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    Mid-Semester Paper 09

    Uploaded by

    Harsh Thakur
    This document appears to be an exam for a chemistry course covering several topics: 1) It contains two sections - Section A with 3 questions and Section B with 3 questions. Section A covers topics like phase equilibria, Gibbs phase rule, and calorimetry. Section B covers topics like adsorption isotherms, enzyme kinetics, reaction mechanisms. 2) The questions involve deriving expressions, explaining concepts through diagrams, calculations to determine calorific values, discussing features of reaction mechanisms, and critically analyzing kinetic isotope effects. 3) The exam tests a range of core chemistry concepts and requires both conceptual understanding and quantitative problem-solving abilities across multiple areas of chemistry like thermodynamics, kinetics,

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    Mid-Semester Paper 09

    Uploaded by

    Harsh Thakur
    18 views2 pages
    This document appears to be an exam for a chemistry course covering several topics: 1) It contains two sections - Section A with 3 questions and Section B with 3 questions. Section A covers topics like phase equilibria, Gibbs phase rule, and calorimetry. Section B covers topics like adsorption isotherms, enzyme kinetics, reaction mechanisms. 2) The questions involve deriving expressions, explaining concepts through diagrams, calculations to determine calorific values, discussing features of reaction mechanisms, and critically analyzing kinetic isotope effects. 3) The exam tests a range of core chemistry concepts and requires both conceptual understanding and quantitative problem-solving abilities across multiple areas of chemistry like thermodynamics, kinetics,

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    Mid-semester Paper 09

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    This document appears to be an exam for a chemistry course covering several topics: 1) It contains two sections - Section A with 3 questions and Section B with 3 questions. Section A covers topics like phase equilibria, Gibbs phase rule, and calorimetry. Section B covers topics like adsorption isotherms, enzyme kinetics, reaction mechanisms. 2) The questions involve deriving expressions, explaining concepts through diagrams, calculations to determine calorific values, discussing features of reaction mechanisms, and critically analyzing kinetic isotope effects. 3) The exam tests a range of core chemistry concepts and requires both conceptual understanding and quantitative problem-solving abilities across multiple areas of chemistry like thermodynamics, kinetics,

    Copyright:

    © All Rights Reserved
    Download as PDF, TXT or read online from Scribd
    Download as pdf or txt
    18 views2 pages

    Mid-Semester Paper 09

    Uploaded by

    Harsh Thakur
    This document appears to be an exam for a chemistry course covering several topics: 1) It contains two sections - Section A with 3 questions and Section B with 3 questions. Section A covers topics like phase equilibria, Gibbs phase rule, and calorimetry. Section B covers topics like adsorption isotherms, enzyme kinetics, reaction mechanisms. 2) The questions involve deriving expressions, explaining concepts through diagrams, calculations to determine calorific values, discussing features of reaction mechanisms, and critically analyzing kinetic isotope effects. 3) The exam tests a range of core chemistry concepts and requires both conceptual understanding and quantitative problem-solving abilities across multiple areas of chemistry like thermodynamics, kinetics,

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    You are on page 1of 2

    Roll No……………………….

    Date- 17/09/2009
    School of Petroleum Technology
    Pandit Deen Dayal Petroleum University, Gandhinagar
    Mid-Semester Examination
    B.Tech. I Semester (2009-10)
    Subject: Chemistry Subject Code: CHEM101
    MM: 60 Time Duration: Two Hours

    Answer section-A and section-B separately.


    All questions are compulsory.
    Section-A
    1. A) Write the number of components in the following equilibriums. (1x4)
    a) CuSO4. 5 H2O(s) CuSO4.3H2O(s) +2H2O(g)
    b) N2O4(g) 2NO2(g)
    c) NH4Cl(s) NH3(g)+
    d)
    e) HCl (g), when P(NH3)=P(HCl)
    f) C(s) CO(g) CO2 O2 (g)
    B) Why three dimensional model is needed for two component Ag-Pb system? How is
    this difficulty overcome? Discuss the application of this system. (1+2+3)

    2. A) What is Gibb’s phase rule? Explain the terms involved in it with suitable diagram.
    Draw a phase diagram for such a one-component system which contains more than one
    solid phase. (2+3+2)
    B) Calculate the gross and net calorific value of a coal sample having following
    composition by weight: C=80%, H=7%, O=3%, S=3.5%, N=2.1% and rest is ash. The
    value of latent heat of vaporization is 580 cal/g. (3)

    3. A)Explain the following with suitable diagram(any two) : (2.5+2.5)


    i) Congruent and incongruent melting compounds ii) Bi-Cd alloy system iii)KI-H2O
    system

    1|Page
    B) Discuss the merits and demerits of gaseous fuel over liquid and solid fuels. Describe
    the determination of calorific value of gaseous fuel by Junkers’ calorimeter with neat and
    labeled diagram. (2+3)

    OR
    3. A) Write an equation for theoretical calculation of calorific value of fuel. (3)
    B) Why should ideal fuel have moderate ignition temperature? (2)
    C) Solid fuel weighing 0.98g and containing 90% carbon and 8% hydrogen gave the
    following results in the Bomb calorimeter experiment: amount of water taken in
    calorimeter=1450g, water equivalent in ht calorimeter =450g, rise in temperature of
    water=1.8%, cooling correction 0.052%, fuse wire correction=10 cal. acid correction=40
    cal. If the value latent heat of steam is 587 cal/g, calculate the gross and net calorific
    value. (5)

    Section-B

    4. Derive an expression for the number of molecules adsorbed at all sites for a single gas
    undergoing multilayer adsorption. (10)

    5. (A) Discuss in brief, the mechanism of enzyme catalysis. Derive the Michaelis-Menten’s
    equation for enzyme catalysis. Show that at high substrate concentration, the rate of product
    formation is independent of the substrate concentration. (2+5+1)
    (B) Write the mechanism for the addition of an inter-halogen compound of type A-B to ethylene,
    where A is more electronegative than B. (2)

    6. (A) Critically discuss the features (with mechanism) of SN1 and SN2 reactions of alkyl halides
    to form alcohols. (7)
    (B) Discuss the primary kinetic isotope effect. Why nitration of C6H6 and C6D6 does not show
    any such effect? (2+1=3)
    …………………………………………………………………………………………………………………………………………………
    Best of Luck!

    2|Page

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