SDS No.

:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 1 of 8

Section 1: Identification of the Hazardous Chemical and of the Supplier

1.1 Product Identifier

Product Name: Liquid NPK Foliar Fertilizer
Trade Name: Selama 8-8-6
Active Ingredient: Nitrogen, Phosphate, Potassium and other micro-nutrients
CAS No.(AI): Please refer Section 3
Structural Formula: -
Recommended Usage: Plant nutrition

1.2 Supplier’s Information

Address: Agricultural Chemicals (M) Sdn. Bhd.
962, Lorong Perusahaan 8
Taman Perindustrian Perai
13600 Perai , Pulau Pinang
Malaysia
Tel.: +6-04-3907988
Fax: +6-04-3905703
Web: www.agrichem.com.my
Emergency Phone: +6-04-3907988

Section 2: Hazard Identification

Classification: Serious eye damage, category 1

Skin irritation, category 2
Specific target organ toxicity – single exposure, category 3

Pictogram:

Signal Word: Danger

Hazard Statement:
H315 Causes skin irritation
H318 Causes serious eye damage
H335 May cause respiratory irritation

Precautionary Statement:
P261 Avoid breathing vapours/spray
P264 Wash exposed body parts thoroughly after handling
P271 Use only outdoor or in a well ventilated area
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 2 of 8

P280 Wear rubber gloves, protective clothing, safety goggles and face
protection
P305+351+338 IF IN EYES: Rinse cautiously with water for several minutes. Remove
contact lenses, if present and easy to do. Continue rinsing.
P501 Dispose of containers in accordance to Environmental Quality
(Scheduled Waste) Regulations or any local regulations.

Section 3: Composition and Information of the Ingredients of the Hazardous Chemical

Component CAS No. Weight, % Hazard Code

Ammonium 12054-85-2 H302, H315, H319, H335
Molybdate
Boric Acid 10043-35-3 < 0.1% H360FD
Chelating agent - < 1% H302, H318
Copper Sulphate 7758-99-8 < 0.1% H302, H315, H319
Ferrous Sulphate 7782-63-0 < 0.1% H302, H315, H319
Manganese Sulphate 7785-87-7 < 0.1% H411
Phosphoric Acid 7664-38-2 < 5% H302, H314
Potassium Nitrate 7757-79-1 < 15% H272, H315, H319, H335
Zinc Chloride 7646-85-7 < 0.1% H302, H314, H318, H335, H373, H400, H410
*This product contains other materials which are not classified as hazardous under CLASS
Regulations.

Section 4: First-aid Measures

Call a POISON CENTER or doctor/physician if you feel unwell.

Inhalation: Remove victim to fresh air and keep at rest in a position comfortable for
breathing.
Skin Contact: Remove/Take off immediately all contaminated clothing. Rinse skin with
water/shower. If skin irritation occurs: Get medical advice/attention. Wash
contaminated clothing before reuse.
Eye Contact: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. If eye irritation persists: Get
medical advice/attention.
Ingestion: DO NOT induce vomiting. Rinse mouth. Immediately call a POISON CENTER or
doctor/physician.
Symptoms: No data available
Notes to Physician: No data available
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 3 of 8

Section 5: Fire-fighting Measures

Suitable Extinguishing Media: Water, carbon dioxide (CO2), chemical foam, dry chemical
Specific Hazard During Fire: Carbon oxides, nitrogen oxides, sulfur oxides, phosphorous oxides,
zinc oxides, hydrogen chloride may evolve upon combustion
Special Protective Equipment: Fire fighters should wear full-faced self-contained breathing
apparatus and protective clothing.

Section 6: Accidental Release Measures

Personal Precautions: Do not handle until all safety precautions have been read and
understood. Use personal protective equipment as required.
Environmental Precautions: Avoid release to the environment.
Method for Cleaning Up: Turn off all ignition sources. Wear protective clothing as indicated
in Section 8. Evacuate non essential personnel. Absorb spills with
inert material such as clay, sand, earth, sawdust etc. and collect in a
drum. Cover up the contaminated area with household detergent
and small amount of water. Brush the slurry and spread inert
absorbents on the slurry liquid and collect the absorbed material in
a drum. Seal drum and dispose of. Do not contaminate water
resources.

Section 7: Handling and Storage

Precautions for Safe Handling: Do not handle until all safety precautions have been read and
understood. Use personal protective equipment as required.
Avoid release to the environment.
Conditions for Safe Storage: Store in a well ventilated place. Store away from combustible
materials. Keep away from heat/sparks/open flames/hot surfaces -
No smoking. Keep container tightly closed.
Incompatibles: Strong oxidizing, strong reducing materials.

Section 8: Exposure Control and Personal Protection

Exposure Limit:
Source Component CAS No. Limit
Ammonium 12054-85-2 Contains no substances with OEL value
Molybdate
ACGIH Boric Acid 10043-35-3 TWA inhalable fraction 2mg/m3
STEL/ceiling inhalable fraction 6mg/m3
Australia Chelating agent - TWA- 8hr 10mg/m3
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 4 of 8

Source Component CAS No. Limit

ACGIH TLV Copper Sulphate 7758-99-8 TWA 1mg/m3
NIOSH IDLH 100mg/m3
IDLH TWA 1mg/m3
Ferrous Sulphate 7782-63-0 No data
Manganese 7785-87-7 No data
Sulphate
OES Phosphoric Acid 7664-38-2 TWA-8hr 1mg/m3
STEL-15min 2mg/m3
Potassium Nitrate 7757-79-1 No data
ACGIH TLV Zinc Chloride-fume 7646-85-7 TWA 1mg/m3
STEL 2mg/m3
US.NIOSH REL 1mg/m3
STEL 2mg/m3
US.OSHA PEL 1mg/m3
STEL 2mg/m3
TWA 1mg/m3

Engineering Control: Local exhaust ventilation

Individual Protection Measure: Do not handle until all safety precautions have been read and
understood. Use personal protective equipment as required.
Personal Protective Equipment:
Eye Protection: Protective goggles
Skin Protection: Rubber gloves and boots
Respiratory Protection: Respirator

Section 9: Physical and Chemical Properties

Appearance: Light yellowish green – light greenish liquid

Odour: Characteristic odour
Odour Threshold: No data
pH: 6.5
Melting/Freezing Point: No data
Initial Boiling Point: No data
Boiling Range: No data
Flash Point: Not applicable
Evaporation Rate: No data
Flammability: Not applicable
Upper Flammability Limit: Not applicable
Lower Flammability Limit: Not applicable
Vapour Pressure: No data
Vapour Density: No data
Relative Density: 1.2g/ml
Solubility in Water: Soluble
Partition Coefficient Po/w: No data
Auto-ignition Temperature: No data
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 5 of 8

Decomposition Temperature: No data

Viscosity: No data

Section 10: Stability and Reactivity

Reactivity: No data
Chemical Stability: The material is stable under normal storage condition
Hazardous Reaction: Carbon oxides, nitrogen oxides, sulfur oxides, phosphorous oxides,
zinc oxides, hydrogen chloride may evolve upon combustion
Condition to Avoid: Direct sunlight, extreme temperature, open flame, sparks
Incompatible Material: Strong reducing agent, strong oxidizing agents
Hazardous Decomposition
Product: No data

Section 11: Toxicological Information

11.1 Acute Toxicity

Component: Ammonium Molybdate
Ingestion, Oral LD50:
Rat 333mg/kg
Component: Boric Acid
Ingestion, Oral LD50:
Rat 3765mg/kg
Dermal, LD50
Rabbit > 2000mg/kg
Inhalation, LC50
Rat > 2.03mg/L
Component: Phosphoric Acid
Ingestion, Oral LD50:
Rat 1530mg/kg
Dermal, LD50
Rat 2740mg/kg
Inhalation, LC50
Rat 850mg/kg/1hr
Component: Potassium Nitrate
Ingestion, Oral LD50:
Rat 3750mg/kg
Component: Zinc Chloride
Ingestion, Oral LD50:
Rat 350mg/kg
Mouse 1260mg/kg
Inhalation, LC50
Rat, 10 min 1975mg/m3
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Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 6 of 8

11.2 Chronic Effect from Short and Long Term Exposure

Skin Contact: Causes skin irritation
Eye Contact: Causes serious eye damage
Inhalation: No data available
Ingestion: No data available
Carcinogenicity: No data available
Mutagenicity: No data available
Teratogenecity:
Boric Acid
Adverse effect on fertility:
Multigeneration study: NOAEL (fertility, male rats): 17.5mg B/kg bw/day
Developmental effects have been observed in laboratory animals. The critical effect is
considered to be decrease fetal body weight in rats. There is no evidence of
developmental effects in hunman attributable to boron in studies of populations with high
exposure to boron
Boric acid is classified and labeled as “Presumed human reproductive toxicant, category
1B”, in accordance with Appendix A to 29CFR section 1910.1200, OSHA-GHS

11.3 Symptoms No data available

Section 12: Ecological Information

Ecotoxicity:
Component: Ammonium Molybdate
Acute Toxicity:
Onchorynchus mykiss, LC50, 96hr 320mg/L
Daphnia magna, EC50, 48 hr 140mg/L
Desmodesmus subspicatus, EC50, 48 hr 41mg/L
Component: Boric Acid
Acute Toxicity
Fish, LC50, 96 hr 74 - 725mg/L
Aquatic invertebrates, EC50, 48hr 45-1376mg/L
Pseudokirchneriella subcapitata, EC50, 72hr 40mg B/L
Chronic Toxicity
Fish, NOEC/EC10 2.89 - 16.65mg B/L
Higher plants/Alga/Clorophita, NOEC/EC10 4 - 50mg B/L
Crustacea/Amphibian, NOEC/EC10 5.67 - 40.62 mg B/L
Aquatic micro-organisms, EC50, 3hr > 175mg B/L
Component: Chelating agent
Acute Toxicity
Fish (Leuciscus idus), LC50, 96hr > 500mg/L
Component: Copper Sulphate
Acute Toxicity
Freshwater fish, LC50, 96 hr 0.1mg/L
Water flea, EC50, 48hr 0.024mg/L
Component: Potassium Nitrate
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 7 of 8

Acute Toxicity
Fish, LC50, 96 hr 162mg/L
Poecilia reticulata, LC50 1378mg/L
Lepomis macrochirus, TLM, 96hr 3000mg/L
Gambusia affinis, TLM, 96hr 162mg/L
Daphnia magna, LC50, 96 hr 39mg/L
Daphnia magna, LC50, 48 hr 490mg/L
Daphnia magna, TLM, 96 hr 39mg/L
Daphnia magna, TLM, 48 hr 490mg/L
Plankton, EC50 200 - 1000mg/L
Component: Zinc Chloride
Acute Toxicity
Onchorynchus mykiss, LC50, 96hr 0.179 - 0.393mg/L Mortality
Lymnaea stagnalis, EC50, 6hr 64mg/L Intoxication
Callianassa australienses, EC50, 7d 1.61 - 2.45mg/L Intoxication
Callianassa australienses, EC50, 10d 1.38 - 1.71mg/L Intoxication
Callianassa australienses, EC50, 14d 0.97 - 1.22mg/L Intoxication

Persistence and Degradability: No data available

Bioaccumulative Potential: No data available
Mobility in Soil: No data available
Other Adverse Effect: No data available

Section 13: Disposal Information

Dispose of contents/container to Kualiti Alam / authorized body by DOE.

Section 14: Transportation Information

Land (ADR/RID) Not regulated

Sea (IMDG) Not regulated
Air (IATA) Not regulated

Section 15: Regulatory Information

Classification: Serious eye damage, category 1

Skin irritation, category 2
Specific target organ toxicity – single exposure, category 3
 SDS No.:
Safety Data Sheet SDS-P/L-S/01
Revision: 1, 1st Issue
Selama 8-8-6 Page 8 of 8

Signal Word: Danger

Pictogram:

Pesticides Act: Not applicable

Classification: Not applicable

Section 16: Other Information

Date of Preparation: 14 December 2015

Date of Revision: 17 November 2016
Reference Document: ICOP on Chemicals Classification and Hazard Communication 2014
GHS Purple Book
MSDS:

Material Source Date

Ammonium Molybdate Tetrahydrate Columbus Chemical Industries 6/11/2012
Boric Acid SQM North America Oct 2012
Chelating agent Orica Australia Pty Ltd, 21/10/2013
Copper Sulphate Fisher Scientific 20 May 2014
Ferrous Sulphate Monohydrate Kimleigh Chemicals SA Pty Ltd 14 Feb 2012
Manganese Sulphate Monohydrate Numinor Chemicals Ind. Ltd Oct 2010
Phosphoric Acid The Carbon Group 30/3/2011
Potassium Nitrate LabChem Inc 26/6/2013
Zinc Chloride Avantos Performance Material Inc 16/5/2014

Disclaimer: To the best of our knowledge, the information contained herein is accurate. However, we cannot assume any
liability whatsoever for the accuracy or completeness of the information contained herein.