Atomic Number: o o o o o o o o o o o o o o o o
Atomic Number: o o o o o o o o o o o o o o o o
Atomic Number: o o o o o o o o o o o o o o o o
Contents
In philosophy
Main article: Atomism
The basic idea that matter is made up of tiny indivisible particles is very old, appearing in many
ancient cultures such as Greece and India. This ancient idea was based in philosophical reasoning
rather than scientific reasoning. The word atom is derived from the Greek word atomos, which
means "uncuttable".[1][2]
Atoms and molecules as depicted in John Dalton's A New System of Chemical Philosophy vol. 1 (1808)
In the early 1800s, John Dalton compiled experimental data gathered by himself and other scientists
and discovered a pattern now known as the "law of multiple proportions". He noticed that in chemical
compounds which contain a particular chemical element, the content of that element in these
compounds will differ by ratios of small whole numbers. This pattern suggested to Dalton that each
chemical element combines with others by some basic and consistent unit of mass.
For example, there are two types of tin oxide: one is a black powder that is 88.1% tin and 11.9%
oxygen, and the other is a white powder that is 78.7% tin and 21.3% oxygen. Adjusting these
figures, in the black oxide there is about 13.5 g of oxygen for every 100 g of tin, and in the white
oxide there is about 27 g of oxygen for every 100 g of tin. 13.5 and 27 form a ratio of 1:2, a ratio of
small whole numbers. In these oxides, for every tin atom there are one or two oxygen atoms
respectively (SnO and SnO2).[3][4]
As a second example, Dalton considered two iron oxides: a black powder which is 78.1% iron and
21.9% oxygen, and a red powder which is 70.4% iron and 29.6% oxygen. Adjusting these figures, in
the black oxide there is about 28 g of oxygen for every 100 g of iron, and in the red oxide there is
about 42 g of oxygen for every 100 g of iron. 28 and 42 form a simple ratio of 2:3. In these
respective oxides, for every two atoms of iron, there are two or three atoms of oxygen (Fe2O2 and Fe2O3).
[a][5][6]
As a final example: nitrous oxide is 63.3% nitrogen and 36.7% oxygen, nitric oxide is 44.05%
nitrogen and 55.95% oxygen, and nitrogen dioxide is 29.5% nitrogen and 70.5% oxygen – adjusting
the figures, for every 140 g of nitrogen, there is about 80 g, 160 g, and 320 g of oxygen in these
oxides respectively, which gives a simple ratio of 1:2:4. The respective formulas for these oxides
are N2O, NO, and NO2.[7][8]
In the late 18th century, a number of scientists found that they could better explain the behavior of
gases by describing them as collections of sub-microscopic particles and modelling their behavior
using statistics and probability. Unlike Dalton's atomic theory, the kinetic theory of gases describes
not how gases react chemically with each other to form compounds, but how they behave physically:
diffusion, viscosity, conductivity, pressure, etc.