Previous HSE Questions From The Chapter "Alcohols, Phenols and Ethers"

Previous HSE questions from the chapter “Alcohols, Phenols and Ethers”
1. Write the preparation of propan-2-ol from a Grignard reagent. (2)

2. Phenols are acidic. Why? (2)
3. (a) What is cumene? Explain the preparation of phenol from cumene. (3)
(b) Identify the compound A.
OH
Na2Cr2O7/H2SO4 A (1)
[SAY 2019]
4. Write the chemical equation representing Reimer-Tiemann reaction. (2)
5. Give the structural formula and IUPAC name of the product formed by the reaction of propanone with
CH3MgBr in dry ether, followed by hydrolysis. (2)
6. Predict the products obtained by the reaction of 2-methoxy-2-methylpropane with HI. (2) [March 2019]
7. (a) Predict the products A and B.
3CH3 - CH =CH2 + (H - BH2)2 A H2O2/OH- B
(b) How methanol is prepared industrially? (4) [SAY 2018]
8. (a) Grignard reagents are important class of organometallic compounds used to prepare alcohols.
Identity the compounds A and B and write the formula.
(b) Write the name of products formed when salicylic acid is treated with acetic anhydride in acid
medium. (4) [March 2018]
9. a) Identify the product:
HCHO CH3MgX/H2O ……………..
i) CH3OH ii) CH3CH2OH iii) CH3-CH-CH3 iv) CH3-CH-CH2-CH3 (1)

OH OH
b) Complete the following:
(3) [SAY 2017]

10. a) Arrange the following compounds in the order of increasing boiling points:
Ethanol, Propan-1-ol, Butan-1-ol, Butan-2-ol (1)
Alcohols, Phenols and Ethers Page 1

b) In the lab, students were asked to carry out the reaction between phenol and conc. HNO3. But one
student, ‘A’ carry out the reaction between phenol and dil. HNO3. Do you think the student ‘A’ got the
same result as others. Substantiate with suitable explanations. [also write the chemical equations
wherever necessary]. (3) [March 2017]
11. a) Phenol when treated with Conc. HNO3 gives,
(i) o-Nitrophenol (ii) p-Nitrophenol (iii) 2,4,6-Trinitrophenol (iv) a mixture of o-
nitrophenol and p-nitrophenol (1)
b) Methanol and ethanol are two commercially important alcohols. Write one method each for the
preaparation of methanol and ethanol. (3) [SAY 2016]
12. a) Complete the following:
(2)
b) Explain the following:
i) Esterification
ii) Williamson Synthesis (2) [March 2016]
13. a) Write a test to distinguish between phenol and alcohol. (1)
b) Write suitable reagent(s) used for the following conversions:
i) CH3-CH2-Cl CH3-CH2-OH
ii) CH3-CH2-OH CH3-CH2-O-CH2-CH3
iii) OH OH
CHO
(3) [SAY 2015]
14. Alcohols are compounds with general formula R-OH.
a) Alcohols are soluble in water. Give reason? (1)
b) i) Explain a method for the manufacture of ethanol. (2)
ii) How will you convert phenol to benzene? (1) [March 2015]
15. a) How will you prepare the following compounds using a Grignard reagent?
i) Primary alcohol
ii) Secondary alcohol (2)
b) How will you distinguish primary and secondary alcohols using Luca’s test? (1)
c) Write the correct pair of reactants for the preparation of t-butyl ether by Williamson synthesis. (1)
[March 2014]
16. a) Write the name or formula of the following:
i) A simple ether
ii) A mixed ether
iii) A dihydric alcohol
iv) A trihydric alcohol (2)
b) Phenol on treatment with Br2 in CS2 at low temperature gives two isomeric monobromophenols ‘X’
and ‘Y’. But phenol on treatment with bromine water gives a white precipitate ‘Z’. Identify the
products ‘X’, ‘Y’ and ‘Z’. (2) [SAY 2014]
17. a) Write the IUPAC names of all the possible isomers with molecular formula C3H8O (1½)

b) Phenol is usually manufactured from cumene. Write the structure of cumene. (½)
c) Primary, secondary and tertiary alcohols can be distinguished by Lucas test.
i) What is Lucas reagent? (½)
ii) Write the observations, for primary, secondary and tertiary alcohols in Lucas test. (1½) [March 2013]
18. How are the following conversions carried out? Represent the chemical reactions.
a) Ethanol to ethanal (1)
b) Phenol to picric acid (1)
c) Phenol to benzene (1)
d) Phenol to tribromophenol (1) [June 2013]
19. a) Write the name or structure of the compounds A and B in the following reactions:
A CHCl3 + NaOH C6H5OH NaOH/CO2 B
H+ H+ (2)
b) Vapours of an alcohol ‘C’ on passing over heated copper produce compound ‘D’. ‘D’ on reaction with
CH3MgCl followed by hydrolysis produces 2-methylbutan-2-ol. Write the name or structure of
compounds ‘C’ and ‘D’. (2) [March 2012]
20. Methanol and ethanol are two commercially important alcohols.
i) Write one method of preparation of methanol and ethanol. (2)
ii) Name the products obtained when ethanol is treated with CrO3 in anhydrous medium. (1)
iii) The boiling point of ethanol is higher than that of methoxy methane. Give reason. (1) [SAY 2012]
21. Ethers are generally non-reactive compounds. One of the important reactions of ethers is the action of
HI.
C6H5-O-CH3 HI A + B
Identify A and B. explain the reaction. (4) [March 2011]
22. Mixture of Conc. HCl and anhydrous ZnCl2 is an important reagent which helps to distinguish between 10,
20 and 30 alcohols.
a) Give the name of the above reagent. (½)
b) Give one example each for 10, 20 and 30 alcohols. (1½)
c) Explain how the above reagent helps to distinguish above three types of alcohols. (2) [SAY 2011]
23. Phenols are more acidic than alcohols.
a) Name the product obtained when phenol is treated with chloroform in the presence of NaOH. (½)
b) Name the above reaction. (½)
c) What is the product obtained when phenol is treated with Conc. HNO3? (½)
d) Write the structure and IUPAC name of the above product. (1)
e) Ethanol and propane have comparable molecular masses, but their boiling points differ widely.
Which of them have higher boiling points? Substantiate your answer. (1½) [March 2010]
24. Ethanol can be prepared by treating HCHO and CH3CH2MgBr.
a) Is the above statement true? (1)
b) Justify your answer. (2) [March 2010]
25. Williamson’s synthesis is an important method of ether synthesis.
c) To synthesis tertiary butyl ether, which of the following reagent sets are better? Justify.
i) (CH3)3C-Br + CH3ONa
ii) (CH3)3C-ONa + CH3-Br. (2)
d) Explain the cleavage of C-O in CH3-CH2-O-CH3 when treated with HI. (1)
26. The bond angle in C-O-H in alcohols is slightly less than tetrahedral angle.
a) Give the reason for the difference in the bond angle observed in alcohol. (1)
b) What is the bond angle in C-O-H in phenol? Give the reason for the variation. (2)
c) Alcohols undergo dehydration. How is ethanol converted to ethene? (1) [March 2008]

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Previous HSE Questions From The Chapter "Alcohols, Phenols and Ethers"

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Previous HSE questions from the chapter “Alcohols, Phenols and Ethers”

1. Write the preparation of propan-2-ol from a Grignard reagent. (2)

i) CH3OH ii) CH3CH2OH iii) CH3-CH-CH3 iv) CH3-CH-CH2-CH3 (1)

(3) [SAY 2017]

Alcohols, Phenols and Ethers Page 1

Alcohols, Phenols and Ethers Page 2

Alcohols, Phenols and Ethers Page 3

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