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    Material Safety Data Sheet: Silica Fume

    Uploaded by

    Hemlata Lodha
    This document provides a material safety data sheet for silica fume. Silica fume is a white amorphous powder used to produce refractories, cement, ceramics and glass. It consists primarily of silica but also contains small amounts of zirconium dioxide and crystalline silica. Inhalation of silica fume dust can irritate the respiratory tract and long term exposure increases the risk of developing silicosis. Personal protective equipment including a respirator and gloves should be worn when handling silica fume to prevent exposure. The material is chemically inert but will react with hydrofluoric acid to produce toxic silicon tetrafluoride gas.

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    Material Safety Data Sheet: Silica Fume

    Uploaded by

    Hemlata Lodha
    218 views3 pages
    This document provides a material safety data sheet for silica fume. Silica fume is a white amorphous powder used to produce refractories, cement, ceramics and glass. It consists primarily of silica but also contains small amounts of zirconium dioxide and crystalline silica. Inhalation of silica fume dust can irritate the respiratory tract and long term exposure increases the risk of developing silicosis. Personal protective equipment including a respirator and gloves should be worn when handling silica fume to prevent exposure. The material is chemically inert but will react with hydrofluoric acid to produce toxic silicon tetrafluoride gas.

    Original Title

    msds-012e---dfm---silica-fume

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    This document provides a material safety data sheet for silica fume. Silica fume is a white amorphous powder used to produce refractories, cement, ceramics and glass. It consists primarily of silica but also contains small amounts of zirconium dioxide and crystalline silica. Inhalation of silica fume dust can irritate the respiratory tract and long term exposure increases the risk of developing silicosis. Personal protective equipment including a respirator and gloves should be worn when handling silica fume to prevent exposure. The material is chemically inert but will react with hydrofluoric acid to produce toxic silicon tetrafluoride gas.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    218 views3 pages

    Material Safety Data Sheet: Silica Fume

    Uploaded by

    Hemlata Lodha
    This document provides a material safety data sheet for silica fume. Silica fume is a white amorphous powder used to produce refractories, cement, ceramics and glass. It consists primarily of silica but also contains small amounts of zirconium dioxide and crystalline silica. Inhalation of silica fume dust can irritate the respiratory tract and long term exposure increases the risk of developing silicosis. Personal protective equipment including a respirator and gloves should be worn when handling silica fume to prevent exposure. The material is chemically inert but will react with hydrofluoric acid to produce toxic silicon tetrafluoride gas.

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
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    The document outlines the material safety data sheet for silica fume, including its composition, potential health effects, safety and handling procedures, and transportation regulations.

    Acute exposure can cause irritation to the gastrointestinal tract, eyes, skin and respiratory tract. Long term exposure in excess of limits can result in fibrotic lung disease.

    Avoid breathing dust and use suitable dust controls like respirators. Wash thoroughly after handling and avoid eating, drinking or smoking to minimize inhalation. Wear protective gloves and clothing.

    MATERIAL SAFETY DATA SHEET

    SILICA FUME
    1. IDENTIFICATION OF MATERIAL AND SUPPLIER
    Product Identification
    Product Name Silica Fume

    Other Names Silica (Silicon Dioxide); Micro Silica

    Recommended Uses Production of Refractories, Portland Cement, Ceramics and Glass.

    Supplier Identification
    Company Doral Fused Materials Pty. Ltd.
    A.B.N. 62 009 415 025
    Address Lot 6 Alumina Road, East Rockingham Western Australia 6168
    PO Box 84, Rockingham Western Australia 6968

    Telephone Number Within Australia (08) 9439 2236 International +61 8 9439 2236
    Facsimile Within Australia (08) 9439 2892 International +61 8 9439 2892
    E-Mail doral@doral.com.au

    Emergency Telephone (24 hours) (08) 9439 2236 (International +61 8 9439 2236)

    2. HAZARD IDENTIFICATION
    Silica Fume is not classified as hazardous according to criteria of Worksafe Australia.

    Risk Phases (R-Phrases) None


    Safety Phrases (S-Phrases) None

    UN Number None Allocated


    Class and Subsidiary Risk None Allocated
    Hazchem Code None Allocated
    Poisons Schedule Number None Allocated

    Potential Health Effects


    Acute
    Swallowed: Can cause severe irritation and damage to gastrointestinal tract.
    Eye: Reacts with tears resulting in severe irritation, corrosive burns and risk of permanent
    damage to eyes.
    Skin: Can cause caustic attacks on skin, especially when wet.
    Inhaled: Can cause irritations of the respiratory tract.
    Chronic Long term exposure to crystalline silica, in excess of suggested limits, can result in
    fibrotic lung disease (silicosis).

    3. COMPOSITION / INFORMATION ON INGREDIENTS


    Ingredients (typical) CAS Number Proportion %
    Silica (amorphous) 69012-64-2 > 93.0 wt.%)
    Zirconium Dioxide 1314-23-4 < 6.0 (wt.%)
    Silica (crystalline) 14808-60-7 < 1.0 (wt.%)
    U (Uranium) 7440-61-1 100 ppm
    Th (Thorium) 7440-29-1 20 ppm

    4. FIRST AID MEASURES


    Swallowed: Drink large amounts of water. Do not induce vomiting.
    Consult a doctor immediately.
    Eyes: Hold eyelids open and wash continuously with water for 15 minutes.
    Do not rub eyes. Seek immediate medical attention.
    Skin: Immediately remove clothing and flush affected area with large quantities of water.
    Seek medical attention.
    Inhaled: Remove from exposure to fresh air. If breathing is laboured or stopped, give artificial
    respiration. Obtain immediate medical attention.
    First Aid Facilities: No special requirements.

    Date of Issue: December 2007 Page 1 of 3


    5. FIRE FIGHTING MEASURES
    Flashpoint None
    Flammability Limits Non-flammable
    General Hazard This product is not flammable and does not support combustion.
    Extinguishing Media Use media suitable for the material that is burning.

    6. ACCIDENTAL RELEASE MEASURES


    Spills and disposal Clean up by sweeping and collection of dry material, avoid dusting.
    Due to possible leachability, approval from appropriate regulatory bodies is to be
    obtained for the disposal of Silica Fume.

    Wear safety equipment as for normal handling. Avoid generating dust. Vacuum
    up if possible, otherwise sweep up and re-cycle. If the spilled product is not
    suitable for re-use, damp down, collect and where possible return to
    manufacturer for reprocessing. Any disposal to an approved landfill site and
    cover with clean fill shall be conducted in accordance with State/Local Council
    regulations.

    7. HANDLING AND STORAGE


    Handling Avoid breathing dust. Suitable dust controls, including wearing a suitable
    respirator, should be utilised when handling bulk materials. Wash thoroughly
    after handling. If handling Silica Fume it is advisable to also use gloves and
    wash hands before eating, drinking or smoking to minimise inhalation or ingestion
    from hands.

    Storage Keep dry. Store separate from hydrofluoric acid.

    8. EXPOSURE CONTROLS/PERSONAL PROTECTION


    Exposure Standards:
    Chemical Name CAS Number Proportion (wt %) NOHSC TWA ACGIH TLV
    3 3
    Silica (amorphous) 69012-64-2 > 85.0 2.0 mg/m 2.0 mg/m
    (respirable dust)
    3 3
    Zirconium Dioxide 1314-23-4 < 10.0 5 mg/m as Zr 5 mg/m as Zr
    3 3
    Silica (crystalline) 14808-60-7 < 1.0 0.1 mg/m 0.05 mg/m
    1
    Radiation Exposure Occupational exposure should be as low as reasonably achievable,
    (ALARA principle), but should not exceed a total of 100 milli-seiverts over five
    consecutive years. (ICRP)
    1
    Denotes recommendation of the International Commission on Radiological Protection, ICRP Publication
    60, Annals of the ICRP Vol 21, No 1 – 3 1991

    Engineering Controls Use with adequate ventilation. Limit dust formation as far as possible to meet
    exposure limits listed above.
    Personal Protection Use dust respirator and face mask to cover eyes, nose and mouth. The use of
    impervious gloves and protective clothing is recommended to reduce unnecessary
    contact with skin.

    9. PHYSICAL AND CHEMICAL PROPERTIES


    Appearance White amorphous powder
    Boiling Point Not Applicable
    Melting Point 1720ºC
    Vapour Pressure Not Applicable
    Specific Gravity 2.5
    Flashpoint Not Applicable
    Flammability Limits Non-flammable
    Solubility Insoluble in water, soluble in concentrated acids and alkalis
    3
    Bulk Density 200 - 300 kg/m
    pH 2 - 4 (10 wt.% in distilled water)
    Reactivity Reacts with hydrofluoric acid (HF) to produce toxic, gaseous silicon
    tetrafluoride (SiF4)

    Additional Information
    Radioactivity Silica Fume contains low levels of U and Th (U + Th ~ 120 ppm, ~1Bq/g). When
    following recommended safe handling practices radiation exposure is unlikely to
    exceed 0.5 mSv/year (whole body average).

    Date of Issue: December 2007 Page 2 of 3


    10. STABILITY AND REACTIVITY
    Reactivity Inert
    Chemical Stability Stable
    Incompatibilities None in normal or expected use
    Decomposition Decomposition will not occur

    11. TOXICOLOGICAL INFORMATION


    This product is non-toxic. Refer to section 2 - Hazards Identification.

    12. ECOLOGICAL INFORMATION


    This material is unlikely to cause any environmental damage. It is insoluble in water and is unlikely to
    contaminate waterways or food chains.

    13. DISPOSAL CONSIDERATION


    Disposal must be in accordance with Federal, State and Local Council regulations. If approved, may be
    transferred to an approved landfill site.

    Note: Many states are developing new regulations for the disposal of waste containing Naturally Occurring
    Radioactive Materials (NORM) or Technologically Enhanced Naturally Occurring Radioactive Materials
    (TENORM) above background levels. Consult and comply with current regulations.

    14. TRANSPORT INFORMATION


    Transport may be regulated in some countries, although the product is not generally regarded as a transport
    hazard. Not classified as radioactive pursuant to paragraph 107 of IAEA TS-R-1 regulations. Trucks
    however should be covered when transporting dry bulk product to prevent dust generation.

    15. REGULARTORY INFORMATION


    None stated.

    16. OTHER INFORMATION


    Labelling Labelling not required according to EC-Dir. 67/548, as amended.

    Other Information This MSDS has been prepared by Doral Fused Materials, Safety Health and
    Environment Department.

    Date of Issue 10/12/2007


    Replaces 27/07/2007

    This MSDS is valid for five (5) years from the date of issue but readers should refer to Doral’s website
    (www.doral.com.au) to ensure that this is the latest issue. As per the Worksafe Guidance Note NOHSC 3017,
    each user should review the information in the specific context of the intended application.

    Abbreviations

    Bq/gm Becquerel per gram


    IAEA Inter national Atom ic Ener gy Agenc y
    IRAC International Agency for Research on Cancer
    ICRP International Commission on Radiation Protection
    3
    mg/m Milligram per cubic metre
    ASCC Australian Safety and Compensation Commission
    TLV Threshold Limit Value
    TWA Time Weighted Average

    End of MSDS

    Date of Issue: December 2007 Page 3 of 3

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