SAMPLE PAPER 1

CHEMISTRY THEORY (043)

MM:70 Time: 3 Hours

General Instructions:
Read the following instructions carefully.
a) There are 33 questions in this question paper. All questions are compulsory.
b) Section A: Q. No. 1 to 16 are objective type questions. Q. No. 1 and 2 are passage based
questions carrying 4 marks each while Q. No. 3 to 16 carry 1 mark each.
c) Section B: Q. No. 17 to 25 are short answer questions and carry 2 marks each.
d) Section C: Q. No. 26 to 30 are short answer questions and carry 3 marks each.
e) Section D: Q. No. 31 to 33 are long answer questions carrying 5 marks each.
f) There is no overall choice. However, internal choices have been provided.
g) Use of calculators and log tables is not permitted.

SECTION A (OBJECTIVE TYPE)

1. Read the passage given below and answer the following questions: (1x4=4)

An efficient, aerobic catalytic system for the transformation of alcohols into carbonyl compounds
under mild conditions, copper-based catalyst has been discovered. This copper-based catalytic
system utilizes oxygen or air as the ultimate, stoichiometric oxidant, producing water as the only
by-product

A wide range of primary, secondary, allylic, and benzylic alcohols can be smoothly oxidized to
the corresponding aldehydes or ketones in good to excellent yields. Air can be conveniently used
instead of oxygen without affecting the efficiency of the process. However, the use of air requires
slightly longer reaction times.
This process is not only economically viable and applicable to large-scale reactions, but it is also
environmentally friendly.
(Reference:Ohkuma, T., Ooka, H., Ikariya, T., & Noyori, R. (1995). Preferential hydrogenation of
aldehydes and ketones. Journal of the American Chemical Society, 117(41), 10417-10418.)
The following questions are multiple choice questions. Choose the most appropriate answer:
(i)The Copper based catalyst mention in the study above can be used to convert:
 a) propanol to propanonic acid
b) propanone to propanoic acid
c) propanone to propan-2-ol
d) propan-2-ol to propanone

(ii)The carbonyl compound formed when ethanol gets oxidised using this copper-based catalyst
can also be obtained by ozonolysis of:
a) But-1-ene
b) But-2-ene
c) Ethene
d) Pent-1-ene
OR

Which of the following is a secondary allylic alcohol?

a) But-3-en-2-ol
b) But-2-en-2-ol
c) Prop-2-enol
d) Butan-2-ol
(iii) Benzyl alcohol on treatment with this copper-based catalyst gives a compound ‘A’ which
on reaction with KOH gives compounds ‘B’ and ‘C’. Compound ‘B’ on oxidation with
KMnO4- KOH gives compound ‘C’. Compounds ‘A’, ‘B’ and ‘C’ respectively are :
a) Benzaldehyde, Benzyl alcohol, potassium salt of Benzoic acid
b) Benzaldehyde, potassium salt of Benzoic acid, Benzyl alcohol
c) Benzaldehyde, Benzoic acid, Benzyl alcohol
d) Benzoic acid, Benzyl alcohol, Benzaldehyde
(iv) An organic compound ‘X’ with molecular formula C3H8O on reaction with this
copper based catalyst gives compound ‘Y’ which reduces Tollen’s reagent. ‘X’ on
reaction with sodium metal gives ‘Z’ . What is the product of reaction of ‘Z’ with 2-
chloro-2-methylpropane?
a) CH3CH2 CH2OC(CH3)3
b) CH3CH2OC(CH3)3
c) CH2=C(CH3)2
d) CH3CH2 CH=C(CH3)2

Read the passage given below and answer the following questions: (1x4=4)

The amount of moisture that leather adsorbs or loses is determined by temperature, relative
humidity, degree of porosity, and the size of the pores. Moisture has great practical significance
because its amount affects the durability of leather, and in articles such as shoes, gloves and other
garments, the comfort of the wearer. High moisture content accelerates deterioration and promotes
mildew action. On the other hand, a minimum amount of moisture is required to keep leather
properly lubricated and thus prevent cracking.
The study indicates that adsorption of moisture by leather is a multi-molecular process and is
accompanied by low enthalpies of adsorption. Further at 75-percent relative humidity, the
adsorption is a function of surface area alone.
Hide is tanned to harden leather. This process of tanning occurs due to mutual coagulation of
positively charged hide with negatively charged tanning material. Untanned hide and chrome-
tanned leathers have the largest surface areas. The leathers tanned with vegetable tanning
materials have smaller surface areas since they are composed of less hide substance and the
capillaries are reduced to smaller diameters, in some cases probably completely filled by tanning
materials. The result of the study indicated that untanned hide and chrome-tanned leather adsorb
the most water vapour.
(Source:Kanagy, J. R. (1947). Adsorption of water vapor by untanned hide and various leathers at
100 F. Journal of Research of the National Bureau of Standards, 38(1), 119-128.)
2. In these questions (Q. No 5-8 , a statement of assertion followed by a statement of reason
is given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
b) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
c) Assertion is correct statement but reason is wrong statement.
d) Assertion is wrong statement but reason is correct statement.

(i) Assertion: Vegetable tanned leather cannot adsorb a large amount of moisture.
Reason: Porous materials have higher surface area.

(ii) Assertion: Animal hide soaked in tannin results in hardening of leather.

Reason: Tanning occurs due to mutual coagulation.

(iii) Assertion: Adsorption of moisture by leather is physisorption.

Reason: It is a multimolecular process and is accompanied by low enthalpies of
adsorption
(iv) Assertion: Leathers tanned with vegetable tanning materials have smaller surface areas
Reason: The capillaries present in leather are reduced to smaller diameters
OR
Assertion: Leather absorbs different amount of moisture.
Reason: Some moisture is necessary to prevent cracking of leather.

Following questions (No. 3 -11) are multiple choice questions carrying 1 mark each:
3 Which of the following option will be the limiting molar conductivity of CH3COOH if the
limiting molar conductivity of CH3COONa is 91 Scm2mol-1? Limiting molar conductivity
for individual ions are given in the following table.

S.No Ions limiting molar conductivity / Scm2mol-1

1 H+ 349.6

2 Na+ 50.1
3 K+ 73.5
4 OH- 199.1
a) 350 Scm2mol-1
b) 375.3 Scm2mol-1
c) 390.5 Scm2mol-1
d) 340.4 Scm2mol-1
4. Curdling of milk is an example of:
a) breaking of peptide linkage
b) hydrolysis of lactose
c) breaking of protein into amino acids
d) denauration of proetin
OR
Dissachrides that are reducing in nature are:
a) sucrose and lactose
b) sucrose and maltose
c) lactose and maltose
d) sucrose, lactose and maltose

5.When 1 mole of benzene is mixed with 1 mole of toluene The vapour will contain: (Given :
vapour of benzene = 12.8kPa and vapour pressure of toluene = 3.85 kPa).
a) equal amount of benzene and toluene as it forms an ideal solution
b) unequal amount of benzene and toluene as it forms a non ideal solution
c) higher percentage of benzene
d) higher percentage of toluene

6.Which of the following is the reason for Zinc not exhibiting variable oxidation state
a) inert pair effect
b) completely filled 3d subshell
c) completely filled 4s subshell
d) common ion effect
OR
Which of the following is a diamagnetic ion: (Atomic numbers of Sc, V, Mn and Cu are 21, 23,
25 and 29 respectively)
a) V2+
b) Sc3+
c) Cu2+
d) Mn3+

7. Propanamide on reaction with bromine in aqueous NaOH gives:

a) Propanamine
b) Ethanamine
c) N-Methyl ethanamine
d) Propanenitrile
OR
IUPAC name of product formed by reaction of methyl amine with two moles of ethyl chloride
a) N,N-Dimethylethanamine
b) N,N-Diethylmethanamine
c) N-Methyl ethanamine
d) N-Ethyl - N-methylethanamine

8.Ambidentate ligands like NO2- and SCN- are :

a) unidentate
b) didentate
c) polydentate
d) has variable denticity
OR
The formula of the coordination compound Tetraammineaquachloridocobalt(III) chloride is
a) [Co(NH3)4(H2O)Cl]Cl2
b) [Co(NH3)4(H2O)Cl]Cl3
c) [Co(NH3)2(H2O)Cl]Cl2
d) [Co(NH3)4(H2O)Cl]Cl

9.Which set of ions exhibit specific colours? (Atomic number of Sc = 21, Ti = 22, V=23, Mn =
25, Fe = 26, Ni = 28 Cu = 29 and Zn =30)

a) Sc3+, Ti4+, Mn3+

b) Sc3+, Zn2+, Ni2+
c) V3+, V2+, Fe3+
d) Ti3+, Ti4+, Ni2+
 10. Identify A,B,C and D:

a) A = C2H4, B= C2H5OH, C= C2H5NC, D= C2H5CN

b) A= C2H5OH, B= C2H4, C = C2H5CN, D=C2H5NC
c) A = C2H4, B= C2H5OH, C= C2H5CN, D= C2H5NC
d) A= C2H5OH, B= C2H4, C= C2H5NC, D= C2H5CN

11.The crystal showing Frenkel defect is :

a)

b)

c)

d)
In the following questions (Q. No. 12 - 16) a statement of assertion followed by a statement of
reason is given. Choose the correct answer out of the following choices.
a) Assertion and reason both are correct statements and reason is correct explanation for
assertion.
b) Assertion and reason both are correct statements but reason is not correct explanation for
assertion.
c) Assertion is correct statement but reason is wrong statement.
d) Assertion is wrong statement but reason is correct statement.

12.Assertion: The two strands of DNA are complementary to each other

Reason: The hydrogen bonds are formed between specific pairs of bases.

13.Assertion: Ozone is thermodynamically stable with respect to oxygen.

Reason:Decomposition of ozone into oxygen results in the liberation of heat

14.Assertion: Aquatic species are more comfortable in cold waters rather than in warm waters.
Reason:Different gases have different KH values at the same temperature
OR
Assertion: Nitric acid and water form maximum boiling azeotrope.
Reason: Azeotropes are binary mixtures having the same composition in liquid and vapour
phase.
15. Assertion: Carboxylic acids are more acidic than phenols.
Reason: Phenols are ortho and para directing.

16.Assertion: Methoxy ethane reacts with HI to give ethanol and iodomethane

Reason: Reaction of ether with HI follows SN2 mechanism

SECTION B

The following questions, Q.No 17 – 25 are short answer type and carry 2 marks each.

17. With the help of resonating structures explain the effect of presence of nitro group at ortho
position in chlorobenzene.
OR
Carry out the following conversions in not more than 2 steps:
 (i)Aniline to chlorobenzene
(ii)2-bromopropane to 1- bromopropane

18. A glucose solution which boils at 101.04 oC at 1 atm. What will be relative lowering of
vapour pressure of an aqueous solution of urea which is equimolal to given glucose
solution? (Given: Kb for water is 0.52 K kg mol-1)

19. (i) Using crystal field theory, write the electronic configuration of iron ion in the following
complex ion. Also predict its magnetic behaviour :
[Fe(H2O)6]2+
(ii)Write the IUPAC name of the coordination complex: [CoCl2(en)2]NO3
OR
2-
(i)Predict the geometry of [Ni(CN)4]
(ii)Calculate the spin only magnetic moment of [Cu(NH3)4]2+ ion.

20. For a reaction the rate law expression is represented as follows:

Rate = k [A][B]1/2
i. Interpret whether the reaction is elementary or complex. Give reason to support your
answer.
ii. Write the units of rate constant for this reaction if concentration of A and B is
expressed in moles/L.
OR
The following results have been obtained during the kinetic studies of the reaction:
P + 2Q  R + 2S

Init. Rate of Formation

Exp. Initial P(mol/L) Initial Q (mol/L)
of R (M min-1)

1 0.10 0.10 3.0 x 10 -4

2 0.30 0.30 9.0 x 10 -4

3 0.10 0.30 3.0 x 10 -4

4 0.20 0.40 6.0 x 10 -4

Determine the rate law expression for the reaction.

 21. The C-14 content of an ancient piece of wood was found to have three tenths of that in
living trees. How old is that piece of wood? (log 3= 0.4771, log 7 = 0.8540 , Half-life of
C-14 = 5730 years )

22. When 3-methylbutan-2-ol is treated with HBr, the following reaction takes place:

Give a mechanism for this reaction.

23. Give the formula and describe the structure of a noble gas species which
is isostructural with IF6-.

24. The following haloalkanes are hydrolysed in presence of aq KOH.

(i) 2- Chlorobutane (ii) 2-chloro-2-methylpropane
Which of the above is most likely to give a racemic mixture? Justify your answer.
25.Atoms of element P form ccp lattice and those of the element Q occupy 1/3rd of tetrahedral
voids and all octahedral voids. What is the formula of the compound formed by the elements
P and Q?

SECTION C

Q.No 26 -30 are Short Answer Type II carrying 3 mark each.

26. Give reasons for the following:
i. Transition elements act as catalysts
ii. It is difficult to obtain oxidation state greater than two for Copper.
iii. Cr2O72- is a strong oxidising agent in acidic medium whereas WO3 and MoO3 are not.

OR
Observed and calculated values for the standard electrode potentials of elements from Ti to Zn in
the first reactivity series are depicted in figure (1):
 FIGURE 1 (source NCERT)
Explain the following observations:
i. The general trend towards less negative Eo values across the series
ii. The unique behaviour of Copper
iii. More negative Eo values of Mn and Zn

27. Arrange the following in increasing order of property specified:

i. Aniline, ethanamine, 2-ethylethanamine (solubility in water)

ii. Ethanoic acid, ethanamine, ethanol (boiling point)
iii. Methanamine, N, N- dimethylmethanamine and N- methylmethanamine (basic strength in
aqueous phase)
OR
i. Give a chemical test to distinguish between N-methylethanamine and N,N-dimethyl
ethanamine.
ii. Write the reaction for catalytic reduction of nitrobenzene followed by reaction of
product so formed with bromine water.
iii. Out of butan-1-ol and butan-1-amine, which will be more soluble in water and why?

28. A metal crystallizes into two cubic system-face centred cubic (fcc) and body centred cubic
(bcc) whose unit cell lengths are 3.5 and 3.0Å respectively. Calculate the ratio of densities of
fcc and bcc.
29. Three amino acids are given below:
Alanine CH3CH(COOH)(NH2) Aspartic acid HOOC-CH2CH(COOH)(NH2) and Lysine H2N-
(CH2)4-CH(COOH)(NH2)
i. Make two tripeptides using these amino acids and mark the peptide linkage in both cases.
ii. Represent Alanine in the zwitter ionic form.
30. i. Arrange the following in decreasing order of bond dissociation enthalpy
F2 , Cl2 , Br2 , I2
ii. Bi does not form pπ-pπ bonds. Give reason for the observation.
iii.Electron gain enthalpy of oxygen is less negative than sulphur. Justify

SECTION D

Q.No 31 to 33 are long answer type carrying 5 marks each.

31. (i) Answer the following questions: (2+3)

a) Write the balanced chemical reaction for reaction of Cu with dilute HNO3.
b) Draw the shape of ClF3
(ii)‘X’ has a boiling point of 4.2K, lowest for any known substance. It is used as a diluent for
oxygen in modern diving apparatus. Identify the gas ‘X’. Which property of this gas makes it
usable as diluent? Why is the boiling point of the gas ‘X’ so low?
OR
(i) Answer the following questions: (2+3)
a) Arrange the following in the increasing order of thermal stability:
H2O, H2S, H2Se, H2Te
b)Give the formula of the brown ring formed at the interface during the ring test for nitrate.
(ii) A greenish yellow gas ‘A’ with pungent and suffocating odour, is a powerful bleaching
agent. ‘A’ on treatment with dry slaked lime it gives bleaching powder. Identify ‘A’ and
explain the reason for its bleaching action. Write the balanced chemical equation for the
reaction of ‘A’ with hot and concentrated NaOH.
32. An organic compound ‘A’ C8H6 on treatment with dilute H2SO4 containing mercuric sulphate
gives compound ‘B’. This compound ‘B’ can also be obtained from a reaction of benzene with
acetyl chloride in presence of anhy AlCl3. ‘B’ on treatment with I2 in aq. KOH gives ‘C’ and a
yellow compound ‘D’. Identify A, B, C and D. Give the chemical reactions involved. (5)

OR
(i) Write the reaction for cross aldol condensation of acetone and ethanal.
(ii) How will you carry out the following conversions:
a) Benzyl alcohol to phenyl ethanoic acid
b) Propanone to propene
c) Benzene to m-Nitroacetophenone
33. (i) State Kohlrausch law. (1+4)
(ii) Calculate the emf of the following cell at 298 K:
Al(s)/Al3+ (0.15M)//Cu2+(0.025M) /Cu(s)
(Given Eo(Al3+/Al) = -1.66 V, Eo(Cu 2+/Cu) = 0.34V, log 0.15 = -0.8239, log 0.025 = -
1.6020)
OR
(i) On the basis of Eo values identify which amongst the following is the strongest
oxidising agent (1+4)
Cl2(g) + 2 e– 2Cl- Eo= +1.36 V,
MnO4– + 8H+ + 5e– → Mn2+ + 4H2O Eo= +1.51 V
Cr2O72– + 14H+ + 6e– → 2Cr3+ + 7H2O Eo= +1.33 V

(ii) The following figure 2, represents variation of (Λm ) vs √c for an electrolyte. Here Λm
is the molar conductivity and c is the concentration of the electrolyte.

Figure 2
a) Define molar conductivity
b) Identify the nature of electrolyte on the basis of the above plot. Justify your answer.
c) Determine the value of Λmo for the electrolyte.
d) Show how to calculate the value of A for the electrolyte using the above graph.