Edexcel IGCSE Chemistry Topic 2: Inorganic Chemistry

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Edexcel​ ​IGCSE​ ​Chemistry

Topic​ ​2:​ ​Inorganic​ ​chemistry


Reactivity​ ​series

Notes

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2.15​ ​understand​ ​how​ ​metals​ ​can​ ​be​ ​arranged​ ​in​ ​a​ ​reactivity​ ​series​ ​based​ ​on
their​ ​reactions​ ​with:​ ​water,​ ​dilute​ ​hydrochloric​ ​or​ ​sulfuric​ ​acid

● A​ ​few​ ​reactive​ ​metals​ ​will​ ​react​ ​with​ ​cold​ ​water:


○ Products​ ​are​ ​a​ ​metal​ ​hydroxide​ ​(forming​ ​an​ ​alkaline​ ​solution)​ ​and
hydrogen​ ​gas​ ​(can​ ​see​ ​bubbles​ ​given​ ​off)
○ E.g.​ ​with​ ​potassium:​ ​2K​ ​+​ ​2H​2​O​ ​->​ ​2KOH​ ​+​ ​H​2
● Most​ ​metals​ ​react​ ​with​ ​acid:
○ acid​ ​+​ ​metal​ ​→​ ​salt​ ​+​ ​hydrogen​ ​(can​ ​see​ ​bubbles​ ​of​ ​H​2​​ ​given​ ​off)
● Almost​ ​all​ ​metals​ ​react​ ​with​ ​oxygen​ ​:
○ metal​ ​+​ ​oxygen​ ​→​ ​metal​ ​oxide
○ Only​ ​metal​ ​that​ ​does​ ​not​ ​react​ ​with​ ​any​ ​of​ ​the​ ​above​ ​is​ ​gold,​ ​because​ ​it​ ​is
extremely​ ​unreactive
● You​ ​can​ ​therefore​ ​deduce​ ​the​ ​relative​ ​reactivity​ ​of​ ​some​ ​metals​ ​by​ ​seeing​ ​if​ ​they
react​ ​with​ ​water​ ​(i.e.​ ​VERY​ ​reactive),​ ​acid​ ​(reactive),​ ​and​ ​oxygen​ ​(not​ ​that
reactive)

2.16​ ​understand​ ​how​ ​metals​ ​can​ ​be​ ​arranged​ ​in​ ​a​ ​reactivity​ ​series​ ​based​ ​on
their​ ​displacement​ ​reactions​ ​between:​ ​metals​ ​and​ ​metal​ ​oxides,​ ​metals​ ​and
aqueous​ ​solutions​ ​of​ ​metal​ ​salts

▪ You​ ​can​ ​see​ ​if​ ​one​ ​metal​ ​is​ ​more​ ​reactive​ ​than​ ​another​ ​by​ ​using​ ​displacement
reactions:
o Easily​ ​seen​ ​when​ ​a​ ​salt​ ​of​ ​the​ ​less​ ​reactive​ ​metal​ ​is​ ​in​ ​the​ ​solution
▪ More​ ​reactive​ ​metal​ ​gradually​ ​disappears​ ​as​ ​it​ ​forms​ ​a​ ​solution
▪ Less​ ​reactive​ ​metal​ ​coats​ ​the​ ​surface​ ​of​ ​the​ ​more​ ​reactive​ ​metal

2.17​ ​know​ ​the​ ​order​ ​of​ ​reactivity​ ​of​ ​these​ ​metals:​ ​potassium,​ ​sodium,
lithium,​ ​calcium,​ ​magnesium,​ ​aluminium,​ ​zinc,​ ​iron,​ ​copper,​ ​silver,​ ​gold

● When​ ​metals​ ​react​ ​with​ ​other​ ​substances,​ ​metal​ ​atoms​ ​form​ ​positive​ ​ions
● Reactivity​ ​of​ ​a​ ​metal​ ​is​ ​related​ ​to​ ​its​ ​tendency​ ​to​ ​form​ ​positive​ ​ions
● Metals​ c​ an​ ​be​ ​arranged​ ​in​ ​order​ ​of​ ​their​ ​reactivity​ ​in​ ​a​ ​reactivity​ ​series
o Metals​ ​potassium,​ ​sodium,​ ​lithium,​ ​calcium,​ ​magnesium,​ ​zinc,​ ​iron​ ​and
copper​ ​can​ ​be​ ​put​ ​in​ ​order​ ​of​ ​their​ ​reactivity​ ​from​ ​their​ ​reactions​ ​with
water​ ​and​ ​dilute​ ​acids
o Non-metals​ ​hydrogen​ ​and​ ​carbon​ ​are​ ​often​ ​included​ ​in​ ​the​ ​reactivity
series
● A​ ​more​ ​reactive​ ​metal​ ​can​ ​displace​ ​a​ ​less​ ​reactive​ ​metals​ ​from​ ​a​ ​compound
(think​ ​about​ ​how​ ​this​ ​is​ ​similar​ ​as​ ​well​ ​to​ ​halogens)

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reactivity​ ​series:

2.18​ ​know​ ​the​ ​conditions​ ​under​ ​which​ ​iron​ ​rusts

● Both​ ​air​ ​and​ ​water​ ​are​ ​necessary​ ​for​ ​iron​ ​to​ ​rust​ ​–​ ​i.e.​ ​oxidation​ ​–​ ​gain​ ​of​ ​oxygen
results​ ​in​ ​corrosion

2.19​ ​understand​ ​how​ ​the​ ​rusting​ ​of​ ​iron​ ​may​ ​be​ ​prevented​ ​by:​ ​barrier
methods,​ ​galvanising,​ ​sacrificial​ ​protection
● rusting​ ​can​ ​be​ ​prevented​ ​by​ ​excluding​ ​oxygen​ ​and​ ​water​ ​e.g.​ ​by:
o painting
o coating​ ​with​ ​plastic
o using​ ​oil​ ​or​ ​grease
● water​ ​can​ ​be​ ​kept​ ​away​ ​using​ ​a​ ​desiccant​ ​in​ ​the​ ​container​ ​(absorbs​ ​water
vapour)
● oxygen​ ​can​ ​be​ ​kept​ ​away​ ​by​ ​storing​ ​the​ ​metal​ ​in​ ​a​ ​vacuum​ ​container
● Sacrificial​ ​protection:​ ​where​ ​the​ ​metal​ ​you​ ​want​ ​to​ ​be​ ​protected​ ​from​ ​rusting​ ​is
galvanised​ ​with​ ​a​ ​more​ ​reactive​ ​metal,​ ​which​ ​will​ ​rust​ ​first​ ​and​ ​prevent​ ​water
and​ ​oxygen​ ​reaching​ ​the​ ​layer​ ​underneath
o E.g.​ ​zinc​ ​is​ ​used​ ​to​ ​galvanise​ ​iron

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2.20​ ​understand​ ​the​ ​terms:​ ​oxidation,​ ​reduction,​ ​redox,​ ​oxidising​ ​agent,
reducing​ ​agent​ ​in​ ​terms​ ​of​ ​gain​ ​or​ ​loss​ ​of​ ​oxygen​ ​and​ ​loss​ ​or​ ​gain​ ​of
electrons

● oxidation:​ ​gain​ ​of​ ​oxygen​ ​OR​ ​loss​ ​of​ ​electrons


● reduction:​ ​loss​ ​of​ ​oxygen​ ​OR​ ​gain​ ​of​ ​electrons
● redox:​ ​a​ ​reaction​ ​in​ ​which​ ​both​ ​oxidation​ ​and​ ​reduction​ ​occur
● oxidising​ ​agent:​ ​causes​ ​another​ ​reactant​ ​to​ ​be​ ​oxidised​ ​and​ ​is​ ​reduced​ ​itself
● reducing​ ​agent:​ ​causes​ ​another​ ​reactant​ ​to​ ​be​ ​reduced​ ​and​ ​is​ ​oxidised​ ​itself

2.21​ ​practical:​ ​investigate​ ​reactions​ ​between​ ​dilute​ ​hydrochloric​ ​and​ ​sulfuric


acids​ ​and​ ​metals​ ​(e.g.​ ​magnesium,​ ​zinc​ ​and​ ​iron)

● in​ ​the​ ​diagram​ ​showing​ ​the​ ​reactivity​ ​series,​ ​you​ ​can​ ​see​ ​that​ ​only​ ​the​ ​more
reactive​ ​metals​ ​will​ ​react​ ​with​ ​dilute​ ​acids​ ​(up​ ​to​ ​iron)
● metal​ ​+​ ​acid​ ​→​ ​hydrogen​ ​+​ ​salt
● you​ ​can​ ​observe​ ​the​ ​reaction​ ​of​ ​different​ ​metals​ ​with​ ​acids,​ ​as​ ​the​ ​most​ ​reactive
will​ ​give​ ​off​ ​large​ ​amounts​ ​of​ ​H​2​​ ​gas​ ​bubbles​ ​and​ ​the​ ​least​ ​reactive​ ​will​ ​not​ ​give
off​ ​any​ ​at​ ​all

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