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Contents
1History
2Theory and construction
o 2.1Order of module connection
3Efficiency
o 3.1Radiation-dependent efficiency
o 3.2Arrays of PV modules
o 3.3Aluminum nanocylinders
4Technology
o 4.1Thin film
5Smart solar modules
6Performance and degradation
7Maintenance
8Recycling
9Production
10Price
11Mounting and tracking
12Standards
13Connectors
14Applications
15Limitations
o 15.1Impact on electricity network
o 15.2Implication onto electricity bill management and energy investment
16Gallery
17See also
18References
History[edit]
See also: Solar cell § History, and Timeline of solar cells
In 1839, the ability of some materials to create an electrical charge from light
exposure was first observed by Alexandre-Edmond Becquerel.[1] Though the
premiere solar panels were too inefficient for even simple electric devices they were
used as an instrument to measure light.[2] The observation by Becquerel was not
replicated again until 1873, when Willoughby Smith discovered that the charge could
be caused by light hitting selenium. After this discovery, William Grylls Adams and
Richard Evans Day published "The action of light on selenium" in 1876, describing
the experiment they used to replicate Smith's results. [1][3]
In 1881, Charles Fritts created the first commercial solar panel, which was reported
by Fritts as "continuous, constant and of considerable force not only by exposure to
sunlight but also to dim, diffused daylight." [4] However, these solar panels were very
inefficient, especially compared to coal-fired power plants. In 1939, Russell
Ohl created the solar cell design that is used in many modern solar panels. He
patented his design in 1941.[5] In 1954, this design was first used by Bell Labs to
create the first commercially viable silicon solar cell.[1] In 1957, Mohamed M.
Atalla developed the process of silicon surface passivation by thermal oxidation at
Bell Labs.[6][7] The surface passivation process has since been critical to solar cell
efficiency.[8]
Photovoltaic modules use light energy (photons) from the Sun to generate electricity
through the photovoltaic effect. Most modules use wafer-based crystalline
silicon cells or thin-film cells. The structural (load carrying) member of a module can
be either the top layer or the back layer. Cells must be protected from mechanical
damage and moisture. Most modules are rigid, but semi-flexible ones based on thin-
film cells are also available. The cells are usually connected electrically in series,
one to another to the desired voltage, and then in parallel to increase current. The
power (watts) of the module is the mathematical product of the voltage (volts) and
the current (amps) of the module. The manufacture specifications on solar panels
are obtained under standard condition which is not the real operating condition the
solar panels are exposed to on the installation site. [9]
A PV junction box is attached to the back of the solar panel and functions as its
output interface. External connections for most photovoltaic modules use MC4
connectors to facilitate easy weatherproof connections to the rest of the system. A
USB power interface can also be used.[citation needed]
Order of module connection[edit]
Module electrical connections are made in series to achieve a desired output voltage
or in parallel to provide a desired current capability (amperes) of the solar panel or
the PV system. The conducting wires that take the current off the modules are sized
according to the current rating and may contain silver, copper or other non-magnetic
conductive transition metals. Bypass diodes may be incorporated or used externally,
in case of partial module shading, to maximize the output of module sections still
illuminated.[citation needed]
Some special solar PV modules include concentrators in which light is focused
by lenses or mirrors onto smaller cells. This enables the use of cells with a high cost
per unit area (such as gallium arsenide) in a cost-effective way.[citation needed]
Solar panels also use metal frames consisting of racking components, brackets,
reflector shapes, and troughs to better support the panel structure.
Efficiency[edit]
See also: Solar cell efficiency
Reported timeline of champion solar module energy conversion efficiencies since 1988 (National
Renewable Energy Laboratory)
Each module is rated by its DC output power under standard test conditions (STC)
and hence the on field output power might vary. Power typically ranges from 100 to
365 Watts (W). The efficiency of a module determines the area of a module given
the same rated output – an 8% efficient 230 W module will have twice the area of a
16% efficient 230 W module. Some commercially available solar modules exceed
24% efficiency.[10][11] Currently, the best achieved sunlight conversion rate (solar
module efficiency) is around 21.5% in new commercial products [12] typically lower
than the efficiencies of their cells in isolation. The most efficient mass-produced solar
modules[disputed – discuss] have power density values of up to 175 W/m2 (16.22 W/ft2).[13]
Scientists from Spectrolab, a subsidiary of Boeing, have reported development
of multi-junction solar cells with an efficiency of more than 40%, a new world record
for solar photovoltaic cells.[14] The Spectrolab scientists also predict that concentrator
solar cells could achieve efficiencies of more than 45% or even 50% in the future,
with theoretical efficiencies being about 58% in cells with more than three junctions.
Radiation-dependent efficiency[edit]
Depending on construction, photovoltaic modules can produce electricity from a
range of frequencies of light, but usually cannot cover the entire solar radiation range
(specifically, ultraviolet, infrared and low or diffused light). Hence, much of the
incident sunlight energy is wasted by solar modules, and they can give far higher
efficiencies if illuminated with monochromatic light. Therefore, another design
concept is to split the light into six to eight different wavelength ranges that will
produce a different color of light, and direct the beams onto different cells tuned to
those ranges.[15] This has been projected to be capable of raising efficiency by 50%.
Arrays of PV modules[edit]
A single solar module can produce only a limited amount of power; most installations
contain multiple modules adding voltages or current to the wiring and PV system. A
photovoltaic system typically includes an array of photovoltaic modules, an inverter,
a battery pack for energy storage, charge controller, interconnection wiring, circuit
breakers, fuses, disconnect switches, voltage meters, and optionally a solar
tracking mechanism. Equipment is carefully selected to optimize output, energy
storage, reduce power loss during power transmission, and conversion from direct
current to alternating current.
Aluminum nanocylinders[edit]
Research by Imperial College London has shown that solar panel efficiency is
improved by studding the light-receiving semiconductor surface
with aluminum nanocylinders, similar to the ridges on Lego blocks.
The scattered light then travels along a longer path in the semiconductor, absorbing
more photons to be converted into current. Although these nanocylinders have been
used previously (aluminum was preceded by gold and silver), the light scattering
occurred in the near-infrared region and visible light was absorbed strongly.
Aluminum was found to have absorbed the ultraviolet part of the spectrum, while the
visible and near-infrared parts of the spectrum were found to be scattered by the
aluminum surface. This, the research argued, could bring down the cost significantly
and improve the efficiency as aluminum is more abundant and less costly than gold
and silver. The research also noted that the increase in current makes thinner film
solar panels technically feasible without "compromising power conversion
efficiencies, thus reducing material consumption". [16]
Technology[edit]
Main articles: Crystalline silicon and Thin film solar cell
Most solar modules are currently produced from crystalline silicon (c-Si) solar
cells made of multicrystalline and monocrystalline silicon. In 2013, crystalline silicon
accounted for more than 90 percent of worldwide PV production, while the rest of the
overall market is made up of thin-film technologies using cadmium
telluride, CIGS and amorphous silicon[18]
Emerging, third generation solar technologies use advanced thin-film cells. They
produce a relatively high-efficiency conversion for the low cost compared to other
solar technologies. Also, high-cost, high-efficiency, and close-packed
rectangular multi-junction (MJ) cells are preferably used in solar panels on
spacecraft, as they offer the highest ratio of generated power per kilogram lifted into
space. MJ-cells are compound semiconductors and made of gallium
arsenide (GaAs) and other semiconductor materials. Another emerging PV
technology using MJ-cells is concentrator photovoltaics ( CPV ).
Thin film[edit]
In rigid thin-film modules, the cell and the module are manufactured in the same
production line. The cell is created on a glass substrate or superstrate, and the
electrical connections are created in situ, a so-called "monolithic integration." The
substrate or superstrate is laminated with an encapsulant to a front or back sheet,
usually another sheet of glass. The main cell technologies in this category are CdTe,
or a-Si, or a-Si+uc-Si tandem, or CIGS (or variant). Amorphous silicon has a sunlight
conversion rate of 6–12%.[citation needed]
Flexible thin film cells and modules are created on the same production line by
depositing the photoactive layer and other necessary layers on a flexible substrate. If
the substrate is an insulator (e.g. polyester or polyimide film)
then monolithic integration can be used. If it is a conductor then another technique
for electrical connection must be used. The cells are assembled into modules
by laminating them to a transparent colourless fluoropolymer on the front side
(typically ETFE or FEP) and a polymer suitable for bonding to the final substrate on
the other side.
Maintenance[edit]
Solar panel conversion efficiency, typically in the 20% range, is reduced by the
accumulation of dust, grime, pollen, and other particulates on the solar panels,
collectively referred to as soiling. "A dirty solar panel can reduce its power
capabilities by up to 30% in high dust/pollen or desert areas", says Seamus Curran,
associate professor of physics at the University of Houston and director of the
Institute for NanoEnergy, which specializes in the design, engineering, and assembly
of nanostructures.[28] The average soiling loss in the world in 2018 is estimated to at
least 3% - 4%.[29]
Paying to have solar panels cleaned is a good investment in many regions, as of
2019.[29] However, in some regions, cleaning is not cost-effective. In California as of
2013 soiling-induced financial losses were rarely enough to warrant the cost of
washing the panels. On average, panels in California lost a little less than 0.05% of
their overall efficiency per day.[30]
There are also occupational hazards with solar panel installation and maintenance.
Birds nests and other debris that can get lodged under the solar panels, which can
cause disruptions in the system, lead to fire if there are any loose connections, or
just cause the system to degrade over time. [citation needed]
Recycling[edit]
Most parts of a solar module can be recycled including up to 95% of certain
semiconductor materials or the glass as well as large amounts of ferrous and non-
ferrous metals.[31] Some private companies and non-profit organizations are currently
engaged in take-back and recycling operations for end-of-life modules. [32]
Recycling possibilities depend on the kind of technology used in the modules:
Silicon based modules: aluminum frames and junction boxes are dismantled
manually at the beginning of the process. The module is then crushed in a mill
and the different fractions are separated - glass, plastics and metals. [33] It is
possible to recover more than 80% of the incoming weight. [34] This process can be
performed by flat glass recyclers since morphology and composition of a PV
module is similar to those flat glasses used in the building and automotive
industry. The recovered glass, for example, is readily accepted by the glass foam
and glass insulation industry.
Non-silicon based modules: they require specific recycling technologies such
as the use of chemical baths in order to separate the different semiconductor
materials.[35] For cadmium telluride modules, the recycling process begins by
crushing the module and subsequently separating the different fractions. This
recycling process is designed to recover up to 90% of the glass and 95% of the
semiconductor materials contained.[36] Some commercial-scale recycling facilities
have been created in recent years by private companies. [37] For aluminium flat
plate reflector: the trendiness of the reflectors has been brought up by fabricating
them using a thin layer (around 0.016 mm to 0.024 mm) of aluminum coating
present inside the non-recycled plastic food packages. [38]
Since 2010, there is an annual European conference bringing together
manufacturers, recyclers and researchers to look at the future of PV module
recycling.[39][40] EU law requires manufacturers to ensure their solar panels are
recycled properly. Similar legislation is underway in Japan, India, and Australia.[41]
Production[edit]
See also: List of photovoltaics companies
The production of PV systems has followed a classic learning curve effect, with
significant cost reduction occurring alongside large rises in efficiency and production
output.[42]
Top Module
Shipments in 2019 (GW) [43]
Producer
JA Solar 10.3
Price[edit]
See also: Grid parity
Swanson's law states that with every doubling of production of panels, there has been a 20 percent
reduction in the cost of panels.[51]
The price of solar electrical power has continued to fall so that in many countries it
has become cheaper than ordinary fossil fuel electricity from the electricity grid since
2012, a phenomenon known as grid parity.[52]
Average pricing information divides in three pricing categories: those buying small
quantities (modules of all sizes in the kilowatt range annually), mid-range buyers
(typically up to 10 MWp annually), and large quantity buyers (self-explanatory—and
with access to the lowest prices). Over the long term there is clearly a systematic
reduction in the price of cells and modules. For example, in 2012 it was estimated
that the quantity cost per watt was about US$0.60, which was 250 times lower than
the cost in 1970 of US$150.[53][54] A 2015 study shows price/kWh dropping by 10% per
year since 1980, and predicts that solar could contribute 20% of total electricity
consumption by 2030, whereas the International Energy Agency predicts 16% by
2050.[55]
Real-world energy production costs depend a great deal on local weather conditions.
In a cloudy country such as the United Kingdom, the cost per produced kWh is
higher than in sunnier countries like Spain.
Short term normalized cost comparisons demonstrating value of various electric generation technologies [56]
Long term normalized cost comparisons demonstrating value of various electric generation technologies [57]
Pole mounts, which are driven directly into the ground or embedded in
concrete.
Foundation mounts, such as concrete slabs or poured footings
Ballasted footing mounts, such as concrete or steel bases that use weight to
secure the solar module system in position and do not require ground
penetration. This type of mounting system is well suited for sites where
excavation is not possible such as capped landfills and simplifies
decommissioning or relocation of solar module systems.
Roof-mounted solar power systems consist of solar modules held in place by racks
or frames attached to roof-based mounting supports. [61] Roof-based mounting
supports include:
Rail mounts, which are attached directly to the roof structure and may use
additional rails for attaching the module racking or frames.
Ballasted footing mounts, such as concrete or steel bases that use weight to
secure the panel system in position and do not require through penetration. This
mounting method allows for decommissioning or relocation of solar panel
systems with no adverse effect on the roof structure.
All wiring connecting adjacent solar modules to the energy harvesting
equipment must be installed according to local electrical codes and should be run
in a conduit appropriate for the climate conditions
Solar trackers increase the energy produced per module at the cost of mechanical
complexity and increased need for maintenance. They sense the direction of the Sun
and tilt or rotate the modules as needed for maximum exposure to the light. [62]
[63]
Alternatively, fixed racks hold modules stationary throughout the day at a given tilt
(zenith angle) and facing a given direction (azimuth angle). Tilt angles equivalent to
an installation's latitude are common. Some systems may also adjust the tilt angle
based on the time of year.[64] Similarly, to maximize total energy output, modules are
often oriented to face south (in the Northern Hemisphere) or north (in the Southern
Hemisphere). On the other hand, east- and west-facing arrays (covering an east–
west facing roof, for example) may also be useful. Even though such installations
might not produce the maximum possible total energy, their power output would
likely be more consistent throughout the day and possibly larger during peak
demand.[65]
Standards[edit]
Standards generally used in photovoltaic modules: