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Safety data sheet

according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

SECTION 1: Identification of the substance/mixture and of the company/

undertaking
1.1 Product identifier
Trade name: Zero oxygen tablets for InLab® sensors
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the mixture Tablets for calibration of InLab sensors
®

1.3 Details of the supplier of the safety data sheet

Supplier:
Mettler-Toledo AG
Im Hackacker 15,
CH-8902 Urdorf
Tel. +41 44 729 62 11
Fax +41 44 729 66 36
Manufacturer:
Oxytabs Tablettenproduktion GmbH
- Member of the Medea Group -
Suhmsberg 40
D-24768 Rendsburg
Germany
Further information obtainable from:
Tel.: +49 4331 69620 0
Fax: +49 4331 69620 22
E-Mail: info@medeagroup.de
1.4 Emergency telephone number:
Giftnotruf der Charité - Universitätsmedizin Berlin
D-13437 Berlin
Tel: +49 30 30686 700

* SECTION 2: Hazards identification

2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
Eye Dam. 1 H318 Causes serious eye damage.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms

GHS05

Signal word Danger

Hazard statements
H318 Causes serious eye damage.
Precautionary statements
P264 Wash hands thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present
and easy to do. Continue rinsing.
P310 Immediately call a POISON CENTER/doctor.
(Contd. on page 2)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 1)
2.3 Other hazards
Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.

SECTION 3: Composition/information on ingredients

3.2 Chemical characterisation: Mixtures
Description: Mixture of substances listed below with nonhazardous additions.
Dangerous components:
CAS: 124-04-9 adipic acid Eye Irrit. 2, H319 10-<25%
EINECS: 204-673-3
Index number: 607-144-00-9
Reg.nr.: 01-2119457561-38
Additional information: For the wording of the listed hazard phrases refer to section 16.

SECTION 4: First aid measures

4.1 Description of first aid measures
After inhalation: No special measures required.
After skin contact: Immediately rinse with water.
After eye contact: Rinse opened eye for several minutes under running water. Then consult a doctor.
After swallowing:
Rinse out mouth and then drink plenty of water.
If symptoms persist consult doctor.
4.2 Most important symptoms and effects, both acute and delayed
No further relevant information available.
4.3 Indication of any immediate medical attention and special treatment needed
No further relevant information available.

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray.
Product itself does not burn.
5.2 Special hazards arising from the substance or mixture No further relevant information available.
5.3 Advice for firefighters
Protective equipment: Wear self-contained respiratory protective device.

SECTION 6: Accidental release measures

6.1 Personal precautions, protective equipment and emergency procedures
Avoid contact with the eyes and skin.
6.2 Environmental precautions: Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Pick up mechanically.
Wash residues with water.
(Contd. on page 3)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 2)
6.4 Reference to other sections
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.

SECTION 7: Handling and storage

7.1 Precautions for safe handling No special precautions are necessary if used correctly.
7.2 Conditions for safe storage, including any incompatibilities
Storage:
Requirements to be met by storerooms and receptacles: Store only in the original receptacle.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Keep container tightly sealed.
Protect from humidity and water.
7.3 Specific end use(s) No further relevant information available.

SECTION 8: Exposure controls/personal protection

Additional information about design of technical facilities: No further data; see item 7.
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
The product does not contain any relevant quantities of materials with critical values that have to be monitored at
the workplace.
Additional information: The lists valid during the making were used as basis.
8.2 Exposure controls
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
Respiratory protection: Not required.
Protection of hands: Protective gloves.
Material of gloves
Nitrile rubber, NBR
Recommended thickness of the material:  0.11 mm
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection: Tightly sealed goggles
Body protection: Protective work clothing.
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 3)

SECTION 9: Physical and chemical properties

9.1 Information on basic physical and chemical properties
General Information
Appearance:
Form: Tablets
Colour: White
Odour: neutral
Odour threshold: Not determined.
pH-value: Not applicable.
Change in condition
Melting point/freezing point: Not determined.
Initial boiling point and boiling range: Not determined.
Flash point: Not applicable.
Flammability (solid, gas): Not determined.
Ignition temperature: Not determined.
Decomposition temperature: Not determined.
Auto-ignition temperature: Product is not selfigniting.
Explosive properties: Product does not present an explosion hazard.
Explosion limits:
Lower: Not determined.
Upper: Not determined.
Vapour pressure: Not applicable.
Density: Not determined.
Relative density Not determined.
Vapour density Not applicable.
Evaporation rate Not applicable.
Solubility in / Miscibility with
water: Easily soluble.
Partition coefficient: n-octanol/water: Not determined.
Viscosity:
Dynamic: Not applicable.
Kinematic: Not applicable.
Solvent content:
Organic solvents: 0.0 %
VOC (EC) 0,00 %
Solids content: 100.0 %
9.2 Other information No further relevant information available.

SECTION 10: Stability and reactivity

10.1 Reactivity No further relevant information available.
10.2 Chemical stability Stable if stored according to specifications.
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
(Contd. on page 5)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 4)
10.3 Possibility of hazardous reactions No dangerous reactions known.
10.4 Conditions to avoid No further relevant information available.
10.5 Incompatible materials: No further relevant information available.
10.6 Hazardous decomposition products: No dangerous decomposition products known.

SECTION 11: Toxicological information

11.1 Information on toxicological effects
Acute toxicity Based on available data, the classification criteria are not met.
Primary irritant effect:
Skin corrosion/irritation Based on available data, the classification criteria are not met.
Serious eye damage/irritation
Causes serious eye damage.
Respiratory or skin sensitisation Based on available data, the classification criteria are not met.
CMR effects (carcinogenity, mutagenicity and toxicity for reproduction)
Germ cell mutagenicity Based on available data, the classification criteria are not met.
Carcinogenicity Based on available data, the classification criteria are not met.
Reproductive toxicity Based on available data, the classification criteria are not met.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure Based on available data, the classification criteria are not met.
Aspiration hazard Based on available data, the classification criteria are not met.

SECTION 12: Ecological information

12.1 Toxicity
Aquatic toxicity:
124-04-9 adipic acid
LC50/48h 46 mg/l (Daphnia magna) (OECD 202)
LC50/96h 230 mg/l (Leuciscus idus)
12.2 Persistence and degradability No further relevant information available.
12.3 Bioaccumulative potential No further relevant information available.
12.4 Mobility in soil No further relevant information available.
Additional ecological information:
General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
12.5 Results of PBT and vPvB assessment
PBT: Not applicable.
vPvB: Not applicable.
12.6 Other adverse effects No further relevant information available.

SECTION 13: Disposal considerations

13.1 Waste treatment methods
Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging:
Recommendation: Disposal must be made according to official regulations.
(Contd. on page 6)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 5)
Recommended cleansing agents: Water, if necessary together with cleansing agents.

SECTION 14: Transport information

14.1 UN-Number
ADR, ADN, IMDG, IATA Not regulated.
14.2 UN proper shipping name
ADR, ADN, IMDG, IATA Not regulated.
14.3 Transport hazard class(es)
ADR, ADN, IMDG, IATA
Class Not regulated.
14.4 Packing group
ADR, IMDG, IATA Not regulated.
14.5 Environmental hazards:
Marine pollutant: No
14.6 Special precautions for user Not applicable.
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
UN "Model Regulation": Not regulated.

SECTION 15: Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
Labelling according to Regulation (EC) No 1272/2008 GHS label elements
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
National regulations:
The product is subject to be labeled according to the prevailing version of the regulations on hazardous substances.
15.2 Chemical safety assessment: A Chemical Safety Assessment has not been carried out.

* SECTION 16: Other information

This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific
product features and shall not establish a legally valid contractual relationship.
Relevant phrases
H319 Causes serious eye irritation.
Department issuing SDS: Department R&D
Contact: Dr. Nico Kotzur
Created by: SKÜ
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of
Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
(Contd. on page 7)
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Safety data sheet
according to 1907/2006/EC, Article 31
Printing date: 20.05.2020 Version number 3 Revision: 20.05.2020

Trade name: Zero oxygen tablets for InLab® sensors

(Contd. of page 6)
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
VOC: Volatile Organic Compounds (USA, EU)
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Eye Dam. 1: Serious eye damage/eye irritation – Category 1
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
* Data changed with respect to previous version.
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