by base. Eg. NaHSO3, NaHCO3, NaHPO4, etc. Some acidic Oxide:
CO2 SO2
Base salt is formed by the replacement of only a part of hydroxyl SO3 N2O5 (Acid anhydride of HNO3)
groups of an ionic metal Hydroxide by the ani onic part of acid. Eg.
Ca(OH)Cl, Ba(OH)Cl, etc. Some basic Oxide:
Na2O CaO
Mixed salts are formed by simultaneous neutralization of one acid by BaO K2O
two base or one base by two acids. Example: Ca(OCl)Cl.
Neutral Oxide:
Double salt: The compound of two salts, whose solution gives test for CO NO
all constituent ions is called double salt. Example: N2O
FeSO4.(NH4)2SO4.6H2O (Mohr’s salt).
Indicator:
A compound whose solution does not give tests for all constituents ion Indicators are complex organic compounds, which give different
is complex salt. Example: K4[Fe(CN)6] (Potassium Ferrocyanide). colours in acidic or basic solutions.
INTEL Bridge Course/Objective Chemistry-93 INTEL Bridge Course/Objective Chemistry-94
Multiple Choice Questions:
The common indicators are litmus, methyl orange and phenolphthalein. 529. Peptic ulcer patient is treated with
The colours given by three indicators in acidic and basic solution are a) Al(OH)3 b) Mg(OH)2
given below: c) a and b d) None
Indicator Colour in acidic Colour in basic 530. If honey bee bites, we use:
solution solution a) calamine lotion b) vinegar
Litmus Red Blue c) caustic soda d) None
Methyl orange Red Yello 531. If wasp bites, we use generally:
Phenolphthalein Colourless Pink a) vinegar b) calamine lotion
c) Hydrochloric acid d) None
These indicators are used to distinguish between acidic and basic 532. pH of distilled water is:
solutions. a) 4 b)10
c) 7 d) None
pH Table: 533. Sodium chloride is:
Colour in Colour in a) Acid b) Base
pH c) Salt d) All of them
acidic basic
Indicator rang Used for titrating
soluti soluti 534. Which of the following is Lewis acid?
e
on on a) HCl b) H2SO4
Strong acid against c) CaO d) AlCl3
Litmus 5.5-7.5 Red Blue
strong base 535. Which of these turn blue litmus paper into blue:
Strong acid against a) Na2CO3 b) NaOH
Methyl
3-4.4 Pink Yellow strong or weak
orange c) FeCl3 d) None
base
536. Which of these are neutral salt:
Strong acid against
Methyl red 4.2-6.3 Red Yellow a) NaCl b) NaNO3
weak base
Bromthymo c) K2SO4 d) All of them
6-7.6 Red Blue - 537. The pH value of good quality of soil ranges from:
l blue
Phenol Strong or weak acid a) 2 to 3 b) 5 to 7
Colour c) 6.5 to 7 d) 6 to
pthalei 8-9.8 Pink against strong
less
n base 538. Proton acceptor chemical species are:
a) Bronsted base b) Lewis Acid
Universal indicator: c) Arrhenius Acid d) Bronsted Acid
An indicator prepared by several organic indicators of different colours 539. The aqueous solution of gas which turns red to blue litmus paper
is called universal indicator. The red colour or deep red colour in the is:
univversal indicator denotes audity whereas the blue colour or deep a) CO2 b) O2
blue colour denotes alkalinity. c) NH3 d) None
540. Aquaregia is mixture of HCl and HNO3 is:
5 6 8 9 10 11 12 14
pH Value 1 2 3 4 7 13 a) 3:1 b) 1:3
Red Pink Orange Yellow Green Greenis Blue Bluish Violet
Blue Violet c) 2:1 d) None
541. FeCl3 is example of ----- salt.
Acidity increases Alkalinity increases a) Acidic b) Basic
c) Neutral d) None